CN103504454A - Food dipping method based on strong electrolyte ion current controlled by function signal - Google Patents
Food dipping method based on strong electrolyte ion current controlled by function signal Download PDFInfo
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Abstract
The invention discloses a food dipping method based on a strong electrolyte ion current controlled by a function signal, and belongs to the technical field of electromagnetic food processing. (A) Drive units comprise an any function signal generator and a power amplifier; (B) sensing units comprise an annular silicon steel iron core, a silicone tube winding and a copper coil winding; (C) dipping units comprise a dipping groove and a vacuum pump. A specific periodic function signal is generated through the function signal generator and amplified through the power amplified for stimulating the copper coil winding at one end, generating changed magnetic flux in the annular silicon steel iron core and generating an induced electromotive force in the silicone tube winding filled up with an electrolyte solution at the other end. Under the drive action of the induced electromotive force, positive and negative ions in a solution loop system directionally move for finishing a food dipping process, and a strong electrolyte ionic compound is required as a dipping solution. According to the food dipping method, the problems of electrolysis of the dipping solution and corrosion and scaling of a polar plate due to an electrochemical reaction are avoided, and a principle is different from electrolysis, electrophoresis, electrodialysis and electroplating technologies.
Description
Technical field
A food impregnation processability method for the strong electrolyte gas current that function signal is controlled, the present invention relates to a kind of novel foodstuff impregnation processability method, is applicable to the maceration extract of strong electrolyte class, belongs to and uses electromagnetic food processing technology field.The present invention compares with vacuum impregnation technology, can within the shorter time, complete the impregnation process to raw-food material.Can complete the reinforcement of wet method salt marsh, painted processing and trace mineral element.
Background technology
The traditional infusion of food processing method of China comprises five large classes, i.e. salt marsh, marinate, cured with germented grains, saucing and sugaring.Infusion of food is of a great variety, and the product being wherein widely known by the people has all kinds of pickles, pickles, acid bubble ginger splices, seasoning sunflower seed, salted eggs, Chicken Feet with Pickled Peppers and pigskin, wine preserved crab etc., and they are all subject to people's favor.The object of impregnation process is if hydrogen, sodium, potassium, calcium, iron, selenium, chlorion and sucrose, the little molecule infiltration of alcohols are in food tissue space and cell by all kinds of solute ions in dipping solution and molecule, because permeable pressure head is removed the part moisture in food, produce good local flavor simultaneously.In this process, in maceration extract solute diffusion rate be subject to that the partial pressure of the inside and outside various materials of histocyte is poor, the impact of dipping temperature, environmental pressure and raw-food material voidage.The aquatic products of brine cure particularly in infusion of food, because solute diffusion rate is slow, steeping can cause rotten, so general how pickled in the cold storage environment of 5 ℃, inevitably because of the long loss that causes soluble protein, vitamin, mineral matter and pigment of time.For accelerating the impregnation process of food, conventionally only have by improving dipping temperature, improve solute concentration and changing environment atmospheric pressure and undertaken.But because high temperature can cause the fermentation of infusion of food and become sour, therefore improve the mode that temperature is accelerated impregnation process, industrial, rarely has employing.Improve maceration extract solute concentration and can form " high salt " product, and must increase later stage desalinating process operation.Technology ripe application and that can accelerate food impregnation process only has vacuum impregnation technology (Vacuum Impregnation is called for short VI) at present, and central principle is to utilize hydrodynamics mechanism and the relaxation of deformation phenomenon that pressure reduction causes to improve pickled efficiency.In food tissue cell, have hole, under vacuum, at the inner low pressure bubble that forms of material, also cause iuntercellular apart from increase and mass expanded, under cell inside and outside differential pressure and capillary effect, outside liquid more easily infiltrates simultaneously.Conventionally in tens of minutes, complete the impregnation process of food, flood required several days with normal pressure or tens day time was compared greatly and shortened process time, therefore can extensive use.
The conductor of electric current is divided into two large classes, and the first kind is metallic conductor, and current forms is electronic current, and Equations of The Second Kind is electrolyte solution or fused electrolyte.Electrolyte can be divided into strong electrolyte and weak electrolyte, and strong electrolyte can ionize completely in solution, mostly is ionic compound and most of salt, and weak electrolyte ionization not exclusively, mostly is covalent compound.The conductive capability of electrolyte solution and degree of ionization, concentration, temperature have correlation, and current forms is gas current.In electrolyte solution, owing to containing a large amount of band negative ions, in having the environment of electrical potential difference, directional migration be can there is, according to the technology application of this principle, electrolysis, plating, electrophoresis and electrodialysis comprised.They are all to cause ion displacement by produce electrical potential difference between electrode, and wherein electrolysis, plating, electrodialytic processing object mostly are the negative ions in electrolyte, and its molecular weight is little; Electrophoresis is processed with the protein macromolecule class of a large amount of positron-electrons for some surfaces in solution.
Induction gas current introduces the magnetic flux changing in being full of electrolytical helical pipeline makes its production induced electromotive force drive the ionic transfer in solution loop system as " driving source ".In solution loop system, according to the different induced electromotive forces with different rules of the variation rate of magnetic flux of its coil, produce, and then there is different driving effects.This is because according to the motion of charged ion in electric field, and the power (F) that promotes charged ion motion equals ion institute with the product of net charge amount (Q) and electric-field intensity (X), i.e. F=QX.Because flux change rate is different, the alternation induced electromotive force producing is different at the peak value of positive negative direction, and the electric field force size that ion is subject at different directions is different with the duration.And the reach of ion to be subject to equally resistance (
f) impact, for a spheroidal ion of class, obey Stokes' law, that is:
f=6 π r η ν (r is ion particle radius, and η is the solution medium coefficient of viscosity, and ν is ionic transfer speed), when reaching balance, charged ion uniform motion, i.e. F=
f.
Summary of the invention
The object of the invention is to provide a kind of food impregnation processability method of the strong electrolyte gas current of controlling based on function signal, relate to a kind of novel foodstuff impregnation processability method, principle is to generate specific periodic signal waves by function signal generator, through power amplifier, signal code is amplified and is encouraged the coil windings of mutual inductance silicon steel core one end, the induced electromotive force that the magnetic flux changing produces respective change rule in the other end is full of the spiral silicone tube winding pipeline of strong electrolytic solution drives the ion in conducting loop and forms directional migration as " driving source ".Because induced electromotive force Changing Pattern is different, ion is subject to big or small and duration of the electric field force of " forward " and " negative sense " to be had differently, and then makes ion have different stepping effects.According to the ion characteristic of solution system, select suitable function waveform to reach best dipping effect.As shown in Figure 1, waveform example is as Fig. 2 for know-why.
Technical scheme of the present invention: a kind of food impregnation processability method of the strong electrolyte gas current of controlling based on function signal, the component units of apparatus of the present invention has (A) driver element: comprise arbitrary function signal generator (1), power amplifier (2); Arbitrary function signal generator (1) is connected with power amplifier (2); (B) sensing unit: comprise annular silicon steel iron core (3), silicone tube winding (4), copper coil winding (5); One end of annular silicon steel iron core (3) is around copper coil winding (5), and the other end of annular silicon steel iron core (3) is around silicone tube winding (4); Copper coil winding (5) is connected with power amplifier (2); Silicone tube winding (4) two ends are connected with the conducting orifice at dipping tank (6) two ends respectively, make strong electrolytic solution form closed-loop path; (C) impregnating unit: comprise dipping tank (6), vavuum pump (7), vavuum pump (7) is connected with dipping tank (6);
By function generator, generate the periodic signal of specific rule, through power amplifier, signal voltage is amplified and encourages to the copper coil winding of annular silicon steel core one end, amplification voltage signal distortion rate≤0.1% wherein, the magnetic flux that periodic law changes is full of the annular silicon steel iron core other end to produce in the spiral silicone tube winding of strong electrolytic solution the induced electromotive force that corresponding rule changes to drive the ion generation directional migration in maceration extract system as " driving source "; According to the ion characteristic of solution system, select applicable periodic function waveform to reach best dipping effect; When periodic function waveform sends, now strong electrolyte maceration extract electrical conductivity need be in 20 ~ 60mS/cm scope, the magnetic flux changing can generate at dipping tank two ends the alternation induced electromotive force of 500mV ~ 1.8V, when food materials thickness is in 3cm, all can in 5min, complete dipping, in food materials internal and external environment, the volumetric concentration of maceration extract solute is basically identical.
Any self-defined waveform signal of function signal generator generated frequency 1Hz ~ 100Hz in driver element, in 1 cycle, signal has 1 rising edge, 2 trailing edges, the slope of rising edge is greater than the slope of trailing edge, fabric width scope 10Vpp(± 5V) within, output impedance 50 Ω, the amplification of the compatible arbitrary function waveform of power amplifier using, total power frequency range 1Hz ~ 100Hz, output voltage fabric width 300Vpp(± 150V), output current 0 ~ 40mA, input impedance 50 Ω, are activated at the coil windings of rectangular silicon steel core one side.
Annular silicon steel iron core in sensing unit is silicon steel rectangle iron core, and copper coil winding is single-layer winding, copper wire diameter scope 0.6 ~ 0.8mm, and the number of turn is 120 ~ 150 circles, is connected with power amplifier.
Its material of silicone tube winding that is full of strong electrolyte maceration extract is good insulating, pliability is good, nonpoisonous and tasteless food-grade platinum silicone tube, inside diameter ranges 1 ~ 5mm, pipe thickness 3mm, winding is that its number of turn scope of single-layer winding is 10 ~ 20 circles, silicone tube two ends with join and be communicated with the conducting orifice of dipping tank both sides respectively, make maceration extract be the loop system of circulation, when the magnetic flux of specific rule variation produces, maceration extract electrical conductivity is when 20 ~ 60mS/cm, can generate at dipping tank two ends the induced electromotive force that the specific rule of 500mV ~ 1.8V changes, can produce directed driven effect to the different ions in maceration extract, thereby complete the impregnation process to food.Induced electromotive force can be by inserting platinum plate electrode and being examined platinum plate electrode size 5mm * 5mm * 0.15mm by voltsalternating table at dipping tank two ends.
In impregnating unit, glass-impregnated groove is cylindrical structural internal diameter 80mm, length 300mm, wall thickness 3mm, top leave vacuum-pumping valve and can sample introduction or the seal cover of sampling, there is conducting orifice the middle part of dipping tank both sides, can be connected with silicone tube, make its whole steeping liq be tied to form closed circuit, by vavuum pump, be controlled the circulation of maceration extract system.
Then the specific waveforms periodic function signal at 1Hz ~ 100Hz by function signal generator generated frequency, in 1 cycle, signal has 1 rising edge, 2 trailing edges, the slope of rising edge is greater than the slope of trailing edge, its fabric width scope is at 10Vpp(± 5V), output impedance 50 Ω, signal passes through total power frequency range at 1Hz ~ 100Hz, output voltage fabric width is at 300Vpp(± 150V), output current is at 0 ~ 40mA, the power amplifier of input impedance 50 Ω also amplifies voltage signal, be activated at the coil windings of rectangular silicon steel core one side, coil windings is single-layer winding, copper wire diameter scope is 0.6 ~ 0.8mm, the number of turn is at 120 ~ 150 circles.So the magnetic flux of the regular variation of meeting produces in being full of the silicone tube winding of strong electrolyte dipping solution, wherein silicone tube material is good, the nonpoisonous and tasteless food-grade platinum silicone tube of good insulating, pliability, inside diameter ranges 1 ~ 5mm, pipe thickness 3mm, winding is that its number of turn scope of single-layer winding is 10 ~ 20 circles.When the magnetic flux of specific rule variation produces, maceration extract electrical conductivity is when 20 ~ 60mS/cm, can generate at dipping tank two ends the induced electromotive force that the specific rule of 500mV ~ 1.8V changes, can produce directed driven effect to the different ions in maceration extract, thereby complete the impregnation process to food.Induced electromotive force can be by inserting platinum plate electrodes and being examined platinum plate electrode size 5mm * 5mm * 0.15mm by voltsalternating table at dipping tank 2 ends.
Beneficial effect of the present invention: can complete fast the impregnation processability to food materials, maceration extract need belong to the ionic compound class of strong electrolyte.Food materials for passing through wet method salt marsh, painted and mineral nutrient element intensive treatment all can complete dipping when thickness is in 3cm in 5min, stable after the volumetric concentration of food materials internal and external environment solute basically identical.During impregnation process, solution concentration 0.01% ~ 6% and electrical conductivity suitable in 20 ~ 60mS/cm scope.Ion concentration is large, responds to ion current density too high, makes the production convection current of solution loop system or turbulent flow, is unfavorable for ion dipping.Because the directional migration driving force of electrolyte ion derives from induced electromotive force but not direct-insert energising pole plate, therefore the present invention has avoided maceration extract electrolysis and the pole plate corrosion and scaling problem due to electrochemical reaction, brought, and principle is different from current electrolysis, electrophoresis, electrodialysis and electroplating technology completely.
Accompanying drawing explanation
The food dipping technique principle schematic of a kind of strong electrolyte gas current of controlling based on function signal of Fig. 1.1, arbitrary function signal generator, 2, power amplifier, 3, annular silicon steel iron core, 4, silicone tube winding, 5, copper coil winding, 6, dipping tank, 7, vavuum pump.
Fig. 2 flux change and induced electromotive force exemplary plot.
The function signal oscillogram of Fig. 3 salt marsh green plum.
After Fig. 4 responds to gas current processing 5min, green plum interior tissue microcosmic salinity is observed.
The function signal oscillogram of Fig. 5 calcium salt dipping apple.
After Fig. 6 responds to gas current processing 5min, apple internal organizes microcosmic calcium salt cloth to observe.
The function signal oscillogram of the painted dipping of Fig. 7 melon seeds.
The specific embodiment
Embodiment 1 salt marsh green plum
Take 300 grams, green plum, clean and be placed in dipping tank, the cavity size of groove is internal diameter 80mm, length 300mm, wall thickness 3mm.The sodium chloride pickling liquid of implantation quality mark 5% concentration is until submergence sample, and now adopting plum Teller-Tuo benefit FE30 conductivity meter to record pickled electrical conductivity of solution is 55mS/cm.After dipping tank sealing, open vavuum pump and vacuumize until solution is full of silica gel pipeline, the dipping solution in system becomes loop state.Wherein silicone tube material is good, the nonpoisonous and tasteless food-grade platinum silicone tube of good insulating, pliability, internal diameter 2mm, and pipe thickness 3mm, silicone tube is wrapped on rectangular silicon steel core one end, and silicone tube winding is single-layer winding, and number of turn scope is 20 circles.After this You Pu source DG1022 type function signal generator generates the periodic function signal of specific waveforms, and in 1 cycle, signal has 1 rising edge, 2 trailing edges, the slope of rising edge is greater than the slope of trailing edge, oscillogram as shown in Figure 3, cycle 750ms, t
0=0s, t
1=100ms, t
2=250ms, t
3=400ms, t
4=500ms, t
5=650ms, t
6=750ms, V
1=2.5V, V
2=5V, its waveform fabric width V
pp=5V, the power amplifier that voltage signal is 2350 by U.S. TEGAM board model again amplifies 10 times, with this, is activated at the coil windings of the rectangular silicon steel core other end, coil windings is single-layer winding, copper wire diameter 0.8mm, the number of turn 140 circles, now the induced electromotive force of system is 1.2V.After starting 5min, take out green plum, reach dipping requirement, now green plum salt content is 4.6%, and untreated front green plum salt content is 0.2%.
The microcosmic detection of salt marsh effect, adopts sem observation green plum inner near the salt distribution situation in the tissue at fruit stone position, as shown in Figure 4, can find out that 5min processes rear green plum interior tissue and contained obvious salinity.Detection method: get the green plum meat near fruit stone position, be cut into the rectangular block shape of 4mm * 1.5mm * 5mm, directly be placed in liquid nitrogen freezing (210 ℃) 5min, after taking-up by its brittle failure, dehydration 30min rapidly under-45 ℃ of cold-traps of freeze dryer, vacuum 12Pa environment.Dry sample surfaces metal spraying is observed, as shown in Figure 4 under Dutch Quanta 200 SEM.
The calcium constituent fortification of embodiment 2 apples
Apple is cleaned and is peeled, be cut into 3 * 3 * 3cm block, take 400g, be placed in dipping tank, dipping tank cavity size is internal diameter 80mm, length 300mm, wall thickness 3mm, the food-grade calcium lactate solution submergence sample of implantation quality mark 1000mg/kg, now adopting plum Teller-Tuo benefit FE30 conductivity meter to record pickled electrical conductivity of solution is 22mS/cm, after sealing, opening vavuum pump vacuumizes until solution is full of silica gel pipeline, solution in system becomes loop state, wherein silicone tube material is good insulating, pliability is good, nonpoisonous and tasteless food-grade platinum silicone tube, inside diameter ranges 4mm, pipe thickness 3mm, silicone tube is wrapped in rectangle silicon steel mutual inductance iron core one end, silicone tube winding is single-layer winding, the number of turn is 15 circles.You Pu source DG1022 type function signal generator generates the periodic function signal of specific waveforms, and in 1 cycle, signal has 1 rising edge, 2 trailing edges, the slope of rising edge is greater than the slope of trailing edge, oscillogram as shown in Figure 5, cycle 540ms, t
0=0s, t
1=50ms, t
2=100ms, t
3=220ms, t
4=300ms, t
5=420ms, t
6=540ms, V
1=4V, V
2=8V, its waveform fabric width Vpp=8V, after the power amplifier that voltage signal is 2350 through the model of U.S. TEGAM board amplifies 10 times, be activated at the coil windings of the square shaped iron core other end, coil windings is single-layer winding, copper wire diameter 0.8mm, the number of turn is at 150 circles, and now the induced electromotive force of solution system is 800mV.Keep taking out after 5min, apple piece reaches dipping requirement, the calcium content 0.1mg/g in apple grunt now, and calcium content 0.003mg/g before untreated.
The microcosmic detection of calcium constituent dipping effect, adopts the calcium salt distribution situation in sem observation apple grunt interior tissue, as shown in Figure 6, can find out 5min process after apple internal organize and contain obvious calcium salt.Detection method: get apple internal pulp organization, be cut into the rectangular block shape of 4mm * 1.5mm * 5mm, directly be placed in liquid nitrogen freezing (210 ℃) 5min, after taking-up by its brittle failure, dehydration 30min rapidly under-45 ℃ of cold-traps of freeze dryer, vacuum 12Pa environment.Dry sample surfaces metal spraying is observed, as shown in Figure 6 under Dutch Quanta 200 SEM.
[0024] embodiment 3: melon seeds are painted
Adopt synthetic dyestuff amaranth, molecular formula C
20h
11o
10n
2s
3na
3, water colo(u)r.This example is the colouring of string surface-stable.Sunflower seeds takes 500 grams, is placed in dipping tank, and dipping tank cavity size is internal diameter 80mm, length 300mm, wall thickness 3mm, the amaranth maceration extract of implantation concentration 40mg/kg is until submergence sample, and now adopting plum Teller-Tuo benefit FE30 conductivity meter to record pickled electrical conductivity of solution is 20mS/cm.After sealing, opening vavuum pump vacuumizes until solution is full of silica gel pipeline, solution in system becomes loop state, wherein silicone tube material is good, the nonpoisonous and tasteless food-grade platinum silicone tube of good insulating, pliability, inside diameter ranges 5mm, pipe thickness 3mm, silicone tube is wrapped in rectangular silicon steel core one end, and silicone tube winding is single-layer winding, and the number of turn is 20 circles.You Pu source DG1022 type function signal generator generates the periodic function signal of specific waveforms, and in 1 cycle, signal has 1 rising edge, 2 trailing edges, the slope of rising edge is greater than the slope of trailing edge, oscillogram as shown in Figure 7, cycle 440ms, t
0=0s, t
1=80ms, t
2=120ms, t
3=240ms, t
4=280ms, t
5=400ms, t
6=440ms, V
1=5V, V
2=10V, its waveform fabric width Vpp=10V, after the power amplifier that voltage signal is 2350 through the model of U.S. TEGAM board amplifies 10 times, be activated at the coil windings of the square type silicon steel core other end, copper winding is single-layer winding, copper wire diameter 0.8mm, the number of turn is at 140 circles, and now the induced electromotive force of solution system is 900mV.Keep taking out after 5min, by sensory evaluation and with the melon seeds of same time of Dipping, compare, the melon seeds color and luster that this method is processed is stable, and after rinsing, color and luster does not take off.According to " food additives handbook (third edition) 》Ling Guan front yard chief editor analyzes about coloring matter total content assay method OT-15, amaranth content 18mg/kg in melon seed cases after processing, and in the melon seed cases of Dipping processing 5min, amaranth content is 5mg/kg.
Claims (5)
1. a food impregnation processability method for the strong electrolyte gas current of controlling based on function signal, the driver element that it is characterized in that the component units of device has (A): comprise arbitrary function signal generator (1), power amplifier (2); Arbitrary function signal generator (1) is connected with power amplifier (2); (B) sensing unit: comprise annular silicon steel iron core (3), silicone tube winding (4), copper coil winding (5); One end of annular silicon steel iron core (3) is around copper coil winding (5), and the other end of annular silicon steel iron core (3) is around silicone tube winding (4); Copper coil winding (5) is connected with power amplifier (2); Silicone tube winding (4) two ends are connected with the conducting orifice at dipping tank (6) two ends respectively, make strong electrolytic solution form closed-loop path; (C) impregnating unit: comprise dipping tank (6), vavuum pump (7), vavuum pump (7) is connected with dipping tank (6);
By function generator, generate the periodic signal of specific rule, through power amplifier, signal voltage is amplified and encourages to the copper coil winding of annular silicon steel core one end, amplification voltage signal distortion rate≤0.1% wherein, the magnetic flux that periodic law changes is full of the annular silicon steel iron core other end to produce in the spiral silicone tube winding of strong electrolytic solution the induced electromotive force that corresponding rule changes to drive the ion generation directional migration in maceration extract system as " driving source "; According to the ion characteristic of solution system, select applicable periodic function waveform to reach best dipping effect; When periodic function waveform sends, now strong electrolyte maceration extract electrical conductivity need be in 20 ~ 60mS/cm scope, the magnetic flux changing can generate at dipping tank two ends the alternation induced electromotive force of 500mV ~ 1.8V, when food materials thickness is in 3cm, all can in 5min, complete dipping, in food materials internal and external environment, the volumetric concentration of maceration extract solute is basically identical.
2. the food impregnation processability method of the strong electrolyte gas current of controlling based on function signal according to claim 1, it is characterized in that, function signal generator in driver element can generated frequency 1Hz ~ 100Hz any self-defined waveform, in 1 cycle, signal has 1 rising edge, 2 trailing edges, the slope of rising edge is greater than the slope of trailing edge, within fabric width scope 10Vpp, + 5V~-5 V, output impedance 50 Ω, the amplification of the compatible arbitrary function waveform of power amplifier using, total power frequency range 1Hz ~ 100Hz, output voltage fabric width 300Vpp, + 150V~-150V, output current 0 ~ 40mA, input impedance 50 Ω.
3. the food impregnation processability method of the strong electrolyte gas current of controlling based on function signal according to claim 1, it is characterized in that, annular silicon steel iron core in sensing unit is silicon steel rectangle iron core, copper coil winding is single-layer winding, copper wire diameter scope 0.6 ~ 0.8mm, the number of turn is 120 ~ 150 circles, is connected with power amplifier.
4. the food impregnation processability method of the strong electrolyte gas current of controlling based on function signal according to claim 1, it is characterized in that, its material of silicone tube winding that is full of strong electrolyte maceration extract is good, the nonpoisonous and tasteless food-grade platinum silicone tube of good insulating, pliability, inside diameter ranges 1 ~ 5mm, pipe thickness 3mm, winding is that its number of turn scope of single-layer winding is 10 ~ 20 circles, silicone tube two ends with join and be communicated with the conducting orifice of dipping tank both sides respectively, make maceration extract be the loop system of circulation.
5. the food impregnation processability method of the strong electrolyte gas current of controlling based on function signal according to claim 1, it is characterized in that, in impregnating unit, glass-impregnated groove is cylindrical structural internal diameter 80mm, length 300mm, wall thickness 3mm, top leave vacuum-pumping valve and can sample introduction or the seal cover of sampling, there is conducting orifice the middle part of dipping tank both sides, can be connected with silicone tube, make its whole steeping liq be tied to form closed circuit, by vavuum pump, be controlled the circulation of maceration extract system.
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CN105268388A (en) * | 2015-09-14 | 2016-01-27 | 江南大学 | Circular magnetic induction reaction system and application |
WO2017045327A1 (en) * | 2015-09-14 | 2017-03-23 | 江南大学 | Multistage induction type continuous flow magnetoelectric processing apparatus and application thereof |
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