CN103601455A - Grouting material with controllable rapid hardening time and preparation method thereof - Google Patents
Grouting material with controllable rapid hardening time and preparation method thereof Download PDFInfo
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- CN103601455A CN103601455A CN201310629602.9A CN201310629602A CN103601455A CN 103601455 A CN103601455 A CN 103601455A CN 201310629602 A CN201310629602 A CN 201310629602A CN 103601455 A CN103601455 A CN 103601455A
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Abstract
A disclosed grouting material with controllable rapid hardening time comprises common 32.5-grade portland cement, 42.5-grade sulphoaluminate cement and ethylene-vinyl acetate copolymer (EVA) emulsion with a weight ratio of 0.5:0.45:0.05, the water cement ratio is 0.6, and ethylene-vinyl acetate copolymer (EVA) emulsion belongs to a gelling foaming material. The grouting material with controllable rapid hardening time has excellent property such as rapid hardening and controllability, makes up the shortages that current single ordinary portland cement grouting materials are slow in strength forming, low in early-stage strength and bad in volume shrinkage, and mainly employs common 32.5-grade cement for proportioning, so that certain cost is saved compared with the current 42.5-grade cement in general use in the industry. Through a large number of tests, correlated material properties are mastered; and by adjusting the ratio of the three main materials, the grouting material provided by the invention is controllable in rapid hardening time such as initial hardening time and final hardening time, and the grouting material is widely applicable to the engineering field of roads, tunnels, emergency dealing and the like.
Description
Technical field
The present invention relates to a kind of controlled injecting paste material of rapid hardening time and preparation method thereof, belong to materials science field.
Background technology
Current grouting cement class description of materials is single, generally adopt 425,525 grades of single ordinary Portland cements, be accompanied by the quickening of current socio-economic development rhythm, day by day require the raising of mortar depositing construction quality, duration to shorten, and such traditional material is first, final setting time is longer, intensity forms slow and getting up early intensity is lower, and there is certain volumetric shrinkage phenomenon in the later stage, can not meet the requirement of grouting process instantly that rapid coagulation, early strength are high, have certain swelling properties.At field of traffic, the speed of construction speed is directly restricting the time that is open to traffic, and Grouting engineering is as an important ring wherein, requires especially slurries to form at short notice intensity, so that workplatform to be provided, is convenient to follow-up work and launches.
Summary of the invention
The invention provides a kind of controlled injecting paste material of rapid hardening time, its object is, for current material, improves, a kind of controlled injecting paste material of rapid hardening time is provided, and this kind of material has rapid coagulation, and early strength is higher, later strength also meets the demands, and has certain expansile feature.
Another object of the present invention is to provide the preparation method of this kind of material.
A kind of controlled injecting paste material of rapid hardening time, this kind of material comprises that mixing ratio by weight is ordinary Portland cement or common 32.5 grades of silicate cements: the mixture of the ethylene-vinyl acetate copolymer emulsion of 42.5 grades of aluminosulfate cement: 99.9wt% (EVA)=0.5:0.45:0.05, the mass ratio of water and this mixture is 0.6(water cement ratio).
Described controlled injecting paste material of rapid hardening time also comprises admixture, admixture is water reducer: hardening accelerator: the composition of the weight percent=50:1:1 of retardant, adds by 0.3~0.5% of the total mass of the ethylene-vinyl acetate copolymer emulsion of ordinary Portland cement or common 32.5 grades of silicate cements, 42.5 grades of aluminosulfate cements and 99.9wt%.
Described water reducer is calcium lignin sulphonate.
Described hardening accelerator is Quilonum Retard.
Described retardant is boric acid.
The preparation method of described a kind of controlled injecting paste material of rapid hardening time:
Proportionally weigh the water of corresponding weight, common 325 grades of silicate cements or ordinary Portland cement, 42.5 grades of aluminosulfate cements, the ethylene-vinyl acetate copolymer emulsion of 99.9wt%, admixture, hardening accelerator, retardant, put into stirrer and be stirred to evenly, make slurries; Made slurries are put into mould with moulding, maintenance.
The invention provides a kind of controlled injecting paste material of rapid hardening time, its slurry degree, initial set and final setting time, 28 days folding strengths, ultimate compression strength character are as described below:
(1) degree of mobilization.For a kind of controlled injecting paste material of rapid hardening time of the present invention, according to GB50119-2003 appendix A, carry out the test of standard flow degree, recording this material degree of mobilization is 26.8cm, the property noted is good.
(2) initial set, final setting time.For a kind of controlled injecting paste material of rapid hardening time of the present invention, according to GB175-2007 general purpose portland cement standard, use standard consistency method to test consumptive use of water normal consistence, initial set final setting time, obtained experimental result sees the following form.
With respect to the Portland cement character of code requirement, can guarantee, under the prerequisite of mortar depositing construction time, to have obtained effective shortening time of coagulation.
(3) resistance to compression, folding strength.For a kind of controlled injecting paste material of rapid hardening time of the present invention, according to GB/T17671-1999, prepare the standard specimen of 40 * 40 * 160mm, maintenance is successively carried out anti-folding, compressive strength test in 28 days afterwards, and obtained experimental result sees the following form.
As seen from the above table, novel material is compared common 32.5 grades of silicate cements and is only starched, and folding strength, ultimate compression strength have all obtained effective lifting.
(4) swelling property.For a kind of controlled injecting paste material of rapid hardening time of the present invention, the volume shrinking when estimating that slurries solidify, use with mould surveyed the volume of slurries and solidify after volume, can for referencely contrast:
Die quality: 6.220kg, quality after moulding: 6.610kg, can extrapolate slurries quality is 390g, slurry volume is 40 * 40 * 160mm
3; After condensing, solid masses is 372.3g, and after condensing, solid volume is 245mL.
As calculated: retraction volume is 245-40 * 40 * 160 * 10
-3=11cm
3,
From above, know: for m=390-372.3=17.7g answers vaporize water, retraction volume is 17.7cm to the quality of the vaporize water that condenses
3;
Hence one can see that test specimen expansion of solids volume v=17.7-11=6.7cm
3
Rate of expansion w=6.7/245 * 100%=2.735%.
From above 4, with respect to current material, material of the present invention has rapid coagulation, and early strength is higher, and later strength also meets the demands, and has certain expansile excellent characteristics.
Embodiment
Below in conjunction with embodiment, be intended to further illustrate the present invention, and unrestricted the present invention.
(1) proportionally weigh the water of corresponding weight, common 325 grades of silicate cements, 42.5 grades of aluminosulfate cements, ethylene-vinyl acetate copolymer (EVA) emulsion, admixture; (ordinary Portland cement or common 32.5 grades of silicate cements: the mixture of the ethylene-vinyl acetate copolymer emulsion of 42.5 grades of aluminosulfate cement: 99.9wt% (EVA)=0.5:0.45:0.05, the mass ratio of water and this mixture is 0.6(water cement ratio).
Admixture is water reducer: hardening accelerator: the composition of the weight percent=50:1:1 of retardant, adds by 0.3~0.5% of the total mass of the ethylene-vinyl acetate copolymer emulsion of ordinary Portland cement or common 32.5 grades of silicate cements, 42.5 grades of aluminosulfate cements and 99.9wt%.
(2) weighed water, common 325 grades of silicate cements, 42.5 grades of aluminosulfate cements, ethylene-vinyl acetate copolymer (EVA) emulsion, admixtures are put into stirrer and are stirred to evenly, make slurries;
(3) made slurries are put into standard size mould with moulding;
(4) mould to be formed and material are put into standard concrete maintaining box and carry out maintenance;
(5) treat that material in model can the demoulding, the material test specimen of moulding is taken out from mould, continue to be positioned over maintenance in standard concrete maintaining box.
The present invention institute is in process of the test:
1, attempted the proportioning of various sulplo-aluminates and normal silicate, at this, take water cement ratio 0.6 as example (in various water cement ratio situations, test-results substantially rule is identical), shown that time of coagulation rule is as following table:
other, along with the increase of aluminosulfate cement content, the first final setting time of mixed cement is too short, cannot be applied in construction, therefore do not proceed test.
2, premenstruum experimental exploration, time of coagulation and later strength that two groups of data of ordinary Portland cement in acquired results: aluminosulfate cement=0.6:0.4,0.5:0.5 embody can be used in Practical Project, and compare current material and embodied fast solidifying feature.Needs in incorporation engineering application for making material have swelling properties, add by a certain percentage EVA emulsion in material, and obtained experimental result sees the following form, attached under rate of expansion method of calculation example.
in conjunction with considering time of coagulation, intensive parameter and rate of expansion, think normal silicate: this kind of proportioning of sulplo-aluminate: EVA=0.5:0.45:0.05 is the most superior in nature.
Swelling property testing experiment:
For a kind of controlled injecting paste material of rapid hardening time of the present invention, the volume shrinking when estimating that slurries solidify, use with mould surveyed the volume of slurries and solidify after volume, can for referencely contrast:
Die quality: 6.220kg, quality after moulding: 6.610kg, can extrapolate slurries quality is 390g, slurry volume is 40 * 40 * 160mm
3; After condensing, solid masses is that 372.3g(weighs), after condensing, solid volume is that 245mL(flooding method measures).
As calculated: retraction volume is 245-40 * 40 * 160 * 10
-3=11cm
3,
From above, know: for m=390-372.3=17.7g answers vaporize water, retraction volume is 17.7cm to the quality of the vaporize water that condenses
3;
Hence one can see that test specimen expansion of solids volume v=17.7-11=6.7cm
3
Rate of expansion w=6.7/245 * 100%=2.735%
This testing data has confirmed the swelling property that material provided by the present invention has.
Claims (6)
1. a controlled injecting paste material of rapid hardening time, it is characterized in that, this kind of material comprises that mixing ratio by weight is ordinary Portland cement or common 32.5 grades of silicate cements: the mixture of ethylene-vinyl acetate copolymer emulsion=0.5:0.45:0.05 of 42.5 grades of aluminosulfate cement: 99.9wt%, the mass ratio of water and this mixture is 0.6.
2. a kind of controlled injecting paste material of rapid hardening time according to claim 1, it is characterized in that, described controlled injecting paste material of rapid hardening time also comprises admixture, admixture is water reducer: hardening accelerator: the composition of the weight percent=50:1:1 of retardant, adds by 0.3~0.5% of the total mass of the ethylene-vinyl acetate copolymer emulsion of ordinary Portland cement or common 32.5 grades of silicate cements, 42.5 grades of aluminosulfate cements and 99.9wt%.
3. a kind of controlled injecting paste material of rapid hardening time according to claim 2, is characterized in that, described water reducer is calcium lignin sulphonate.
4. a kind of controlled injecting paste material of rapid hardening time according to claim 2, is characterized in that, described hardening accelerator is Quilonum Retard.
5. a kind of controlled injecting paste material of rapid hardening time according to claim 2, is characterized in that, described retardant is boric acid.
6. the preparation method of a kind of controlled injecting paste material of rapid hardening time described in claim 1-5 any one, it is characterized in that, proportionally weigh the water of corresponding weight, common 325 grades of silicate cements or ordinary Portland cement, 42.5 grades of aluminosulfate cements, the ethylene-vinyl acetate copolymer emulsion of 99.9wt%, admixture, hardening accelerator, retardant, put into stirrer and be stirred to evenly, make slurries; Made slurries are put into mould with moulding, maintenance.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105481324A (en) * | 2015-12-15 | 2016-04-13 | 嘉华特种水泥股份有限公司 | Inorganic grouting blocking material |
CN106082886A (en) * | 2016-06-14 | 2016-11-09 | 中铁十四局集团第二工程有限公司 | After tunnel wall, cavity is filled and is used foamed cement injecting paste material |
CN108467245A (en) * | 2018-04-11 | 2018-08-31 | 北京市政建设集团有限责任公司 | A kind of anchor cable construction cement and the combined anchor cable grouting serous fluid of sulphate aluminium cement |
CN113831094A (en) * | 2021-10-21 | 2021-12-24 | 界首市宝业瑞祥建筑工业化有限公司 | Preparation method of early-strength quick-hardening cement mortar |
CN114956745A (en) * | 2022-04-29 | 2022-08-30 | 郑州大学 | Quick-setting foaming cement for grouting and preparation method thereof |
CN116768574A (en) * | 2023-06-30 | 2023-09-19 | 北京市政建设集团有限责任公司 | Shield synchronous double-liquid grouting material and preparation method thereof |
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CN101343162A (en) * | 2008-08-25 | 2009-01-14 | 武汉理工大学 | High-ductility polymer-rubber powder-honey-combed cement concrete road covering material and construction process thereof |
CN101508547A (en) * | 2009-04-09 | 2009-08-19 | 中国铁道科学研究院铁道建筑研究所 | Early-strong-fast-hard end capping anchorage mortar material for fragment-free railway plate |
CN103073253A (en) * | 2013-01-24 | 2013-05-01 | 中国铁道科学研究院金属及化学研究所 | Mortar for quickly repairing filling layer of slab ballastless track, and preparation method and use method of mortar |
CN103265249A (en) * | 2013-05-23 | 2013-08-28 | 中国铁道科学研究院金属及化学研究所 | Fast rush-repair mortar for ballastless track filling layer and preparation method and application thereof |
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CN101343162A (en) * | 2008-08-25 | 2009-01-14 | 武汉理工大学 | High-ductility polymer-rubber powder-honey-combed cement concrete road covering material and construction process thereof |
CN101508547A (en) * | 2009-04-09 | 2009-08-19 | 中国铁道科学研究院铁道建筑研究所 | Early-strong-fast-hard end capping anchorage mortar material for fragment-free railway plate |
CN103073253A (en) * | 2013-01-24 | 2013-05-01 | 中国铁道科学研究院金属及化学研究所 | Mortar for quickly repairing filling layer of slab ballastless track, and preparation method and use method of mortar |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105481324A (en) * | 2015-12-15 | 2016-04-13 | 嘉华特种水泥股份有限公司 | Inorganic grouting blocking material |
CN106082886A (en) * | 2016-06-14 | 2016-11-09 | 中铁十四局集团第二工程有限公司 | After tunnel wall, cavity is filled and is used foamed cement injecting paste material |
CN106082886B (en) * | 2016-06-14 | 2018-01-02 | 中铁十四局集团第二工程有限公司 | Foamed cement injecting paste material is used in cavity filling after tunnel wall |
CN108467245A (en) * | 2018-04-11 | 2018-08-31 | 北京市政建设集团有限责任公司 | A kind of anchor cable construction cement and the combined anchor cable grouting serous fluid of sulphate aluminium cement |
CN113831094A (en) * | 2021-10-21 | 2021-12-24 | 界首市宝业瑞祥建筑工业化有限公司 | Preparation method of early-strength quick-hardening cement mortar |
CN114956745A (en) * | 2022-04-29 | 2022-08-30 | 郑州大学 | Quick-setting foaming cement for grouting and preparation method thereof |
CN116768574A (en) * | 2023-06-30 | 2023-09-19 | 北京市政建设集团有限责任公司 | Shield synchronous double-liquid grouting material and preparation method thereof |
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Application publication date: 20140226 |