CN103496785A - Degradation-resistant waste water graphene enhanced anaerobic treatment method - Google Patents
Degradation-resistant waste water graphene enhanced anaerobic treatment method Download PDFInfo
- Publication number
- CN103496785A CN103496785A CN201310486371.0A CN201310486371A CN103496785A CN 103496785 A CN103496785 A CN 103496785A CN 201310486371 A CN201310486371 A CN 201310486371A CN 103496785 A CN103496785 A CN 103496785A
- Authority
- CN
- China
- Prior art keywords
- reactor
- anaerobic
- sludge
- graphene
- waste water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- Y02W10/12—
Abstract
The invention relates to a degradation-resistant waste water graphene enhanced anaerobic treatment method and belongs to the technical field of environmental engineering water treatment. The method is characterized in that after sludge pretreatment and taming, graphene-anaerobic sludge composite is prepared in situ in an anaerobic bioreactor to form an anaerobic sludge expansion bed good in mass transfer and sedimentation performance, and accordingly extracellular electron transfer performance and anaerobic metabolism are enhanced to increase anaerobic hydrolytic acidification and methane generating performance of degradation-resistant waste water. The method has the advantages that the graphene-anaerobic sludge composite is simple in preparation process, high in bioactivity and high in stability. The method is low in reactor configuration requirements, fast in starting, simple to operate and low in energy consumption, and defects of current anaerobic treatment processes of degradation-resistant waste water such as phenols waste water, dye waste water and nitro-aromatic waste water are overcome.
Description
Technical field
The invention belongs to the technical field of sewage in environmental engineering, relate to a kind of method that Graphene reinforced anaerobic is processed used water difficult to degradate.
Background technology
Along with the development of industrial or agricultural, produced a large amount of poisonous hardly degraded organic substances, as aromatic compound and halogenated aryl hydrocarbon etc.These compounds are widely used in entering physical environment in people's production and life and through number of ways, present the characteristics such as extended residual and high toxicity, can cause serious public health and environmental problem.The processing of poisonous difficult degradation pollutent waste water has the combination of physics, chemistry, biological process and these methods.Wherein, that biological process has is simple to operate, running cost is low, and the advantage of non-secondary pollution, be the first-selected treatment technology of used water difficult to degradate.Hardly degraded organic substance is processed and can be improved its biodegradability through anaerobic hydrolysis-acidification, and the simple aromatic compound of certain structures is anaerobe mineralising and product methane directly, and therefore, the anaerobic biological treatment used water difficult to degradate has obvious technology and economic advantages.Common used water difficult to degradate anaerobic treatment process mainly contains anaerobic activated sludge method, anaerobic grain sludge method, inert support absorption or embedded immobilization method etc. at present.
But the subject matter existed in above-mentioned Anaerobic treatment technique is: in (1) anaerobic activated sludge method, difficult degradation pollutent anaerobic metabolism speed is slow, degradation rate is low, the anti impulsion load poor performance; (2) large, the mechanical property of the resistance to mass transfer of embedded immobilization microbial particle and biological activity is lower and cost of manufacture is high, seriously limited its large-scale application; (3), in the inert support absorbing process, biofilm difficulty, start-up period length, microbial film easily come off; (4) in anaerobic grain sludge technique, the reactor start-up time is long, the granule sludge resistance to mass transfer is large, poor stability; Some technique is in order to improve mass-transfer performance, and the higher upflow velocity formed by the effluent recycling mode increases energy consumption, and reactor configuration is had higher requirements.
Summary of the invention
The objective of the invention is the drawback existed in current common Anaerobic treatment technique, a kind of economy, efficient used water difficult to degradate anaerobic biological treatment method are provided.
Technical solution of the present invention is to prepare Graphene-anaerobic sludge complex body at the anaerobic biological reactor situ, form all good anaerobic sludge expanded beds of mass-transfer performance and settling property, transmit performance and anaerobic metabolism process with strengthening born of the same parents exoelectron, thereby improved the used water difficult to degradate anaerobic hydrolysis-acidification and produced the methane performance.Its concrete steps are as follows:
Step 1. sludge pretreatment
Add fresh active sludge in anaerobic biological reactor, regulating its concentration is 3-20g/L, and initial pH is controlled at 8-11, and temperature is controlled at 20-60 ℃, by recycle pump, makes mud at reactor internal recycle 12-48h.
Step 2. sludge acclimatization
Sludge acclimatization is initial, and used water difficult to degradate dilution 1-10 is doubly rear as water inlet, the operation of anaerobic reactor intermittent mode; Whenever the influent COD clearance reaches 80% when above, more progressively strengthen used water difficult to degradate ratio in water inlet, enter the next round domestication, until tamed.During sludge acclimatization, temperature remains on 10-60 ℃, and in reactor, dissolved oxygen is less than 0.5mg/L.
Step 3. Graphene-anaerobic sludge compound system is standby
After sludge acclimatization completes, add the graphene oxide that length of a film is 1-10 μ m, graphene oxide is controlled at 0.005-0.2 with the sludge quality ratio, and in reactor, temperature remains on 10-60 ℃, and dissolved oxygen is less than 0.5mg/L, reaction 18-36h.
Step 4. reactor start-up and operation
Graphene-anaerobic sludge compound system is for after completing, and reactor starts continuous operation.Remove situation according to influent COD, adjust matrix load and hydraulic detention time, with the startup of accelerating reactor.
After reactor steady running, in water inlet, the difficult degradation pollutent is removed by anaerobism.
The reactor run duration, temperature remains on 10-60 ℃, and in reactor, dissolved oxygen is less than 0.5mg/L.
Effect of the present invention and benefit are:
(1) preparation technology of Graphene-anaerobic sludge complex body is simple, biological activity is high, have good settleability and stability.
(2) the method to reactor configuration require low, start quick, simple to operate, energy consumption is low.
(3) the method overcomes the many drawbacks that exist in current used water difficult to degradate anaerobic treatment process, for such waste water provides a kind of economy and efficient biologic treating technique.
The accompanying drawing explanation
Fig. 1 is the stereoscan photograph figure of Graphene provided by the invention-anaerobic sludge complex body.
Fig. 2 is the graphic representation of Graphene reinforced anaerobic treatment of Nitrobenzene waste water provided by the invention.In figure, ordinate zou means nitro phenenyl concentration, and unit is mg/L; X-coordinate means the time, and unit is sky.-◆-represent reactor water inlet nitro phenenyl concentration;-■-represent reactor water outlet nitro phenenyl concentration.After Fig. 2 shows reactor steady running, the oil of mirbane clearance remains on 90% left and right.
Embodiment
Describe specific embodiments of the invention in detail below in conjunction with technical scheme and accompanying drawing.
Embodiment 1
Graphene reinforced anaerobic Phenol-Containing Wastewater Treatment
[1] sludge pretreatment
Add fresh active sludge in upflow anaerobic sludge blanket reactor, regulating its concentration is 8g/L, and initial pH is controlled at 10, and temperature is controlled at 30 ± 1 ℃, by recycle pump, makes mud at reactor internal recycle 16h.
[2] sludge acclimatization
Influent composition is phenol 1000mg/L, (NH
4)
2sO
4, Na
2hPO
4, KH
2pO
4, micro-CaCl
2, MgSO
4, FeCl
3, COD:N:P=200:5:1.
Former water inlet is diluted to 8 times as initially intaking, the operation of reactor intermittent mode; Whenever the influent COD clearance reaches 80% when above, more progressively strengthen phenolic waste water ratio in water inlet, enter the next round domestication, until tamed.During sludge acclimatization, temperature remains on 30 ± 1 ℃, and in reactor, dissolved oxygen is less than 0.2mg/L.
[3] Graphene-anaerobic sludge compound system is standby
After sludge acclimatization completes, add the graphene oxide that length of a film is 3-5 μ m, graphene oxide is controlled at 0.075 with the sludge quality ratio, and in reactor, temperature remains on 30 ± 1 ℃, and dissolved oxygen is less than 0.2mg/L, reaction 24h.
[4] reactor start-up and operation
Graphene-anaerobic sludge compound system is for after completing, and reactor starts continuous operation.Influent composition is phenol 1000mg/L, (NH
4)
2sO
4, Na
2hPO
4, KH
2pO
4, micro-CaCl
2, MgSO
4, FeCl
3, COD:N:P=200:5:1.
The reactor run duration, hydraulic detention time is 24h, and temperature remains on 30 ± 1 ℃, and in reactor, dissolved oxygen is less than 0.2mg/L.
After reactor steady running, in water inlet, phenol is by anaerobic degradation.
Embodiment 2
Graphene reinforced anaerobic treatment of Nitrobenzene waste water
[1] sludge pretreatment
Add fresh active sludge in upflow anaerobic sludge blanket reactor, regulating its concentration is 6g/L, and initial pH is controlled at 9, and temperature is controlled at 30 ± 1 ℃, by recycle pump, makes mud at reactor internal recycle 20h.
[2] sludge acclimatization
Influent composition is oil of mirbane 300mg/L, sucrose 1000mg/L, (NH
4)
2sO
4, Na
2hPO
4, KH
2pO
4, micro-CaCl
2, MgSO
4, FeCl
3, COD:N:P=200:5:1.
Former water inlet is diluted to 5 times as initially intaking, the operation of reactor intermittent mode; Whenever the influent COD clearance reaches 80% when above, more progressively strengthen nitrobenzene waste water ratio in water inlet, enter the next round domestication, until tamed.During sludge acclimatization, temperature remains on 30 ± 1 ℃, and in reactor, dissolved oxygen is less than 0.2mg/L.
[3] Graphene-anaerobic sludge compound system is standby
After sludge acclimatization completes, add the graphene oxide that length of a film is 3-5 μ m, graphene oxide is controlled at 0.05 with the sludge quality ratio, and in reactor, temperature remains on 30 ± 1 ℃, and dissolved oxygen is less than 0.2mg/L, reaction 24h.
[4] reactor start-up and operation
Graphene-anaerobic sludge compound system is for after completing, and reactor starts continuous operation.Influent composition is oil of mirbane 300mg/L, sucrose 1000mg/L, (NH
4)
2sO
4, Na
2hPO
4, KH
2pO
4, micro-CaCl
2, MgSO
4, FeCl
3, COD:N:P=200:5:1.
The reactor run duration, temperature remains on 30 ± 1 ℃, and in reactor, dissolved oxygen is less than 0.2mg/L, and hydraulic detention time is 24h.
After reactor steady running, in water inlet, oil of mirbane is removed by anaerobism.
Embodiment 3
The Graphene reinforced anaerobic is processed azo dye wastewater
[1] sludge pretreatment
Add fresh active sludge in upflow anaerobic sludge blanket reactor, regulating its concentration is 10g/L, and initial pH is controlled at 10, and temperature is controlled at 30 ± 1 ℃, by recycle pump, makes mud at reactor internal recycle 24h.
[2] sludge acclimatization
Influent composition is Acid Brilliant Scarlet GR 200mg/L, sucrose 800mg/L, (NH
4)
2sO
4, Na
2hPO
4, KH
2pO
4, micro-CaCl
2, MgSO
4, FeCl
3, COD:N:P=200:5:1.
Former water inlet is diluted to 4 times as initially intaking, the operation of reactor intermittent mode; Whenever the influent COD clearance reaches 80% when above, more progressively strengthen azo dye wastewater ratio in water inlet, enter the next round domestication, until tamed.During sludge acclimatization, temperature remains on 28 ± 1 ℃, and in reactor, dissolved oxygen is less than 0.2mg/L.
[3] Graphene-anaerobic sludge compound system is standby
After sludge acclimatization completes, add the graphene oxide that length of a film is 1-3 μ m, graphene oxide is controlled at 0.06 with the sludge quality ratio, and in reactor, temperature remains on 28 ± 1 ℃, and dissolved oxygen is less than 0.2mg/L, reaction 24h.
[4] reactor start-up and operation
Graphene-anaerobic sludge compound system is for after completing, and reactor starts continuous operation.Influent composition is Acid Brilliant Scarlet GR 200mg/L, sucrose 800mg/L, (NH
4)
2sO
4, Na
2hPO
4, KH
2pO
4, micro-CaCl
2, MgSO
4, FeCl
3, COD:N:P=200:5:1.
The reactor run duration, temperature remains on 28 ± 1 ℃, and in reactor, dissolved oxygen is less than 0.2mg/L, and hydraulic detention time is 12h.
After reactor steady running, in water inlet, Acid Brilliant Scarlet GR is removed by anaerobism.
Claims (1)
1. a Graphene reinforced anaerobic is processed the method for used water difficult to degradate, it is characterized in that comprising the following steps:
(1) sludge pretreatment: add fresh active sludge in anaerobic biological reactor, regulating its concentration is 3-20g/L, and initial pH is controlled at 8-11, and temperature is controlled at 20-60 ℃, by recycle pump, makes mud at reactor internal recycle 12-48h;
(2) sludge acclimatization: sludge acclimatization is initial, and used water difficult to degradate dilution 1-10 is doubly rear as water inlet, the operation of anaerobic reactor intermittent mode; Whenever the influent COD clearance reaches 80% when above, more progressively strengthen used water difficult to degradate ratio in water inlet, enter the next round domestication, until tamed; During sludge acclimatization, temperature remains on 10-60 ℃, and in reactor, dissolved oxygen is less than 0.5mg/L;
(3) Graphene-anaerobic sludge compound system is standby: after sludge acclimatization completes, add the graphene oxide that length of a film is 1-10 μ m, graphene oxide is controlled at 0.005-0.2 with the sludge quality ratio, and in reactor, temperature remains on 10-60 ℃, dissolved oxygen is less than 0.5mg/L, reaction 18-36h;
(4) reactor start-up and operation: Graphene-anaerobic sludge compound system is for after completing, and reactor starts continuous operation; Remove situation according to influent COD, adjust matrix load and hydraulic detention time, with the startup of accelerating reactor; After reactor steady running, in water inlet, the difficult degradation pollutent is removed by anaerobism; The reactor run duration, temperature remains on 10-60 ℃, and in reactor, dissolved oxygen is less than 0.5mg/L.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310486371.0A CN103496785A (en) | 2013-10-17 | 2013-10-17 | Degradation-resistant waste water graphene enhanced anaerobic treatment method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310486371.0A CN103496785A (en) | 2013-10-17 | 2013-10-17 | Degradation-resistant waste water graphene enhanced anaerobic treatment method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103496785A true CN103496785A (en) | 2014-01-08 |
Family
ID=49862078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310486371.0A Pending CN103496785A (en) | 2013-10-17 | 2013-10-17 | Degradation-resistant waste water graphene enhanced anaerobic treatment method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103496785A (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105347480A (en) * | 2015-11-18 | 2016-02-24 | 大连理工大学 | Method used for promoting biological reduction of nitrobenzene with biological carbon |
| CN106830311A (en) * | 2017-03-01 | 2017-06-13 | 大连理工大学 | A kind of graphene oxide and naphtoquinone compounds are modified the preparation method of hydroxyl macrocellular foam carrier altogether |
| CN107043162A (en) * | 2017-06-26 | 2017-08-15 | 苏州科技大学 | A kind of method of straw activated carbon reinforced anaerobic sludge Combined Processing azo dye wastewater |
| CN107176701A (en) * | 2017-07-25 | 2017-09-19 | 南京大学盐城环保技术与工程研究院 | A kind of broad spectrum activity control biochemical sludge expansion medicament and preparation method |
| CN107215956A (en) * | 2017-06-26 | 2017-09-29 | 苏州科技大学 | A kind of method of carbon-nanotube enhanced anaerobic sludge Combined Processing azo dye wastewater |
| CN107500406A (en) * | 2017-10-10 | 2017-12-22 | 中国科学技术大学 | The processing method and benzoic acid anaerobic biodegradation method of the waste water containing benzoic acid |
| CN108689564A (en) * | 2018-06-25 | 2018-10-23 | 同济大学 | A method of anaerobic sludge digestion methane phase gas is promoted using graphene |
| CN105668767B (en) * | 2016-04-13 | 2018-12-25 | 大连理工大学 | A kind of insoluble redox mediators type bio-carrier and preparation method thereof |
| CN109534510A (en) * | 2019-01-11 | 2019-03-29 | 青岛科技大学 | A kind of method of chemical method strengthened anaerobic ammoxidation denitrification process |
| CN111500646A (en) * | 2020-05-06 | 2020-08-07 | 苏州科技大学 | Method for producing methane from phenol-containing waste water |
| CN111517460A (en) * | 2020-04-13 | 2020-08-11 | 上海应用技术大学 | Domestication method of anaerobic granular sludge |
| CN111689649A (en) * | 2020-06-19 | 2020-09-22 | 安徽国星生物化学有限公司 | Treatment method of acetaldehyde wastewater |
| CN111924964A (en) * | 2020-07-06 | 2020-11-13 | 广州大学 | Aerobic granular sludge and culture method thereof |
| CN113582463A (en) * | 2021-08-16 | 2021-11-02 | 三桶油环保科技(宜兴)有限公司 | Direct-discharge treatment method for high-salinity fracturing flowback fluid |
| CN113652453A (en) * | 2021-08-16 | 2021-11-16 | 海南大学 | Method for promoting anaerobic methanation of organic acid by using nano graphene |
| CN115259367A (en) * | 2022-07-26 | 2022-11-01 | 上海净豚环保科技有限公司 | Method for proliferating and culturing anaerobic granular sludge for food wastewater |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH067791A (en) * | 1992-06-30 | 1994-01-18 | Toshiba Corp | Anaerobic waste water treatment apparatus |
| CN1215029A (en) * | 1997-10-21 | 1999-04-28 | 中国石化扬子石油化工公司 | Anaerobic reation pool and method for treating waste water |
| CN102249494A (en) * | 2011-06-23 | 2011-11-23 | 南京大学 | Method for improving activity of methanogens while reducing high-concentration ammonia nitrogen in anaerobic process |
-
2013
- 2013-10-17 CN CN201310486371.0A patent/CN103496785A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH067791A (en) * | 1992-06-30 | 1994-01-18 | Toshiba Corp | Anaerobic waste water treatment apparatus |
| CN1215029A (en) * | 1997-10-21 | 1999-04-28 | 中国石化扬子石油化工公司 | Anaerobic reation pool and method for treating waste water |
| CN102249494A (en) * | 2011-06-23 | 2011-11-23 | 南京大学 | Method for improving activity of methanogens while reducing high-concentration ammonia nitrogen in anaerobic process |
Non-Patent Citations (2)
| Title |
|---|
| JING WANG ET AL: ""Enhanced nitrobenzene biotransformation by graphene-anaerobic sludge composite"", 《2013 SOCIETY OF CHEMICAL INDUSTRY》 * |
| 马东辉: ""升流式厌氧污泥床UASB工艺概论"", 《科技前沿》 * |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105347480A (en) * | 2015-11-18 | 2016-02-24 | 大连理工大学 | Method used for promoting biological reduction of nitrobenzene with biological carbon |
| CN105668767B (en) * | 2016-04-13 | 2018-12-25 | 大连理工大学 | A kind of insoluble redox mediators type bio-carrier and preparation method thereof |
| CN106830311A (en) * | 2017-03-01 | 2017-06-13 | 大连理工大学 | A kind of graphene oxide and naphtoquinone compounds are modified the preparation method of hydroxyl macrocellular foam carrier altogether |
| CN107043162A (en) * | 2017-06-26 | 2017-08-15 | 苏州科技大学 | A kind of method of straw activated carbon reinforced anaerobic sludge Combined Processing azo dye wastewater |
| CN107215956A (en) * | 2017-06-26 | 2017-09-29 | 苏州科技大学 | A kind of method of carbon-nanotube enhanced anaerobic sludge Combined Processing azo dye wastewater |
| CN107176701A (en) * | 2017-07-25 | 2017-09-19 | 南京大学盐城环保技术与工程研究院 | A kind of broad spectrum activity control biochemical sludge expansion medicament and preparation method |
| CN107500406A (en) * | 2017-10-10 | 2017-12-22 | 中国科学技术大学 | The processing method and benzoic acid anaerobic biodegradation method of the waste water containing benzoic acid |
| CN108689564A (en) * | 2018-06-25 | 2018-10-23 | 同济大学 | A method of anaerobic sludge digestion methane phase gas is promoted using graphene |
| CN109534510A (en) * | 2019-01-11 | 2019-03-29 | 青岛科技大学 | A kind of method of chemical method strengthened anaerobic ammoxidation denitrification process |
| CN111517460A (en) * | 2020-04-13 | 2020-08-11 | 上海应用技术大学 | Domestication method of anaerobic granular sludge |
| CN111500646A (en) * | 2020-05-06 | 2020-08-07 | 苏州科技大学 | Method for producing methane from phenol-containing waste water |
| CN111689649A (en) * | 2020-06-19 | 2020-09-22 | 安徽国星生物化学有限公司 | Treatment method of acetaldehyde wastewater |
| CN111924964A (en) * | 2020-07-06 | 2020-11-13 | 广州大学 | Aerobic granular sludge and culture method thereof |
| CN113582463A (en) * | 2021-08-16 | 2021-11-02 | 三桶油环保科技(宜兴)有限公司 | Direct-discharge treatment method for high-salinity fracturing flowback fluid |
| CN113652453A (en) * | 2021-08-16 | 2021-11-16 | 海南大学 | Method for promoting anaerobic methanation of organic acid by using nano graphene |
| CN113652453B (en) * | 2021-08-16 | 2023-10-24 | 海南大学 | Method for promoting anaerobic methanation of organic acid by utilizing nano graphene |
| CN115259367A (en) * | 2022-07-26 | 2022-11-01 | 上海净豚环保科技有限公司 | Method for proliferating and culturing anaerobic granular sludge for food wastewater |
| CN115259367B (en) * | 2022-07-26 | 2023-11-17 | 上海净豚环保科技有限公司 | Proliferation and bacteria cultivation method of anaerobic granular sludge for food wastewater |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103496785A (en) | Degradation-resistant waste water graphene enhanced anaerobic treatment method | |
| Wang et al. | Potassium permanganate-based advanced oxidation processes for wastewater decontamination and sludge treatment: a review | |
| Cervantes et al. | Immobilized redox mediators on anion exchange resins and their role on the reductive decolorization of azo dyes | |
| US9540268B2 (en) | Method for treating highly concentrated resin-desorption liquid generated from wastewater deep purification | |
| CN101602547A (en) | A kind of method of strengthening the organic wastewater with difficult degradation thereby biological treatment | |
| CN101229944A (en) | Intensified biological treatment method for high strength ammonia wastewater | |
| KR101386599B1 (en) | Water treatment agent, manufacturing method thereof, and water treatment system and in-situ treatment system for underground water using that | |
| Ma et al. | Phenol removal and biofilm response in coupling of visible-light-driven photocatalysis and biodegradation: Effect of hydrothermal treatment temperature | |
| CN110357347B (en) | Method for treating wastewater by persulfate advanced oxidation coupling biological sulfate reduction | |
| CN103193364B (en) | Resource utilization method of ion exchange resin desorption solution | |
| CN103031298A (en) | Immobilized microorganism particle for degrading petroleum in water | |
| CN105366899A (en) | Ozone-anaerobic iron reduction combined Fenton oxidation technology for sludge reduction | |
| CN103819024B (en) | Pretreatment method for fluorenone production wastewater | |
| CN101565231B (en) | Biological treatment method for polynitro arene or azo dye wastewater | |
| CN107043162A (en) | A kind of method of straw activated carbon reinforced anaerobic sludge Combined Processing azo dye wastewater | |
| CN107215956A (en) | A kind of method of carbon-nanotube enhanced anaerobic sludge Combined Processing azo dye wastewater | |
| Li et al. | Long-term performance, microbial evolution and spatial microstructural characteristics of anammox granules in an upflow blanket filter (UBF) treating high-strength nitrogen wastewater | |
| CN102897951B (en) | The method of reuse after a kind of coking wastewater deep treatment | |
| CN103086546A (en) | Methyl naphthol wastewater treatment process | |
| Bai et al. | A comparative study of removal efficiency of organic contaminant in landfill leachate-contaminated groundwater under micro-nano-bubble and common bubble aeration | |
| Wei et al. | Aerobic biodegradation of 2, 6-dichlorophenol in a nitrifying granular sludge reactor: system performance and microbial community evolution | |
| CN103304097B (en) | Method for combined treatment of wastewater of phenol-containing gas by ozone flocculant | |
| Yang et al. | Electro-dissolved ozone flotation (E-DOF) integrated anoxic/oxic membrane reactor for leachate treatment from a waste transfer station | |
| CN104261556B (en) | A kind of method starting short-cut nitrification technology under antiphlogiston existence condition | |
| CN108558001B (en) | Biological activator for in-situ remediation of polluted water and bottom mud and use method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140108 |