CN103627207A - Deep blue disperse dye mixture - Google Patents
Deep blue disperse dye mixture Download PDFInfo
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- CN103627207A CN103627207A CN201310582345.8A CN201310582345A CN103627207A CN 103627207 A CN103627207 A CN 103627207A CN 201310582345 A CN201310582345 A CN 201310582345A CN 103627207 A CN103627207 A CN 103627207A
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Abstract
The invention relates to the field of dyes and in particular relates to a deep blue disperse dye mixture. The deep blue disperse dye mixture comprises one or more dye components A as shown in a formula (A) and one or more dye components B as shown in a formula (B) as well as the balance of aids, wherein the mass percentage of the components A is 1%-90%, the mass percentage of the components B is 1%-60%, and X1 and X2 are independent H, Cl or Br respectively. The disperse dye mixture subjected to commercialization can be supplied for dyeing in the form of a liquid state or a cream state after micro-granulation or a powder state or a granule state after drying by using a spray-drying process and the like. When a hydrophobic fiber material is dyed on the disperse dye mixture, various dyeing performance and fastness are excellent; a deep blue dyed fabric can be obtained through adjusting the ratio of different components.
Description
Technical field
The present invention relates to dye field, be specifically related to mazarine admixture of disperse dyes.
Background technology
Enter after 21 century, the competition in world textile market is more and more fierce, and the economy in South East Asia has become the synonym of low cost, high growth, and the textile industry business in Europe, the U.S. etc. is also accelerated to shift to Asia.In order to adapt to the situation of piece market cut-throat competition, the production cost of textiles is constantly reduced, quality product improves constantly, carrying capacity of environment constantly alleviates, and has become the common target of textile enterprise.
Dispersed dye solubleness in water is very low, and particle is very thin, is dispersion in dye liquor, belongs to nonionic dye, is mainly used in the dyeing of terylene, and its dyefastness is higher.But; dispersed dye exist the incompatible part of some and environment and ecological protection; mainly that part dispersed dye can reduction decomposition produce carcinogenic aromatic amine; some products are irritative dyes, and many products exist AOX problem and because the thermophoresis in dyeing and printing process process moves the fastness reduction that causes etc.
Summary of the invention
For overcoming the above problems, the invention provides and be applied to hydrophobic fiber material dyeing, and the mazarine admixture of disperse dyes of every dyeing behavior and colour fastness excellence.
Mazarine admixture of disperse dyes, comprise the dye component B shown in the dye component A shown in one or more formulas (A) and one or more formulas (B), surplus is auxiliary agent, and the mass percent of described component A is 1-90%, and the quality percentage composition of described B component is 1-60%
Wherein, X1, X2 are independent is respectively H, Cl or Br.
Further, described component A is formula (A-1) to one of compound shown in formula (A-3) or the mixture of two or more compound wherein
Further, described B component is compound shown in formula (B-1) or formula (B-2), or the mixture of compound shown in formula (B-1) and formula (B-2)
Further, described auxiliary agent is one or more of dispersion agent, diffusant and tensio-active agent.
Further, described auxiliary agent is a kind of of naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound and sulfonated lignin or any several mixture.
Further, described auxiliary agent is NNO, MF, a kind of or any several mixture of Reax85A.
Further, the quality sum of described dye component A and B and the mass ratio of auxiliary agent are 1:0.3-5.
Further, the quality sum of described dye component A and B and the mass ratio of auxiliary agent are 1:2.
Further, the mass ratio of described dye component A and B is 3:2.
Admixture of disperse dyes of the present invention, during as commodity selling or use, generally include dyestuff composition and auxiliary agent two portions, its compound method can be carried out in a known manner, for example, after each dye monomer being mixed by said ratio, under the existence of auxiliary agent, water or other wetting agents, with sand mill, clarifixator etc., carry out corpusculed, also can, by each dye monomer respectively under the existence of auxiliary agent, water or other wetting agents, with sand mill, clarifixator etc., carry out with above-mentioned ratio, mixing after corpusculed processing.
Described auxiliary agent conventional dispersion agent, diffusant and tensio-active agent etc. while being dispersed dye commercialization, preferably one of following or its several mixture arbitrarily: the anionic dispersing agents such as naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin.Concrete as NNO, MF, Reax85A etc.
According to the admixture of disperse dyes of making of the present invention, can adopt common dip method, pad dyeing method to dye.Wherein, common dip method, as dacron fabric is carried out to pre-treatment, is put into dye vat and is contaminated, and dyes completely, and cold water cleans to neutral, and strand is dry, then carries out reduction clearing, dries.
Admixture of disperse dyes of the present invention, after commercialization is processed, the liquid state after can corpusculed, emulsifiable paste state or with spray-drying process etc. carry out dried powdery, graininess is supplied with dyeing.While dying hydrophobic fiber material on admixture of disperse dyes of the present invention, every dyeing behavior and fastness are excellent; By adjusting ratio between different components, can obtain mazarine dyeing and weaving thing.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but protection content of the present invention is not limited only to these embodiment.
In the following example, method therefor if no special instructions, is ordinary method.Needed material or reagent in following examples, be if no special instructions market and buy.
Embodiment 1
By the component of 30 grams of formula A-1, the component of 12 grams of formula B-2,25 grams of MF, 25 grams of Reax85A, 120 grams of water, stir, and sand milling disperses and is dried, and has both obtained finished product, and this dyestuff can offer the good mazarine of fabric properties.
Embodiment 2
By the component of 36 grams of formula A-1, the component of 12 grams of formula A-2, the component of 16 grams of formula B-1,15 grams of NNO, 15 grams of Reax85A, 120 grams of water, stir, and sand milling disperses and is dried, and has both obtained finished product, and this dyestuff can offer the good mazarine of fabric properties.
The concrete steps of embodiment 3-16 are as embodiment 1, and concrete proportioning is as shown in table 1:
Table 1
Embodiment 17: the material of getting 0.5 gram of embodiment 1-16, be dispersed in 500ml water, draw 20ml, with 18ml water, mix, with acetic acid, adjust pH=5, add 2 grams of trevira cloth dyeings, by the speed of 3 degree/seconds, be warming up to 60 degree, by the speed of 1.5 degree/seconds, rise to 130 degree again, be incubated 45 minutes, be cooled to 70 degree and start sampling, observe cloth specimen coloured light, press GB/T3921, GB/T3920, GB/T3922, GB/T8427, GB/T5718 tests respectively the performances such as its washing fastness, fastness to rubbing, sublimation fastness, and the specific performance of embodiment 1-16 is in Table 2.
Table 2
More than can find out, the cloth specimen that dye mixture of the present invention dyes, washing fastness, crock fastness and sublimation fastness effect are all fine, and especially, when the quality sum of dye component and the ratio of auxiliary agent are 1:2 (embodiment 10), it is best that washing fastness and sublimation fastness effect reach.When the quality sum of dye component and the ratio of auxiliary agent are 1:2, when the mass ratio of A component and B component is 3:2 (embodiment 11), it is best that crock fastness also can reach.More optimize, in the situation that (A-1) all exists to compound shown in formula (A-3) and formula (B-1) or formula (B-2) (embodiment 12), every fastness of the material of being dyed cloth reaches best.
Claims (9)
1. mazarine admixture of disperse dyes, it is characterized in that: comprise the dye component B shown in the dye component A shown in one or more formulas (A) and one or more formulas (B), surplus is auxiliary agent, and the mass percent of described component A is 1-90%, and the quality percentage composition of described B component is 1-60%
Wherein, X1, X2 are independent is respectively H, Cl or Br.
2. mazarine admixture of disperse dyes according to claim 1, is characterized in that: described component A is formula (A-1) to one of compound shown in formula (A-3) or the mixture of two or more compound wherein
。
4. mazarine admixture of disperse dyes according to claim 1 and 2, is characterized in that: described auxiliary agent is one or more of dispersion agent, diffusant and tensio-active agent.
5. mazarine admixture of disperse dyes according to claim 4, is characterized in that: described auxiliary agent is a kind of of naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound and sulfonated lignin or any several mixture.
6. mazarine admixture of disperse dyes according to claim 5, is characterized in that: described auxiliary agent is NNO, MF, a kind of or any several mixture of Reax 85A.
7. mazarine admixture of disperse dyes according to claim 1 and 2, is characterized in that: the quality sum of described dye component A and B and the mass ratio of auxiliary agent are 1:0.3-5.
8. mazarine admixture of disperse dyes according to claim 7, is characterized in that: the quality sum of described dye component A and B and the mass ratio of auxiliary agent are 1:2.
9. mazarine admixture of disperse dyes according to claim 8, is characterized in that: the mass ratio of described dye component A and B is 3:2.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105694532A (en) * | 2015-12-30 | 2016-06-22 | 绍兴市上虞康汇化工有限公司 | Blue disperse dye composition, blue disperse dye and preparation method and application of blue disperse dye |
CN106349753A (en) * | 2016-08-22 | 2017-01-25 | 九江富达实业有限公司 | Novel disperse dye composition |
CN112048190A (en) * | 2020-09-21 | 2020-12-08 | 浙江龙盛染料化工有限公司 | Disperse blue-to-black dye composition and dye product thereof |
CN112500717A (en) * | 2020-09-21 | 2021-03-16 | 浙江龙盛染料化工有限公司 | Disperse blue dye composition and dye product thereof |
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US4405330A (en) * | 1981-10-28 | 1983-09-20 | Basf Aktiengesellschaft | Navy disperse dye mixtures |
US4960434A (en) * | 1987-07-22 | 1990-10-02 | Imperial Chemical Industries Plc | Azo disperse dye mixture giving bright blue shades on polyester textiles |
CN1696205A (en) * | 2005-05-20 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environment-friendly disperse dye |
CN1844260A (en) * | 2006-04-29 | 2006-10-11 | 浙江闰土股份有限公司 | Mixed black and blue series combined disperse dye |
CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black and blue series environment-friendly disperse dye composition |
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2013
- 2013-11-19 CN CN201310582345.8A patent/CN103627207B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4405330A (en) * | 1981-10-28 | 1983-09-20 | Basf Aktiengesellschaft | Navy disperse dye mixtures |
US4960434A (en) * | 1987-07-22 | 1990-10-02 | Imperial Chemical Industries Plc | Azo disperse dye mixture giving bright blue shades on polyester textiles |
CN1696205A (en) * | 2005-05-20 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environment-friendly disperse dye |
CN1844260A (en) * | 2006-04-29 | 2006-10-11 | 浙江闰土股份有限公司 | Mixed black and blue series combined disperse dye |
CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black and blue series environment-friendly disperse dye composition |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105694532A (en) * | 2015-12-30 | 2016-06-22 | 绍兴市上虞康汇化工有限公司 | Blue disperse dye composition, blue disperse dye and preparation method and application of blue disperse dye |
CN106349753A (en) * | 2016-08-22 | 2017-01-25 | 九江富达实业有限公司 | Novel disperse dye composition |
CN112048190A (en) * | 2020-09-21 | 2020-12-08 | 浙江龙盛染料化工有限公司 | Disperse blue-to-black dye composition and dye product thereof |
CN112500717A (en) * | 2020-09-21 | 2021-03-16 | 浙江龙盛染料化工有限公司 | Disperse blue dye composition and dye product thereof |
CN112048190B (en) * | 2020-09-21 | 2021-10-15 | 浙江龙盛染料化工有限公司 | Disperse blue-to-black dye composition and dye product thereof |
CN112500717B (en) * | 2020-09-21 | 2022-08-05 | 浙江龙盛染料化工有限公司 | Disperse blue dye composition and dye product thereof |
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