CN103642330B - A kind of cable frie retardant coating - Google Patents

A kind of cable frie retardant coating Download PDF

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Publication number
CN103642330B
CN103642330B CN201310564872.6A CN201310564872A CN103642330B CN 103642330 B CN103642330 B CN 103642330B CN 201310564872 A CN201310564872 A CN 201310564872A CN 103642330 B CN103642330 B CN 103642330B
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China
Prior art keywords
parts
cable
retardant coating
frie retardant
photostabilizer
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Expired - Fee Related
Application number
CN201310564872.6A
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Chinese (zh)
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CN103642330A (en
Inventor
石小强
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Shanghai Shi Fan Le Jianxin Materials Co ltd
Original Assignee
JIANGSU BOSIYUAN FIREPROOF MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201310564872.6A priority Critical patent/CN103642330B/en
Publication of CN103642330A publication Critical patent/CN103642330A/en
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Publication of CN103642330B publication Critical patent/CN103642330B/en
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Abstract

A kind of cable frie retardant coating, its composition with mass fraction representation is: polyvinyl chloride (PVC) RESINS 100 parts; Aluminium sesquioxide 5-10 part; Antimonous oxide 2-8 part; Trimeric cyanamide 6-10 part; Sodium disilicate 15-20 part; Titanium dioxide 2-5 part; Calcium carbonate 15-25 part; Decabromodiphenyl oxide is 20-25 part; Tetrabromo-bisphenol is 4-6 part; Photostabilizer 1-3 part; DOP25-30 part; Urea 3-8 part; Dimethylbenzene 12-20 part; Product oxygen index 28-30; Surface drying 2h, does solid work 20-24h; With low cost, fire line is good, and toxicity is little; Film is not afraid of and is exposed to the sun and rain, wear-resisting acid and alkali-resistance can the widespread production not division of history into periods for current material.

Description

A kind of cable frie retardant coating
Technical field
The application belongs to fire-retardant material field, particularly relates to a kind of cable frie retardant coating.
Background technology
The development of China's cable fire-refractory coating product starts from late 1970s and the beginning of the eighties; it grows up in conjunction with oneself requirement on finishing fire retardant paint basis; its physicochemical property and weather resistance better; coating is thinner; meet the spongy foam thermofin that fire can generate even compact; there is significant heat-insulating, fire-preventing effect, thus the object reaching protection cable, stop propagation of flame, prevent the generation of fire and development.A kind of staple product that cable fire-refractory coating is protected as cable fire-proof, by the application over nearly 20 years, play a positive role to the loss of minimizing cable fire, protection people property safety, its application is also from lack of standardization to specification.But due to the develop rapidly of modern society, the environment that cable uses, the variation of mode of laying, from cable fire-refractory coating applicable cases for many years, existing aqueous fire-proof coating also some performance need improves and improves, and could meet the requirement of cable environment for use.Service condition is preferably solvent-borne type frie retardant coating, but because this kind of coating itself is inflammable, the disaster hidden-trouble used is also quite large, in addition solvent has injury in various degree to human body, therefore particularly should strengthen safety prevention measure when the narrow space such as cable shaft, cable trench, cable tunnel or the place that not easily ventilates use.Consider from the angle of environmental protection, should make great efforts to develop physicochemical property and the excellent aqueous fire-proof coating of weather resistance from now on.
Affecting the fire-proof and thermal-insulation function of cable fire-refractory coating is selecting of fire retardant greatly, and fire retardant is another hinge component of cable fire-refractory coating.Need with reference to pertinent data at home and abroad, in conjunction with resource situation through the country, the research of individual event Functional Experiment is carried out to the fire-retardant data that preliminary election is share.By thermogravimetric and differential thermal analysis, determine pyrolytic and the flame retardant resistance of raw material, frie retardant coating is classified by basis, then observes synergy by Experiment of Compatibility, determines selected fire-retardant data like this via analysis and experiment.The fire retardant selected must cooperatively interact with other components in cable fire-refractory coating, cable fire-refractory coating is made to have above-mentioned excellent physics and chemistry function, and at the thermofin by expanded foamed formation firm compact during fire, along with the development of social city, technicalization, hommization, design a kind of oxygen index high, fast drying and the little cable frie retardant coating of toxicity, to meet the need of market, are very important.
Summary of the invention
the technical problem solved:
The technical problems such as the application is low for existing frie retardant coating oxygen index, and slowly dry and toxicity is large, provide a kind of cable frie retardant coating.
technical scheme:
A kind of cable frie retardant coating, is made up of following raw materials according, with mass fraction representation is: polyvinyl chloride (PVC) RESINS 100 parts; Aluminium sesquioxide 5-10 part; Antimonous oxide 2-8 part; Trimeric cyanamide 6-10 part; Sodium disilicate 15-20 part; Titanium dioxide 2-5 part; Calcium carbonate 15-25 part; Decabromodiphenyl oxide is 20-25 part; Tetrabromo-bisphenol is 4-6 part; Photostabilizer 1-3 part; DOP25-30 part; Urea 3-8 part; Dimethylbenzene 12-20 part.
As a preferred technical solution of the present invention: described cable frie retardant coating, its moiety, with mass fraction representation is: polyvinyl chloride (PVC) RESINS 100 parts; Aluminium sesquioxide 7.5 parts; Antimonous oxide 5 parts; Trimeric cyanamide 8 parts; Sodium disilicate 18 parts; Titanium dioxide 4 parts; 20 parts, calcium carbonate; Decabromodiphenyl oxide is 22 parts; Tetrabromo-bisphenol is 5 parts; Photostabilizer 2 parts; DOP28 part; 6 parts, urea; Dimethylbenzene 16 parts.
As a preferred technical solution of the present invention: described photostabilizer adopts photostabilizer UV-9.
beneficial effect:
A kind of cable frie retardant coating of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product oxygen index 28-30; 2, surface drying 2h, does solid work 20-24h; 3, with low cost, fire line is good, and toxicity is little; 4, film is not afraid of and is exposed to the sun and rain, wear-resisting acid and alkali-resistance can the widespread production not division of history into periods for current material.
Embodiment
embodiment 1:
A kind of cable frie retardant coating, its composition with mass fraction representation is: polyvinyl chloride (PVC) RESINS 100 parts; Aluminium sesquioxide 5 parts; Antimonous oxide 2 parts; Trimeric cyanamide 6 parts; Sodium disilicate 15 parts; Titanium dioxide 2 parts; 15 parts, calcium carbonate; Decabromodiphenyl oxide is 20 parts; Tetrabromo-bisphenol is 4 parts; Photostabilizer UV-9 is 1 part; DOP25 part; 3 parts, urea; Dimethylbenzene 12 parts.
Product oxygen index 28; Surface drying 2h, does solid work 24h, and film is not afraid of and is exposed to the sun and rain.
embodiment 2:
A kind of cable frie retardant coating, its composition with mass fraction representation is: polyvinyl chloride (PVC) RESINS 100 parts; Aluminium sesquioxide 10 parts; Antimonous oxide 8 parts; Trimeric cyanamide 10 parts; Sodium disilicate 20 parts; Titanium dioxide 5 parts; 25 parts, calcium carbonate; Decabromodiphenyl oxide is 25 parts; Tetrabromo-bisphenol is 6 parts; Photostabilizer UV-9 is 3 parts; DOP30 part; 8 parts, urea; Dimethylbenzene 20 parts.
Product oxygen index 29; Surface drying 2h, does solid work 22h, and film is not afraid of and is exposed to the sun and rain.
embodiment 3:
A kind of cable frie retardant coating, is characterized in that: its composition with mass fraction representation is: polyvinyl chloride (PVC) RESINS 100 parts; Aluminium sesquioxide 7.5 parts; Antimonous oxide 5 parts; Trimeric cyanamide 8 parts; Sodium disilicate 18 parts; Titanium dioxide 4 parts; 20 parts, calcium carbonate; Decabromodiphenyl oxide is 22 parts; Tetrabromo-bisphenol is 5 parts; Photostabilizer UV-9 is 2 parts; DOP28 part; 6 parts, urea; Dimethylbenzene 16 parts.
Product oxygen index 30; Surface drying 2h, does solid work 20h, and film is not afraid of and is exposed to the sun and rain.
All components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth content of the present invention, instead of restriction, and any change therefore in the implication suitable with claims of the present invention and scope, all should think to be included in the scope of claims.

Claims (3)

1. a cable frie retardant coating, is characterized in that: its moiety with mass fraction representation is: polyvinyl chloride (PVC) RESINS 100 parts; Aluminium sesquioxide 5-10 part; Antimonous oxide 2-8 part; Trimeric cyanamide 6-10 part; Sodium disilicate 15-20 part; Titanium dioxide 2-5 part; Calcium carbonate 15-25 part; Decabromodiphenyl oxide is 20-25 part; Tetrabromo-bisphenol is 4-6 part; Photostabilizer 1-3 part; DOP25-30 part; Urea 3-8 part; Dimethylbenzene 12-20 part.
2. a kind of cable frie retardant coating according to claim 1, is characterized in that: its moiety with mass fraction representation is: polyvinyl chloride (PVC) RESINS 100 parts; Aluminium sesquioxide 7.5 parts; Antimonous oxide 5 parts; Trimeric cyanamide 8 parts; Sodium disilicate 18 parts; Titanium dioxide 4 parts; 20 parts, calcium carbonate; Decabromodiphenyl oxide is 22 parts; Tetrabromo-bisphenol is 5 parts; Photostabilizer 2 parts; DOP28 part; 6 parts, urea; Dimethylbenzene 16 parts.
3. a kind of cable frie retardant coating according to claim 1 and 2, is characterized in that: described photostabilizer adopts photostabilizer UV-9.
CN201310564872.6A 2013-11-14 2013-11-14 A kind of cable frie retardant coating Expired - Fee Related CN103642330B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310564872.6A CN103642330B (en) 2013-11-14 2013-11-14 A kind of cable frie retardant coating

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Application Number Priority Date Filing Date Title
CN201310564872.6A CN103642330B (en) 2013-11-14 2013-11-14 A kind of cable frie retardant coating

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CN103642330A CN103642330A (en) 2014-03-19
CN103642330B true CN103642330B (en) 2016-02-10

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194633B (en) * 2014-08-27 2016-08-24 苏州诚晟信息技术有限公司 A kind of uvioresistant fireproof coating and preparation method thereof
CN105206341A (en) * 2015-08-19 2015-12-30 国网山东省电力公司临沂供电公司 Power transmission cable suitable for city underground power transmission line
CN105047277B (en) * 2015-08-20 2017-10-27 国网山东省电力公司临沂供电公司 Water resistant tree low-voltage insulating cable
CN105244078A (en) * 2015-09-28 2016-01-13 安徽环宇电缆集团有限公司 Aluminum alloy conductor power cable
CN107353721A (en) * 2017-08-23 2017-11-17 安徽意力电缆有限公司 A kind of cable fire-refractory coating
CN107556830A (en) * 2017-10-17 2018-01-09 刘勇 A kind of cable fireproof coating

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1092091A (en) * 1993-03-06 1994-09-14 韩永海 Fire retardant insulating coating
CN1146472A (en) * 1995-09-27 1997-04-02 山东省烟台市人造革厂 Flame retardant paint for plastic flooring
CN1152012A (en) * 1995-12-15 1997-06-18 中国人民解放军海军后勤技术装备研究所 Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint
CN103059437A (en) * 2011-10-20 2013-04-24 常熟市筑紫机械有限公司 Flame retardant polyvinyl chloride wire and cable material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1092091A (en) * 1993-03-06 1994-09-14 韩永海 Fire retardant insulating coating
CN1146472A (en) * 1995-09-27 1997-04-02 山东省烟台市人造革厂 Flame retardant paint for plastic flooring
CN1152012A (en) * 1995-12-15 1997-06-18 中国人民解放军海军后勤技术装备研究所 Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint
CN103059437A (en) * 2011-10-20 2013-04-24 常熟市筑紫机械有限公司 Flame retardant polyvinyl chloride wire and cable material

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Effective date of registration: 20180719

Address after: 201507 A6218 room 2, 80 Tiangong Road, Jinshan Industrial Zone, Shanghai.

Patentee after: Shanghai Shi fan Le Jianxin Materials Co.,Ltd.

Address before: 226300 Wujia Town Industrial Park, Tongzhou District, Nantong City, Jiangsu Province

Patentee before: JIANGSU BOSSYUAN FIREPROOF MATERIAL TECHNOLOGY Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160210

Termination date: 20211114