CN103555197A - High-temperature-resisting diffuse reflection paint for LED (light emitting diode) - Google Patents

High-temperature-resisting diffuse reflection paint for LED (light emitting diode) Download PDF

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Publication number
CN103555197A
CN103555197A CN201310597869.4A CN201310597869A CN103555197A CN 103555197 A CN103555197 A CN 103555197A CN 201310597869 A CN201310597869 A CN 201310597869A CN 103555197 A CN103555197 A CN 103555197A
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percent
diffuse reflection
temperature resistant
light
led
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CN201310597869.4A
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桑永树
吴百超
涂如辉
刘军
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Anhui Shilin Lighting Co Ltd
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Anhui Shilin Lighting Co Ltd
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Abstract

The invention relates to high-temperature-resisting diffuse reflection paint for an LED (light emitting diode). The high-temperature-resisting diffuse reflection paint comprises the following raw materials by weight percent: 55 to 82 percent of high-temperature-resisting organic silicon resin, 16 to 25 percent of titanium dioxide, 6 to 12percent of nano diatomite powder, 6 to 12 percent of rare-earth element oxide, 1.5 to 5 percent of a dispersant, 0.5 to 1 percent of a flattening agent, 0.5 to 1 percent of an antifoaming agent, 5 to 15 percent of a light dispersant and 5 to 15 percent of butyl acetate and a mixed solvent. The preparation process is simple and easy to realize and high in production efficiency; by adding the nano material, the heat radiating effect is remarkably improved; by adding the rare-earth element oxide, the activity of the paint composition is improved, the paint can work normally under the high-temperature situation, the diffuse reflection effect is good, the light is soft and uniform, the utilization rate of the light energy is high, the light intensity is greatly enhanced, the cost of a light source can be greatly saved, and the power consumption of the product can be reduced.

Description

The high temperature resistant diffuse reflection coating that a kind of LED uses
Technical field:
The present invention relates to a kind of coating material production field, be specially the high temperature resistant diffuse reflection coating that a kind of LED uses.
Background technology:
LED is solid cold light source of new generation, with its impayable energy-saving and environmental protection, long lifetime, controllability high-technology advantage, can be widely used in the fields such as various indications, demonstration, decoration, backlight, general lighting and urban landscape.China has issued national semiconductor lighting plan in 2003, and has write into national medium-term and long-term development in science and technology plan.LED semiconductor energy-saving lighting engineering will become one of main flow direction of following Lighting Industry.Along with the technology of LED semiconductor grain is in recent years constantly progressive, its function expands illumination to from showing, LED semi-conductor becomes the optimal selection of alternative conventional incandescent and luminescent lamp solid light source gradually, is one of main flow direction of following new light sources.
But LED electricity-saving lamp, due to itself, also has the following disadvantages:
(1) LED electricity-saving lamp is the same with ordinary incandescent lamp under alternating-current drives has stroboscopic phenomenon, and common energy-saving lamp does not have stroboscopic phenomenon.Stroboscopic can make eyes easily tired.
(2) light of each LED bulb is excessively bright, and meeting intense stimulus eyes, can not look at straight, even the short period of time, and common energy-saving lamp is relatively softer.
(3) irradiating angle is restricted, generally can only irradiate 120 °, and common energy-saving lamp almost can irradiate 360 °.
(4) brightness in irradiation room is outstanding unlike electricity-saving lamp, because LED only has high brightness in the narrow and small angle of direct-view, and after departing from this angle, light weakens rapidly.
For this reason, must adopt appropriate means to overcome above shortcoming, and carry out soft LED light by diffuse-reflectance coating, expand shadow surface, a kind of practicable method of can yet be regarded as.Chinese patent CN101126487 (A) discloses a kind of LED nano energy-saving environment-friendly road lamp, the surface of its nanometer reflection plate has photocatalyst coating, both solved the direct projection problem of LED lamp, the illumination that is conducive to again LED promotes photocatalyst reaction, can dustproof sterilizing, self keeps a public place clean, and purifies air, and plays the effect of environmental protection.Chinese patent CN1768231A discloses a kind of means of illumination, and its case has been equipped with diffuse-reflectance coating, and coating comprises a kind of water-based solvent and a kind of binding agent.
Existing diffuse reflection coating, visible ray diffuse-reflectance efficiency is low, and heat-resistant stable is poor, and in addition, for guaranteeing that coating has higher reflectivity, the content of reflectivity particle is generally higher, often causes the not good problem of coating and matrix adhesive force.Application at present comparatively successfully has the diffuse reflection coating 6080 of blue luxuriant and rich with fragrance optics, adopt baric sulphur formula, in visible wavelength region internal reflection rate value, can reach 95%, but this coating only can be used under the environment lower than 80 ℃, if higher than this temperature, this diffuse reflection coating is by the even roasting paste of obvious xanthochromia, the even no-reflection effect of reflectivity degradation.
Summary of the invention:
The high temperature resistant diffuse reflection coating that provides a kind of LED to use is provided the object that the present invention will solve, to solve the problem in background technology.
Technical problem solved by the invention realizes by the following technical solutions:
A high temperature resistant diffuse reflection coating of using, is characterized in that, each component and the weight percent thereof of raw material are as follows:
High-temperature resistant organic silicon resin: 55~82%, titanium dioxide: 16~25%,
Nano diatomite powder: 6~12%, rare earth oxide: 6~12%,
Dispersion agent: 1.5~5%, flow agent: 0.5~1%,
Defoamer: 0.5~1%, light diffusing agent: 5~15%,
Butylacetate: 1~5%, mixed solvent: 5~15%;
As a kind of optimization of above technical scheme, each component and the weight percent thereof of raw material are as follows:
High-temperature resistant organic silicon resin: 60~70%, titanium dioxide: 20~22%,
Nano diatomite powder: 8~10%, rare earth oxide: 9~10%,
Dispersion agent: 1.5~3%, flow agent: 0.5~0.8%,
Defoamer: 0.5~0.8%, light diffusing agent: 6~12%,
Butylacetate: 2~5%, mixed solvent: 8~10%.
A kind of optimization as above technical scheme: the particle size diameter of described rare earth oxide is 3~10 μ m.
A kind of optimization as above technical scheme: described high-temperature resistant organic silicon resin is for tolerating poly-alkyl organic resin, epoxy modified silicone resin or the fluorine silicon resin of 100~160 ℃ of high temperature.
A kind of optimization as above technical scheme: described mixed solvent is the mixing solutions of butylacetate and dimethylbenzene.
Beneficial effect of the present invention: the high temperature resistant diffuse reflection coating that LED provided by the invention uses has better mechanical property and sticking power, can be coated with and be contained on all kinds of LED light fixtures, adds nano material, significantly improving radiating effect; Add rare earth oxide, improve the activity of coating composition, under high-temperature condition, work, diffuse effect is good, and light is soft, and evenly the efficiency of light energy utilization is high, greatly strengthens luminance brightness, can save largely the power consumption of light source cost and reduction product.
Embodiment:
In order to make technique means of the present invention, creation characteristic, workflow, using method reach object and effect is easy to understand, below in conjunction with specific embodiment, further set forth the present invention.
Embodiment 1
The high temperature resistant diffuse reflection coating that a kind of LED uses, each component and the weight percent thereof of raw material are as follows: high-temperature resistant organic silicon resin: 55%, titanium dioxide: 16%, nano diatomite powder: 6%, rare earth oxide: 6%, dispersion agent: 1.5%, flow agent: 0.5%, defoamer: 0.5%, light diffusing agent: 5%, butylacetate: 1%, the mixed solvent of butylacetate and dimethylbenzene: 5%;
Then by the part by weight of 5:1, high-temperature resistant organic silicon resin is dissolved completely with mixed solvent at normal temperatures, then by stirring and be slowly heated to 80 ℃ with steam in the titanium dioxide of the high-temperature resistant organic silicon resin solution after dissolving and corresponding proportional quantity, nano diatomite powder, rare earth oxide, dispersion agent input reactor, keep isothermal reaction 2 hours;
Again pyrosol is carried out to underpressure distillation and slough butylacetate and dimethylbenzene mixed solvent wherein, underpressure distillation starts sampling and testing reactant fugitive constituent per hour after 3 hours, when fugitive constituent is less than 1%, while hot reactant is discarded to feed basin, question response thing is fully cooling obtains modified mixture by fragmentation;
After obtaining again modified mixture mixture and being transferred to ball mill and grinding; with 300 eye mesh screens, filter macrobead mixture; the mixture grinding after screening is transferred in high speed dispersor; and the flow agent of corresponding weight proportion, defoamer, butylacetate and light diffusing agent are added and in high speed dispersor, carry out dispersing and mixing; with Hegman grind gage, detect during this time fineness and the viscosity of mixture; when the fineness of mixture reaches 20 μ m, viscosity 26s, make coating.
Embodiment 2
The high temperature resistant diffuse reflection coating that a kind of LED uses, each component and the weight percent thereof of raw material are as follows: high-temperature resistant organic silicon resin: 82%, titanium dioxide: 25%, nano diatomite powder: 12%, rare earth oxide: 12%, dispersion agent: 5%, flow agent: 1%, defoamer: 1%, light diffusing agent: 15%, butylacetate: 5%, butylacetate and dimethylbenzene mixed solvent: 15%;
Then by the part by weight of 5:1, high-temperature resistant organic silicon resin is dissolved completely with mixed solvent at normal temperatures, then by stirring and be slowly heated to 80 ℃ with steam in the titanium dioxide of the high-temperature resistant organic silicon resin solution after dissolving and corresponding proportional quantity, nano diatomite powder, rare earth oxide, dispersion agent input reactor, keep isothermal reaction 2 hours;
Again pyrosol is carried out to underpressure distillation and slough butylacetate and dimethylbenzene mixed solvent wherein, underpressure distillation starts sampling and testing reactant fugitive constituent per hour after 3 hours, when fugitive constituent is less than 1%, while hot reactant is discarded to feed basin, question response thing is fully cooling obtains modified mixture by fragmentation;
After obtaining again modified mixture mixture and being transferred to ball mill and grinding; with 300 eye mesh screens, filter macrobead mixture; the mixture grinding after screening is transferred in high speed dispersor; and the flow agent of corresponding weight proportion, defoamer, butylacetate and light diffusing agent are added and in high speed dispersor, carry out dispersing and mixing; with Hegman grind gage, detect during this time fineness and the viscosity of mixture; when the fineness of mixture reaches 20 μ m, viscosity 20s, make coating.
Embodiment 3
The high temperature resistant diffuse reflection coating that a kind of LED uses, each component and the weight percent thereof of raw material are as follows: high-temperature resistant organic silicon resin: 69%, titanium dioxide: 20%, nano diatomite powder: 9%, rare earth oxide: 9%, dispersion agent: 3%, flow agent: 0.8%, defoamer: 0.8%, light diffusing agent: 10%, butylacetate: 3%, butylacetate and dimethylbenzene mixed solvent: 10%;
Then by the part by weight of 5:1, high-temperature resistant organic silicon resin is dissolved completely with mixed solvent at normal temperatures, then by stirring and be slowly heated to 80 ℃ with steam in the titanium dioxide of the high-temperature resistant organic silicon resin solution after dissolving and corresponding proportional quantity, nano diatomite powder, rare earth oxide, dispersion agent input reactor, keep isothermal reaction 2 hours;
Again pyrosol is carried out to underpressure distillation and slough butylacetate and dimethylbenzene mixed solvent wherein, underpressure distillation starts sampling and testing reactant fugitive constituent per hour after 3 hours, when fugitive constituent is less than 1%, while hot reactant is discarded to feed basin, question response thing is fully cooling obtains modified mixture by fragmentation;
After obtaining again modified mixture mixture and being transferred to ball mill and grinding; with 300 eye mesh screens, filter macrobead mixture; the mixture grinding after screening is transferred in high speed dispersor; and the flow agent of corresponding weight proportion, defoamer, butylacetate and light diffusing agent are added and in high speed dispersor, carry out dispersing and mixing; with Hegman grind gage, detect during this time fineness and the viscosity of mixture; when the fineness of mixture reaches 20 μ m, viscosity 24s, make coating.
Above-mentioned high-temperature resistant organic silicon resin is for tolerating poly-alkyl organic resin, epoxy modified silicone resin or the fluorine silicon resin of 100~160 ℃ of high temperature and the particle size diameter of the rare earth oxide that uses is 3~10 μ m.
The product that comparative example 1, embodiment 2 and embodiment 3 obtain, the coating that wherein embodiment 3 makes in use, good heat dissipation effect; Under high-temperature condition, work, diffuse effect is good, and light is soft evenly, and the efficiency of light energy utilization is high, greatly strengthens luminance brightness.Coating can be worked at 100 ℃ and above temperature, and be difficult for xanthochromia and aging occurs, can not crack, reflectivity can reach more than 96%.Utilize titanium dioxide to the random diffuse-reflectance of light, make through light transmition direction there is irregular change, be equivalent to numerous secondary light source, make light become soft evenly, luminous energy is not suffered a loss substantially, greatly improves the light output efficiency of LED light fixture.
More than show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification sheets, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Claimed scope of the present invention is defined by appending claims and equivalent thereof.

Claims (5)

1. the high temperature resistant diffuse reflection coating that LED uses, is characterized in that: each component and the weight percent thereof of raw material are as follows:
High-temperature resistant organic silicon resin: 55~82%, titanium dioxide: 16~25%,
Nano diatomite powder: 6~12%, rare earth oxide: 6~12%,
Dispersion agent: 1.5~5%, flow agent: 0.5~1%,
Defoamer: 0.5~1%, light diffusing agent: 5~15%,
Butylacetate: 1~5%, mixed solvent: 5~15%.
2. the high temperature resistant diffuse reflection coating that a kind of LED according to claim 1 uses, is characterized in that: each component and the weight percent thereof of raw material are as follows:
High-temperature resistant organic silicon resin: 60~70%, titanium dioxide: 20~22%,
Nano diatomite powder: 8~10%, rare earth oxide: 9~10%,
Dispersion agent: 1.5~3%, flow agent: 0.5~0.8%,
Defoamer 0.5~0.8%, light diffusing agent 6~12%,
Butylacetate: 2~5%, mixed solvent: 8~10%.
3. the high temperature resistant diffuse reflection coating that a kind of LED according to claim 1 and 2 uses, is characterized in that: the particle size diameter of described rare earth oxide is 3~10 μ m.
4. the high temperature resistant diffuse reflection coating that a kind of LED according to claim 1 and 2 uses, is characterized in that: described high-temperature resistant organic silicon resin is for tolerating poly-alkyl organic resin, epoxy modified silicone resin or the fluorine silicon resin of 160~200 ℃ of high temperature.
5. the high temperature resistant diffuse reflection coating that a kind of LED according to claim 1 and 2 uses, is characterized in that: described mixed solvent is the mixing solutions of butylacetate and dimethylbenzene.
CN201310597869.4A 2013-11-22 2013-11-22 High-temperature-resisting diffuse reflection paint for LED (light emitting diode) Pending CN103555197A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449355A (en) * 2014-11-24 2015-03-25 侨健新能源科技(苏州)有限公司 Method for preparing high temperature resistant diffuse reflection coating
CN104817952A (en) * 2015-04-30 2015-08-05 佛山市禾才科技服务有限公司 High-temperature-resistant, reflection-resistant and aging-resistant heat-dissipating powder coating and preparation method thereof
CN105585917A (en) * 2015-12-18 2016-05-18 李小鹏 Water-based light diffusion coating and preparation method thereof
CN105985719A (en) * 2015-02-09 2016-10-05 文豪 Waterproof explosion-proof LED lamp tube coating and preparation method thereof
CN113437196A (en) * 2021-06-24 2021-09-24 深圳市华皓伟业光电有限公司 SMD packaging and forming method with large divergence angle

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1995250A (en) * 2006-01-04 2007-07-11 北京国邦技术发展中心 Thermostable heat-isolating coating and its preparation method
CN102277044A (en) * 2011-07-12 2011-12-14 北京展辰化工有限公司 Bamboo charcoal odor-removing antibacterial emulsion paint and preparation method thereof
CN102321433A (en) * 2011-08-15 2012-01-18 东莞上海大学纳米技术研究院 Preparation method of high temperature resistant and diffuse reflection coating for LED and coating thereof
CN102329501A (en) * 2010-03-30 2012-01-25 信越化学工业株式会社 Resin composition, reflector for light-emitting semiconductor device, and light-emitting semiconductor unit

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1995250A (en) * 2006-01-04 2007-07-11 北京国邦技术发展中心 Thermostable heat-isolating coating and its preparation method
CN102329501A (en) * 2010-03-30 2012-01-25 信越化学工业株式会社 Resin composition, reflector for light-emitting semiconductor device, and light-emitting semiconductor unit
CN102277044A (en) * 2011-07-12 2011-12-14 北京展辰化工有限公司 Bamboo charcoal odor-removing antibacterial emulsion paint and preparation method thereof
CN102321433A (en) * 2011-08-15 2012-01-18 东莞上海大学纳米技术研究院 Preparation method of high temperature resistant and diffuse reflection coating for LED and coating thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449355A (en) * 2014-11-24 2015-03-25 侨健新能源科技(苏州)有限公司 Method for preparing high temperature resistant diffuse reflection coating
CN105985719A (en) * 2015-02-09 2016-10-05 文豪 Waterproof explosion-proof LED lamp tube coating and preparation method thereof
CN104817952A (en) * 2015-04-30 2015-08-05 佛山市禾才科技服务有限公司 High-temperature-resistant, reflection-resistant and aging-resistant heat-dissipating powder coating and preparation method thereof
CN105585917A (en) * 2015-12-18 2016-05-18 李小鹏 Water-based light diffusion coating and preparation method thereof
CN113437196A (en) * 2021-06-24 2021-09-24 深圳市华皓伟业光电有限公司 SMD packaging and forming method with large divergence angle

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Application publication date: 20140205