CN103689060A - Chinese herbal medicine preservative - Google Patents
Chinese herbal medicine preservative Download PDFInfo
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- CN103689060A CN103689060A CN201310641075.3A CN201310641075A CN103689060A CN 103689060 A CN103689060 A CN 103689060A CN 201310641075 A CN201310641075 A CN 201310641075A CN 103689060 A CN103689060 A CN 103689060A
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Abstract
The invention discloses a Chinese herbal medicine preservative which consists of mixed extracting liquor of Chinese herbal medicines, propolis extracting liquor and pure water, wherein the mixed extracting liquor of the natural herbal medicines is prepared from one or more of the following Chinese herbal medicines: medlar, galangal, garlic, black pepper, fennel, clove, jasmine and rheum officinale. The Chinese herbal medicine preservative disclosed by the invention adopts pure natural plant type Chinese herbal medicine food materials as materials, realizes freshness-keeping for meat food or meat products by virtue of active ingredients contained in the materials for naturally sterilizing and disinfecting, and restraining microorganisms, can keep color, aroma and taste, and texture form of the meat food or meat product, and is long in freshness-keeping time and free from toxic and side effects; the preserved and cooked meat further has light natural aroma of the Chinese herbal medicines, is unique in aroma, and has nutrition healthcare value; and the preservative is simple in preparation method, pure natural, environment-friendly, free from toxic and side effects on a human body and environment, rich in material resource, low in price and capable of being industrially produced.
Description
Technical field
The present invention relates to a kind of antistaling agent, specifically a kind of Chinese herbal medicine antistaling agent, belongs to technical field of traditional Chinese medicines.
Background technology
The fresh-keeping conventional method of meat and meat products is generally had to refrigeration and high-temperature sterilization, refrigeration can keep color, smell and taste and the structural state of goods, but be inconvenient to carry, must there is the assurance of cold chain, cost is higher, high-temperature sterilization can room temperature preservation, is easy to carry, but has destroyed local flavor and the structural state of goods.
Existing meat cold storing and fresh-keeping is in strict accordance with quarantine system, to require the animal trunk of butchering to carry out rapidly cooling processing, to make its temperature be reduced to 0 to 4 ℃, to be made into cooling meat, to be convenient to following process, circulation and retail.Cooling meat is owing to having passed through natural maturity process, juice delicate flavour U.S., delicate mouthfeel so taste, its security, trophism are all better than traditional chilled meat, although most of at low temperatures bacteriums have not bred, but low temperature resistant bacterium or quite a lot of, the temperature adopting due to meat springhouse can not thoroughly suppress microbial growth breeding and other relevant generation changing, so its freshness date is shorter, cannot meet the requirement of market circulation.Therefore, people's demand, by meat antistaling agent, to the cold Preservation Treatment of carrying out of meat, to extend meat freshness, obtains longer fresh keeping time.
Natural or chemical preservative common are Nisin, lysozyme, natamycin, kojic acid, shitosan, trehalose, Tea Polyphenols, organic acid etc., in recent years, the impact of the food-safety problem being occurred repeatedly, people pay close attention to pollution-free food, healthy food, therefore, use crude antistaling agent to carry out the favor that fresh-keeping meat has obtained people.
Compare with current a large amount of chemical synthesis antistaling agents that use, Chinese herbal medicine antistaling agent has natural bactericidal action, and to human body and environment, without harm, safety coefficient is high.The essential oil containing in Chinese herbal medicine has broad-spectrum sterilization and suppresses the effect of microorganism, the essential oil extracting in pungent perfumery material such as garlic, pepper, nutmeg, fennel, also have the materials such as hydroxy compounds, terpene, bacterium, mould or the yeast such as staphylococcus aureus, salmonella typhimurium, dust Xi Shi Escherichia coli, vibrio parahaemolytious, Aspergillus flavus are had to significant inhibitory action; Aldehydes matter in Chinese herbal medicine, is also the main active of food antiseptic, has broad-spectrum antiseptic ability.
Fresh-keeping aspect at meat, patent CN101180981 B discloses a kind of preservation method of low temperature birds meat products, what its antistaling agent that is used for dipping meat adopted is composite preservative, composition in its formula mainly contains CMC, dehydro sodium acetate, nisin, niacinamide, disodium ethylene diamine tetraacetate and pure water, though these compositions are recognized spendable additive by food-processing industry, but part is still chemicals, has potential harm; Utilize Chinese herbal medicine fresh-keeping, for example, patent CN 1180713C discloses a kind of thickening-antistaling agent for meat food, and this antistaling agent main component is three kinds of varigrained sand sagebrush (Artemisia filifolia) powder and flax green pepper powder; Patent CN101427705 B discloses preparation and the operation technique of the middle employing antistaling agent of a kind of vegetables.
But at present, Chinese herbal medicine antistaling agent fails to obtain large-scale commercial application, main cause may be because the medicinal herb components adopting in part antistaling agent is complicated, active constituent content and the mechanism of action are wherein not very clear, the stability of medicine source, content and preparation itself is difficult for solving, also there is special smell in some Chinese herbal medicine, differ and by masses, accepted surely when heavy dose is used; Secondly, in Chinese herbal medicine, for the extraction of the active ingredient of antistaling agent, also do not possess industrialized condition with producing in enormous quantities.
There is abundant natural Chinese medicinal herb plant resources in China, researches and develops a kind ofly to take that Chinese herbal medicine is main component, green, crude antistaling agent and have good development prospect.
Summary of the invention
The object of the invention is for the deficiencies in the prior art, a kind of crude antistaling agent that is raw material by natural Chinese medicinal herb is provided, for meat product or meat products fresh-keeping have can keep the color, smell and taste of meat product or meat products and structural state, fresh keeping time long, have no side effect, through the fresh-keeping meat boiling again, the light natural fragrance also with Chinese herbal medicine, unique flavor, has healthy nutritive value, this antistaling agent preparation method is simple, can carry out suitability for industrialized production.
For addressing the above problem, the technical solution adopted in the present invention is: a kind of crude antistaling agent, mixed extract, propolis extract and pure water by natural Chinese medicinal herb form, each component forms quality proportioning: the mixed extract of natural Chinese medicinal herb accounts for the 10-35% of antistaling agent quality, propolis extract accounts for the 3-8% of antistaling agent quality, and pure water is surplus; The mixed extract of described natural Chinese medicinal herb is that one or more in following Chinese herbal medicine prepare: matrimony vine, galangal, garlic, pepper, fennel, cloves, cape jasmine, rheum officinale.
The extract of described Chinese herbal medicine is to using pure water or ethanol as extracting solvent, adopt conventional extracting method, the extract of one or more in the following Chinese herbal medicine of preparation is mixed to get respectively: matrimony vine, galangal, garlic, pepper, fennel, cloves, cape jasmine, rheum officinale.
In the extract of described Chinese herbal medicine, the mass fraction that the concentration of raw material accounts for extract in it is as follows: matrimony vine 1-20%, galangal 0.5-30%, garlic 0.5-30%, pepper 0.5-30%, fennel 3-30%, cloves 3-30%, cape jasmine 1-20%, rheum officinale 2-28%.
Described propolis extract is to using ethanol as extracting solvent, adopts conventional extracting method to prepare.
Described propolis extract concentration is 0.5%-5%.
The preparation method of Chinese herbal medicine antistaling agent of the present invention, is characterized in that: comprise the steps:
(1) preparation of natural Chinese medicinal herb mixed extract: take in following Chinese herbal medicine that one or more are raw material, adopt conventional extracting method, prepare respectively extract: matrimony vine, galangal, garlic, pepper, fennel, cloves, cape jasmine, rheum officinale, the mass fraction that the concentration of extract accounts for extract in it is as follows: matrimony vine 1-20%, galangal 0.5-30%, garlic 0.5-30%, pepper 0.5-30%, fennel 3-30%, cloves 3-30%, cape jasmine 1-20%, rheum officinale 2-28%, then respectively extract is concentrated into concentration for the 0.05-0.1 of its mother liquor doubly, then the extract after concentrating is respectively mixed, obtain mixed extract,
(2) preparation of propolis extract: take ethanol as extracting solvent, adopt conventional method, the propolis extract of preparation concentration 0.5%-5%;
(3) the natural Chinese medicinal herb mixed extract that accounts for antistaling agent quality 10-35% is mixed with the propolis extract of antistaling agent quality 3-8%, stir, then add pure water to 100%, stir, can make.
Chinese herbal medicine antistaling agent of the present invention is applicable to the fresh-keeping of food, is especially suitable for the fresh-keeping processing to meat product or meat products.
In the present invention, when preparing garlic extract, first fresh garlic section is soaked to 12-16h in cold water, then extract, for product of the present invention, there is better effect.When preparing galangal, gardenia extract, first galangal or cape jasmine are soaked in to 0.5-3h in cold water, then extract, for product of the present invention, there is better effect.
The effect of Chinese herbal medicine antistaling agent main component of the present invention or the effect playing are as follows:
(1) matrimony vine, refers to the fruit of Chinese wolfberry, has " medicine-food two-purpose ", there is nourishing the liver, nourshing kidney, the effect of moistening lung, wherein contained LBP-X have Promote immunity, anti-ageing, antitumor, remove free radical, antifatigue, radioresistance, protect the liver, the effect such as reproductive function protection and improvement;
(2) galangal: be the dry rhizome of zingiberaceous plant Alpinia officinarum Hance, galangal extract all has antibacterial action in various degree to bacillus anthracis, alpha-Hemolytic streptococcus, beta hemolytic streptococcus, corynebacterium diphtheriae, bacillus pseudodiphthericus, Diplococcus pneumopniae, staphylococcus aureus, Staphylococcus citreus, staphylococcus albus, hay bacillus etc.;
(3) garlic: contain galic essential oil in garlic, main component in oil is allicin, allicin is that garlic amino acid contained in fresh garlic produces through large allinase double decomposition, comprising garlic rhzomorph and Allicin, allicin Mycophyta is suppressed and killing action as anthrax-bacilus, vertical withered bacterium, rhizopus etc. have; The antibacterial principle of allicin is: the oxygen atom in allicin molecule can combine with the sulfydryl that bacterial growth is bred in required cysteine molecule, thereby has suppressed the growth and breeding of bacterium, makes garlic have broad-spectrum antibacterial action;
(4) pepper, fennel, cloves: in pungent perfumery material, contain multiple types chromocor compound, and some aldehyde radicals, ketone group, hydroxyl, ether isoreactivity group and some heterocyclic compounds, these compositions, scavenger as active oxygen or free radical, have obvious fat anti-oxidation effect, the natural component in pungent perfumery material suppresses or sterilization by the mode that the effect of microbial cell film, inhibitory enzyme are lived; In cloves, contain clove oil, there is broad-spectrum sterilization, suppress growth of microorganism effect;
(7) cape jasmine: cape jasmine has inhibitory action, agent to have the effect of killing Leptospira and imago of blood fluke to staphylococcus aureus, diplococcus meningitidis, micrococcus catarrhalis etc., and infusion has inhibitory action to various skin fungi in vitro.
(8) rheum officinale: wherein contain Rhein, archen, aloe-emodin, there is resisting pathogenic microbes effect: responsive bacterium has staphylococcus, hemolytic streptococcus, micrococcus gonococcus, corynebacterium diphtheriae, typhoid bacillus, shigella dysenteriae etc.; Responsive virus has influenza virus, orphan virus, hepatitis B, poliovirus etc.; Other sensitive microbials have Amoeba, Trichomonas vaginalis, blood fluke and Leptospira etc.; Antibacterial mechanism: the enzyme system that affects folic acid; Anti-bacteria nucleic acid and protein are synthetic; Anti-bacteria biological oxidation enzyme system; Inducement interferon.
(9) propolis: propolis is that honeybee gathers resin from the positions such as tree bud bark of long-lived glue source plant, mixed with glandular secretion things such as honeybee lingual gland, wax glands again, through honeybee a kind of colloid substance that metabolism is synthesized repeatedly, the flavone compounds such as the rutin in propolis, Quercetin, Galangin, caffeic acid, a-catechin have very strong antioxidation; Flavonoids in propolis have can be antibacterial, anti-oxidant etc. effect.
The present invention with respect to the beneficial effect of prior art is: the plant type herbal raw material that adopts pure natural, by natural disinfection contained in Chinese herbal medicine, the active ingredient of sterilizing and inhibition microorganism, realization is fresh-keeping to meat product or meat products, color, smell and taste and the structural state that can keep meat product or meat products, fresh keeping time is long, have no side effect, through the fresh-keeping meat boiling again, the light natural fragrance also with Chinese herbal medicine, unique flavor, there is healthy nutritive value, this antistaling agent preparation method is simple, pure natural, environmental protection, human body and environment are had no side effect, entering human body also easily decomposes, raw material sources are abundant, price is low, can carry out suitability for industrialized production.
The specific embodiment
Below by embodiment, the present invention is described in further details, these embodiment are only used for illustrating the present invention, do not limit the scope of the invention.
embodiment 1adopt following steps to prepare Chinese herbal medicine antistaling agent of the present invention:
(1) preparation of natural Chinese medicinal herb mixed extract: adopt conventional extracting method, take ethanol as extracting solvent, prepare respectively the galangal extract of concentration 0.5-30% and the garlic extract of concentration 0.5-30%, be concentrated into respectively 0.05 times that concentration is its mother liquor, then the extract after concentrating is respectively mixed, obtain mixed extract;
(2) preparation of propolis extract: take ethanol as extracting solvent, prepare propolis extract, diluted concentration to 0.5%;
(3) the natural Chinese medicinal herb mixed extract that accounts for antistaling agent quality 35% is mixed with the propolis extract of antistaling agent quality 8%, stir, then add pure water to 100%, stir, can make.
embodiment 2adopt following steps to prepare Chinese herbal medicine antistaling agent of the present invention:
(1) preparation of natural Chinese medicinal herb mixed extract: adopt conventional extracting method, take ethanol as extracting solvent, preparation respectively:
The pepper extract of the medlar extract liquid of concentration 1-20%, concentration 0.5-30%, concentration are 3-30% cloves extract, are concentrated into respectively 0.1 times that concentration is its mother liquor, then the extract after concentrating are respectively mixed, and obtain mixed extract;
(2) preparation of propolis extract: take ethanol as extracting solvent, prepare propolis extract, diluted concentration to 2.5%;
(3) the natural Chinese medicinal herb mixed extract that accounts for antistaling agent quality 22% is mixed with the propolis extract of antistaling agent quality 6%, stir, then add pure water to 100%, stir, can make.
embodiment 3adopt following steps to prepare Chinese herbal medicine antistaling agent of the present invention:
(1) preparation of natural Chinese medicinal herb mixed extract: adopt conventional extracting method, take pure water as extracting solvent, preparation respectively:
The Radix Et Rhizoma Rhei extract that the fennel extract of concentration 3-30%, the gardenia extract of concentration 1-20%, concentration are 2-28%, is concentrated into respectively 0.1 times that concentration is its mother liquor, then the extract after concentrating is respectively mixed, and obtains mixed extract;
(2) preparation of propolis extract: take ethanol as extracting solvent, prepare propolis extract, diluted concentration to 5%;
(3) the natural Chinese medicinal herb mixed extract that accounts for antistaling agent quality 10% is mixed with the propolis extract of antistaling agent quality 3%, stir, then add pure water to 100%, stir, can make.
embodiment 4adopt following steps to prepare Chinese herbal medicine antistaling agent of the present invention:
(1) preparation of natural Chinese medicinal herb mixed extract: adopt conventional extracting method, take pure water as extracting solvent, the garlic extract of preparation concentration 0.5-30% and the galangal extract of concentration 0.5-30%, be concentrated into 0.1 times that concentration is its mother liquor, then the extract after concentrating is respectively mixed, obtain mixed extract;
(2) preparation of propolis extract: take ethanol as extracting solvent, the propolis extract of preparation concentration 4%;
(3) the natural Chinese medicinal herb mixed extract that accounts for antistaling agent quality 18% is mixed with the propolis extract of antistaling agent quality 5%, stir, then add pure water to 100%, stir, can make.
Claims (7)
1. a Chinese herbal medicine antistaling agent, it is characterized in that: mixed extract, propolis extract and pure water by natural Chinese medicinal herb form, each component forms quality proportioning: the mixed extract of natural Chinese medicinal herb accounts for the 10-35% of antistaling agent quality, propolis extract accounts for the 3-8% of antistaling agent quality, and pure water is surplus; The mixed extract of described natural Chinese medicinal herb is that one or more in following Chinese herbal medicine prepare: matrimony vine, galangal, garlic, pepper, fennel, cloves, cape jasmine, rheum officinale.
2. Chinese herbal medicine antistaling agent according to claim 1, it is characterized in that: the extract of described Chinese herbal medicine is to using pure water or ethanol as extracting solvent, adopt conventional extracting method, the extract of one or more in the following Chinese herbal medicine of preparation is mixed to get respectively: matrimony vine, galangal, garlic, pepper, fennel, cloves, cape jasmine, rheum officinale.
3. Chinese herbal medicine antistaling agent according to claim 1 and 2, it is characterized in that: in the extract of described Chinese herbal medicine, the mass fraction that the concentration of raw material accounts for extract in it is as follows: matrimony vine 1-20%, galangal 0.5-30%, garlic 0.5-30%, pepper 0.5-30%, fennel 3-30%, cloves 3-30%, cape jasmine 1-20%, rheum officinale 2-28%.
4. Chinese herbal medicine antistaling agent according to claim 1, is characterized in that: described propolis extract is to using ethanol as extracting solvent, adopts conventional extracting method to prepare.
5. according to the Chinese herbal medicine antistaling agent described in claim 1 or 4, it is characterized in that: described propolis extract concentration is 0.5%-5%.
6. according to the Chinese herbal medicine antistaling agent described in any one in claim 1 to 5, it is characterized in that: the application of described Chinese herbal medicine antistaling agent in meat or meat products fresh-keeping.
7. a preparation method for Chinese herbal medicine antistaling agent as claimed in claim 1, is characterized in that: comprise the steps:
(1) preparation of natural Chinese medicinal herb mixed extract: take in following Chinese herbal medicine that one or more are raw material, adopt conventional extracting method, prepare respectively extract: matrimony vine, galangal, garlic, pepper, fennel, cloves, cape jasmine, rheum officinale, the mass fraction that the concentration of extract accounts for extract in it is as follows: matrimony vine 1-20%, galangal 0.5-30%, garlic 0.5-30%, pepper 0.5-30%, fennel 3-30%, cloves 3-30%, cape jasmine 1-20%, rheum officinale 2-28%, then respectively extract is concentrated into concentration for the 0.05-0.1 of its mother liquor doubly, then the extract after concentrating is respectively mixed, obtain mixed extract,
(2) preparation of propolis extract: take ethanol as extracting solvent, adopt conventional method, the propolis extract of preparation concentration 0.5%-5%;
(3) the natural Chinese medicinal herb mixed extract that accounts for antistaling agent quality 10-35% is mixed with the propolis extract of antistaling agent quality 3-8%, stir, then add pure water to 100%, stir, can make.
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| CN201310641075.3A CN103689060A (en) | 2013-12-04 | 2013-12-04 | Chinese herbal medicine preservative |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104186644A (en) * | 2014-09-04 | 2014-12-10 | 佛山市新战略知识产权文化有限公司 | Chinese herbal medicine preservative |
| CN104397153A (en) * | 2014-11-24 | 2015-03-11 | 柳州市天姿园艺有限公司 | Special antistaling agent for summer squashes |
| CN104920599A (en) * | 2015-06-24 | 2015-09-23 | 南京大地冷冻食品有限公司 | Ginger juice and goji berry coating preservation liquid |
| CN104982502A (en) * | 2015-06-24 | 2015-10-21 | 南京大地冷冻食品有限公司 | Application of ginger juice and wolfberry coating preservation liquid in preservation of fruits, vegetables and chilled meat |
| CN104982504A (en) * | 2015-06-24 | 2015-10-21 | 南京大地冷冻食品有限公司 | Method for preparing ginger juice and wolfberry coating preservation liquid |
| CN105613709A (en) * | 2016-04-05 | 2016-06-01 | 连云港恒图农牧开发有限公司 | Pork fresh-keeping agent with excellent fresh-keeping performance and preparation method thereof |
| CN105660819A (en) * | 2016-01-22 | 2016-06-15 | 黄庆辉 | Chinese herb preservative and preservation method for frozen beef |
| CN106035609A (en) * | 2016-08-06 | 2016-10-26 | 尹浩 | Biogenic composite pork preservative |
| CN106212634A (en) * | 2016-08-06 | 2016-12-14 | 灏规旦 | A kind of cold fresh pork natural antiseptic agent and preparation method thereof |
| CN106359567A (en) * | 2016-08-29 | 2017-02-01 | 王开 | Fresh keeping agent containing essential oil, for fruits, and application |
| CN107047755A (en) * | 2017-05-05 | 2017-08-18 | 集美大学 | A kind of Compositional type biological antiseptic preservative preserved for taro and preparation method thereof |
| CN107079976A (en) * | 2017-06-09 | 2017-08-22 | 太仓苏浏水产有限公司 | A kind of biological aquatic product fresh keeping agent |
| CN107087670A (en) * | 2017-06-09 | 2017-08-25 | 太仓苏浏水产有限公司 | A kind of bio-preservative |
| CN107258874A (en) * | 2017-06-09 | 2017-10-20 | 太仓苏浏水产有限公司 | A kind of compound fishes and shrimps antistaling agent |
| CN107318946A (en) * | 2017-06-09 | 2017-11-07 | 太仓苏浏水产有限公司 | A kind of fresh-keeping composition of aquatic product bio |
| CN107410443A (en) * | 2017-06-09 | 2017-12-01 | 太仓苏浏水产有限公司 | A kind of aquatic products composite safe antistaling agent |
| CN110973443A (en) * | 2019-12-23 | 2020-04-10 | 宜兴市天石饲料有限公司 | Propionic acid and sodium propionate type Chinese herbal medicine mildew preventive and preparation method thereof |
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- 2013-12-04 CN CN201310641075.3A patent/CN103689060A/en not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104186644A (en) * | 2014-09-04 | 2014-12-10 | 佛山市新战略知识产权文化有限公司 | Chinese herbal medicine preservative |
| CN104397153A (en) * | 2014-11-24 | 2015-03-11 | 柳州市天姿园艺有限公司 | Special antistaling agent for summer squashes |
| CN104920599A (en) * | 2015-06-24 | 2015-09-23 | 南京大地冷冻食品有限公司 | Ginger juice and goji berry coating preservation liquid |
| CN104982502A (en) * | 2015-06-24 | 2015-10-21 | 南京大地冷冻食品有限公司 | Application of ginger juice and wolfberry coating preservation liquid in preservation of fruits, vegetables and chilled meat |
| CN104982504A (en) * | 2015-06-24 | 2015-10-21 | 南京大地冷冻食品有限公司 | Method for preparing ginger juice and wolfberry coating preservation liquid |
| CN105660819A (en) * | 2016-01-22 | 2016-06-15 | 黄庆辉 | Chinese herb preservative and preservation method for frozen beef |
| CN105613709A (en) * | 2016-04-05 | 2016-06-01 | 连云港恒图农牧开发有限公司 | Pork fresh-keeping agent with excellent fresh-keeping performance and preparation method thereof |
| CN106212634A (en) * | 2016-08-06 | 2016-12-14 | 灏规旦 | A kind of cold fresh pork natural antiseptic agent and preparation method thereof |
| CN106035609A (en) * | 2016-08-06 | 2016-10-26 | 尹浩 | Biogenic composite pork preservative |
| CN106359567A (en) * | 2016-08-29 | 2017-02-01 | 王开 | Fresh keeping agent containing essential oil, for fruits, and application |
| CN107047755A (en) * | 2017-05-05 | 2017-08-18 | 集美大学 | A kind of Compositional type biological antiseptic preservative preserved for taro and preparation method thereof |
| CN107079976A (en) * | 2017-06-09 | 2017-08-22 | 太仓苏浏水产有限公司 | A kind of biological aquatic product fresh keeping agent |
| CN107087670A (en) * | 2017-06-09 | 2017-08-25 | 太仓苏浏水产有限公司 | A kind of bio-preservative |
| CN107258874A (en) * | 2017-06-09 | 2017-10-20 | 太仓苏浏水产有限公司 | A kind of compound fishes and shrimps antistaling agent |
| CN107318946A (en) * | 2017-06-09 | 2017-11-07 | 太仓苏浏水产有限公司 | A kind of fresh-keeping composition of aquatic product bio |
| CN107410443A (en) * | 2017-06-09 | 2017-12-01 | 太仓苏浏水产有限公司 | A kind of aquatic products composite safe antistaling agent |
| CN110973443A (en) * | 2019-12-23 | 2020-04-10 | 宜兴市天石饲料有限公司 | Propionic acid and sodium propionate type Chinese herbal medicine mildew preventive and preparation method thereof |
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Application publication date: 20140402 |