CN103642363A - Wear-resisting epoxy paint - Google Patents

Wear-resisting epoxy paint Download PDF

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Publication number
CN103642363A
CN103642363A CN201310673609.0A CN201310673609A CN103642363A CN 103642363 A CN103642363 A CN 103642363A CN 201310673609 A CN201310673609 A CN 201310673609A CN 103642363 A CN103642363 A CN 103642363A
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parts
epoxy
wear
resisting
epoxy resin
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CN201310673609.0A
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CN103642363B (en
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Jiangxi Hengda High Tech Co.,Ltd.
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JIANGXI HENGDA ADVANCED TECHNOLOGY Co Ltd
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Abstract

The invention belongs to the technical field of macromolecules, and particularly relates to wear-resisting epoxy resin which can be used for repairing equipment and pipelines. The paint comprises a component A and a component B, and is characterized in that the component A comprises the following raw materials in parts by weight: 20 to 45 parts of mixed epoxy resin, 2 to 8 parts of diluent, 1 to 4 parts of silane coupling agent, 10 to 30 parts of iron-base alloy powder, 10 to 30 parts of aluminum oxide powder, 5 to 20 parts of silicon carbide, 10 to 20 parts of ceramic powder, 1 to 4 parts of glass flakes and 1 to 4 parts of carbon black; the component B comprises the following raw materials in parts by weight: 70 to 80 parts of high-hardness wear-resisting epoxy curing agent and 20 to 30 parts of epoxy promoter. The adhesion force of the wear-resisting epoxy resin on a base material can be improved by adopting the mixed epoxy resin; the wear resistance and the medium resistance of the epoxy paint are improved by adopting p-aminophenol glycidyl amine (ether) trifunctional epoxy resin; the wear resistance of the epoxy resin can be improved by adding the wear-resisting filler such as the iron-base alloy powder and the silicon carbide.

Description

A kind of wear-resisting epoxy coating
Technical field
The invention belongs to technical field of macromolecules, be specifically related to a kind of wear-resisting epoxy coating that can be used for prosthetic appliance, pipeline.
Background technology
Epoxypaint is of many uses, and its shrinking percentage is low, cohesive strength is high, preparation is easy, technique is simple, cured article hardness is high, modification is easier to, and various metals and most of non-metallic material are all had to good sticking power.
Two-phase fluid erosive wear is to cause one of major reason that equipment, Pipeline damage scrap, and the high-abrasive material kind of domestic and international application has alloy material, inorganic materials (as silicon carbide, high alumina ceramic etc.), organic materials (as urethane, nylon, rubber etc.) at present.Alloy material has heat resistant and wear resistant performance, but its density is large, moulding is complicated, cost is high, site operation is difficult; Although inorganic materials has very high wear resistance, along with the increase of its hardness, fragility also increases, and on-the-spot use is easily hit and ruptures, and in machine-shaping process, scrap rate is high, and production energy consumption is high; Organic materials possesses certain wear resistance, lightweight, but its anti-solid particulate scratches ability.And above-mentioned three class materials all do not possess the function of repairing worn parts.
In epoxypaint, add filler not only can reduce costs, also can improve many performances of epoxypaint, as improved sticking power, compressive strength and wear resistance etc.The more employing silica powder of filler, lapis amiridis, talcum powder, light calcium carbonate etc.Existing epoxy group(ing) wear-resistant paint, be generally in epoxypaint, to add the mechanically resistant materials such as the antifriction materials such as graphite, molybdenumdisulphide and oxide compound, iron powder, aluminium powder, the epoxypaint forming is like this not enough to resist abrasive conditions and the environment of very severe.
Summary of the invention
In order to overcome above-mentioned defect, the object of the invention is to provide a kind of wear-resisting epoxy coating that can be used for prosthetic appliance, pipeline.
To achieve these goals, the present invention adopts following technical scheme:
A wear-resisting epoxy coating, this coating comprises that A, B two portions component raw material make, wherein it comprises A part component raw material by weight:
2045 parts of blending epoxies, 28 parts of thinners, 14 parts of silane coupling agents, 1030 parts of fe-based alloy powders, 1030 parts of aluminum oxide powders, 520 parts, silicon carbide, 1020 parts, porcelain powder, 14 parts of glass flakes, 14 parts of carbon blacks;
Wherein it comprises B part component raw material by weight:
7080 parts of high hardness wear-resisting epoxy hardeners, 2030 parts of epoxy promotor;
Described blending epoxy is E-51 epoxy resin and E-44 epoxy resin, and wherein E-51 content of epoxy resin is 4060% of blending epoxy gross weight, and E-44 content of epoxy resin is 4060% of blending epoxy gross weight.
Described high hardness wear-resisting epoxy hardener is modified aromatic amine epoxy curing agent and daiamid epoxy curing agent, wherein modified aromatic amine epoxy curing agent consumption is 5070% of high hardness wear-resisting epoxy hardener gross weight, and daiamid epoxy curing agent consumption is 3050% of high hardness wear-resisting epoxy hardener gross weight.
Described thinner is p-aminophenol glycidyl amine (ether) type trifunctional epoxy resin.
Described curable epoxide promotor is DMP-30 curable epoxide promotor.
Described silane coupling agent is KH-560 coupling agent.
Beneficial effect of the present invention:
The present invention adopts blending epoxy to improve the sticking power to base material; Adopt p-aminophenol glycidyl amine (ether) type trifunctional epoxy resin to improve wear resistance and the resistance to medium of epoxy coating; Add the wear resisting property that the wear resistant fillers such as fe-based alloy powder and silicon carbide improve epoxy coating.
Embodiment
Example 1
The A component of this coating comprises 20 parts of blending epoxies, 8 parts of thinners, 1 part of silane coupling agent, 20 parts of fe-based alloy powders, 20 parts of aluminum oxide powders, 15 parts, silicon carbide, 10 parts, porcelain powder, 4 parts of glass flakes, 1 part of carbon black.
70 parts of B component high hardness wear-resisting epoxy hardeners, 30 parts of epoxy promotor.
Example 2
The A component of this coating comprises 25 parts of blending epoxies, 5 parts of thinners, 3 parts of silane coupling agents, 10 parts of fe-based alloy powders, 10 parts of aluminum oxide powders, 20 parts, silicon carbide, 14 parts, porcelain powder, 2 parts of glass flakes, 2 parts of carbon blacks.
75 parts of B component high hardness wear-resisting epoxy hardeners, 25 parts of epoxy promotor.
Example 3
The A component of this coating comprises 45 parts of blending epoxies, 2 parts of thinners, 4 parts of silane coupling agents, 30 parts of fe-based alloy powders, 30 parts of aluminum oxide powders, 5 parts, silicon carbide, 20 parts, porcelain powder, 1 part of glass flake, 4 parts of carbon blacks.
80 parts of B component high hardness wear-resisting epoxy hardeners, 20 parts of epoxy promotor.
In above embodiment 1 ~ 3
Further can: described blending epoxy is E-51 epoxy resin and E-44 epoxy resin, and wherein E-51 content of epoxy resin is 4060% of blending epoxy gross weight, and E-44 content of epoxy resin is 4060% of blending epoxy gross weight.
Further can: described high hardness wear-resisting epoxy hardener is modified aromatic amine epoxy curing agent and daiamid epoxy curing agent, wherein modified aromatic amine epoxy curing agent consumption is 5070% of high hardness wear-resisting epoxy hardener gross weight, and daiamid epoxy curing agent consumption is 3050% of high hardness wear-resisting epoxy hardener gross weight.
Further can: described thinner is p-aminophenol glycidyl amine (ether) type trifunctional epoxy resin.
Further can: described curable epoxide promotor is DMP-30 curable epoxide promotor;
Further can: the silane coupling agent described in root is KH-560 coupling agent.
With the wear-resisting epoxy coating of embodiment 13, test its performance as shown in the table:
Figure 20131067360901000021
Above-described specific embodiment; object of the present invention, technical scheme and beneficial effect have been carried out to further detailed description; institute is understood that; the foregoing is only specific embodiments of the invention; be not limited to the present invention, within the spirit and principles in the present invention all, any modification of making, be equal to replacement, improvement etc.; within protection scope of the present invention all should be included in, and can not be interpreted as any restriction to it.As solidifying agent, thinner can adopt any suitable solidifying agent, thinner etc.

Claims (6)

1. a wear-resisting epoxy coating, this coating comprises that A, B two portions component raw material make, and it is characterized in that:
Wherein it comprises A part component raw material by weight:
20 45 parts of blending epoxies, 28 parts of thinners, 14 parts of silane coupling agents, 10 30 parts of fe-based alloy powders, 10 30 parts of aluminum oxide powders, 5 20 parts, silicon carbide, 10 20 parts, porcelain powder, 14 parts of glass flakes, 14 parts of carbon blacks;
Wherein it comprises B part component raw material by weight:
70 80 parts of high hardness wear-resisting epoxy hardeners, 20 30 parts of epoxy promotor.
2. wear-resisting epoxy coating according to claim 1, it is characterized in that: described blending epoxy is E-51 epoxy resin and E-44 epoxy resin, wherein E-51 content of epoxy resin is that 40 60%, E-44 content of epoxy resin of blending epoxy gross weight are 40 60% of blending epoxy gross weight.
3. wear-resisting epoxy coating according to claim 1, it is characterized in that: described high hardness wear-resisting epoxy hardener is modified aromatic amine epoxy curing agent and daiamid epoxy curing agent, wherein modified aromatic amine epoxy curing agent consumption is 50 70% of high hardness wear-resisting epoxy hardener gross weight, and daiamid epoxy curing agent consumption is 30 50% of high hardness wear-resisting epoxy hardener gross weight.
4. wear-resisting epoxy coating according to claim 1, is characterized in that: described thinner is p-aminophenol glycidyl amine (ether) type trifunctional epoxy resin.
5. wear-resisting epoxy coating according to claim 1, is characterized in that: described curable epoxide promotor is DMP-30 curable epoxide promotor.
6. wear-resisting epoxy coating according to claim 1, is characterized in that: described silane coupling agent is KH-560 coupling agent.
CN201310673609.0A 2013-12-12 2013-12-12 A kind of wear-resisting epoxy coating Active CN103642363B (en)

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Cited By (7)

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Publication number Priority date Publication date Assignee Title
CN104004435A (en) * 2014-05-27 2014-08-27 江苏欣安新材料技术有限公司 High-temperature (800 DEG C) wear-resistant paint and preparation method thereof
CN105315841A (en) * 2015-09-25 2016-02-10 洛阳暖盈电子技术有限公司 Wear-resistant ceramic paint
CN106084655A (en) * 2016-06-14 2016-11-09 东莞市联洲知识产权运营管理有限公司 A kind of environmentally friendly polymer matrix composites of high-strength wearable and preparation method thereof
CN108795233A (en) * 2018-06-04 2018-11-13 北京碧海舟腐蚀防护工业股份有限公司 Wear-resisting epoxy coating, wear-resistant coating and its application
CN110396346A (en) * 2019-06-12 2019-11-01 蓝海利 A kind of bi-component epoxy anticorrosive paint
CN115678381A (en) * 2022-09-30 2023-02-03 安徽信息工程学院 Chromium-free paint for steel and preparation method thereof
CN116426197A (en) * 2023-05-06 2023-07-14 安徽众博新材料有限公司 Wear-resistant epoxy paint and preparation process thereof

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CN102220068A (en) * 2011-06-08 2011-10-19 北京天山新材料技术股份有限公司 Epoxy resin wear-resisting adhesive coating and preparation method thereof
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104004435A (en) * 2014-05-27 2014-08-27 江苏欣安新材料技术有限公司 High-temperature (800 DEG C) wear-resistant paint and preparation method thereof
CN104004435B (en) * 2014-05-27 2016-03-02 江苏欣安新材料技术有限公司 High temperature abrasion material under a kind of 800 degree of high temperature and preparation method thereof
CN105315841A (en) * 2015-09-25 2016-02-10 洛阳暖盈电子技术有限公司 Wear-resistant ceramic paint
CN106084655A (en) * 2016-06-14 2016-11-09 东莞市联洲知识产权运营管理有限公司 A kind of environmentally friendly polymer matrix composites of high-strength wearable and preparation method thereof
CN106084655B (en) * 2016-06-14 2018-07-10 东莞市博铨橡塑有限公司 A kind of environmentally friendly polymer matrix composites of high-strength wearable and preparation method thereof
CN108795233A (en) * 2018-06-04 2018-11-13 北京碧海舟腐蚀防护工业股份有限公司 Wear-resisting epoxy coating, wear-resistant coating and its application
CN110396346A (en) * 2019-06-12 2019-11-01 蓝海利 A kind of bi-component epoxy anticorrosive paint
CN115678381A (en) * 2022-09-30 2023-02-03 安徽信息工程学院 Chromium-free paint for steel and preparation method thereof
CN116426197A (en) * 2023-05-06 2023-07-14 安徽众博新材料有限公司 Wear-resistant epoxy paint and preparation process thereof
CN116426197B (en) * 2023-05-06 2024-06-11 安徽众博新材料有限公司 Wear-resistant epoxy paint and preparation process thereof

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Effective date of registration: 20180615

Address after: 330096 Hengda administrative building second, Jinlu North Road, Nanchang high tech Industrial Development Zone, Jiangxi, China, second

Patentee after: Jiangxi Hengda Engineering Technology Co., Ltd.

Address before: 330096 Jinlu North Road, Nanchang hi tech Zone, Jiangxi Province, No. 88

Patentee before: Jiangxi Hengda Advanced Technology Co., Ltd.

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Address after: 330096 Hengda administrative building second, Jinlu North Road, Nanchang high tech Industrial Development Zone, Jiangxi, China, second

Patentee after: Jiangxi Hengda High Tech Co.,Ltd.

Address before: 330096 Hengda administrative building second, Jinlu North Road, Nanchang high tech Industrial Development Zone, Jiangxi, China, second

Patentee before: JIANGXI HENGDA ENGINEERING TECHNOLOGY Co.,Ltd.