CN103553854A - High-energy infrared-radiation incendiary agent - Google Patents
High-energy infrared-radiation incendiary agent Download PDFInfo
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- CN103553854A CN103553854A CN201310467816.0A CN201310467816A CN103553854A CN 103553854 A CN103553854 A CN 103553854A CN 201310467816 A CN201310467816 A CN 201310467816A CN 103553854 A CN103553854 A CN 103553854A
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- high energy
- incendiary material
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Abstract
The invention discloses a high-energy infrared-radiation incendiary agent. The incendiary agent comprises, by mass, 30 to 40% of polytetrafluoroethylene, 30 to 45% of magnesium powder, 5 to 10% of a phenolic resin, 10 to 30% of a nanometer composite thermite and 3 to 8% of a slagging flux. During combustion of the incendiary agent, infrared radiation covers wavebands in ranges of 3 to 5 mu m and 8 to 14 mu m, and specific radiant energy are respectively no less than 187 J/g/Sr and 35 J/g/Sr. According to the invention, the high-energy infrared-radiation incendiary agent can generate strong infrared radiation during combustion, so thermal conduction performance of an igniting (or flame-transferring) reagent can be effectively enhanced.
Description
Technical field
The invention belongs to energetic material technical field, particularly can produce the high energy ir radiation incendiary material of high energy ir radiation output during a kind of burning.
Background technology
Magnesium/tetrafluoroethylene have containing can be high, flameholding, making is simple and safe, with low cost and have the features such as good consistency with other components, it is widely used in igniting (or passing fire) medicament of car safety air bag and rocket engine as incendiary material.According to heat transfer theory, the ir radiation producing in magnesium/tetrafluoroethylene combustion processes is the heat conducting important channel of ignition powder.Therefore, the infrared radiation property of research raising incendiary material is the research emphasis in this field.And in the situation that equipment load is certain, being subject to the restriction of volume and weight, infrared energy when emphasis need to improve the burning of incendiary material unit mass, than radiating capacity.
At present, Chinese scholars, for improving the ratio radiating capacity of magnesium/tetrafluoroethylene incendiary material, has been carried out the research of a large amount of this respects.Chen Minghua studied magnalium as combustible agent proportionings different from tetrafluoroethylene, in magnesium/tetrafluoroethylene incendiary material, add the impact on incendiary material radiance such as carbon fiber, result shows that the best than radiating capacity is: 3-5 mu m waveband 134.9Jg
-1sr
-1, 8-14 mu m waveband 16.39Jg
-1sr
-1(the .Mg such as Chen Minghua
4al
3the radiance research of/PTFE infrared decoy agent. laser and infrared, 2005,35 (7): 500-503; Chen Minghua, Ma Zhuhai. the impact of carbon fiber on magnesium/tetrafluoroethylene combustionvelocity and infrared intensity. laser and infrared, 2008,38 (10): 1008-1010).Ernst-Christian Koch adds Fe in magnesium/tetrafluoroethylene incendiary material
2o
3/ Si composite particles, result shows than radiating capacity at 3-5 mu m waveband 139Jg
-1sr
-1(Ernst-Christian Koch.Metal – Fluorocarbon Pyrolants:X.Influence of Ferric Oxide/Silicon Additive on Burn Rate and Radiometric Performance of Magnesium/Teflon/Viton (MTV) .Propellants Explos.Pyrotech, 2009,34:472-474).
Aforesaid method only by increase combustible agent kind, regulate combustible agent and tetrafluoroethylene proportioning, add non-energetic material or granularity is the ratio radiating capacity that micron-sized composite particles improves magnesium/tetrafluoroethylene incendiary material, its effect is very limited, and the infrared energy producing during burning is strong not.
Summary of the invention
The object of the present invention is to provide a kind of high energy ir radiation incendiary material, during burning, can produce strong infrared energy.
The technical solution that realizes the object of the invention is: a kind of high energy ir radiation incendiary material, and its component and content are:
Described content is mass percent.
The granularity of described tetrafluoroethylene is 200~325 orders.
The granularity of described magnesium powder is 325~500 orders.
Described nano combined term is one or both in following combination: Ni/SiO
2nano combined term, B/SiO
2nano combined term.
Described Ni/SiO
2the component of nano combined term and quality percentage composition are:
Nano Ni Powder 61%,
Nanometer SiO
234%,
Two-11 standard double-base powders 5%.
Described B/SiO
2the component of nano combined term and quality percentage composition are:
Nanometer B powder 19%,
Nanometer SiO
276%,
Two-11 standard double-base powders 5%.
Described slag former is CaF
2, CaSO
4in one or both.
The granularity of described slag former is 200-300 order.
The present invention compared with prior art, its remarkable advantage:
1, infrared higher than radiating capacity: infrared than the significant raising of radiating capacity at 3~5 μ m and 8~14 mu m wavebands;
2, dosing is economized: because unit mass medicament quantity of radiant energy improves, can reduce the usage quantity of medicament, thereby alleviate the load of instrument and equipment.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
In the embodiment of the present invention raw materials used be commercially available.
The preparation method of the nano combined term of each embodiment and incendiary material is identical, all carries out in the steps below.
In high energy ir radiation incendiary material of the present invention, the preparation method of nano combined term is:
Accurately take Nano Ni Powder or B powder and SiO
2, fully mix;
Two-11 (code name S-11) standards of general are acetone (two-11 (code name S-11) standard double-base powders of 1g: 5ml acetone) dissolve, evenly mix with above-mentioned uniform powder, with 120 order granulations, naturally dry standby for double-base powder.
High energy ir radiation incendiary material preparation method of the present invention is:
A, mixed medicine: accurately weigh above-mentioned nano combined term, magnesium powder, tetrafluoroethylene and slag former, fully mix, add ethanolic soln (the 1g resol: 1ml dehydrated alcohol) mix, with 60-80 mesh sieve granulations, naturally dry containing resol under hygrometric state;
B, moulding: the powder column that said mixture material is pressed in mould to definite shape and density.
Ratio radiating capacity test instrument and condition in each embodiment are as shown in table 1.
Table 1 is than radiating capacity testing tool and test condition
Embodiment 1
High energy ir radiation incendiary material forms and content: tetrafluoroethylene 200 orders 30%, magnesium powder 325 orders 35%, resol 5%, Ni/SiO
2nano combined term 25%, CaF
2slag former 200 orders 5%, all percentage ratio is mass percent.
Be prepared into as stated above powder column, light, test is than radiating capacity, and result is as shown in table 2.
Embodiment 2
High energy ir radiation incendiary material forms and content: tetrafluoroethylene 325 orders 35%, magnesium powder 500 orders 40%, resol 5%, Ni/SiO
2compound term 15%, CaF
2slag former 300 orders 5%, all percentage ratio is mass percent.
Be prepared into as stated above powder column, light, test is than radiating capacity, and result is as shown in table 2.
Embodiment 3
High energy ir radiation incendiary material forms and content: tetrafluoroethylene 200 orders 30%, magnesium powder 325 orders 35%, resol 5%, B/SiO
2compound term 25%, CaSO
4slag former 200 orders 5%, all percentage ratio is mass percent.
Be prepared into as stated above powder column, light, test is than radiating capacity, and result is as shown in table 2.
Embodiment 4
High energy ir radiation incendiary material forms and content: tetrafluoroethylene 325 orders 35%, magnesium powder 500 orders 40%, resol 5%, B/SiO
2compound term 15%, CaSO
4slag former 300 orders 5%, all percentage ratio is mass percent.
Be prepared into as stated above powder column, light, test is than radiating capacity, and result is as shown in table 2.
Embodiment 5
High energy ir radiation incendiary material and content: tetrafluoroethylene 200 orders 30%, magnesium powder 325 orders 35%, resol 5%, Ni/SiO
2nano combined term 12%, B/SiO
2nano combined term 12%, CaF
2slag former 200 orders 3%, CaSO
4slag former 200 orders 3%, all percentage ratio is mass percent.
Be prepared into as stated above powder column, light, test is than radiating capacity, and result is as shown in table 2.
Comparative example
Take light a fire at present or starting mix agent in conventional ir radiation incendiary material be comparative example.
Ir radiation incendiary material forms and content: tetrafluoroethylene 325 orders 44%, and magnesium powder 500 orders 51%, resol 5%, all percentage ratio is mass percent.
Be prepared into as stated above powder column, light, test is than radiating capacity, and result is as shown in table 2.
Ratio radiating capacity when each embodiment of table 2 and comparative example burning
Test result shows, high energy ir radiation incendiary material of the present invention at the ratio radiating capacity of 3~5 μ m and 8~14 mu m wavebands apparently higher than comparative example and other disclosed incendiary materials; In addition, because unit mass medicament quantity of radiant energy improves, can reduce the usage quantity of medicament, thereby alleviate the load of instrument and equipment.
Claims (8)
2. high energy ir radiation incendiary material according to claim 1, is characterized in that: the granularity of described tetrafluoroethylene is 200~325 orders.
3. high energy ir radiation incendiary material according to claim 1, is characterized in that: the granularity of described magnesium powder is 325~500 orders.
4. high energy ir radiation incendiary material according to claim 1, is characterized in that, described nano combined term is one or both in following combination: Ni/SiO
2nano combined term, B/SiO
2nano combined term.
5. high energy ir radiation incendiary material according to claim 4, is characterized in that: described Ni/SiO
2the component of nano combined term and quality percentage composition are:
Nano Ni Powder 61%,
Nanometer SiO
234%,
Two-11 standard double-base powders 5%.
6. high energy ir radiation incendiary material according to claim 4, is characterized in that: described B/SiO
2the component of nano combined term and quality percentage composition are:
Nanometer B powder 19%,
Nanometer SiO
276%,
Two-11 standard double-base powders 5%.
7. high energy ir radiation incendiary material according to claim 1, is characterized in that: described slag former is CaF
2, CaSO
4in one or both.
8. high energy ir radiation incendiary material according to claim 7, is characterized in that: the granularity of described slag former is 200-300 order.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105175201A (en) * | 2015-09-03 | 2015-12-23 | 南京理工大学 | Multi-molten slag incendiary agent and preparation method thereof |
CN105218280A (en) * | 2015-09-03 | 2016-01-06 | 南京理工大学 | Many slags magnesium-polytetrafluoroethylene (PTFE) base incendiary material and preparation method thereof |
Citations (4)
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US4402774A (en) * | 1981-11-20 | 1983-09-06 | Hi-Shear Corporation | Pyrotechnic composition |
CN1603289A (en) * | 2004-10-08 | 2005-04-06 | 中国科学院长春应用化学研究所 | Long wave infrared burning radiation medicine |
US8048242B1 (en) * | 2007-04-05 | 2011-11-01 | Sandia Corporation | Nanocomposite thermite ink |
CN102925120A (en) * | 2012-11-08 | 2013-02-13 | 中国人民解放军理工大学 | Thermit and preparation method thereof |
-
2013
- 2013-10-09 CN CN201310467816.0A patent/CN103553854B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US4402774A (en) * | 1981-11-20 | 1983-09-06 | Hi-Shear Corporation | Pyrotechnic composition |
CN1603289A (en) * | 2004-10-08 | 2005-04-06 | 中国科学院长春应用化学研究所 | Long wave infrared burning radiation medicine |
US8048242B1 (en) * | 2007-04-05 | 2011-11-01 | Sandia Corporation | Nanocomposite thermite ink |
CN102925120A (en) * | 2012-11-08 | 2013-02-13 | 中国人民解放军理工大学 | Thermit and preparation method thereof |
Non-Patent Citations (6)
Title |
---|
ERNST-CHRISTIAN KOCH等,: ""Metal-Fluorocarbon Pyrolants:X.Influence of Ferric Oxide/Silicon Additive on Burn Rate and Radiometric Performance of Magnesium/Teflon/Viton®(MTV)"", 《PROPELLANTS EXPLOS. PYROTECH.》, vol. 34, no. 6, 1 December 2009 (2009-12-01) * |
K.W.WATSON等,: ""Fast reactions with nano- and micrometer aluminum:A study on oxidation versus fluorination"", 《COMBUSTION AND FLAME》, no. 155, 28 July 2008 (2008-07-28), pages 619 - 634 * |
OSBORNE,DUSTIN TRAVIS: ""The effects of fuel particle size on the reaction of Al/Teflon mixtures"", 《MASTER OF SCIENCE IN MECHANICAL ENGINEERING》, 18 February 2011 (2011-02-18) * |
WATSON,KYLE W.: ""Fast reaction of nano-aluminum:A study on fluorination versus oxidation"", 《MASTER OF SCIENCE IN MECHANICAL ENGINEERING》, no. 8, 1 June 2012 (2012-06-01) * |
吕惠平等,: ""高热剂的红外辐射特性研究"", 《红外技术》, vol. 33, no. 11, 30 November 2011 (2011-11-30) * |
安亭等,: ""铝热剂对双基推进剂激光点火特性的影响"", 《火炸药学报》, vol. 34, no. 1, 28 February 2011 (2011-02-28) * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105175201A (en) * | 2015-09-03 | 2015-12-23 | 南京理工大学 | Multi-molten slag incendiary agent and preparation method thereof |
CN105218280A (en) * | 2015-09-03 | 2016-01-06 | 南京理工大学 | Many slags magnesium-polytetrafluoroethylene (PTFE) base incendiary material and preparation method thereof |
CN105218280B (en) * | 2015-09-03 | 2017-08-29 | 南京理工大学 | Many slag magnesium PTFE base incendiary agents and preparation method thereof |
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CN103553854B (en) | 2015-11-04 |
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