CN103554604A - Low-temperature impact-resistant tubular product - Google Patents

Low-temperature impact-resistant tubular product Download PDF

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Publication number
CN103554604A
CN103554604A CN201310524457.8A CN201310524457A CN103554604A CN 103554604 A CN103554604 A CN 103554604A CN 201310524457 A CN201310524457 A CN 201310524457A CN 103554604 A CN103554604 A CN 103554604A
Authority
CN
China
Prior art keywords
parts
temperature impact
raw material
low
tubular product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310524457.8A
Other languages
Chinese (zh)
Inventor
徐全茂
夏传兴
吴文利
孔德成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUOTONG NOVEL PIPES CO Ltd ANHUI
Original Assignee
GUOTONG NOVEL PIPES CO Ltd ANHUI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUOTONG NOVEL PIPES CO Ltd ANHUI filed Critical GUOTONG NOVEL PIPES CO Ltd ANHUI
Priority to CN201310524457.8A priority Critical patent/CN103554604A/en
Publication of CN103554604A publication Critical patent/CN103554604A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a low-temperature impact-resistant tubular product, which is characterized by being composed of the following raw materials in parts by weight: 70-76 parts of polyethylene GF7750, 4-6 parts of drying oil alkyd resin, 2-3 parts of ethylene-octene copolymer, 1-2 parts of diacetone alcohol, 0.7-2 parts of triclosan, 2-3 parts of polyimide, 3-4 parts of di(2-ethylhexyl)-epoxy tetrahydrophthalate, 2-3 parts of carbon fibers, 3-4 parts of illite powder, 2-3 parts of aluminum stearate and 5-7 parts of composite filler. The PE pipe provided by the invention is prepared from recycled polyethylene material so that the production cost is reduced and resources are saved; the tubular product provided by the invention has excellent low-temperature impact resistance; for construction in winter, pipe breakage is avoided; the low-temperature impact-resistant tubular product also has high shear strength and excellent scratch resistance.

Description

A kind of low temperature impact tubing
Technical field
The present invention relates generally to a kind of tubing, relates in particular to a kind of low temperature impact tubing.
Background technology
Pvc pipe (UPVC pipe) hard polvinyl choride pipe, is to use pressure sintering extrusion molding after being coordinated with stablizer, lubricant etc. by polyvinyl chloride (PVC) RESINS, is the plastic pipe being developed and applied the earliest.UPVC pipe resistance to corrosion is strong, it is bonding to be easy to, price is low, quality is hard, but owing to having UPVC monomer and additive exudation, is only applicable in water feeding system that delivery temperature is no more than 45 ℃.Plastic conduit is for delivery of tap water, waste water, chemical, heating fluid and cooling fluid, food, ultrarapture liquid, mud, gas, the application of pressurized air and vacuum system.
PE pipe has medium-density polyethylene pipe and high density polyethylene pipe.The former is applicable to carry artificial coal gas, Sweet natural gas, the liquefied petroleum gas (LPG) of gaseous state, and the latter is mainly for delivery of Sweet natural gas.With steel pipe comparison, construction technology is simple, has certain snappiness, and main is to be not used as rotproofing, will save a large amount of operations.Shortcoming is with regard to apparatus not as steel pipe, and the special safe spacing of noting heating power heating in construction, and can not being exposed in air under sunlight, and responsive to chemical substance, prevents that the leakage of sewer line from damaging.
Summary of the invention
The object of the invention is just to provide a kind of low temperature impact tubing.
The present invention is achieved by the following technical solutions:
A tubing, it is comprised of the raw material of following weight parts:
Polyethylene GF7750 70-76, drying oil alkyd resin 4-6, ethylene-octene copolymer 2-3, diacetone alcohol 1-2, triclosan 0.7-2, polyimide 2-3, epoxy tetrahydro-2-ethylhexyl phthalate 3-4, the stone flour 3-4 of carbon fiber 2-3, Erie, aluminum stearate 2-3, compounded mix 5-7;
Described compounded mix is comprised of the raw material of following weight parts:
Chrysotile 30-40, gibbsite 10-15, chromium carbonate 3-5, ricinolic acid 1-2, aluminium hydroxide 1-2, methacrylic acid-2-hydroxy methacrylate 2-3, glyceryl monostearate 4-5, linking agent TAC1-2,butyl polyacrylate 2.5-4, irgasfos 168 0.4-1;
By gibbsite and chrysotile, chromium carbonate mix and blend, pulverize, add ricinolic acid, 400-600 rev/min of dispersed with stirring 3-5 minute, add aluminium hydroxide, butyl polyacrylate, at 100-160 ℃, insulated and stirred 40-50 minute, is cooled to normal temperature, adds each raw material of residue, fully stir, dry, granulation, particle diameter is 2-4 μ m.
A preparation method for low temperature impact tubing, comprises the following steps:
Above-mentioned each raw material is mixed, send into kneader, at 70-80 ℃, mediate, discharging is cooled to normal temperature, melt extrudes, and cooling, moulding obtains described low temperature impact tubing.
Advantage of the present invention is:
Tubing of the present invention has good low-temperature impact resistance, while constructing in the winter time, tube brakes can not occur, and also has high shearing resistance and excellent anti-scratch trace ability.
Embodiment
Embodiment 1
A tubing, it by following weight parts (kilogram) raw material form:
Polyethylene GF7750 76, drying oil alkyd resin 6, ethylene-octene copolymer 3, diacetone alcohol 1, triclosan 0.7, polyimide 2, epoxy tetrahydro-2-ethylhexyl phthalate 3, carbon fiber 3, Erie's stone flour 3, aluminum stearate 2, compounded mix 5;
Described compounded mix is comprised of the raw material of following weight parts:
Chrysotile 40, gibbsite 15, chromium carbonate 5, ricinolic acid 1, aluminium hydroxide 2, methacrylic acid-2-hydroxy methacrylate 3, glyceryl monostearate 4, linking agent TAC1,butyl polyacrylate 4, irgasfos 168 1;
By gibbsite and chrysotile, chromium carbonate mix and blend, pulverize, add ricinolic acid, 600 revs/min of dispersed with stirring 5 minutes, add aluminium hydroxide, butyl polyacrylate, at 160 ℃, insulated and stirred is 50 minutes, is cooled to normal temperature, adds each raw material of residue, fully stir, dry, granulation, particle diameter is 4 μ m.
A preparation method for low temperature impact tubing, comprises the following steps:
Above-mentioned each raw material is mixed, send into kneader, at 80 ℃, mediate, discharging is cooled to normal temperature, melt extrudes, and cooling, moulding obtains described low temperature impact tubing.
Performance test:
Impact property (TIR) :≤10%;
Ring stiffness (KN/m 2): 13.1;
Ring is flexible: sample is round and smooth, crack-free, and two walls are without disengagement, without reverse bending;
Baking oven experiment (110 ℃, 30min): without layering, without cracking, without bubble.

Claims (2)

1. a low temperature impact tubing, is characterized in that what it was comprised of the raw material of following weight parts
Polyethylene GF7750 70-76, drying oil alkyd resin 4-6, ethylene-octene copolymer 2-3, diacetone alcohol 1-2, triclosan 0.7-2, polyimide 2-3, epoxy tetrahydro-2-ethylhexyl phthalate 3-4, the stone flour 3-4 of carbon fiber 2-3, Erie, aluminum stearate 2-3, compounded mix 5-7;
Described compounded mix is comprised of the raw material of following weight parts:
Chrysotile 30-40, gibbsite 10-15, chromium carbonate 3-5, ricinolic acid 1-2, aluminium hydroxide 1-2, methacrylic acid-2-hydroxy methacrylate 2-3, glyceryl monostearate 4-5, linking agent TAC1-2,butyl polyacrylate 2.5-4, irgasfos 168 0.4-1;
By gibbsite and chrysotile, chromium carbonate mix and blend, pulverize, add ricinolic acid, 400-600 rev/min of dispersed with stirring 3-5 minute, add aluminium hydroxide, butyl polyacrylate, at 100-160 ℃, insulated and stirred 40-50 minute, is cooled to normal temperature, adds each raw material of residue, fully stir, dry, granulation, particle diameter is 2-4 μ m.
2. a preparation method for low temperature impact tubing as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned each raw material is mixed, send into kneader, at 70-80 ℃, mediate, discharging is cooled to normal temperature, melt extrudes, and cooling, moulding obtains described low temperature impact tubing.
CN201310524457.8A 2013-10-30 2013-10-30 Low-temperature impact-resistant tubular product Pending CN103554604A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310524457.8A CN103554604A (en) 2013-10-30 2013-10-30 Low-temperature impact-resistant tubular product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310524457.8A CN103554604A (en) 2013-10-30 2013-10-30 Low-temperature impact-resistant tubular product

Publications (1)

Publication Number Publication Date
CN103554604A true CN103554604A (en) 2014-02-05

Family

ID=50008979

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310524457.8A Pending CN103554604A (en) 2013-10-30 2013-10-30 Low-temperature impact-resistant tubular product

Country Status (1)

Country Link
CN (1) CN103554604A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194201A (en) * 2014-07-29 2014-12-10 锐展(铜陵)科技有限公司 Low-temperature-resistant high impact PVC (polyvinyl chloride) tubular product and preparation method thereof
CN105062026A (en) * 2015-08-06 2015-11-18 安徽电信器材贸易工业有限责任公司 Preparation method of impact-resistance environmentally-friendly resin communication tubing
CN110818984A (en) * 2019-11-15 2020-02-21 冯彦林 Plastic composite pipe and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102617914A (en) * 2012-04-01 2012-08-01 广东三凌塑料管材有限公司 Polyethylene cable duct
CN102649848A (en) * 2011-08-16 2012-08-29 上海公元建材发展有限公司 Toughness-improved HDPE (High-Density Polyethylene) trenchless tubular product

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102649848A (en) * 2011-08-16 2012-08-29 上海公元建材发展有限公司 Toughness-improved HDPE (High-Density Polyethylene) trenchless tubular product
CN102617914A (en) * 2012-04-01 2012-08-01 广东三凌塑料管材有限公司 Polyethylene cable duct

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194201A (en) * 2014-07-29 2014-12-10 锐展(铜陵)科技有限公司 Low-temperature-resistant high impact PVC (polyvinyl chloride) tubular product and preparation method thereof
CN105062026A (en) * 2015-08-06 2015-11-18 安徽电信器材贸易工业有限责任公司 Preparation method of impact-resistance environmentally-friendly resin communication tubing
CN110818984A (en) * 2019-11-15 2020-02-21 冯彦林 Plastic composite pipe and preparation method thereof

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Application publication date: 20140205

RJ01 Rejection of invention patent application after publication