CN103666328A - Rubber adhesive - Google Patents
Rubber adhesive Download PDFInfo
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- CN103666328A CN103666328A CN201310620265.7A CN201310620265A CN103666328A CN 103666328 A CN103666328 A CN 103666328A CN 201310620265 A CN201310620265 A CN 201310620265A CN 103666328 A CN103666328 A CN 103666328A
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- based adhesives
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- aging agent
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Abstract
The invention belongs to the rubber field, and particularly relates to a rubber adhesive. The rubber adhesive comprises the components in parts by weight as follows: 20-120 parts of chloroprene rubber, 30-90 parts of nitrile rubber, 20-60 parts of polyurethane rubber, 20-60 parts of polyacrylate rubber, 2-10 parts of nano-zinc oxide, 1-4 parts of pottery clay, 15-50 parts of carbon black N100, 2-12 parts of coumarone resin, 4-15 parts of diatomaceous earth, 2-10 parts of sulphur, 1-5 parts of an anti-aging agent, 1-8 parts of p-tert butyl phenol formaldehyde resin, 1-6 parts of engine oil, 1-3 parts of magnesium oxide, 1-5 parts of white carbon black, 1-5 parts of an anti-scorching agent, 1-4 parts of dibutyl phthalate, 1-4 parts of zinc diethyl dithiocarbamate, 1-4 parts of 2-imidazolidinethione and 1-10 parts of diphenylguanidine. The rubber adhesive has the benefits as follows: the rubber adhesive produced by adopting the formula is good in flexibility, has the characteristics of excellent creeping resistance, bending resistance, impact shock resistance and the like, and can be suitable for glued joint between materials with different coefficients of linear expansion as well as dynamically used parts or products.
Description
Technical field
The invention belongs to rubber materials, be specifically related to a kind of rubber based adhesives.
background technology
Rubber based adhesives is the tackiness agent forming with the configuration of rubber taste base-material, and nearly all natural rubber and synthetic rubber may be used to configure tackiness agent, according to the composition of rubber base-material, can be divided into natural rubber adhesive and the large class of synthetic rubber tackiness agent two.The kind that synthetic rubber tackiness agent is conventional has chloroprene rubber, paracril, styrene-butadiene rubber(SBR), silicon rubber etc., and wherein neoprene adhesive is the kind that in synthetic rubber tackiness agent, output is maximum, purposes is the widest.Rubber is a kind of elastomerics, not only has at normal temperatures significant snappiness, and can very in large-temperature range, have this character, and deformability can reach several times.Utilize the tackiness agent of this character preparation of rubber, snappiness is good, there is the excellent characteristics such as resistance to creep, resistance to deflection and shock-resistant vibrations, be applicable between different linear expansivity materials and the parts that dynamically use or the splicing of goods, should be very extensive in industrial production.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of snappiness good, the rubber based adhesives of resistance to creep, resistance to deflection, shock-resistant vibrations.
Rubber based adhesives of the present invention comprises the component of following portions by weight:
Chloroprene rubber 20-120 paracril 30-90
Urethanes 20-60 acrylic elastomer 20-60
Nano zine oxide 2-10 potter's clay 1-4
Carbon black N100 15-50 coumarone indene resin 2-12
Diatomite 4-15 sulphur 2-10
Anti-aging agent 1-5 tertiary butyl phenol formaldehyde resin 1-8
Machine oil 1-6 magnesium oxide 1-3
White carbon black 1-5 scorch retarder 1-5
Dibutyl phthalate 1-4 zinc diethyldithiocarbamate 1-4
2-thiol group tetrahydroglyoxaline 1-4 vulkacit D 1-10.
Preferably, rubber based adhesives of the present invention comprises the component of following portions by weight:
Chloroprene rubber 20-110 paracril 30-80
Urethanes 20-50 acrylic elastomer 20-50
Nano zine oxide 2-8 potter's clay 1-3
Carbon black N100 15-40 coumarone indene resin 2-10
Diatomite 4-13 sulphur 2-9
Anti-aging agent 1-5 tertiary butyl phenol formaldehyde resin 1-7
Machine oil 1-5 magnesium oxide 1-3
White carbon black 1-5 scorch retarder 1-4
Dibutyl phthalate 1-4 zinc diethyldithiocarbamate 1-4
2-thiol group tetrahydroglyoxaline 1-4 vulkacit D 1-8.
Preferred, rubber based adhesives of the present invention comprises the component of following portions by weight:
Chloroprene rubber 90 paracrils 60
Urethanes 40 acrylic elastomers 30
Nano zine oxide 6 potter's clay 2
Carbon black N100 25 coumarone indene resins 6
Diatomite 10 sulphur 6
Anti-aging agent 3 tertiary butyl phenol formaldehyde resins 4
Machine oil 3 magnesium oxide 2
White carbon black 2 scorch retarder 2
Dibutyl phthalate 2 zinc diethyldithiocarbamates 2
2-thiol group tetrahydroglyoxaline 2 vulkacit D 6.
Above-mentioned anti-aging agent is N-phenyl-2 naphthylamines, 2,2,4-trimethylammonium 1, at least one in 2-dihydro quinoline polymer, diaryl secondary amine antioxidant, Ursol D class.
Above-mentioned anti-aging agent is at least one of N-phenyl-α-aniline, N-phenyl-N '-sec.-propyl-Ursol D, N-N '-phenylbenzene-Ursol D, antioxidant 4020.
Above-mentioned anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and both ratios of weight and number are 1-3:1.
Above-mentioned anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and both ratios of weight and number are 2:1.
Rubber is a kind of elastomerics, not only has at normal temperatures significant snappiness, and can very in large-temperature range, have this character, and deformability can reach several times.
The tackiness agent that utilizes this character preparation of rubber, snappiness is good, has the excellent characteristics such as resistance to creep, resistance to deflection and shock-resistant vibrations, is applicable between different linear expansivity materials and the parts that dynamically use or the splicing of goods.
The main component of the neoprene adhesive of employing of the present invention is chloroprene rubber, is the polymkeric substance of chloroprene, and its structure is more regular, on molecule, there is again the chlorine atom that polarity is larger, therefore crystallinity is strong, at room temperature just there are good bonding property and force of cohesion, the very suitable tackiness agent of doing.
Its feature is as follows:
There is the high polarity that is only second to nitrile rubber adhesive, therefore good to the bonding property of polar material;
At normal temperature, do not vulcanize and there is higher cohesive strength and adhesion strength yet;
The performance with good resistance to combustion, resistance to ozone, oil resistant, resistance to solvent and chemical reagent.
Glue-line good springiness, resistance to impact shock and the stripping strength of glueing joint body are good;
Tack is good, only needs contact pressure just can well glued joint, and is particularly suitable for the special surperficial sticker of some shapes;
Coating processes performance is good, easy to use.
Beneficial effect of the present invention is, the rubber based adhesives that adopts formula of the present invention to produce, snappiness is good, has the excellent characteristics such as resistance to creep, resistance to deflection and shock-resistant vibrations, can be applicable between different linear expansivity materials and the parts that dynamically use or the splicing of goods.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
Chloroprene rubber 90 paracrils 60
Urethanes 40 acrylic elastomers 30
Nano zine oxide 6 potter's clay 2
Carbon black N100 25 coumarone indene resins 6
Diatomite 10 sulphur 6
Anti-aging agent 3 tertiary butyl phenol formaldehyde resins 4
Machine oil 3 magnesium oxide 2
White carbon black 2 scorch retarder 2
Dibutyl phthalate 2 zinc diethyldithiocarbamates 2
2-thiol group tetrahydroglyoxaline 2 vulkacit D 6.
Embodiment 2
Chloroprene rubber 20 paracrils 30
Urethanes 20 acrylic elastomers 20
Nano zine oxide 2 potter's clay 1-4
Carbon black N100 15 coumarone indene resins 2
Diatomite 4 sulphur 2
Anti-aging agent 1 tertiary butyl phenol formaldehyde resin 1
Machine oil 1 magnesium oxide 1
White carbon black 1 scorch retarder 1
Dibutyl phthalate 1 zinc diethyldithiocarbamate 1
2-thiol group tetrahydroglyoxaline 1 vulkacit D 1.
Embodiment 3
Chloroprene rubber 120 paracrils 90
Urethanes 60 acrylic elastomers 60
Nano zine oxide 10 potter's clay 4
Carbon black N100 50 coumarone indene resins 12
Diatomite 15 sulphur 10
Anti-aging agent 5 tertiary butyl phenol formaldehyde resins 8
Machine oil 6 magnesium oxide 3
White carbon black 5 scorch retarder 5
Dibutyl phthalate 4 zinc diethyldithiocarbamates 4
2-thiol group tetrahydroglyoxaline 4 vulkacit D 10.
Embodiment 4
Chloroprene rubber 60 paracrils 60
Urethanes 30 acrylic elastomers 30
Nano zine oxide 4 potter's clay 2
Carbon black N100 20 coumarone indene resins 4
Diatomite 6 sulphur 6
Anti-aging agent 2 tertiary butyl phenol formaldehyde resins 3
Machine oil 2 magnesium oxide 2
White carbon black 2 scorch retarder 2
Dibutyl phthalate 2 zinc diethyldithiocarbamates 2
2-thiol group tetrahydroglyoxaline 2 vulkacit D 3.
Embodiment 5
Chloroprene rubber 80 paracrils 70
Urethanes 20-60 acrylic elastomer 40
Nano zine oxide 2-10 potter's clay 3
Carbon black N100 15-50 coumarone indene resin 9
Diatomite 4-15 sulphur 8
Anti-aging agent 1-5 tertiary butyl phenol formaldehyde resin 6
Machine oil 1-6 magnesium oxide 2
White carbon black 1-5 scorch retarder 3
Dibutyl phthalate 1-4 zinc diethyldithiocarbamate 2
2-thiol group tetrahydroglyoxaline 1-4 vulkacit D 1-10.
Claims (7)
1. a rubber based adhesives, is characterized in that, described rubber based adhesives comprises the component of following portions by weight:
Chloroprene rubber 20-120 paracril 30-90
Urethanes 20-60 acrylic elastomer 20-60
Nano zine oxide 2-10 potter's clay 1-4
Carbon black N100 15-50 coumarone indene resin 2-12
Diatomite 4-15 sulphur 2-10
Anti-aging agent 1-5 tertiary butyl phenol formaldehyde resin 1-8
Machine oil 1-6 magnesium oxide 1-3
White carbon black 1-5 scorch retarder 1-5
Dibutyl phthalate 1-4 zinc diethyldithiocarbamate 1-4
2-thiol group tetrahydroglyoxaline 1-4 vulkacit D 1-10.
2. a kind of rubber based adhesives as claimed in claim 1, is characterized in that, described rubber based adhesives comprises the component of following portions by weight:
Chloroprene rubber 20-110 paracril 30-80
Urethanes 20-50 acrylic elastomer 20-50
Nano zine oxide 2-8 potter's clay 1-3
Carbon black N100 15-40 coumarone indene resin 2-10
Diatomite 4-13 sulphur 2-9
Anti-aging agent 1-5 tertiary butyl phenol formaldehyde resin 1-7
Machine oil 1-5 magnesium oxide 1-3
White carbon black 1-5 scorch retarder 1-4
Dibutyl phthalate 1-4 zinc diethyldithiocarbamate 1-4
2-thiol group tetrahydroglyoxaline 1-4 vulkacit D 1-8.
3. a kind of rubber based adhesives as claimed in claim 1, is characterized in that, described rubber based adhesives comprises the component of following portions by weight:
Chloroprene rubber 90 paracrils 60
Urethanes 40 acrylic elastomers 30
Nano zine oxide 6 potter's clay 2
Carbon black N100 25 coumarone indene resins 6
Diatomite 10 sulphur 6
Anti-aging agent 3 tertiary butyl phenol formaldehyde resins 4
Machine oil 3 magnesium oxide 2
White carbon black 2 scorch retarder 2
Dibutyl phthalate 2 zinc diethyldithiocarbamates 2
2-thiol group tetrahydroglyoxaline 2 vulkacit D 6.
4. a kind of rubber based adhesives as claimed in claim 1, is characterized in that, described anti-aging agent is N-phenyl-2 naphthylamines, 2,2,4-trimethylammonium 1, at least one in 2-dihydro quinoline polymer, diaryl secondary amine antioxidant, Ursol D class.
5. a kind of rubber based adhesives as claimed in claim 3, is characterized in that, described anti-aging agent is at least one of N-phenyl-α-aniline, N-phenyl-N '-sec.-propyl-Ursol D, N-N '-phenylbenzene-Ursol D, antioxidant 4020.
6. a kind of rubber based adhesives as claimed in claim 3, is characterized in that, described anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and both ratios of weight and number are 1-3:1.
7. a kind of rubber based adhesives as claimed in claim 6, is characterized in that, described anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and both ratios of weight and number are 2:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620265.7A CN103666328A (en) | 2013-11-29 | 2013-11-29 | Rubber adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620265.7A CN103666328A (en) | 2013-11-29 | 2013-11-29 | Rubber adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666328A true CN103666328A (en) | 2014-03-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310620265.7A Pending CN103666328A (en) | 2013-11-29 | 2013-11-29 | Rubber adhesive |
Country Status (1)
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109500A (en) * | 2014-07-08 | 2014-10-22 | 安徽京鸿密封件技术有限公司 | Adhesive and manufacturing method thereof |
| CN104371593A (en) * | 2014-10-30 | 2015-02-25 | 田琳琳 | High-viscosity rubber adhesive |
| CN104403581A (en) * | 2014-11-04 | 2015-03-11 | 张桂华 | Quick dry rubber glue adhesion agent |
| CN104479589A (en) * | 2014-10-30 | 2015-04-01 | 田琳琳 | Corrugated paper board adhesive |
| CN105385307A (en) * | 2015-12-30 | 2016-03-09 | 王丽萍 | High-performance weather-resistant sealant for building |
| CN105400456A (en) * | 2015-12-30 | 2016-03-16 | 王丽萍 | Durable sealant for bathrooms |
| CN106118546A (en) * | 2016-07-27 | 2016-11-16 | 马爱芬 | A kind of high temperature bonding binding agent of engineering footwear and its preparation method and application |
| CN107987741A (en) * | 2017-12-28 | 2018-05-04 | 湖北航聚科技有限公司 | A kind of rubber based adhesives |
| CN109749155A (en) * | 2017-11-02 | 2019-05-14 | 丹阳市贝尔特橡塑制品有限公司 | A kind of high tenacity rubber material |
| CN116179114A (en) * | 2023-02-20 | 2023-05-30 | 江苏国立化工科技有限公司 | Composite rubber adhesive with good heat resistance and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310620265.7A patent/CN103666328A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| 张玉龙: "《水性胶黏剂：制备.配方.应用》", 30 June 2012, 化学工业出版社 * |
| 顾继友: "《胶黏剂与涂料》", 30 September 2012, 中国林业出版社 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109500A (en) * | 2014-07-08 | 2014-10-22 | 安徽京鸿密封件技术有限公司 | Adhesive and manufacturing method thereof |
| CN104109500B (en) * | 2014-07-08 | 2015-11-18 | 安徽京鸿密封件技术有限公司 | A kind of tackiness agent and preparation method thereof |
| CN104371593A (en) * | 2014-10-30 | 2015-02-25 | 田琳琳 | High-viscosity rubber adhesive |
| CN104479589A (en) * | 2014-10-30 | 2015-04-01 | 田琳琳 | Corrugated paper board adhesive |
| CN104403581A (en) * | 2014-11-04 | 2015-03-11 | 张桂华 | Quick dry rubber glue adhesion agent |
| CN105400456A (en) * | 2015-12-30 | 2016-03-16 | 王丽萍 | Durable sealant for bathrooms |
| CN105385307A (en) * | 2015-12-30 | 2016-03-09 | 王丽萍 | High-performance weather-resistant sealant for building |
| CN106118546A (en) * | 2016-07-27 | 2016-11-16 | 马爱芬 | A kind of high temperature bonding binding agent of engineering footwear and its preparation method and application |
| CN106118546B (en) * | 2016-07-27 | 2017-11-21 | 东莞爱的合成材料科技有限公司 | A kind of high temperature engineering footwear bonding adhesive and its preparation method and application |
| CN109749155A (en) * | 2017-11-02 | 2019-05-14 | 丹阳市贝尔特橡塑制品有限公司 | A kind of high tenacity rubber material |
| CN107987741A (en) * | 2017-12-28 | 2018-05-04 | 湖北航聚科技有限公司 | A kind of rubber based adhesives |
| CN116179114A (en) * | 2023-02-20 | 2023-05-30 | 江苏国立化工科技有限公司 | Composite rubber adhesive with good heat resistance and preparation method thereof |
| CN116179114B (en) * | 2023-02-20 | 2023-11-17 | 江苏国立化工科技有限公司 | Composite rubber adhesive with good heat resistance and preparation method thereof |
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Application publication date: 20140326 |
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