CN103526851B - Unburned red mud foaming abatvoix - Google Patents

Unburned red mud foaming abatvoix Download PDF

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CN103526851B
CN103526851B CN201310475378.2A CN201310475378A CN103526851B CN 103526851 B CN103526851 B CN 103526851B CN 201310475378 A CN201310475378 A CN 201310475378A CN 103526851 B CN103526851 B CN 103526851B
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red mud
foaming agent
built
frame
abatvoix
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CN103526851A (en
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唐珂
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Zhejiang Chuangwei New Material Co., Ltd
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Chongqing Huande Technology Co Ltd
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Abstract

The invention discloses a kind of unburned red mud foaming abatvoix, its technical scheme is characterized by, built-in frame is lain on mould, after short steel pipes in built-in frame inserts column, cement made from red mud foaming agent is adopted to be cast in built-in frame periphery, built-in frame is embedded in the inside of cement made from red mud foaming agent completely, carries out maintenance according to the conventional maintenance process of cement products, is packaged as unburned red mud foaming abatvoix finished product; Cement made from red mud foaming agent is made up of raw materials such as the red mud after acidifying, highly viscous attapulgite clay powder and cement; Cement made from red mud foaming agent forms an integrated entirety with built-in frame after solidifying, and adds the unburned red mud foaming bulk strength of abatvoix, bending resistance and practical effect. Unburned red mud foaming abatvoix not only can effectively control sound pollution, also has insulation and purifies the function of air; Unburned red mud foaming abatvoix is suitably mounted in the facilities such as highway, overpass, urban light rail, subway, public place.

Description

Unburned red mud foaming abatvoix
Technical field
The present invention relates to abatvoix, be specifically related to a kind of unburned red mud foaming abatvoix.
Background technology
City noise drastically influence orthobiosis and the health of human body of urbanite, city noise is primarily referred to as traffic noise, factory noise, construction noise pollution and noise of social activities, its effect of noise scope and influence degree are day by day serious, on civic living environment impact greatly, one of noticeable city environmental pollution problem is become.
Generally adopting sound-absorbing material to produce the products such as some abatvoixs, soundproof wall, sound-absorbing net and deafener to control sound pollution, also having some sound-absorbing materials is produce the products such as abatvoix by foaming after being processed, to improve the performance of product.
Selling the abatvoix quality after foaming in the market more crisp, the bulk strength of abatvoix, bending resistance and result of use are undesirable; It is installed in the process on building wall at abatvoix, abatvoix needs the bolt hole that scene bores more than 4, not only time-consuming, increase difficulty of construction, and be easy to when boring and abatvoix is broken or shatter, after abatvoix is arranged on building wall, due to the effect of gravity, the abatvoix after boring can be caused to crush from building wall and to come off.
Red mud is that aluminium industry extracts the contaminative waste residue of discharge during aluminium oxide, and average often produces 1 ton of aluminium oxide, incidentally produces 1.0~2.0 tons of red muds. The pH value of red mud is 10~12, and China is as big alumina producing state of the world the 4th, and the red mud of annual discharge is up to millions of tons. Substantial amounts of red mud can not sufficiently effective utilize, large-area stockyard can only be relied on to stack, occupy a large amount of soil, the production of the mankind, life are caused many-sided impact directly or indirectly by the generation of red mud, so reducing yield and the harm of red mud to greatest extent, it is achieved by all kinds of means, the resource of big quantity extremely urgent.
Summary of the invention
It is an object of the invention to overcome weak point in prior art, it is provided that a kind of unburned red mud foaming abatvoix.
Unburned red mud foaming abatvoix is made up of cement made from red mud foaming agent and built-in frame, built-in frame is lain on mould, after short steel pipes in built-in frame inserts column, cement made from red mud foaming agent is adopted to be cast in built-in frame periphery, built-in frame is embedded in the inside of cement made from red mud foaming agent completely, carry out maintenance according to the conventional maintenance process of cement products, be packaged as unburned red mud foaming abatvoix finished product.
After the acidified process of red mud, red mud pH value controls 5.5~8.0, it is possible to improves the utilization rate of red mud, turns waste into wealth.
Attapulgite has another name called Paligorskite or Palygorskite, be a kind of layer of chain structure containing Shuifu County's zeopan clay mineral, attapulgite has the layer chain structure feature of uniqueness, there is crystal lattice in its structure, therefore containing variable amount of Na+, Ca2+, Fe3+, Al3+ in crystal, crystal is needle-like, fibrous or fiber collection shape. Attapulgite has the dispersion of uniqueness, good colloidal nature and the higher absorbability such as saline and alkaline high temperature resistant, anti-, and has certain plasticity and cohesive force.
Highly viscous attapulgite clay is the attapulgite clay that the processing technique adopting and improving viscosity of attapulgite clay produces, attapulgite clay soil property is fine and smooth, there is oily soapy, light weight, property are crisp, fracture is conchoidal or irregular shape, and water absorption is strong, tool viscosity and plasticity time wet, its viscosity can reach more than 3000mPa s, is conducive to the bonding between raw material.
Highly viscous attapulgite clay powder refers to and takes 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add 372g water, suspension cup is placed on homogenizer, stir 20 minutes under the rotating speed of 11000 revs/min, in the beaker pouring 250mL through high-speed stirred sample suspension into, the viscosity of NDJ-1 type rotating cylinder viscometer test suspension, tested viscosity value >=2200 will be used againmPa·sAttapulgite clay powder.
Sodium lauryl sulphate is white or faint yellow powdery, is dissolved in water, and alkali and hard water is insensitive, has the foaming power of decontamination, emulsifying and excellence, is a kind of nontoxic anion surfactant; When powdery red mud foaming agent and water mixing, sodium lauryl sulphate and SODIUM PERCARBONATE generate substantial amounts of bubble jointly.
SODIUM PERCARBONATE is a kind of inorganic salt, and white particulate powder, SODIUM PERCARBONATE can be decomposed rapidly after contacting with water, discharges substantial amounts of oxygen.
Sodium polyacrylate is a kind of new functional macromolecule material, for white or buff powder, it is dissolved in cold water, variations in temperature is stable, it is a kind of surfactant with multiple property, is conducive to improving the effect of the thickening of powdery red mud foaming agent, foaming, stable, emulsifying, dispersion, bonding, film forming and water conservation in the present invention.
Sodium pyrophosphate is a kind of water white transparency crystallization or white crystalline powder, soluble in water, is used as dispersant and emulsifying agent in the present invention.
Poly-naphthalene formaldehyde sulfonate salt is brown or dark brown powder, soluble in water, acidproof, alkaline-resisting, and resistance to hard water has good diffusibility; When powdery red mud foaming agent and water generate substantial amounts of bubble when mixing, sodium pyrophosphate and poly-naphthalene formaldehyde sulfonate salt are conducive to the bubble distribution ratio generated more uniform.
Cement selection portland cement.
The technical scheme is that:
Unburned red mud foaming abatvoix is a kind of rectangular plate-shaped body, is made up of cement made from red mud foaming agent and built-in frame, and in built-in frame, design has 4~32 short steel pipes, and the endoporus of short steel pipes is the installing hole of unburned red mud foaming abatvoix;Being lain in by built-in frame on mould, after the short steel pipes in built-in frame inserts column, adopt cement made from red mud foaming agent to be cast in built-in frame periphery, it is unburned red mud foaming abatvoix semi-finished product that built-in frame is embedded in the inside of cement made from red mud foaming agent completely; After standing cured, the abatvoix semi-finished product that foamed by unburned red mud are removed from the molds, and carry out maintenance according to the conventional maintenance process of cement products, are packaged as unburned red mud foaming abatvoix finished product.
Cement made from red mud foaming agent dispensing is made up of following component by weight percentage: powdery red mud foaming agent 25~65%, cement 5~30% and water 20~65%; The preparation method of cement made from red mud foaming agent: it is paste cement made from red mud foaming agent that the dispensing of cement made from red mud foaming agent adds stirring in foaming blender;
Powdery red mud foaming agent dispensing is made up of following component by weight percentage: red mud 25~75% after acidifying, highly viscous attapulgite clay powder 5~15%, sodium lauryl sulphate 1~35%, SODIUM PERCARBONATE 1~25%, sodium polyacrylate 0.01~5%, sodium pyrophosphate 0.01~5% and poly-naphthalene formaldehyde sulfonate salt 0.01~5%; The production method of powdery red mud foaming agent: powdery red mud foaming agent dispensing inputted in blender and be stirred, inputs in grinding machine after stirring and is processed as powdery red mud foaming agent, fineness of the particles≤0.074 millimeter;
Patent of invention applied for by powdery red mud foaming agent, China Patent Publication No.: CN103265308A, publication date: on August 28th, 2013.
Red mud production method after acidifying is: the 1. preparation of dilute sulfuric acid, is made up of following component by weight percentage: the sulphuric acid 5~35% of concentration 98, water 65~95%; 2. the dispensing of acidification includes following component by weight percentage: red mud 55~85%, attapulgite clay 2~15% and dilute sulfuric acid 10~35%, it is red mud mixture that red mud and attapulgite clay first input stirring in blender, then dilute sulfuric acid is slowly added in red mud mixture carry out acidification; 3. extruding: by the red mud mixture of acidification, is red mud tablet, thickness≤3 millimeter of tablet by twin rollers extruding; 4. roasting: the tablet of red mud is transported in revolution drying oven and carries out roasting, and roasting time is 1~3 hour, and sintering temperature controls at 320~550 DEG C, and the red mud tablet after roasting is the red mud after acidifying, red mud water content≤5% after acidifying.
Highly viscous attapulgite clay is the attapulgite clay that the processing technique adopting and improving viscosity of attapulgite clay produces, it is characterised in that from the attapulgite clay of mining area exploitation, it is necessary to through the weathering of 30~120 days; Modification processing method is: calculate by weight percentage, takes the attapulgite clay after weathering 94~98%, is uniformly added into 2~6% sodium carbonate, in common input fermentation vat, adds clear water and carries out soaking ageing, and soak time is 72~120 hours; Take the attapulgite clay after immersion, input blender is stirred, and by the attapulgite clay after stirring, being extruded into thin slice through extruder, its THICKNESS CONTROL is at 0.5~2 millimeter, by attapulgite clay thin slice, carry out dry in the sun, the attapulgite clay thin slice after dry in the sun, its water content≤15%; Dispensing is calculated by weight percentage: attapulgite clay 94~98% after dry in the sun, High hydrophilous resin 0.5~5% and cellulose 0.5~3%, above-mentioned dispensing is stirred, and inputs in grinding machine and carry out pulverizing, fineness of the particles≤0.074 millimeter after stirring.
Above-mentioned production technology is to adopt to be applied for " improving the processing technique of viscosity of attapulgite clay " by the present inventor on June 20th, 2005, and Chinese patent Authorization Notice No. is: CN1317067C, authorized announcement date: on May 23rd, 2007.
Described water content is weight percentage.
Described built-in frame is a kind of rectangular steel structure frame, is made up of 4~32 short steel pipes, 4~52 pieces of punching expanded metal laths and 2~42 reinforcements in built-in frame; The upper plane of short steel pipes is processed as a kind of counter sink, it is welded as a rectangular frame with punching expanded metal lath between short steel pipes and short steel pipes, punching expanded metal lath hole is circular opening, the horizontal center line at the horizontal center line at short steel pipes height 1/2 place and punching expanded metal lath width 1/2 place overlaps, with the diagonal at height 1/2 place between short steel pipes and short steel pipes for interface in rectangular frame, it is welded as reinforcement with screw-thread steel, collectively constitutes a built-in frame; In built-in frame, the plane of short steel pipes top counter sink collectively constitutes as plane on built-in frame, and short steel pipes lower flat collectively constitutes as built-in frame lower plane;
For producing the built-in frame separate case application of abatvoix utility model patent, number of patent application is: 201320579228.1, the applying date: on JIUYUE 18th, 2013.
Described mould is a kind of rectangular mould, is made up of a block length square floor, a rectangle locating slot, a rectangle frame, 2 rectangle handles and 4~32 cylindrical columns; Locating slot is welded on the upper plane of die bottom plate according to the position dimension of design, column is arranged on the upper plane of die bottom plate according to the relative position size of design, frame is placed in locating slot, 2 handles are separately mounted to middle outside frame the right and left, and the lower plane of die bottom plate is placed on vibrations workbench;
For producing the mould separate case application of abatvoix utility model patent, number of patent application is: 201320575991.7, the applying date: on JIUYUE 17th, 2013.
Having inlayed built-in frame in unburned red mud foaming abatvoix, cement made from red mud foaming agent forms an integrated entirety with built-in frame after solidifying, and adds the unburned red mud foaming bulk strength of abatvoix, bending resistance and practical effect.
Cement made from red mud foaming agent in unburned red mud foaming abatvoix has that foaming capacity is strong, coefficient of foaming is high, unit volume bubble production volume is big, foam adventitia good toughness is not broken, foam stability is good, can for a long time not froth breaking, the advantage such as foam hole size fine and smooth, that generate in medium is uniform, bleeding quantity is low and uses the compatibility of medium good.
Unburned red mud foaming abatvoix does not have layering in casting process, and product stripping speed is fast, and surface smoothness is good.
Unburned red mud foaming abatvoix not only can effectively control sound pollution, also has insulation and purifies the function of air.
At construction site, it is not necessary to boring, directly with cross recessed countersunk head tapping screw, unburned red mud foaming abatvoix is arranged on the metope of building, saving of work and time, come off from broken building wall without causing unburned red mud foaming abatvoix.
Unburned red mud foaming abatvoix is suitably mounted in the facilities such as highway, overpass, urban light rail, subway, factory, warehouse, public place.
Accompanying drawing explanation
Fig. 1 is unburned red mud foaming abatvoix schematic diagram, and Fig. 2 is the A-A direction view of Fig. 1, and Fig. 3 is the schematic diagram that built-in frame lies in when pouring into a mould in mould, and Fig. 4 is the schematic diagram being arranged on building wall by unburned red mud foaming abatvoix.
As shown in the figure: 1 is unburned red mud foaming abatvoix, and 2 is built-in frame, and 3 is cement made from red mud foaming agent, and 4 is mould, and 5 is short steel pipes, and 6 is column, and 7 is cross recessed countersunk head tapping screw, and 8 is the metope of building.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Unburned red mud foaming abatvoix is a kind of rectangular plate-shaped body 1, is made up of built-in frame 2 and cement made from red mud foaming agent 3, and in built-in frame 2, design has 6 short steel pipes 5; Built-in frame 2 is lain on mould 4, after short steel pipes 5 in built-in frame 2 inserts column 6, cement made from red mud foaming agent 3 is adopted to be cast in built-in frame 2 peripheral, after built-in frame 2 is embedded in the inside of cement made from red mud foaming agent 3 completely, for unburned red mud foaming abatvoix semi-finished product; After standing cured, the abatvoix semi-finished product that foamed by unburned red mud are removed from the molds, and carry out maintenance according to the conventional maintenance process of cement products, are packaged as unburned red mud foaming abatvoix finished product.
Cement made from red mud foaming agent dispensing is made up of following component by weight percentage: powdery red mud foaming agent 48%, cement 14% and water 38%; The preparation method of cement made from red mud foaming agent: it is paste cement made from red mud foaming agent that the dispensing of cement made from red mud foaming agent adds stirring in foaming blender;
Powdery red mud foaming agent dispensing is made up of following component by weight percentage: red mud 44% after acidifying, highly viscous attapulgite clay powder 10%, sodium lauryl sulphate 30%, SODIUM PERCARBONATE 14.2%, sodium polyacrylate 0.8%, sodium pyrophosphate 0.6% and poly-naphthalene formaldehyde sulfonate salt 0.4%; The production method of powdery red mud foaming agent: powdery red mud foaming agent dispensing inputted in blender and be stirred, inputs in grinding machine after stirring and is processed as powdery red mud foaming agent, fineness of the particles≤0.074 millimeter.
At construction site, directly with cross recessed countersunk head tapping screw 7, unburned red mud foaming abatvoix 1 is arranged on the metope 8 of building.

Claims (1)

1. a unburned red mud foaming abatvoix, it is characterised in that unburned red mud foaming abatvoix is a kind of rectangular plate-shaped body, is made up of cement made from red mud foaming agent and built-in frame, and in built-in frame, design has 4~32 short steel pipes; Being lain in by built-in frame on mould, after the short steel pipes in built-in frame inserts column, adopt cement made from red mud foaming agent to be cast in built-in frame periphery, it is unburned red mud foaming abatvoix semi-finished product that built-in frame is embedded in the inside of cement made from red mud foaming agent completely; After standing cured, the abatvoix semi-finished product that foamed by unburned red mud are removed from the molds, and carry out maintenance according to the conventional maintenance process of cement products, are packaged as unburned red mud foaming abatvoix finished product;
Described cement made from red mud foaming agent dispensing is made up of following component by weight percentage: powdery red mud foaming agent 25~65%, cement 5~30% and water 20~65%; The preparation method of cement made from red mud foaming agent: it is paste cement made from red mud foaming agent that the dispensing of cement made from red mud foaming agent adds stirring in foaming blender;
Described powdery red mud foaming agent dispensing is made up of following component by weight percentage: red mud 25~75% after acidifying, highly viscous attapulgite clay powder 5~15%, sodium lauryl sulphate 1~35%, SODIUM PERCARBONATE 1~25%, sodium polyacrylate 0.01~5%, sodium pyrophosphate 0.01~5% and poly-naphthalene formaldehyde sulfonate salt 0.01~5%; The production method of powdery red mud foaming agent: powdery red mud foaming agent dispensing inputted in blender and be stirred, inputs in grinding machine after stirring and is processed as powdery red mud foaming agent, fineness of the particles≤0.074 millimeter;
Red mud production method after described acidifying is: the 1. preparation of dilute sulfuric acid, is made up of following component by weight percentage: the sulphuric acid 5~35% of concentration 98, water 65~95%; 2. the dispensing of acidification includes following component by weight percentage: red mud 55~85%, attapulgite clay 2~15% and dilute sulfuric acid 10~35%, it is red mud mixture that red mud and attapulgite clay first input stirring in blender, then dilute sulfuric acid is slowly added in red mud mixture carry out acidification; 3. extruding: by the red mud mixture of acidification, is red mud tablet, thickness≤3 millimeter of tablet by twin rollers extruding; 4. roasting: the tablet of red mud is transported in revolution drying oven and carries out roasting, and roasting time is 1~3 hour, and sintering temperature controls at 320~550 DEG C, and the red mud tablet after roasting is the red mud after acidifying, red mud water content≤5% after acidifying;
Described highly viscous attapulgite clay powder refers to and takes 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add 372g water, suspension cup is placed on homogenizer, stir 20 minutes under the rotating speed of 11000 revs/min, in the beaker pouring 250mL through high-speed stirred sample suspension into, the viscosity of NDJ-1 type rotating cylinder viscometer test suspension, tested viscosity value >=2200 will be used againmPa·sAttapulgite clay powder.
CN201310475378.2A 2013-10-13 2013-10-13 Unburned red mud foaming abatvoix Active CN103526851B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1557618A (en) * 2004-01-18 2004-12-29 熊吉如 Apparatus and method for producing foaming concrete construction wall plate coated by glass fiber reinforced cement
CN2709554Y (en) * 2004-03-12 2005-07-13 成都金圣实业有限公司 Outer thermal-insulation board for exposed wall
DE202007007553U1 (en) * 2007-05-25 2007-08-02 Lahnau Akustik Gmbh panel member
KR100919229B1 (en) * 2008-11-04 2009-09-28 김두원 Eco low noise mold panel
CN101618567A (en) * 2009-08-04 2010-01-06 王建国 Manufacturing method of ecological fire preventing and heat insulating building material
CN103265308A (en) * 2013-05-27 2013-08-28 许盛英 Powdery red mud foamer

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1557618A (en) * 2004-01-18 2004-12-29 熊吉如 Apparatus and method for producing foaming concrete construction wall plate coated by glass fiber reinforced cement
CN2709554Y (en) * 2004-03-12 2005-07-13 成都金圣实业有限公司 Outer thermal-insulation board for exposed wall
DE202007007553U1 (en) * 2007-05-25 2007-08-02 Lahnau Akustik Gmbh panel member
KR100919229B1 (en) * 2008-11-04 2009-09-28 김두원 Eco low noise mold panel
CN101618567A (en) * 2009-08-04 2010-01-06 王建国 Manufacturing method of ecological fire preventing and heat insulating building material
CN103265308A (en) * 2013-05-27 2013-08-28 许盛英 Powdery red mud foamer

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