CN103571417B - High-impact hot melt adhesive - Google Patents
High-impact hot melt adhesive Download PDFInfo
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- CN103571417B CN103571417B CN201310505464.3A CN201310505464A CN103571417B CN 103571417 B CN103571417 B CN 103571417B CN 201310505464 A CN201310505464 A CN 201310505464A CN 103571417 B CN103571417 B CN 103571417B
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- hot melt
- melt adhesive
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- 239000004831 Hot glue Substances 0.000 title claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 8
- 239000004695 Polyether sulfone Substances 0.000 claims abstract description 7
- 239000012188 paraffin wax Substances 0.000 claims abstract description 7
- 229920006393 polyether sulfone Polymers 0.000 claims abstract description 7
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims abstract description 4
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 claims abstract description 4
- 239000003208 petroleum Substances 0.000 claims abstract description 4
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 229910052923 celestite Inorganic materials 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 239000010977 jade Substances 0.000 claims description 6
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 6
- -1 polysiloxane Polymers 0.000 claims description 6
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- 229910017083 AlN Inorganic materials 0.000 claims description 3
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000005662 Paraffin oil Substances 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 3
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-impact hot melt adhesive, which is prepared from the following raw materials in parts by weight: 1.2-2.4 parts of 3-aminopropyltrimethoxysilane, 5-7 parts of linear low-density polyethylene (LLDPE), 2-4 parts of paraffin wax, 2-4 parts of polyethersulfone resin, 19-28 parts of epoxy resin E20, 18-25 parts of C5 petroleum resin, 3-5 parts of cross-linking agent TAC, 7-10 parts of composite filler, 1.5-2.5 parts of dioctyl maleate, and 0.8-1.5 parts of acetyl triethyl citrate.
Description
Technical field
The invention belongs to binding agent field, particularly relate to a kind of hot melt adhesive of high impact-resistant.
Background technology
In recent years, the application of the novel material such as matrix material and plastics on automobile made automobile stick with glue agent and the also sustainable growth of seal gum consumption, and wherein automotive upholstery is the field that tackiness agent consumption increases rapidly.The demand of Automotive upholstery hot melt adhesive gets more and more.
Summary of the invention
The object of this invention is to provide a kind of hot melt adhesive of high impact-resistant.
The present invention adopts following technical scheme to achieve these goals:
A hot melt adhesive for high impact-resistant, is characterized in that, it is obtained by the raw material of following weight parts:
3-aminopropyl trimethoxysilane 1.2-2.4, LLDPE 5-7, paraffin 2-4, polyethersulfone resin 2-4, epoxy resin E20 19-28, C5 petroleum resin 18-25, linking agent TAC3-5, compounded mix 7-10, dioctyl maleate 1.5-2.5, acetyl triethyl citrate 0.8-1.5;
Compounded mix is obtained by the raw material of following weight parts: wilkinite 12-18, celestite powder 4-6, jade powder 3-6, polysiloxane 1.5-1.7, paraffin oil 1-2, aluminium nitride powder 1-2, rosin 1-2, Silane coupling agent KH550 0.3-0.5, Radix Angelicae Sinensis oil 0.2-0.4, silicon carbide 0.2-0.4, Secondary ammonium phosphate 0.1-0.2, dinoctyl phthalate 0.1-0.2, nano-carbon powder 1-2, Graphite Powder 99 1-2, alkylphenol polyoxyethylene 0.4-0.6;
The preparation method of described compounded mix is: preparation method is by after wilkinite, celestite powder, jade powder mixing, 4-5 hour is calcined at 500-550 DEG C, then, take out, be soak 4-6 hour in the sodium hydroxide solution of 8-10% in concentration, take out, deionized water wash, dry, add in suitable quantity of water in the lump with nano-carbon powder and grind, adding 10-15% sodium hydroxide solution adjusts PH to be 8.8-9.5, after ground slurry to 400-500 order, then add hydrochloric acid soln and be adjusted to neutrality, dry, mix with surplus stock, ground and mixed evenly and get final product again.
The hot melt adhesive of described a kind of high impact-resistant, is characterized in that:
Preparation process is:
(1) paraffin, epoxy resin E20 are put into blender and mix for subsequent use;
(2) again compounded mix, polyethersulfone resin are put into blender and mixed for subsequent use;
(3), after all the other raw materials being put into blender mixing, granulation, cooling and pelletizing, to obtain final product.
Beneficial effect of the present invention: epoxy resin of the present invention, compounded mix and all the other materials compatibility are good, after mixing, the fusion time is short, has superior shock resistance, and its development time is short simultaneously, and cohesive strength is high.
Embodiment
A hot melt adhesive for high impact-resistant, it is obtained by the raw material of following weight kg:
3-aminopropyl trimethoxysilane 2.4, LLDPE 7, paraffin 4, polyethersulfone resin 4, epoxy resin E20 28, C5 petroleum resin 25, linking agent TAC5, compounded mix 10, dioctyl maleate 2.5, acetyl triethyl citrate 1.5;
Compounded mix is obtained by the raw material of following weight kg: wilkinite 18, celestite powder 6, jade powder 6, polysiloxane 1.7, paraffin oil 2, aluminium nitride powder 2, rosin 1, Silane coupling agent KH550 0.5, Radix Angelicae Sinensis oil 0.3, silicon carbide 0.4, Secondary ammonium phosphate 0.2, dinoctyl phthalate 0.2, nano-carbon powder 1, Graphite Powder 99 2, alkylphenol polyoxyethylene 0.6;
The preparation method of described compounded mix is: preparation method is by after wilkinite, celestite powder, jade powder mixing, calcines 5 hours, then at 550 DEG C, take out, be soak 6 hours in the sodium hydroxide solution of 10% in concentration, take out, deionized water wash, dry, add in suitable quantity of water in the lump with nano-carbon powder and grind, adding 15% sodium hydroxide solution adjusts PH to be 9.5, after ground slurry to 500 order, then add hydrochloric acid soln and be adjusted to neutrality, dry, mix with surplus stock, ground and mixed evenly and get final product again.
The hot melt adhesive of described a kind of high impact-resistant, preparation process is:
(1) paraffin, epoxy resin E20 are put into blender and mix for subsequent use;
(2) again compounded mix, polyethersulfone resin are put into blender and mixed for subsequent use;
(3), after all the other raw materials being put into blender mixing, granulation, cooling and pelletizing, to obtain final product.
The apparent viscosity of the binding agent of the present embodiment is 5400MPa.s, stripping strength 56N/2.5cm
2, initial bonding strength reaches No. 5 steel balls, open hour 37s, and within 24 hours, thermally-stabilised proterties is stablized.
Claims (2)
1. a hot melt adhesive for high impact-resistant, is characterized in that, it is obtained by the raw material of following weight parts:
3-aminopropyl trimethoxysilane 1.2-2.4, LLDPE 5-7, paraffin 2-4, polyethersulfone resin 2-4, epoxy resin E20 19-28, C5 petroleum resin 18-25, linking agent TAC3-5, compounded mix 7-10, dioctyl maleate 1.5-2.5, acetyl triethyl citrate 0.8-1.5;
Compounded mix is obtained by the raw material of following weight parts: wilkinite 12-18, celestite powder 4-6, jade powder 3-6, polysiloxane 1.5-1.7, paraffin oil 1-2, aluminium nitride powder 1-2, rosin 1-2, Silane coupling agent KH550 0.3-0.5, Radix Angelicae Sinensis oil 0.2-0.4, silicon carbide 0.2-0.4, Secondary ammonium phosphate 0.1-0.2, dinoctyl phthalate 0.1-0.2, nano-carbon powder 1-2, Graphite Powder 99 1-2, alkylphenol polyoxyethylene 0.4-0.6;
The preparation method of described compounded mix is: preparation method is by after wilkinite, celestite powder, jade powder mixing, 4-5 hour is calcined at 500-550 DEG C, then, take out, be soak 4-6 hour in the sodium hydroxide solution of 8-10% in concentration, take out, deionized water wash, dry, add in suitable quantity of water in the lump with nano-carbon powder and grind, adding 10-15% sodium hydroxide solution adjusts PH to be 8.8-9.5, after ground slurry to 400-500 order, then add hydrochloric acid soln and be adjusted to neutrality, dry, mix with surplus stock, ground and mixed evenly and get final product again.
2. the hot melt adhesive of a kind of high impact-resistant according to claim 1, is characterized in that:
Preparation process is:
(1) paraffin, epoxy resin E20 are put into blender and mix for subsequent use;
(2) again compounded mix, polyethersulfone resin are put into blender and mixed for subsequent use;
(3), after all the other raw materials being put into blender mixing, granulation, cooling and pelletizing, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310505464.3A CN103571417B (en) | 2013-10-24 | 2013-10-24 | High-impact hot melt adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310505464.3A CN103571417B (en) | 2013-10-24 | 2013-10-24 | High-impact hot melt adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103571417A CN103571417A (en) | 2014-02-12 |
| CN103571417B true CN103571417B (en) | 2015-06-17 |
Family
ID=50044141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310505464.3A Active CN103571417B (en) | 2013-10-24 | 2013-10-24 | High-impact hot melt adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103571417B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107903870A (en) * | 2017-08-03 | 2018-04-13 | 苏州艾普娜斯纺织品有限公司 | copolyester hot melt adhesive particle |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004085510B1 (en) * | 2003-03-24 | 2004-11-25 | Dow Global Technologies Inc | Reactive hot melt adhesive formulation for joining stamped metal and plastic parts |
| CN1712483A (en) * | 2004-06-23 | 2005-12-28 | Lg电线有限公司 | Isotropic conductive adhesive and adhesive film using the same |
| CN102746622A (en) * | 2012-07-26 | 2012-10-24 | 哈尔滨玻璃钢研究院 | Prepreg with moderate-temperature cured epoxy resin as substrate material and preparation method thereof |
| CN102942765A (en) * | 2012-10-24 | 2013-02-27 | 中国航空工业集团公司北京航空材料研究院 | Method for preparing high toughness epoxy resin matrix by using heat fusion method |
-
2013
- 2013-10-24 CN CN201310505464.3A patent/CN103571417B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004085510B1 (en) * | 2003-03-24 | 2004-11-25 | Dow Global Technologies Inc | Reactive hot melt adhesive formulation for joining stamped metal and plastic parts |
| CN1712483A (en) * | 2004-06-23 | 2005-12-28 | Lg电线有限公司 | Isotropic conductive adhesive and adhesive film using the same |
| CN102746622A (en) * | 2012-07-26 | 2012-10-24 | 哈尔滨玻璃钢研究院 | Prepreg with moderate-temperature cured epoxy resin as substrate material and preparation method thereof |
| CN102942765A (en) * | 2012-10-24 | 2013-02-27 | 中国航空工业集团公司北京航空材料研究院 | Method for preparing high toughness epoxy resin matrix by using heat fusion method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103571417A (en) | 2014-02-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180517 Address after: 363800 Kowloon Industrial Park, Huaan Economic Development Zone, Zhangzhou, Fujian Patentee after: FUJIAN JIALONG ADHESIVE TAPE CO.,LTD. Address before: 241009 auto parts road of Yijiang high tech Industrial Development Zone, Wuhu, Anhui Patentee before: WUHU ZHONGLI PARTS Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high impact resistant hot melt adhesive Effective date of registration: 20231228 Granted publication date: 20150617 Pledgee: Bank of China Limited by Share Ltd. Zhangzhou Huaan branch Pledgor: FUJIAN JIALONG ADHESIVE TAPE CO.,LTD. Registration number: Y2023350000265 |