CN103589042A - 一种抑菌复合塑料薄膜及其制备方法 - Google Patents

一种抑菌复合塑料薄膜及其制备方法 Download PDF

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CN103589042A
CN103589042A CN201310550227.9A CN201310550227A CN103589042A CN 103589042 A CN103589042 A CN 103589042A CN 201310550227 A CN201310550227 A CN 201310550227A CN 103589042 A CN103589042 A CN 103589042A
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王欣南
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Suzhou Xinying Special Material Technologies Co Ltd
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Abstract

本发明涉及一种抑菌复合塑料薄膜及其制备方法,它是由下述重量份数的物质制成:塑料40-60份、抗氧化剂10-15份、聚对苯二甲酸丁二醇酯5-20份、抑菌复合物25-30份,氧化铁5-15份,1,4-丁烯二醇5-10份。本发明燃烧释放烟气少,使用寿命长,较广泛的应用于建筑、室内装潢等领域。

Description

一种抑菌复合塑料薄膜及其制备方法
技术领域
本发明涉及高分子材料技术领域,尤其涉及一种抑菌复合塑料薄膜及其制备方法。
背景技术
随着工业的不断发展,塑料得到越来越广泛的应用。聚乙烯、聚丙烯、PTT聚酯、ABS等等大量使用在节水灌溉、建筑、室内装潢、家具、电力、运输等行业。但是塑料中的碳、氢两种元素含量很高,所以极容易燃烧,因而限制了塑料的使用。一般使用塑料时都需进行阻燃处理。目前阻燃主要以外添加阻燃剂为主。采用外添加阻燃剂方式对材料进行阻燃处理, 其阻燃效率高,技术成熟,价格便宜,但添加的阻燃剂一般卤素含量较高,燃烧时,塑料受热释放出含卤烟气,具有毒性,会危害人体的健康,甚至造成人员死亡;阻燃剂添加量大,对材料本身的后期加工影响较大,且阻燃剂易析出不能长久保持阻燃性,缩短了使用寿命。
发明内容
为了实现本发明的目的,本发明提供一种抑菌复合塑料薄膜,其特征在于:它是由下述重量份数的物质制成:塑料40-60份、抗氧化剂 10-15份、聚对苯二甲酸丁二醇酯5-20份、氧化铁5-15份,1,4-丁烯二醇5-10份、抑菌复合物   20-25份;所述的抑菌复合物的制备方法为:将黄顶菊、飞机草、五爪金龙、胜红蓟、高良姜、大蒜、香芹、水按照20-25:15-20:10-15 :10-15:8-10:8-10: 5-7:10-20的质量份数配比混合,加入(10份的活力单位为100U)的纤维素酶进行酶解,酶解反应温度为30℃,酶解反应时间为1小时,过滤得到中草药液;去渣后再加入浓度为50%~70%的乙醇水溶液,再将固液混合物超声波辅助提取,超声波提取条件:超声温度为45~56℃、超声频率为20~30kHz、超声提取时间为1~2个小时,然后将固液混合物在20~30kPa真空条件下抽滤,取滤液在15~25kPa真空、45~50℃条件下减压蒸馏得抑菌复合物。
抗氧化剂为酚类,包括:单酚、双酚、多酚、对苯二酚、二苯胺、对苯二胺中的一种或几种。
所述塑料为高压低密度聚乙烯、低压高密度聚乙烯、高低压复合聚乙烯、乙烯- 醋酸乙烯共聚物中的一种或几种。
所述改性纳米塑料中还包括氧化锑5-8份。
所述改性纳米塑料中还包括硼酸锌5-8份。
所述的一种抑菌复合塑料薄膜的制备方法,其特征在于:其步骤为:
称重,将各成分按照比例称量好;
搅拌,把上述各成分放入在40-60℃下真空搅拌10-30分钟;
混合,将上述混合好的各成分在双辊开炼机上熔融混合,温度为120-160℃; 
成型,采用塑料吹膜机挤出吹膜,即得产品;
所述的吹膜机料筒后段温度分四段控制,分别控制在180~200℃,料筒前段温度分四段控制,分别控制在210~230℃,机头温度分两段控制,分别控制在220~240℃,吹胀比为1.5~2.0,螺杆转速20~40r/min,牵引速度10~50m/min。
有益效果:本发明采用的组分混合后,能够较好的阻燃,而且受热放出烟气较少,对人体损害小;阻燃剂不易析出,使用寿命长。具有杀菌效果的薄膜材料、绿色环保并且具有抑菌效果;对人、畜无害。另外,本发明配方合理,制备方法简单。
具体实施方式
下面结合具体实施方式对本发明作进一步详细的描述:
实施例1:
   一种抑菌复合塑料薄膜,其特征在于:它是由下述重量份数的物质制成:塑料40 份、抗氧化剂 10 份、聚对苯二甲酸丁二醇酯5 份、氧化铁5 份,1,4-丁烯二醇5 份、抑菌复合物   20 份;所述的抑菌复合物的制备方法为:将黄顶菊、飞机草、五爪金龙、胜红蓟、高良姜、大蒜、香芹、水按照20-25:15-20:10-15 :10-15:8-10:8-10: 5-7:10-20的质量份数配比混合,加入(10份的活力单位为100U)的纤维素酶进行酶解,酶解反应温度为30℃,酶解反应时间为1小时,过滤得到中草药液;去渣后再加入浓度为50%~70%的乙醇水溶液,再将固液混合物超声波辅助提取,超声波提取条件:超声温度为45~56℃、超声频率为20~30kHz、超声提取时间为1~2个小时,然后将固液混合物在20~30kPa真空条件下抽滤,取滤液在15~25kPa真空、45~50℃条件下减压蒸馏得抑菌复合物。
抗氧化剂为酚类,包括:单酚、双酚、多酚、对苯二酚、二苯胺、对苯二胺中的一种或几种。
所述塑料为高压低密度聚乙烯、低压高密度聚乙烯、高低压复合聚乙烯、乙烯- 醋酸乙烯共聚物中的一种或几种。
所述改性纳米塑料中还包括氧化锑5-8份。
所述改性纳米塑料中还包括硼酸锌5-8份。
所述的一种抑菌复合塑料薄膜的制备方法,其特征在于:其步骤为:
称重,将各成分按照比例称量好;
搅拌,把上述各成分放入在40-60℃下真空搅拌10-30分钟;
混合,将上述混合好的各成分在双辊开炼机上熔融混合,温度为120-160℃; 
成型,采用塑料吹膜机挤出吹膜,即得产品;
所述的吹膜机料筒后段温度分四段控制,分别控制在180~200℃,料筒前段温度分四段控制,分别控制在210~230℃,机头温度分两段控制,分别控制在220~240℃,吹胀比为1.5~2.0,螺杆转速20~40r/min,牵引速度10~50m/min。.
实施例2:
   一种抑菌复合塑料薄膜,其特征在于:它是由下述重量份数的物质制成:塑料 60份、抗氧化剂  15份、聚对苯二甲酸丁二醇酯 20份、氧化铁 15份,1,4-丁烯二醇 10份、抑菌复合物  25份;所述的抑菌复合物的制备方法为:将黄顶菊、飞机草、五爪金龙、胜红蓟、高良姜、大蒜、香芹、水按照20-25:15-20:10-15 :10-15:8-10:8-10: 5-7:10-20的质量份数配比混合,加入(10份的活力单位为100U)的纤维素酶进行酶解,酶解反应温度为30℃,酶解反应时间为1小时,过滤得到中草药液;去渣后再加入浓度为50%~70%的乙醇水溶液,再将固液混合物超声波辅助提取,超声波提取条件:超声温度为45~56℃、超声频率为20~30kHz、超声提取时间为1~2个小时,然后将固液混合物在20~30kPa真空条件下抽滤,取滤液在15~25kPa真空、45~50℃条件下减压蒸馏得抑菌复合物。
抗氧化剂为酚类,包括:单酚、双酚、多酚、对苯二酚、二苯胺、对苯二胺中的一种或几种。
所述塑料为高压低密度聚乙烯、低压高密度聚乙烯、高低压复合聚乙烯、乙烯- 醋酸乙烯共聚物中的一种或几种。
所述改性纳米塑料中还包括氧化锑5-8份。
所述改性纳米塑料中还包括硼酸锌5-8份。
所述的一种抑菌复合塑料薄膜的制备方法,其特征在于:其步骤为:
称重,将各成分按照比例称量好;
搅拌,把上述各成分放入在40-60℃下真空搅拌10-30分钟;
混合,将上述混合好的各成分在双辊开炼机上熔融混合,温度为120-160℃; 
成型,采用塑料吹膜机挤出吹膜,即得产品;
所述的吹膜机料筒后段温度分四段控制,分别控制在180~200℃,料筒前段温度分四段控制,分别控制在210~230℃,机头温度分两段控制,分别控制在220~240℃,吹胀比为1.5~2.0,螺杆转速20~40r/min,牵引速度10~50m/min。
具有杀菌效果的薄膜材料、绿色环保并且具有抑菌效果;对人、畜无害。另外,本发明配方合理,制备方法简单。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的只是说明本发明的原理,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (6)

1.一种抑菌复合塑料薄膜,其特征在于:它是由下述重量份数的物质制成:塑料40-60份、抗氧化剂 10-15份、聚对苯二甲酸丁二醇酯5-20份、氧化铁5-15份,1,4-丁烯二醇5-10份、抑菌复合物   20-25份;所述的抑菌复合物的制备方法为:将黄顶菊、飞机草、五爪金龙、胜红蓟、高良姜、大蒜、香芹、水按照20-25:15-20:10-15 :10-15:8-10:8-10: 5-7:10-20的质量份数配比混合,加入(10份的活力单位为100U)的纤维素酶进行酶解,酶解反应温度为30℃,酶解反应时间为1小时,过滤得到中草药液;去渣后再加入浓度为50%~70%的乙醇水溶液,再将固液混合物超声波辅助提取,超声波提取条件:超声温度为45~56℃、超声频率为20~30kHz、超声提取时间为1~2个小时,然后将固液混合物在20~30kPa真空条件下抽滤,取滤液在15~25kPa真空、45~50℃条件下减压蒸馏得抑菌复合物。
2.根据权利要求1所述的改性纳米塑料,其特征在于:抗氧化剂为酚类,包括:单酚、双酚、多酚、对苯二酚、二苯胺、对苯二胺中的一种或几种。
3.根据权利要求3或4所述的改性纳米塑料,其特征在于:所述塑料为高压低密度聚乙烯、低压高密度聚乙烯、高低压复合聚乙烯、乙烯- 醋酸乙烯共聚物中的一种或几种。
4.根据权利要求5所述的改性纳米塑料,其特征在于:所述改性纳米塑料中还包括氧化锑5-8份。
5.根据权利要求5所述的改性纳米塑料,其特征在于:所述改性纳米塑料中还包括硼酸锌5-8份。
6.根据权利要求1所述的一种抑菌复合塑料薄膜的制备方法,其特征在于:其步骤为:
称重,将各成分按照比例称量好;
搅拌,把上述各成分放入在40-60℃下真空搅拌10-30分钟;
混合,将上述混合好的各成分在双辊开炼机上熔融混合,温度为120-160℃; 
成型,采用塑料吹膜机挤出吹膜,即得产品;
所述的吹膜机料筒后段温度分四段控制,分别控制在180~200℃,料筒前段温度分四段控制,分别控制在210~230℃,机头温度分两段控制,分别控制在220~240℃,吹胀比为1.5~2.0,螺杆转速20~40r/min,牵引速度10~50m/min。
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