CN103579610A - Preparation method for lithium ion battery cathode material-lithium nickel manganese oxide - Google Patents
Preparation method for lithium ion battery cathode material-lithium nickel manganese oxide Download PDFInfo
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- CN103579610A CN103579610A CN201310586472.5A CN201310586472A CN103579610A CN 103579610 A CN103579610 A CN 103579610A CN 201310586472 A CN201310586472 A CN 201310586472A CN 103579610 A CN103579610 A CN 103579610A
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- Prior art keywords
- oxalate
- lithium
- nickel
- hydroxide
- manganese oxide
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 title abstract 3
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 46
- 229910052759 nickel Inorganic materials 0.000 claims description 20
- 239000003153 chemical reaction reagent Substances 0.000 claims description 16
- 239000011572 manganese Substances 0.000 claims description 16
- 238000001556 precipitation Methods 0.000 claims description 16
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000010405 anode material Substances 0.000 claims description 12
- 239000012153 distilled water Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 239000000376 reactant Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- RGVLTEMOWXGQOS-UHFFFAOYSA-L manganese(2+);oxalate Chemical compound [Mn+2].[O-]C(=O)C([O-])=O RGVLTEMOWXGQOS-UHFFFAOYSA-L 0.000 claims description 10
- 239000012266 salt solution Substances 0.000 claims description 8
- 238000000137 annealing Methods 0.000 claims description 7
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 claims description 6
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 6
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims description 4
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims description 3
- 229940039790 sodium oxalate Drugs 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical group 0.000 claims description 2
- 238000005245 sintering Methods 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract description 5
- 239000002243 precursor Substances 0.000 abstract description 5
- 229910052744 lithium Inorganic materials 0.000 abstract description 4
- 238000000975 co-precipitation Methods 0.000 abstract description 3
- 239000011261 inert gas Substances 0.000 abstract description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 6
- FRMOHNDAXZZWQI-UHFFFAOYSA-N lithium manganese(2+) nickel(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Ni+2].[Li+] FRMOHNDAXZZWQI-UHFFFAOYSA-N 0.000 abstract 3
- -1 nickel hydroxide compound Chemical class 0.000 abstract 2
- 230000002194 synthesizing effect Effects 0.000 abstract 2
- 239000007790 solid phase Substances 0.000 abstract 1
- 238000007599 discharging Methods 0.000 description 6
- 238000001354 calcination Methods 0.000 description 5
- BDKWOJYFHXPPPT-UHFFFAOYSA-N lithium dioxido(dioxo)manganese nickel(2+) Chemical compound [Mn](=O)(=O)([O-])[O-].[Ni+2].[Li+] BDKWOJYFHXPPPT-UHFFFAOYSA-N 0.000 description 5
- 229940099596 manganese sulfate Drugs 0.000 description 4
- 239000011702 manganese sulphate Substances 0.000 description 4
- 235000007079 manganese sulphate Nutrition 0.000 description 4
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 4
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 4
- 150000003891 oxalate salts Chemical class 0.000 description 3
- 229910052596 spinel Inorganic materials 0.000 description 3
- 239000011029 spinel Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011010 synthetic spinel Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical compound [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
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Priority Applications (1)
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CN201310586472.5A CN103579610B (en) | 2013-11-15 | 2013-11-15 | The preparation method of lithium ion battery anode material nickel LiMn2O4 |
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CN201310586472.5A CN103579610B (en) | 2013-11-15 | 2013-11-15 | The preparation method of lithium ion battery anode material nickel LiMn2O4 |
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CN103579610A true CN103579610A (en) | 2014-02-12 |
CN103579610B CN103579610B (en) | 2016-03-30 |
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CN201310586472.5A Active CN103579610B (en) | 2013-11-15 | 2013-11-15 | The preparation method of lithium ion battery anode material nickel LiMn2O4 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106684350A (en) * | 2016-12-21 | 2017-05-17 | 桑顿新能源科技有限公司 | Preparation method of lithium nickel manganese oxide serving as high-voltage positive electrode material |
CN108288711A (en) * | 2018-02-12 | 2018-07-17 | 成都理工大学 | A kind of quaternary lithium-ion battery positive electrode material and preparation method |
CN109811412A (en) * | 2018-12-28 | 2019-05-28 | 广东邦普循环科技有限公司 | A kind of stratiform nickel lithium manganate cathode material of monocrystalline pattern and preparation method thereof |
CN110137445A (en) * | 2019-03-26 | 2019-08-16 | 广西卓能新能源科技有限公司 | Battery anode slice, lithium ion battery, stratiform nickel ion doped and preparation method thereof |
CN114408987A (en) * | 2022-03-30 | 2022-04-29 | 宜宾锂宝新材料有限公司 | Nickel-cobalt-manganese precursor, ternary cathode material and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101269849A (en) * | 2008-03-05 | 2008-09-24 | 广州融捷材料科技有限公司 | High-density spherical lithium nickel cobalt manganese oxygen and method for preparing the same |
US20090297947A1 (en) * | 2008-05-30 | 2009-12-03 | Haixia Deng | Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries |
CN102034967A (en) * | 2010-11-09 | 2011-04-27 | 中国海洋石油总公司 | Coprecipitation preparation method of nickel manganese lithium oxide of anode material of high-voltage lithium battery |
WO2011114605A1 (en) * | 2010-03-19 | 2011-09-22 | 第一工業製薬株式会社 | Lithium secondary battery using ionic liquid |
CN103107328A (en) * | 2013-01-25 | 2013-05-15 | 湖南桑顿新能源有限公司 | Preparation method of modified spinel type lithium manganate |
-
2013
- 2013-11-15 CN CN201310586472.5A patent/CN103579610B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101269849A (en) * | 2008-03-05 | 2008-09-24 | 广州融捷材料科技有限公司 | High-density spherical lithium nickel cobalt manganese oxygen and method for preparing the same |
US20090297947A1 (en) * | 2008-05-30 | 2009-12-03 | Haixia Deng | Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries |
WO2011114605A1 (en) * | 2010-03-19 | 2011-09-22 | 第一工業製薬株式会社 | Lithium secondary battery using ionic liquid |
CN102034967A (en) * | 2010-11-09 | 2011-04-27 | 中国海洋石油总公司 | Coprecipitation preparation method of nickel manganese lithium oxide of anode material of high-voltage lithium battery |
CN103107328A (en) * | 2013-01-25 | 2013-05-15 | 湖南桑顿新能源有限公司 | Preparation method of modified spinel type lithium manganate |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106684350A (en) * | 2016-12-21 | 2017-05-17 | 桑顿新能源科技有限公司 | Preparation method of lithium nickel manganese oxide serving as high-voltage positive electrode material |
CN108288711A (en) * | 2018-02-12 | 2018-07-17 | 成都理工大学 | A kind of quaternary lithium-ion battery positive electrode material and preparation method |
CN109811412A (en) * | 2018-12-28 | 2019-05-28 | 广东邦普循环科技有限公司 | A kind of stratiform nickel lithium manganate cathode material of monocrystalline pattern and preparation method thereof |
CN109811412B (en) * | 2018-12-28 | 2021-06-11 | 广东邦普循环科技有限公司 | Single-crystal-shaped layered lithium nickel manganese oxide positive electrode material and preparation method thereof |
CN110137445A (en) * | 2019-03-26 | 2019-08-16 | 广西卓能新能源科技有限公司 | Battery anode slice, lithium ion battery, stratiform nickel ion doped and preparation method thereof |
CN114408987A (en) * | 2022-03-30 | 2022-04-29 | 宜宾锂宝新材料有限公司 | Nickel-cobalt-manganese precursor, ternary cathode material and preparation method thereof |
CN114408987B (en) * | 2022-03-30 | 2022-06-21 | 宜宾锂宝新材料有限公司 | Nickel-cobalt-manganese precursor, ternary cathode material and preparation method thereof |
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CN103579610B (en) | 2016-03-30 |
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Address after: 230000 Yaohai Industrial Zone, Hefei New District, Anhui, No. D weft Road, No. 7 Applicant after: Gotion High-tech Co., Ltd. Address before: 230000 Yaohai Industrial Park, Anhui, Hefei No. D weft Road, No. 7 Applicant before: Hefei Guoxuan High-Tech Power Energy Co.,Ltd. |
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Application publication date: 20140212 Assignee: NANJING GUOXUAN BATTERY Co.,Ltd. Assignor: Gotion High-tech Co., Ltd. Contract record no.: 2017320000046 Denomination of invention: Method for preparing nickel lithium manganate serving as cathode material of lithium ion battery Granted publication date: 20160330 License type: Exclusive License Record date: 20170306 |
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