CN103555298B - Method and the application of additive for drilling fluid is prepared by green peel of walnut - Google Patents
Method and the application of additive for drilling fluid is prepared by green peel of walnut Download PDFInfo
- Publication number
- CN103555298B CN103555298B CN201310568632.3A CN201310568632A CN103555298B CN 103555298 B CN103555298 B CN 103555298B CN 201310568632 A CN201310568632 A CN 201310568632A CN 103555298 B CN103555298 B CN 103555298B
- Authority
- CN
- China
- Prior art keywords
- walnut
- green peel
- massfraction
- particle
- under
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000009496 Juglans regia Nutrition 0.000 title claims abstract description 181
- 235000020234 walnut Nutrition 0.000 title claims abstract description 180
- 238000005553 drilling Methods 0.000 title claims abstract description 80
- 239000012530 fluid Substances 0.000 title claims abstract description 64
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000000654 additive Substances 0.000 title claims description 10
- 230000000996 additive effect Effects 0.000 title claims description 10
- 240000007049 Juglans regia Species 0.000 title description 2
- 241000758789 Juglans Species 0.000 claims abstract description 180
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 56
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000002245 particle Substances 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 42
- 238000010009 beating Methods 0.000 claims abstract description 29
- 239000002002 slurry Substances 0.000 claims abstract description 28
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 27
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 27
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 27
- 239000008098 formaldehyde solution Substances 0.000 claims abstract description 14
- 230000008569 process Effects 0.000 claims abstract description 14
- 229920005610 lignin Polymers 0.000 claims description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 8
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- 229910052791 calcium Inorganic materials 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 4
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 16
- 239000002699 waste material Substances 0.000 abstract description 16
- 230000009467 reduction Effects 0.000 abstract description 10
- 239000008186 active pharmaceutical agent Substances 0.000 abstract description 8
- 238000001914 filtration Methods 0.000 abstract description 8
- 239000007790 solid phase Substances 0.000 abstract description 8
- 238000003756 stirring Methods 0.000 abstract description 8
- 238000010411 cooking Methods 0.000 abstract description 2
- 238000002791 soaking Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 14
- 239000008346 aqueous phase Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 230000008859 change Effects 0.000 description 6
- 239000005017 polysaccharide Substances 0.000 description 5
- 150000004676 glycans Chemical class 0.000 description 4
- 229920001282 polysaccharide Polymers 0.000 description 4
- 150000008442 polyphenolic compounds Chemical class 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- -1 diaryl heptane class Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- ZVRMGCSSSYZGSM-CCEZHUSRSA-N (E)-hexadec-2-enoic acid Chemical compound CCCCCCCCCCCCC\C=C\C(O)=O ZVRMGCSSSYZGSM-CCEZHUSRSA-N 0.000 description 1
- OYHQOLUKZRVURQ-UHFFFAOYSA-N 9,12-Octadecadienoic Acid Chemical compound CCCCCC=CCC=CCCCCCCCC(O)=O OYHQOLUKZRVURQ-UHFFFAOYSA-N 0.000 description 1
- AFSDNFLWKVMVRB-UHFFFAOYSA-N Ellagic acid Chemical compound OC1=C(O)C(OC2=O)=C3C4=C2C=C(O)C(O)=C4OC(=O)C3=C1 AFSDNFLWKVMVRB-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- POQICXMTUPVZMX-FWYGIPPASA-N Juglanin Natural products O[C@H]1[C@H](O)[C@@H](CO)O[C@@H]1OC1=C(C=2C=CC(O)=CC=2)OC2=CC(O)=CC(O)=C2C1=O POQICXMTUPVZMX-FWYGIPPASA-N 0.000 description 1
- UPYKUZBSLRQECL-UKMVMLAPSA-N Lycopene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1C(=C)CCCC1(C)C)C=CC=C(/C)C=CC2C(=C)CCCC2(C)C UPYKUZBSLRQECL-UKMVMLAPSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 150000001746 carotenes Chemical class 0.000 description 1
- 235000005473 carotenes Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 229930005346 hydroxycinnamic acid Natural products 0.000 description 1
- 235000010359 hydroxycinnamic acids Nutrition 0.000 description 1
- 230000000640 hydroxylating effect Effects 0.000 description 1
- KQPYUDDGWXQXHS-UHFFFAOYSA-N juglone Chemical compound O=C1C=CC(=O)C2=C1C=CC=C2O KQPYUDDGWXQXHS-UHFFFAOYSA-N 0.000 description 1
- POQICXMTUPVZMX-UXYNSRGZSA-N kaempferol 3-arabinofuranoside Chemical compound O[C@@H]1[C@@H](O)[C@H](CO)O[C@H]1OC1=C(C=2C=CC(O)=CC=2)OC2=CC(O)=CC(O)=C2C1=O POQICXMTUPVZMX-UXYNSRGZSA-N 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- NGSWKAQJJWESNS-ZZXKWVIFSA-N trans-4-coumaric acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C=C1 NGSWKAQJJWESNS-ZZXKWVIFSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- NCYCYZXNIZJOKI-UHFFFAOYSA-N vitamin A aldehyde Natural products O=CC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C NCYCYZXNIZJOKI-UHFFFAOYSA-N 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
Method and the application of Environment-protecting Drilling Fluids treatment agent is prepared by green peel of walnut, method is rolled by Cortex walnut to be crushed to particle, green peel of walnut particle is added in hollander, add ethanol, soak under normal temperature and pressure, by the green peel of walnut particle making beating of soaking, formaldehyde solution and Sodium Benzoate is added in green peel of walnut slurry, making beating, xylogen goods are added in the green peel of walnut slurry after process, making beating, obtain Environment-protecting Drilling Fluids treatment agent, during application, Environment-protecting Drilling Fluids treatment agent is scattered in water-base drilling fluid, adopt API its filtration reduction of standard test and tackifying, or Environment-protecting Drilling Fluids treatment agent is scattered in waste water-base drilling liquid, stir, leave standstill, solid phase in waste water-base drilling liquid is flocculated, strengthen through modified pericarp dispersiveness, effectively can reduce viscosity and the filter loss of water-base drilling fluid, may be used for cooking fluid loss agent and the tackifier of drilling fluid in field produces.
Description
Technical field
The present invention relates to Cortex walnut applied technical field, be specifically related to method and the application of being prepared Environment-protecting Drilling Fluids treatment agent by green peel of walnut.
Background technology
Walnut is Juglandaceae Juglans deciduous tree, and formal name used at school English walnut, cultivation history is long.Walnut Resources in China is very abundant, produces outstanding many with Shandong, Hebei, Henan, Zhejiang, Shanxi, Shaanxi, Gansu, Qinghai, Sichuan, Guizhou, West of Hubei Province and southern Xinjiang.Research shows in green peel of walnut containing natural polymers such as a large amount of tannin (10.49mg/g), tannin (1.78%) and polysaccharide.In addition, green peel of walnut is also containing polytype micromolecular compound: juglanin, regianin, naphthoquinones, flavonoid, Polyphenols, diaryl heptane class, terpene, unsaturated fatty acids (gaidic acid, 9-octadecenoic acid, 9,12-octadecadienoic acid, 9,12,15-punicic acid), VITAMIN, carotene, coffic acid, gallic acid, benzoaric acid, Hydroxycinnamic acid, succsinic acid etc.
According to statistics, the output of the rascal of current China artificial culture walnut is 27.4 ten thousand t every year, add that output China of wild walnut rascal produces green peel of walnut about 350,000 about t per year, but green peel of walnut is not also by utilization on a large scale at present.Drilling fluid additive can be used as in field of oilfield chemistry plant phenols and poly-saccharide material, there is viscosity reduction, fall the effects such as dehydration, and containing compounds such as lignin class, polysaccharide in green peel of walnut, if used as drilling fluid additive, good economic benefit and environmental benefit can will be produced.
Summary of the invention
In order to expand the purposes of green peel of walnut, improve its added value, the object of the present invention is to provide method and the application of being prepared Environment-protecting Drilling Fluids treatment agent by green peel of walnut, the polyphenolic compound in formaldehyde and Cortex walnut is adopted to carry out hydroxylating, strengthen through modified pericarp dispersiveness, effectively can reduce viscosity and the filter loss of water-base drilling fluid, may be used for cooking fluid loss agent and the tackifier of drilling fluid in field produces.
In order to achieve the above object, the technical solution used in the present invention is:
Prepared the method for Environment-protecting Drilling Fluids treatment agent by green peel of walnut, comprise the following steps:
The first step, Cortex walnut is rolled the particle be crushed within diameter 2cm, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 1-10%, soak more than 30min under normal temperature and pressure, and described ethanol is the product of the above purity of technical grade;
3rd step, at normal temperatures and pressures, under 1000-20000 rev/min, pull an oar the green peel of walnut particle soaked by second step 3-15min;
4th step, in above-mentioned green peel of walnut slurry, add the formaldehyde solution accounting for green peel of walnut massfraction 0.1-1%, and account for the Sodium Benzoate of green peel of walnut massfraction 0.1-1%, under 100-500 rev/min, making beating 3-15min, described formaldehyde and Sodium Benzoate are the above purity product of technical grade;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 0-50% xylogen goods, under 100-500 rev/min, making beating 3-15min, obtain Environment-protecting Drilling Fluids treatment agent, the mixture changing sodium lignosulfonate, calcium lignin sulphonate, alkalization xylogen and any mass ratio thereof that xylogen goods are the above purity of technical grade used.
During application, be scattered in water-base drilling fluid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is the solution of 0.1-1%, adopts API its filtration reduction of standard test and tackifying, reduces leak-off 10-40%, and viscosity reduces 10-50%.Or be scattered in waste water-base drilling liquid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is 2-6%, stirs, leave standstill, the solid phase in waste water-base drilling liquid is flocculated, and in aqueous phase, solid content is lower than 0.1%.
Be raw material owing to present invention employs with Cortex walnut and xylogen goods, have the natural feature of environmental protection and recyclability, be easy to biological degradation, a small amount of phenylformic acid added can strengthen the germ resistance of this system; The xylogen contained in green peel of walnut, polysaccharide, polyphenol and xylogen-polysaccharide composite body class substance advantageous is in its viscosifying action of raising, enhance the adsorption of clay particle surface in itself and drilling fluid, the network structure of clay in water-base drilling fluid can be broken, play viscosity reduction effect; Tiny particle can play the tiny duct in blocking mud cake simultaneously, is conducive to improving its filtrate reducing effect.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
Prepared the method for Environment-protecting Drilling Fluids treatment agent by green peel of walnut, comprise the following steps:
The first step, rolls the particle being crushed to diameter 1-2cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 10%, soak 40min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 10000 revs/min, pull an oar the green peel of walnut particle soaked by second step 5min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.2%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.1% in above-mentioned green peel of walnut slurry, under 100 revs/min, and making beating 10min, described formaldehyde and Sodium Benzoate are technical grade product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 10% xylogen goods, under 100 revs/min, making beating 15min, obtain Environment-protecting Drilling Fluids treatment agent, the xylogen goods that change used are technical grade calcium lignin sulphonate.
During application, be scattered in water-base drilling fluid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is the solution of 0.1%, adopts API its filtration reduction of standard test and tackifying, reduces leak-off 11%, and viscosity reduces by 15%.Or be scattered in waste water-base drilling liquid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is 2%, stirs, leave standstill, the solid phase in waste water-base drilling liquid is flocculated, and in aqueous phase, solid content is lower than 0.1%.
Embodiment 2
Prepared the method for Environment-protecting Drilling Fluids treatment agent by green peel of walnut, comprise the following steps:
The first step, rolls the particle being crushed to diameter 0.5-1cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 5%, soak 50min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 15000 revs/min, pull an oar the green peel of walnut particle soaked by second step 5min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.5%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.6% in above-mentioned green peel of walnut slurry, under 300 revs/min, and making beating 2min, described formaldehyde and Sodium Benzoate are chemical pure product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 20% xylogen goods, under 400 revs/min, making beating 10min, obtain Environment-protecting Drilling Fluids treatment agent, the xylogen goods that change used are technical grade sodium lignosulfonate.
During application, be scattered in water-base drilling fluid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is the solution of 0.3%, adopts API its filtration reduction of standard test and tackifying, reduces leak-off 20%, and viscosity reduces by 18%.Or be scattered in waste water-base drilling liquid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is 2.5%, stirs, leave standstill, the solid phase in waste water-base drilling liquid is flocculated, and in aqueous phase, solid content is lower than 0.1%.
Embodiment 3
Prepared the method for Environment-protecting Drilling Fluids treatment agent by green peel of walnut, comprise the following steps:
The first step, rolls the particle being crushed to diameter 1-2cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 8%, soak 60min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 20000 revs/min, pull an oar the green peel of walnut particle soaked by second step 3min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.3%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.8% in above-mentioned green peel of walnut slurry, under 500 revs/min, and making beating 3min, described formaldehyde and Sodium Benzoate are technical grade product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 30% xylogen goods, under 300 revs/min, making beating 15min, obtains Environment-protecting Drilling Fluids treatment agent, and the xylogen goods that change used are technical grade alkalization xylogen.
During application, be scattered in water-base drilling fluid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is the solution of 0.5%, adopts API its filtration reduction of standard test and tackifying, reduces leak-off 30%, and viscosity reduces by 41%.Or be scattered in waste water-base drilling liquid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is 3%, stirs, leave standstill, the solid phase in waste water-base drilling liquid is flocculated, and in aqueous phase, solid content is lower than 0.08%.
Embodiment 4
Prepared the method for Environment-protecting Drilling Fluids treatment agent by green peel of walnut, comprise the following steps:
The first step, rolls the particle being crushed to diameter 0.2-1cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 7%, soak 60min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 8000 revs/min, pull an oar the green peel of walnut particle soaked by second step 15min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.1%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.8% in above-mentioned green peel of walnut slurry, under 400 revs/min, and making beating 10min, described formaldehyde and Sodium Benzoate are analytical pure product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 50% xylogen goods, under 500 revs/min, making beating 10min, obtain Environment-protecting Drilling Fluids treatment agent, the xylogen goods that change used are technical grade calcium lignin sulphonate.
During application, be scattered in water-base drilling fluid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is the solution of 0.7%, adopts API its filtration reduction of standard test and tackifying, reduces leak-off 35%, and viscosity reduces by 45%.Or be scattered in waste water-base drilling liquid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is 4.5%, stirs, leave standstill, the solid phase in waste water-base drilling liquid is flocculated, and in aqueous phase, solid content is lower than 0.08%.
Embodiment 5
Prepared the method for Environment-protecting Drilling Fluids treatment agent by green peel of walnut, comprise the following steps:
The first step, rolls the particle being crushed to diameter 0.5-2cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 3%, soak 120min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 12000 revs/min, pull an oar the green peel of walnut particle soaked by second step 12min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 1%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.1% in above-mentioned green peel of walnut slurry, under 500 revs/min, and making beating 5min, described formaldehyde and Sodium Benzoate are technical grade product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 15% xylogen goods, under 300 revs/min, making beating 12min, obtains Environment-protecting Drilling Fluids treatment agent, and the xylogen goods that change used are technical grade alkalization xylogen.
During application, be scattered in water-base drilling fluid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is the solution of 1%, adopts API its filtration reduction of standard test and tackifying, reduces leak-off 40%, and viscosity reduces by 50%.Or be scattered in waste water-base drilling liquid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is 6%, stirs, leave standstill, the solid phase in waste water-base drilling liquid is flocculated, and in aqueous phase, solid content is lower than 0.05%.
Embodiment 6
Prepared the method for Environment-protecting Drilling Fluids treatment agent by green peel of walnut, comprise the following steps:
The first step, rolls the particle being crushed to diameter 1-2cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 10%, soak 50min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 9000 revs/min, pull an oar the green peel of walnut particle soaked by second step 15min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.8%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.1% in above-mentioned green peel of walnut slurry, under 300 revs/min, and making beating 10min, described formaldehyde and Sodium Benzoate are chemical pure product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 20% xylogen goods, under 400 revs/min, making beating 8min, obtain Environment-protecting Drilling Fluids treatment agent, used to change xylogen goods be mass ratio is technical grade alkalization xylogen and the calcium lignin sulphonate of 1:1.
During application, be scattered in water-base drilling fluid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is the solution of 0.6%, adopts API its filtration reduction of standard test and tackifying, reduces leak-off 35%, and viscosity reduces by 46%.Or be scattered in waste water-base drilling liquid by above-mentioned Environment-protecting Drilling Fluids treatment agent, its mass concentration is 5%, stirs, leave standstill, the solid phase in waste water-base drilling liquid is flocculated, and in aqueous phase, solid content is lower than 0.08%.
Claims (6)
1. prepared the method for additive for drilling fluid by green peel of walnut, it is characterized in that, comprise the following steps:
The first step, Cortex walnut is rolled the particle be crushed within diameter 2cm, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 1-10%, soak more than 30min under normal temperature and pressure, and described ethanol is the product of the above purity of technical grade;
3rd step, at normal temperatures and pressures, under 1000-20000 rev/min, pull an oar the green peel of walnut particle soaked by second step 3-15min;
4th step, in above-mentioned green peel of walnut slurry, add the formaldehyde solution accounting for green peel of walnut massfraction 0.1-1%, and account for the Sodium Benzoate of green peel of walnut massfraction 0.1-1%, under 100-500 rev/min, making beating 3-15min, described formaldehyde and Sodium Benzoate are the above purity product of technical grade;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 0-50% xylogen goods, under 100-500 rev/min, making beating 3-15min, obtain Environment-protecting Drilling Fluids treatment agent, xylogen goods used are the mixture of the sodium lignosulfonate of the above purity of technical grade, calcium lignin sulphonate, alkalization xylogen and mass ratio arbitrarily thereof.
2. the method being prepared additive for drilling fluid by green peel of walnut according to claim 1, is characterized in that, comprise the following steps:
The first step, rolls the particle being crushed to diameter 1-2cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 10%, soak 40min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 10000 revs/min, pull an oar the green peel of walnut particle soaked by second step 5min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.2%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.1% in above-mentioned green peel of walnut slurry, under 100 revs/min, and making beating 10min, described formaldehyde and Sodium Benzoate are technical grade product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 10% xylogen goods, under 100 revs/min, making beating 15min, obtain Environment-protecting Drilling Fluids treatment agent, xylogen goods used are technical grade calcium lignin sulphonate.
3. the method being prepared additive for drilling fluid by green peel of walnut according to claim 1, is characterized in that, comprise the following steps:
The first step, rolls the particle being crushed to diameter 1-2cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 8%, soak 60min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 20000 revs/min, pull an oar the green peel of walnut particle soaked by second step 3min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.3%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.8% in above-mentioned green peel of walnut slurry, under 500 revs/min, and making beating 3min, described formaldehyde and Sodium Benzoate are technical grade product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 30% xylogen goods, under 300 revs/min, making beating 15min, obtains Environment-protecting Drilling Fluids treatment agent, and xylogen goods used are technical grade alkalization xylogen.
4. the method being prepared additive for drilling fluid by green peel of walnut according to claim 1, is characterized in that, comprise the following steps:
The first step, rolls the particle being crushed to diameter 0.2-1cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 7%, soak 60min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 8000 revs/min, pull an oar the green peel of walnut particle soaked by second step 15min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.1%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.8% in above-mentioned green peel of walnut slurry, under 400 revs/min, and making beating 10min, described formaldehyde and Sodium Benzoate are analytical pure product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 50% xylogen goods, under 500 revs/min, making beating 10min, obtain Environment-protecting Drilling Fluids treatment agent, xylogen goods used are technical grade calcium lignin sulphonate.
5. the method being prepared additive for drilling fluid by green peel of walnut according to claim 1, is characterized in that, comprise the following steps:
The first step, rolls the particle being crushed to diameter 0.5-2cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 3%, soak 120min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 12000 revs/min, pull an oar the green peel of walnut particle soaked by second step 12min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 1%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.1% in above-mentioned green peel of walnut slurry, under 500 revs/min, and making beating 5min, described formaldehyde and Sodium Benzoate are technical grade product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 15% xylogen goods, under 300 revs/min, making beating 12min, obtains Environment-protecting Drilling Fluids treatment agent, and xylogen goods used are technical grade alkalization xylogen.
6. the method being prepared additive for drilling fluid by green peel of walnut according to claim 1, is characterized in that, comprise the following steps:
The first step, rolls the particle being crushed to diameter 1-2cm by Cortex walnut, Cortex walnut is the rascal that fresh walnut strips down;
Second step, adds in hollander by above-mentioned green peel of walnut particle, adds the ethanol accounting for green peel of walnut massfraction 10%, soak 50min under normal temperature and pressure, and described ethanol is technical grade product;
3rd step, at normal temperatures and pressures, under 9000 revs/min, pull an oar the green peel of walnut particle soaked by second step 15min;
4th step, adds the formaldehyde solution accounting for green peel of walnut massfraction 0.8%, and accounts for the Sodium Benzoate of green peel of walnut massfraction 0.1% in above-mentioned green peel of walnut slurry, under 300 revs/min, and making beating 10min, described formaldehyde and Sodium Benzoate are chemical pure product;
5th step, add in the green peel of walnut slurry after above-mentioned process and account for green peel of walnut massfraction 20% xylogen goods, under 400 revs/min, making beating 8min, obtain Environment-protecting Drilling Fluids treatment agent, the technical grade alkalization xylogen of xylogen goods used to be mass ratio be 1:1 and calcium lignin sulphonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310568632.3A CN103555298B (en) | 2013-11-15 | 2013-11-15 | Method and the application of additive for drilling fluid is prepared by green peel of walnut |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310568632.3A CN103555298B (en) | 2013-11-15 | 2013-11-15 | Method and the application of additive for drilling fluid is prepared by green peel of walnut |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103555298A CN103555298A (en) | 2014-02-05 |
| CN103555298B true CN103555298B (en) | 2015-10-14 |
Family
ID=50009671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310568632.3A Expired - Fee Related CN103555298B (en) | 2013-11-15 | 2013-11-15 | Method and the application of additive for drilling fluid is prepared by green peel of walnut |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103555298B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107011880B (en) * | 2017-05-22 | 2018-03-23 | 任丘市力科节能材料有限公司 | A kind of high temperature resistance pressure-bearing retaining wall agent and preparation method thereof of drilling fluid, application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4637883A (en) * | 1984-10-17 | 1987-01-20 | Dresser Industries, Inc. | Fluid loss additives for oil base muds and low fluid loss compositions thereof |
| CN102326746A (en) * | 2011-06-13 | 2012-01-25 | 徐春根 | Process for compressively utilizing grapefruits |
| CN103239502A (en) * | 2013-05-23 | 2013-08-14 | 中国科学院成都生物研究所 | Walnut green seedcase extractive, preparation method of extractive, and application of extractive as antioxidant |
| CN103340923A (en) * | 2013-06-20 | 2013-10-09 | 吕梁学院 | Preparation method for walnut tannin |
-
2013
- 2013-11-15 CN CN201310568632.3A patent/CN103555298B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4637883A (en) * | 1984-10-17 | 1987-01-20 | Dresser Industries, Inc. | Fluid loss additives for oil base muds and low fluid loss compositions thereof |
| CN102326746A (en) * | 2011-06-13 | 2012-01-25 | 徐春根 | Process for compressively utilizing grapefruits |
| CN103239502A (en) * | 2013-05-23 | 2013-08-14 | 中国科学院成都生物研究所 | Walnut green seedcase extractive, preparation method of extractive, and application of extractive as antioxidant |
| CN103340923A (en) * | 2013-06-20 | 2013-10-09 | 吕梁学院 | Preparation method for walnut tannin |
Non-Patent Citations (3)
| Title |
|---|
| HCHO与LGV型无铬木质素磺酸盐降粘剂;张黎明;《西南石油学院学报》;19920831;第14卷(第3期);第94-102页 * |
| 树皮酚类制备油田钻井液添加剂的研究;张洁等;《精细化工》;20010831;第18卷(第8期);第479-481页 * |
| 核桃青皮中鞣质的提取与含量测定;薛华丽等;《食品工业科技》;20101231;第31卷(第9期);第279-280和374页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103555298A (en) | 2014-02-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103333268B (en) | The preparation method of lycium ruthenicum polysaccharide | |
| CN102993328B (en) | Method for comprehensively extracting polysaccharides, polyphenol and saponin from camellia oleifera abel defatted cakes | |
| CN103555300B (en) | Method and the application of Environment-protecting Drilling Fluids viscosity reduction fluid loss agent is prepared by Cortex walnut | |
| CN105820598A (en) | Antibacterial textile plant dye and preparation method thereof | |
| CN102807570B (en) | The fragrant fruit of a kind ofization prepares the method for ellagic acid | |
| CN109206393B (en) | Method for extracting flavonoid compounds from young golden pomelo fruits | |
| CN101912445B (en) | Method for extracting general flavonoids from toona sinensis leaves under assistance of surfactant | |
| CN103555298B (en) | Method and the application of additive for drilling fluid is prepared by green peel of walnut | |
| CN104666226A (en) | Floral water containing pummelo peel extract and preparation method of floral water | |
| CN108159100A (en) | A kind of method that Taihang chrysanthemum general flavone is extracted in the chrysanthemum from Taihang | |
| CN103462140B (en) | Low frequency ultrasonic-assisted desugaring and deacidification method for concentrated waxberry juice | |
| CN103463160A (en) | Preparation method of high-content total flavones of chrysanthemum | |
| CN102952636A (en) | Preparation method of fenugreek extract for cigarettes | |
| CN106380458A (en) | Method for extracting anthocyanidin in blueberry | |
| CN103588890B (en) | A kind of method of modifying of citrus plant pericarp and the application in Deal With Drilling Fluid | |
| CN101186757B (en) | Method for producing purple sweet potato haematochrome | |
| CN104072630A (en) | Huangshan iwatake mushroom cold-induced gel polysaccharide and preparation method thereof | |
| CN102614308A (en) | Method for extracting bioactivator in hot chili residue through subcritical water | |
| CN105153096A (en) | Method for extracting procyanidins (OPC) from grape seeds | |
| CN104449595A (en) | Filtrate reducer for drilling fluid and preparation method of filtrate reducer | |
| CN102641316A (en) | Method for extracting bioactive substances from marigold slag through subcritical water extraction technology | |
| CN102807565B (en) | Improved method for extracting berberine | |
| CN103555297B (en) | Method for preparing environment-friendly oil field thickening agent from citrus peel and application | |
| CN107674452B (en) | Method for extracting Dan osmanthus yellow pigment | |
| CN104098636A (en) | Method for extracting rutin from Japanese pagoda tree flowers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Chen Gang Inventor after: Zhang Jie Inventor before: Chen Gang Inventor before: Zhang Jie Inventor before: Song Yingpan Inventor before: Zhang Jianjia Inventor before: Qu Kun |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170504 Address after: 710068 Shaanxi high tech Zone in Xi'an City, the new City Plaza, No. A10-1200: Maple Leaf Patentee after: Shaanxi Jin Ge Bay Industrial Development Co. Ltd. Address before: 710065, No. 18, two east section of electronic road, Yanta District, Shaanxi, Xi'an Patentee before: Xian Petroleum Univ. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180919 Address after: 710075 room 1, 5 units, 1 International Garden, 1 Tang Yan Road, Xi'an High-tech Zone, Shaanxi. Patentee after: Shaanxi Xinfu Han Hai Petroleum Technology Co., Ltd. Address before: 710068 A10-1200, New Town Plaza, maple leaf new town, Xi'an, Shaanxi Patentee before: Shaanxi Jin Ge Bay Industrial Development Co. Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151014 Termination date: 20201115 |