CN103509464A - White asphalt anticorrosive paint and preparation method thereof - Google Patents

White asphalt anticorrosive paint and preparation method thereof Download PDF

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Publication number
CN103509464A
CN103509464A CN201310413454.7A CN201310413454A CN103509464A CN 103509464 A CN103509464 A CN 103509464A CN 201310413454 A CN201310413454 A CN 201310413454A CN 103509464 A CN103509464 A CN 103509464A
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China
Prior art keywords
parts
film
forming resin
albino bitumen
preparation
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Pending
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CN201310413454.7A
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Chinese (zh)
Inventor
许成雄
李寿国
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Maanshan City Jin Han Coating Manufacturing Co Ltd
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Maanshan City Jin Han Coating Manufacturing Co Ltd
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Priority to CN201310413454.7A priority Critical patent/CN103509464A/en
Publication of CN103509464A publication Critical patent/CN103509464A/en
Pending legal-status Critical Current

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Abstract

The invention provides a white asphalt anticorrosive paint. The white asphalt anticorrosive paint is prepared from the following raw material components in weight part: 40-50 parts of white asphalt, 2-5 parts of triethyl citrate, 15-20 parts of titanium dioxide, 5-8 parts of zinc oxide, 8-15 parts of barium sulfate, 0.3-1.4 parts of organic bentonite, 6-13 parts of xylene, 12-23 parts of vinyl chloride-vinyl isobutyl ether copolymer liquid, and 4-5 parts of film-forming resin, wherein the vinyl chloride-vinyl isobutyl ether copolymer liquid is an aqueous solution of vinyl chloride-vinyl isobutyl ether copolymer with concentration of 20-40%. The raw materials are nontoxic, so that during the production and use process, the paint causes less harm to human bodies, and the environmental pollution is low. In the formula, the film-forming resin is added to improve the compatibility of the components, so that the film forming effect is greatly improved. The obtained paint film is water resistant, excellently corrosion resistant, firm in bonding strength, and good in alkaline resistance and water resistance.

Description

A kind of albino bitumen protective system and preparation method thereof
Technical field
The present invention relates to metal rust preventing technical field, be specifically related to a kind of albino bitumen protective system and preparation method thereof.
Background technology
Metallic corrosion is the very serious problem that people face.The metal that scrap because of metallic corrosion every year in the whole world reaches more than several hundred million tons, and financial loss accounts for 1.5%~2.5% of total value of production in national economy.Metal rusting is the most general, loss is maximum a kind of corrosion.Antirust work is always one of great scientific research task both domestic and external, and people work out the corrosion that many kinds of measures prevented and suppressed metal, and antirust with coating is a kind of effective means.
Summary of the invention
The object of this invention is to provide a kind of albino bitumen protective system and preparation method thereof, various metals is had to antirust function.
Technical scheme of the present invention is as follows:
A protective system, is characterized in that, its feed composition by following weight part is prepared from:
Albino bitumen 40-50, triethyl citrate 2-5, titanium dioxide 15-20, zinc oxide 5-8, barium sulfate 8-15, organobentonite 0.3-1.4, dimethylbenzene 6-13, chlorinated polyether resin liquid 12-23, film-forming resin 4-5, wherein, described chlorinated polyether resin liquid is that concentration is the aqueous solution of the chlorinated polyether resin of 20-40%.
Described albino bitumen protective system, is characterized in that: described film-forming resin is prepared from by the raw material of following weight part:
Alcohol ester 12 18-20, calcium stearate 2-3, lapis amiridis 1-1.4, Zirconium tetrafluoride 1-2, alum 2-3, ethyl acetate 13-16, wintergreen oil 1-2, nano-sized carbon 0.1-0.2, polyisobutene 2-3, aluminate coupling agent DL-4111-2,
Preparation method: lapis amiridis, Zirconium tetrafluoride, calcium stearate, alum are added in ethyl acetate, and grinding distribution, then, adds other remaining component, is heated to 85-90 ℃, stirs 1-2 hour, obtains.
The preparation method of described albino bitumen protective system, is characterized in that, comprises the following steps:
(1) the chlorinated polyether resin liquid of formula ratio, albino bitumen, triethyl citrate and dimethylbenzene are dropped into Scattered Kettle, stir;
(2) in Scattered Kettle, add titanium dioxide, zinc oxide, barium sulfate, organobentonite, the stirring 20-40min of formula ratio, then add film-forming resin, continue to stir 10-15 minute;
(3) raw material in Scattered Kettle is ground, to particle diameter≤60 μ m, filters.
Beneficial effect of the present invention:
Albino bitumen coating of the present invention advantages of nontoxic raw materials used, therefore production and use procedure are little to human body murder by poisoning, and environmental pollution is low, adds film-forming resin in formula, has improved the consistency of each composition, has greatly improved film-formation result.Have paint film firm, good leveling property, does not need primer coating film, and mechanical property is good, erosion resistance, and chemical proofing, applied range is water-fast, antiseptic property is excellent, and bonding strength is firm, alkaline-resisting, water tolerance is all good.
Embodiment:
Embodiment
A protective system, its feed composition by following weight (kg) is prepared from:
Albino bitumen 50, triethyl citrate 4, titanium dioxide 18, zinc oxide 6, barium sulfate 10, organobentonite 0.8, dimethylbenzene 11, chlorinated polyether resin liquid 15, film-forming resin 5, wherein, described chlorinated polyether resin liquid is that concentration is the aqueous solution of 30% chlorinated polyether resin.;
Concrete preparation method, comprises the following steps:
1, the preparation of film-forming resin:
(kg) takes alcohol ester 12, calcium stearate 3, lapis amiridis 1.4, Zirconium tetrafluoride 1, alum 3, ethyl acetate 14, wintergreen oil 1, nano-sized carbon 0.2, polyisobutene 2, aluminate coupling agent DL-4112 by weight, just lapis amiridis, Zirconium tetrafluoride, calcium stearate, alum add in ethyl acetate, grinding distribution, then, add other remaining component, be heated to 87 ℃, stir 1.5 hours, obtain.
2, the preparation of albino bitumen protective system, make according to the following steps:
(1) the chlorinated polyether resin liquid of formula ratio, albino bitumen, triethyl citrate and dimethylbenzene are dropped into Scattered Kettle, stir;
(2) in Scattered Kettle, add titanium dioxide, zinc oxide, barium sulfate, organobentonite, the stirring 20-40min of formula ratio, then add film-forming resin, continue to stir 10-15 minute;
(3) raw material in Scattered Kettle is ground, to particle diameter≤60 μ m, filters.
Testing data
Rust proof paint prepared by above-described embodiment is tested according to standard: HG/T2244-1991 " lathe priming paint ", and result is as following table 1.
The detected result of the performance of table 1 rust proof paint
Figure BDA0000380141000000031

Claims (3)

1. an albino bitumen protective system, is characterized in that, its feed composition by following weight part is prepared from:
Albino bitumen 40-50, triethyl citrate 2-5, titanium dioxide 15-20, zinc oxide 5-8, barium sulfate 8-15, organobentonite 0.3-1.4, dimethylbenzene 6-13, chlorinated polyether resin liquid 12-23, film-forming resin 4-5, wherein, described chlorinated polyether resin liquid is that concentration is the aqueous solution of the chlorinated polyether resin of 20-40%.
2. albino bitumen protective system according to claim 1, is characterized in that: described film-forming resin is prepared from by the raw material of following weight part:
Alcohol ester 12 18-20, calcium stearate 2-3, lapis amiridis 1-1.4, Zirconium tetrafluoride 1-2, alum 2-3, ethyl acetate 13-16, wintergreen oil 1-2, nano-sized carbon 0.1-0.2, polyisobutene 2-3, aluminate coupling agent DL-411 1-2,
Preparation method: lapis amiridis, Zirconium tetrafluoride, calcium stearate, alum are added in ethyl acetate, and grinding distribution, then, adds other remaining component, is heated to 85-90 ℃, stirs 1-2 hour, obtains.
3. the preparation method of albino bitumen protective system according to claim 1, is characterized in that, comprises the following steps:
(1) the chlorinated polyether resin liquid of formula ratio, albino bitumen, triethyl citrate and dimethylbenzene are dropped into Scattered Kettle, stir;
(2) in Scattered Kettle, add titanium dioxide, zinc oxide, barium sulfate, organobentonite, the stirring 20-40min of formula ratio, then add film-forming resin, continue to stir 10-15 minute;
(3) raw material in Scattered Kettle is ground, to particle diameter≤60 μ m, filters.
CN201310413454.7A 2013-09-10 2013-09-10 White asphalt anticorrosive paint and preparation method thereof Pending CN103509464A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310413454.7A CN103509464A (en) 2013-09-10 2013-09-10 White asphalt anticorrosive paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310413454.7A CN103509464A (en) 2013-09-10 2013-09-10 White asphalt anticorrosive paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN103509464A true CN103509464A (en) 2014-01-15

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CN201310413454.7A Pending CN103509464A (en) 2013-09-10 2013-09-10 White asphalt anticorrosive paint and preparation method thereof

Country Status (1)

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CN (1) CN103509464A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107384128A (en) * 2017-08-16 2017-11-24 天津市津海特种涂料装饰有限公司 A kind of novel aqueous asphalt anticorrosion paint

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102336667A (en) * 2010-07-18 2012-02-01 肖连朝 Preparation method of non-toxic and efficient plasticizer triethyl citrate
CN103013334A (en) * 2012-11-28 2013-04-03 天长市开林化工有限公司 Asphalt anticorrosive paint applied to hull bottoms

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102336667A (en) * 2010-07-18 2012-02-01 肖连朝 Preparation method of non-toxic and efficient plasticizer triethyl citrate
CN103013334A (en) * 2012-11-28 2013-04-03 天长市开林化工有限公司 Asphalt anticorrosive paint applied to hull bottoms

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107384128A (en) * 2017-08-16 2017-11-24 天津市津海特种涂料装饰有限公司 A kind of novel aqueous asphalt anticorrosion paint

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