CN103571371A - Preparation method of adhesive for mounting of calligraphy and painting - Google Patents
Preparation method of adhesive for mounting of calligraphy and painting Download PDFInfo
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- CN103571371A CN103571371A CN201310353920.7A CN201310353920A CN103571371A CN 103571371 A CN103571371 A CN 103571371A CN 201310353920 A CN201310353920 A CN 201310353920A CN 103571371 A CN103571371 A CN 103571371A
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Abstract
The invention provides a preparation method of an adhesive for the mounting of calligraphy and painting. The preparation method comprises the following steps of: (1) adding wheat starch to water at the concentration of 0.75-4.5g/25mL, and stirring at 85-95 DEG C for 2-7 minutes at the stirring speed of 120-200rpm; (2) aging for 0-15 days. According to the invention, an optimal preparation process for preparing the adhesive for the mounting of the calligraphy and painting is determined through a large quantity of experiment screening and comparing optimization. A stripping strength experiment indicates that the adhesive prepared through the method provided by the invention is very suitable for the mounting of the calligraphy and painting in term of adhesion, can be put into large-scale industrialized production and lays a foundation for increasing the work efficiency of the mounting of the calligraphy and painting and enlarging the production scale.
Description
Technical field
The present invention relates to a kind of binding agent and preparation method thereof, be specifically related to binding agent and preparation method thereof for a kind of mounting of calligraphy and painting.
Background technology
Ancient Chinese painting and calligraphy are famous in the world, and the preservation of painting and calligraphy, displaying and research all be unable to do without mounting work, and the mounting of calligraphy and painting becomes the indispensable technical guarantee of calligraphy and painting art.Mounting is a conventional art, and wherein the quality of mounting binding agent can affect mounting quality, is also related to painting and calligraphy preservation in the future.For ancient calligraphy and painting, a romantic charm is just lost in many mountings.Paste is jointing material important in mounting of calligraphy and painting process, is also the key factor of mounting quality and success or failure.Painting and calligraphy mount that part occurs damaging by worms, goes mouldy, watt trouble, warpage, hollow, pipe, invariably relevant with paste quality, modulation and use.Ming Dynasty Zhou Jiazhou says in < < decoration will > >: " mount in paste, China ink in glue still.China ink becomes with glue, just mounts to stick with paste ".
Foreign scholar did some researchs to the long-term method of seal of paste, and domestic scholars has also been done large quantity research at aspects such as the development of paste and additives.But in historical relic reparation and mounting, concentration, temperature, churning time and the speed etc. of paste modulation are all the accumulation of master worker's mounting experience for many years, the mounting of calligraphy and painting is not carried out to the research of system science by preparation method and the characteristic thereof, particularly adhesivity of paste so far.Although also have some about the adhering testing method of slurry, as rove method, bending rubbing manipulation, obvolvent force method, solubility parameter method, microcosmic fractograph analysis method etc., but these methods are all indirect methods, experimental error is large, poor repeatability, inaccurate, and the viscosity that is not suitable for mounting of calligraphy and painting slurry therewith is measured.Mounting of calligraphy and painting industry does not have a set of feasible method to carry out the adhesivity of testing size at present, and this causes the mounting of calligraphy and painting to be difficult to industrialization by the preparation technology of binding agent.
Summary of the invention
The object of the present invention is to provide binding agent and preparation method thereof for a kind of mounting of calligraphy and painting, this binding agent is specially adapted to the mounting of calligraphy and painting and can carries out large-scale commercial production.
As follows for realizing the technical scheme of above-mentioned purpose:
A preparation method for binding agent for the mounting of calligraphy and painting, this preparation method comprises the following steps:
(1) wheat starch is placed in to water with the concentration of 0.75-4.5g/25mL, at 85-95 ℃, stirs 2-7 minute, stirring velocity is 120-200 rev/min;
(2) ageing 0-15 days.
In above-mentioned preparation method's step (1), preferably, the concentration of described wheat starch in water is 3g/25mL; Preferably, described in, be stirred at 95 ℃ and carry out; Preferably, the time of described stirring is 4 minutes; Preferably, described stirring velocity is 120 revs/min.
In above-mentioned preparation method's step (2), preferably, described ageing is at room temperature carried out; The time of described ageing can or be 15 days for 0 day.
The mounting of calligraphy and painting binding agent that the present invention also provides above-mentioned preparation method to prepare.
The present invention also provides a kind of mounting of calligraphy and painting method, and the method comprises and adopts the above-mentioned mounting of calligraphy and painting to carry out mounting with binding agent.
Because the mounting of calligraphy and painting is special by binding agent purposes, its viscosity is required to different and other tackiness agent, the present invention finds that kind, concentration, agitation condition and the ageing condition of starch exist very large impact to its adhesivity after deliberation.Through a large amount of experiment screenings and contrast, optimize, the present invention has determined the best preparation technology with binding agent for the mounting of calligraphy and painting.Stripping strength experimental result shows that the adhesivity of binding agent prepared by the present invention is suitable for the mounting of calligraphy and painting very much, and can carry out large-scale industrial production, for improving the working efficiency of the mounting of calligraphy and painting and expanding the scale of production, lays a good foundation.
The present invention adopts the stripping strength of binding agent for the stripping method test mounting of calligraphy and painting, and stripping strength means the direct indicator of adhesive power, is about to a certain amount of adhesive coated on adherend, under certain pressure bonding and dry after peel off to the required power of unit length.The peeling force of measuring in this process is the bonding force of tackiness agent.6 tests of mean value can get to(for) each measurement result, the limit of error of permission is: relative deviation/mean value * 100%≤5%, cast out inappropriate numerical value.
The mounting of calligraphy and painting of the present invention comprises the following steps by the testing method of the stripping strength of binding agent:
1, in 2 minutes, with brush, 7 grams of binding agents to be measured are uniformly coated in the one side of 23 centimetres of length, wide 11.5 centimetres of silks, silk is coated with to the one side doubling of binding agent and makes it bonding, and within 3 minutes, remove bubble with brush brush, at room temperature place 12 minutes, then press under 45 minutes and room temperature and place and dry for 4 hours, the grow up cloth of 10.5 centimetres, wide 1.5 centimetres of its cutting is made and mounts part;
2, described one side of mounting the bonding end of part is fixed on to the chassis of Physical Property Analysis instrument, another side is fixed on probe, first described chassis and probe are contacted with 50N pressure, keep 10 seconds, again with 0.50 mm/second at the uniform velocity mobile probe carry out 180 ° and peel off, probe miles of relative movement is 20 centimetres, records peeling force and changes and draw peeling force-probe miles of relative movement curve.
Accompanying drawing explanation
Below, describe by reference to the accompanying drawings embodiment of the present invention in detail, wherein:
Fig. 1 a: the Wheat starch Paste that different concns is made changes with the viscosity of digestion time;
Fig. 1 b: the Wheat starch Paste that different churning time are made changes with the viscosity of digestion time;
Fig. 1 c: the Wheat starch Paste that different whipping temps are made changes with the viscosity of digestion time;
Fig. 1 d: the Wheat starch Paste that different stirring velocitys are made changes with the viscosity of digestion time;
Fig. 2: the stripping strength of three of ageing kinds of starch pastes not;
Fig. 3: the stripping strength curve after potato starch ageing different time;
Fig. 4: three kinds of starch pastes change with the viscosity of digestion time.
Embodiment
Below by embodiment, describe the present invention in detail, should be appreciated that following embodiment is only for the present invention is described, the scope that it does not limit the present invention in any way.
Embodiment 1
The present embodiment adopts stripping method test peel strength value, and the mounting of calligraphy and painting caking agent that the main raw material of take is starch is object, and its viscosity is measured and analyzed with the variation of the factors such as concentration, whipping temp, churning time, stir speed (S.S.), digestion time.
1, paste is mounted the preparation of part
The starch paste of being made under different condition by RVA instrument is pasted into paste gel.Gel is smash in mortar to even pasty state, the time is 5 minutes, so that paste can evenly be applied on test silk.Test silk is cut out and grown up 23 centimetres, wide 11.5 centimetres.Take 7.00 grams of pastes, evenly spread upon on silk, need to brush up and down 2 minutes with brush, guarantee that paste is evenly distributed on cloth.By the cloth doubling brushing, change a clean brush and brush up and down 3 minutes, make the cloth of doubling not occur bubble, evenly stick together.Under room temperature, place 10-30 minute, mounting part is half-dried not dry state.Then 20kg paperweight is placed on to mounting on part of preparation and presses 10 minutes, make fully contact between upper and lower silk and paste.Room temperature is placed 1 hour, and after silk parches, the part of mounting that cutting growth is 10.5 centimetres, wide 1.5 centimetres carries out stripping test.
2, the test of stripping strength
The two sides of mounting the bonding one end of part making is fixed on the chassis and upper outstanding SMSP/36R probe of physical property instrument with double faced adhesive tape respectively, first allow chassis and probe with 50N pressure contact, then do 180 ° and peel off, with the speed of 0.50mm/s, evenly pull open, stretching distance is 20cm.Record peeling force-distance Curve in this process, described peeling force is the cohesive force of paste, and result is got the mean value of 6 test results.The limit of error allowing is: relative deviation/mean value * 100%≤5%, cast out inappropriate numerical value.During preliminary experiment selection condition, comprise chassis and upper outstanding probe pressure, hold-time, pull open speed.Pressure excessive (>=100N) or too small (≤10N) all do not meet actual mounting requirement, 30N, 50N are set, 70N tests respectively, and 50N effect is relatively best, can better separate the paste of making under different condition.Hold-time arranges 5 seconds, 10 seconds, 15 seconds, 20 seconds, find that 5 second time is too short, bonding inhomogeneous, within 15 seconds and 20 seconds, long experimental result is not had to large impact, but a speed of experiment that slows down, preferably 10 seconds.Draw speed is set to 0.10 mm/second, 0.50 mm/second, 1.00 mm/second, and speed affects test progress too slowly, mounts too soon the inertia that part separates with draw speed too large, can not accurately express peeling force, preferably 0.50 mm/second.
3, test result and analysis
(1) test of wheat starch stripping strength: by making and mount part after the Wheat starch Paste ageing of making under different condition, do stripping test on physical property instrument, the stripping strength of test paste is adhesivity, and experimental data is in Table 1.Do respectively adhesivity curve corresponding to different condition.All in all, storage period is longer, and peel strength value is lower, adhesivity also declines, be because pasted starch along with the spontaneous water-insoluble state that becomes of time growth meeting, this phenomenon is ageing, it is contrary with gelatinization phenomenon, and by unordered, to orderly conversion, part is recovered crystalline state.From table 1, Fig. 1 a, with concentration, increase, the peel strength value that same digestion time is corresponding becomes large, adhesivity also strengthens, but when concentration is 1.5g/25ml and 3g/25ml, viscosity is little with digestion time rangeability, and the amplitude that its viscosity of 4.5g/25ml increases is very large.An ageing 5-10 days molecular chain ruptures in various degree, sharply aging, shows as viscosity bust, the corresponding gelatinization churning time of digestion time-adhesivity from table 1, Fig. 1 b changes, churning time is longer, and stripping strength and bonding force are understood corresponding increase at same digestion time, but when ageing is in the time of 15 days, the aging destruction to molecular chain is preponderated, and stripping strength and viscosity degradation have arrived same value, by table 1, the corresponding top temperature of the digestion time of Fig. 1 c-adhesivity changes known, 90 ℃ of pastes during with 95 ℃ are consistent with digestion time viscosity variation tendency line, a little higher than 95 ℃ of corresponding 90 ℃ of viscosity, but there is larger variation with digestion time viscosity in 85 ℃ of pastes, while placing 10 days there is peak value in viscosity, decline subsequently, in conjunction with 85 ℃ of RVA pasting curves, analyze reason, in the time of may being gelatinization, starch molecule does not have complete expansion, gelatinization is insufficient, in the process of in the future placing, the molecule of complete expansion does not absorb moisture swelling again, viscosity increased, aging preponderating to a certain extent, viscosity starts again to decline, digestion time-adhesivity corresponding to peak value stirring velocity is from table 1, Fig. 1 d, and stirring velocity acquires a certain degree little to the viscosity influence of paste, but stir speed (S.S.) is higher, and stripping strength and cohesive force have corresponding raising.With digestion time, increase, pasted starch molecular rupture or recrystallization cause paste aging, and stripping strength reduces cohesive force and weakens.
Table 1 digestion time is on the impact of pasted starch bonding force under different condition (g/ mm second)
(2) under identical conditions with three kinds of starch, potato starch, sweet potato starch and W-Gum are made paste.After ageing different time, make and mount part, on Physical Property Analysis instrument, carry out respectively stripping test, the stripping strength of testing different pastes, i.e. adhesivity.Fig. 2 is the stripping strength curve of three kinds of starch pastees of the new not ageing of making, and the peel strength value of corn starch paste is maximum, and the value of potato and Ipomoea batatas is suitable, lower than corn starch paste.Fig. 3 is the stripping strength after potato starch ageing different time, and in the scope that the fluctuation of peel strength value allows in error, along with the increase of digestion time, stripping strength step value presents downtrending.By the paste stripping strength experimental result Data-Statistics mapping of three kinds of starch, see Fig. 4.Trend from curve, with digestion time increase, there is reduction trend in stripping strength, the paste that sweet potato starch and W-Gum are made stripping strength downtrending is in time basically identical, while placing 5 days, strength degradation is the fastest, downtrending in 5-15 days slows down, and the paste that potato starch is made declines steadily with increasing stripping strength storage period.The paste peel strength value that potato and sweet potato starch are made is close, and the value of W-Gum is slightly high, and this is relevant from the molecular structure of different starch.According to above-mentioned experimental result, contrast different types of starch, under various manufacturing conditions the same terms, the viscosity of wheat starch is put up the best performance, and increases its viscosity reduction also relatively little with digestion time, can meet mounting of calligraphy and painting requirement.Optimal conditions when paste is made, concentration 3g/25mL, 95 ℃ of temperature, churning time 4min, stirring velocity 120r/min, the stripping strength of digestion time and paste is inversely proportional to, time is longer, and stripping strength is lower, uses the paste of different ageing according to actual mounting different sites.
Claims (9)
1. the preparation method of binding agent for the mounting of calligraphy and painting, this preparation method comprises the following steps:
(1) wheat starch is placed in to water with the concentration of 0.75-4.5g/25mL, at 85-95 ℃, stirs 2-7 minute, stirring velocity is 120-200 rev/min;
(2) ageing 0-15 days.
2. preparation method according to claim 1, is characterized in that, in described preparation method's step (1), the concentration of described wheat starch in water is 3g/25mL.
3. preparation method according to claim 1 and 2, is characterized in that, in described preparation method's step (1), described in be stirred at 95 ℃ and carry out.
4. according to the preparation method described in any one in claims 1 to 3, it is characterized in that, in described preparation method's step (1), the time of described stirring is 4 minutes.
5. according to the preparation method described in any one in claim 1 to 4, it is characterized in that, in described preparation method's step (1), described stirring velocity is 120 revs/min.
6. according to the preparation method described in any one in claim 1 to 5, it is characterized in that, in described preparation method's step (2), described ageing is at room temperature carried out.
7. according to the preparation method described in any one in claim 1 to 6, it is characterized in that, in described preparation method's step (2), the time of described ageing is 0 day or 15 days.
8. the mounting of calligraphy and painting binding agent of preparing according to the preparation method described in any one in claim 1 to 7.
9. a mounting of calligraphy and painting method, the method comprises and adopts the mounting of calligraphy and painting according to claim 8 to carry out mounting with binding agent.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263281A (en) * | 2014-10-25 | 2015-01-07 | 曾飞 | Production method for glue |
| CN104449458A (en) * | 2014-10-25 | 2015-03-25 | 曾飞 | Adhesive |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260468A (en) * | 2010-05-27 | 2011-11-30 | 张少娟 | Method for quickly making paste for adhering picture |
-
2013
- 2013-08-14 CN CN201310353920.7A patent/CN103571371B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260468A (en) * | 2010-05-27 | 2011-11-30 | 张少娟 | Method for quickly making paste for adhering picture |
Non-Patent Citations (6)
| Title |
|---|
| 张玄微: "书画装裱用变性淀粉胶粘剂_表面施胶剂制备与应用的可行性分析", 《传统装裱技术研讨会论文集》, 31 July 2005 (2005-07-31) * |
| 张美云等: "《纸加工原理与技术》", 30 April 1998 * |
| 曹枫等: "淀粉胶粘剂在传统书画修裱工艺中的应用", 《粘接》, vol. 29, no. 5, 31 May 2008 (2008-05-31) * |
| 李娜等: "用RVA仪分析玉米淀粉的糊化特性", 《中国粮油学报》, vol. 26, no. 6, 30 June 2011 (2011-06-30) * |
| 李涛: "小麦淀粉胶粘剂在传统书画装裱工艺中的应用", 《粘接》, no. 4, 30 April 2011 (2011-04-30) * |
| 钟耕: "《谷物科学原理》", 31 December 2012 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263281A (en) * | 2014-10-25 | 2015-01-07 | 曾飞 | Production method for glue |
| CN104449458A (en) * | 2014-10-25 | 2015-03-25 | 曾飞 | Adhesive |
| CN104449458B (en) * | 2014-10-25 | 2018-10-16 | 泉州台商投资区本盛机械科技有限公司 | A kind of cup convenient for label |
| CN104263281B (en) * | 2014-10-25 | 2018-10-23 | 泉州台商投资区捷赢网络科技有限公司 | A kind of cup convenient for label |
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