CN103524855A - Rare earth corrugated pipe - Google Patents

Rare earth corrugated pipe Download PDF

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Publication number
CN103524855A
CN103524855A CN201310524517.6A CN201310524517A CN103524855A CN 103524855 A CN103524855 A CN 103524855A CN 201310524517 A CN201310524517 A CN 201310524517A CN 103524855 A CN103524855 A CN 103524855A
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CN
China
Prior art keywords
rare earth
parts
corrugated pipe
raw material
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310524517.6A
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Chinese (zh)
Inventor
徐全茂
吴文利
刘雪慧
余明峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUOTONG NOVEL PIPES CO Ltd ANHUI
Original Assignee
GUOTONG NOVEL PIPES CO Ltd ANHUI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUOTONG NOVEL PIPES CO Ltd ANHUI filed Critical GUOTONG NOVEL PIPES CO Ltd ANHUI
Priority to CN201310524517.6A priority Critical patent/CN103524855A/en
Publication of CN103524855A publication Critical patent/CN103524855A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a rare earth corrugated pipe. The rare earth corrugated pipe is characterized in that the rare earth corrugated pipe is composed of, by weight, 93-100 parts of high-density polyethylene, 0.4-0.6 part of lanthanum oxide, 1-2 parts of bisphenol a diglycidyl ether, 2-4 parts of alcohol ester-12, 2-3 parts of gibbsite, 3-4 parts of palm wax, 0.6-1 part of sodium potassium tartrate tetrahydrate, 0.3-0.5 part of tetrabutylammonium bromide, 1-2 parts of copper naphthenate, 1-2 parts of citronella oil, 0.5-1 part of 1,2-dimethyl imidazole and 5-10 parts of composite filler. The rare earth corrugated pipe has very high mechanical property and friction resistant capacity, and is high in heat stability and weather resistance, excellent in comprehensive capacity and wide in application.

Description

A kind of rare earth corrugated tube
Technical field
The present invention relates generally to a kind of tubing, relates in particular to a kind of rare earth corrugated tube.
Background technology
Pvc pipe (UPVC pipe) hard polvinyl choride pipe, is to use pressure sintering extrusion molding after being coordinated with stablizer, lubricant etc. by polyvinyl chloride (PVC) RESINS, is the plastic pipe being developed and applied the earliest.UPVC pipe resistance to corrosion is strong, it is bonding to be easy to, price is low, quality is hard, but owing to having UPVC monomer and additive exudation, is only applicable in water feeding system that delivery temperature is no more than 45 ℃.Plastic conduit is for delivery of tap water, waste water, chemical, heating fluid and cooling fluid, food, ultrarapture liquid, mud, gas, the application of pressurized air and vacuum system.
PE pipe has medium-density polyethylene pipe and high density polyethylene pipe.The former is applicable to carry artificial coal gas, Sweet natural gas, the liquefied petroleum gas (LPG) of gaseous state, and the latter is mainly for delivery of Sweet natural gas.With steel pipe comparison, construction technology is simple, has certain snappiness, and main is to be not used as rotproofing, will save a large amount of operations.Shortcoming is with regard to apparatus not as steel pipe, and the special safe spacing of noting heating power heating in construction, and can not being exposed in air under sunlight, and responsive to chemical substance, prevents that the leakage of sewer line from damaging.
Summary of the invention
The object of the invention is just to provide a kind of rare earth corrugated tube.
The present invention is achieved by the following technical solutions:
A corrugated tube, it is comprised of the raw material of following weight parts:
High density polyethylene(HDPE) 93-100, lanthanum trioxide 0.4-0.6, bis-phenol a diglycidylether 1-2, Lauryl Alcohol ester 2-4, gibbsite 2-3, palm wax 3-4, Seignette salt 0.6-1, Tetrabutyl amonium bromide 0.3-0.5, copper naphthenate 1-2, pamorusa oil 1-2,1,2 dimethylimidazole 0.5-1, compounded mix 5-10;
Described compounded mix is comprised of the raw material of following weight parts:
Agalmatolite 20-24, attapulgite 10-16, jade 3-5, polydimethylsiloxane 0.6-1, two Imidurea 1-2, Oil of Eucalyptus 1-2, oxidized polyethlene wax 2-4;
Above-mentioned agalmatolite, attapulgite are mixed with jade, ball milling is even, adds oxidized polyethlene wax, insulated and stirred 3-6 minute at 80-120 ℃, reduction temperature is 40-50 ℃, add polydimethylsiloxane, 600-1000 rev/min of dispersed with stirring 10-13 minute, adds two Imidureas, Oil of Eucalyptus successively, abundant ball milling, granulation, particle diameter is 2-4 μ m, obtains described compounded mix.
A preparation method for rare earth corrugated tube, comprises the following steps:
Above-mentioned each raw material is mixed, at 120-140 ℃ of temperature, stir, automatically cooling after stirring, after vibratory screening apparatus, automatic charging, is extruded through High Temperature High Pressure by twin screw extruder, after forming machine is pulled out product, by cutting machine fixed length cutting, send into pipe-expanding machine, packing warehouse-in after enlarging completes.
Advantage of the present invention is:
Corrugated tube of the present invention has very high mechanical property and friction resistant performance, and thermostability and weathering resistance are strong, and over-all properties is outstanding, is widely used.
Embodiment
Embodiment 1
A corrugated tube, it by following weight parts (kilogram) raw material form:
High density polyethylene(HDPE) 100, lanthanum trioxide 0.6, bis-phenol a diglycidylether 2, Lauryl Alcohol ester 2, gibbsite 3, palm wax 4, Seignette salt 0.6, Tetrabutyl amonium bromide 0.5, copper naphthenate 1, pamorusa oil 2,1,2 dimethylimidazole 0.5, compounded mix 5;
Described compounded mix is comprised of the raw material of following weight parts:
Agalmatolite 24, attapulgite 16, jade 5, polydimethylsiloxane 0.6, two Imidurea 1, Oil of Eucalyptus 2, oxidized polyethlene wax 4;
Above-mentioned agalmatolite, attapulgite are mixed with jade, ball milling is even, adds oxidized polyethlene wax, and at 120 ℃, insulated and stirred is 3 minutes, reducing temperature is 50 ℃, add polydimethylsiloxane, 1000 revs/min of dispersed with stirring 13 minutes, add two Imidureas, Oil of Eucalyptus successively, abundant ball milling, granulation, particle diameter is 4 μ m, obtains described compounded mix.
A preparation method for rare earth corrugated tube, comprises the following steps:
Above-mentioned each raw material is mixed, at 140 ℃ of temperature, stir, automatically cooling after stirring, after vibratory screening apparatus, automatic charging, is extruded through High Temperature High Pressure by twin screw extruder, after forming machine is pulled out product, by cutting machine fixed length cutting, send into pipe-expanding machine, packing warehouse-in after enlarging completes.
Performance test:
Impact property (TIR) :≤10%;
Ring stiffness (KN/m 2): 13.26;
Ring is flexible: sample is round and smooth, crack-free, and two walls are without disengagement, without reverse bending;
Baking oven experiment (110 ℃, 30min): without layering, without cracking, without bubble.

Claims (2)

1. a rare earth corrugated tube, is characterized in that what it was comprised of the raw material of following weight parts:
High density polyethylene(HDPE) 93-100, lanthanum trioxide 0.4-0.6, bis-phenol a diglycidylether 1-2, Lauryl Alcohol ester 2-4, gibbsite 2-3, palm wax 3-4, Seignette salt 0.6-1, Tetrabutyl amonium bromide 0.3-0.5, copper naphthenate 1-2, pamorusa oil 1-2,1,2 dimethylimidazole 0.5-1, compounded mix 5-10;
Described compounded mix is comprised of the raw material of following weight parts:
Agalmatolite 20-24, attapulgite 10-16, jade 3-5, polydimethylsiloxane 0.6-1, two Imidurea 1-2, Oil of Eucalyptus 1-2, oxidized polyethlene wax 2-4;
Above-mentioned agalmatolite, attapulgite are mixed with jade, ball milling is even, adds oxidized polyethlene wax, insulated and stirred 3-6 minute at 80-120 ℃, reduction temperature is 40-50 ℃, add polydimethylsiloxane, 600-1000 rev/min of dispersed with stirring 10-13 minute, adds two Imidureas, Oil of Eucalyptus successively, abundant ball milling, granulation, particle diameter is 2-4 μ m, obtains described compounded mix.
2. a preparation method for rare earth corrugated tube as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned each raw material is mixed, at 120-140 ℃ of temperature, stir, automatically cooling after stirring, after vibratory screening apparatus, automatic charging, is extruded through High Temperature High Pressure by twin screw extruder, after forming machine is pulled out product, by cutting machine fixed length cutting, send into pipe-expanding machine, packing warehouse-in after enlarging completes.
CN201310524517.6A 2013-10-30 2013-10-30 Rare earth corrugated pipe Pending CN103524855A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310524517.6A CN103524855A (en) 2013-10-30 2013-10-30 Rare earth corrugated pipe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310524517.6A CN103524855A (en) 2013-10-30 2013-10-30 Rare earth corrugated pipe

Publications (1)

Publication Number Publication Date
CN103524855A true CN103524855A (en) 2014-01-22

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Family Applications (1)

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CN201310524517.6A Pending CN103524855A (en) 2013-10-30 2013-10-30 Rare earth corrugated pipe

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Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387648A (en) * 2014-11-11 2015-03-04 合肥皖为电气设备工程有限责任公司 Flame-retardant dielectric substrate material for printed circuit

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1821297A (en) * 2006-03-09 2006-08-23 安徽国风集团有限公司 Nano modified poly ethylene large caliber double wall corrugated pipe
CN102050983A (en) * 2010-11-18 2011-05-11 天津市耀新科技发展有限公司 Prestress plastic corrugated pipe and preparation method thereof
CN102786730A (en) * 2012-08-07 2012-11-21 安徽国通高新管业股份有限公司 HDPE (high-density polyethylene) double-wall corrugated pipe with high ring stiffness

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1821297A (en) * 2006-03-09 2006-08-23 安徽国风集团有限公司 Nano modified poly ethylene large caliber double wall corrugated pipe
CN102050983A (en) * 2010-11-18 2011-05-11 天津市耀新科技发展有限公司 Prestress plastic corrugated pipe and preparation method thereof
CN102786730A (en) * 2012-08-07 2012-11-21 安徽国通高新管业股份有限公司 HDPE (high-density polyethylene) double-wall corrugated pipe with high ring stiffness

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387648A (en) * 2014-11-11 2015-03-04 合肥皖为电气设备工程有限责任公司 Flame-retardant dielectric substrate material for printed circuit

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Application publication date: 20140122