CN103492614A - Process and apparatus for the preparation of combustible fluid - Google Patents

Process and apparatus for the preparation of combustible fluid Download PDF

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Publication number
CN103492614A
CN103492614A CN201180048546.9A CN201180048546A CN103492614A CN 103492614 A CN103492614 A CN 103492614A CN 201180048546 A CN201180048546 A CN 201180048546A CN 103492614 A CN103492614 A CN 103492614A
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China
Prior art keywords
bath
water
liquid hydrocarbon
electrolysis
encloses container
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Pending
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CN201180048546.9A
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Chinese (zh)
Inventor
G·J·贝休雷姆
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Advanced Person's Combustion Technology Limited-Liability Co
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Advanced Person's Combustion Technology Limited-Liability Co
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Publication of CN103492614A publication Critical patent/CN103492614A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • C10G32/02Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by electric or magnetic means
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/04Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1037Hydrocarbon fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006Temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80Additives
    • C10G2300/805Water
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A fuel and hydrogen generator includes electrolysis in a first closed vessel containing a bath of water, electrolyte and sufficient liquid hydrocarbon fuel to serve as an oxygen barrier. The hydrogen produced in the first closed vessel is introduced into a second closed vessel having a bath of water, electrolyte and liquid hydrocarbon fuel in an amount volumetrically equal to the water. Electrodes extend through the liquid hydrocarbon fuel to the water to conduct electrolysis. Makeup water and liquid hydrocarbon fuel is supplied to both closed vessels as needed. The bath in the second closed vessel is recirculated to entrain all constituents within the bath and to cool the bath to ambient temperature. Gas is drawn off of the bath in the second closed vessel though vacuum with constituents then fractionally liquefied to create a reformed liquid hydrocarbon fuel and to separate the fuel from the gaseous hydrogen.

Description

Method and apparatus for the preparation of flammable fluid
Technical field
The field of the invention is the hydrocarbon refining.
Background technology
Brine electrolysis be take and produced hydrogen and oxygen as well-known.Known HHO producer also, but it utilizes electrolysis that water is converted into to its integral part does not separate once d/d hydrogen and oxygen.Such device burns to improve for direct charging oil engine.In Modern Engine, when oxygen sensor sensing oxygen changes, oxygen sensor is for controlling air fuel mixture.Even the oxygen of being introduced by the HHO producer is stoichiometric ratio with the hydrogen of also introducing, oxygen sensor does not calculate the inflammable hydrogen added, and the excessive oxygen of sensing.Result is, must revise the adjustment of engine, to consider introducing hydrogen together with the other oxygen with producer from such.In addition, because the stoichiometric mixture of oxygen and hydrogen has explosivity, have the threshold value input of energy, such producer is generally used for providing immediately burning, makes explosive mixture not accumulate.Be supplied to air-intake of combustion engine and be intended to operate in every way to improve performance for the HHO that advances liquid hydrocarbon fuels operation, raise the efficiency and/or reduce exhaust contaminant.Also do not set up the such device of commercialization in the urgent need to, the result of mixing has caused further research.
For the hydrocarbon liquid fuel wide scope of oil engine, wherein the most conventional fuel is gasoline, diesel oil and kerosene.These liquid are the hydrocarbon with blend of various molecular weight and structure.The size of such molecule and structure can affect rate of combustion and emitted exhaust products.Additive is for changing those impacts.
Summary of the invention
The present invention relates to for example, produce by liquid hydrocarbon fuels (gasoline, diesel oil and kerosene) fuel of reforming, it seems that burning is more clean, and provides substantial energy for burning in using than the oil engine of the hydrocarbon blends of lightweight.
Of the present invention first independently aspect, be included in the bath mainly formed by water, ionogen and liquid hydrocarbon and carry out electrolysis for the preparation of the method for flammable fluid, remove gas from bath during electrolysis, and add make up water and liquid hydrocarbon, to realize successive processes.In carrying out the method, the volumetric ratio of hydrocarbon fuel and water can extremely only be limited to the very little ratio ranges of the oxygen barrier (oxygen barrier) above water from about 6:1 with a small amount of hydrocarbon fuel.Different ratios can affect the final blend of resulting hydrocarbon component.
Of the present invention second independently aspect, be included in the bath mainly formed by water, ionogen and liquid hydrocarbon and carry out electrolysis for the preparation of the method for flammable fluid.The method also comprises that the circulation liquid phase is to keep midbody product to suspend for further processing.The electrolysis imagination extends into the electrode with opposite polarity of hydrocarbon and water in bath.The two all can be used for keeping the envrionment temperature in bath voltage-regulation between electrode and recirculation.Neutral electrode can be used for making impedance and power supply coupling in addition, to increase efficiency.
The of the present invention the 3rd independently aspect, a plurality of baths that mainly formed by water, ionogen and liquid hydrocarbon according to the ratio of different liquid hydrocarbon fuels and water by continuous arrangement.Bathing associates continuously is considered to the ratio that meeting affects the product obtained.
The of the present invention the 4th independently aspect, fuel generator adopts encloses container, water, liquid hydrocarbon fuels, ionogen and extend into the electrode with opposite polarity of hydrocarbon and water in container.Electrolysis causes water and liquid hydrocarbon fuels to be converted into hydrogen and new formulated fuel.The vacuum pump be communicated with the gas space in encloses container is removed the product that may volatilize, and the initial liquid hydrocarbon fuels that can significantly not volatilize.
The of the present invention the 5th independently aspect, any aforementioned aspect is capable of being combined to better result.
Therefore, an object of the present invention is to provide a kind of new method for generation of new formula hydrocarbon fuel.Other and further purpose and advantage hereinafter will be described.
The accompanying drawing explanation
The schematic diagram of the method and apparatus that accompanying drawing is one embodiment of the present invention.
Embodiment
By schematic diagram, the first encloses container 10 is included in anode in chamber 14 and the arrangement of negative electrode 12.Neutral electrode also can be used for making impedance and power supply coupling to make maximizing efficiency, and this point can be determined by rule of thumb.The electrode adopted in a preferred embodiment is for extending the plate 12 across the alter polarity of crossing chamber 14.Used stainless steel, but known rarer metal can improve the plate life-span.Electricity input 16 is communicated with electrode 12 routinely.This first encloses container 10 contains the main bath be comprised of the thin layer of water, ionogen and liquid hydrocarbon fuels in chamber 14.Ionogen can be introduced into as potassium hydroxide.Fuel can be in the environment of bathing as any flammable hydrocarbons of liquid, is generally gasoline, diesel oil fuel or kerosene most.The layer of liquid hydrocarbon fuels is enough to formation oxygen barrier on water.In most of the cases, be less than 1/4th inches just enough.Electrode 12 extends in water by the hydrocarbon layer.
By the power drives electrolysis, described power supply can be other voltage of battery, 110AC or rectification as required and originates.System is operational excellence under 19 volts, for encloses container 10 is drawn approximately 3 amperes.Power supply stands voltage pulse by spells, to be reduced in the generation of heat in bath.
For raw material, make up water is introduced by hole 18, and liquid hydrocarbon fuels supplements by hole 20.Gas in encloses container 10 interior generations extracts by the hole 22 be positioned on fluid level.
The second encloses container 24 is by hole 22 and encloses container 10 couplings, and in hole, 26 places accept the gas produced by the first container 10 to encloses container 24 thus.Encloses container 24 comprises the chamber 28 of the electrode 30 with alter polarity, described electrode 30 in the bath mainly formed by water, ionogen and liquid hydrocarbon fuels by hydrocarbon fuel and in extending to water.Electrode 30 in this embodiment is for the hydrocarbon fuel by bathing and extend to the stainless steel plate in water.Rarer metal may improve the life-span, as mentioned above.26 position, hole is lower than the bath in encloses container 24, so that hydrogen is introduced to electrolytic process.Can adopt identical ionogen in the second bath, but, compared with first bath, the volume ratio of liquid hydrocarbon fuels and water is much higher.As if under the ratio of about 6:1, the efficiency at this in preferred embodiment maximizes.Equally, as mentioned above for the power supply of electrolytic process as be 19 volts to the first encloses container 10, when power pulse, draw approximately 3 amperes in encloses container 24.Each in these parameters experiences experience adjustments, makes maximizing efficiency in the environment of each reactor vessel.
During electrolytic process in the second encloses container 24, wherein contained liquid is recycled to groove 36 by recirculating pump 34 by hole 32.Groove 36 has the second composition of bathing that comprises some intermediate hydrocarbon materials, and they circulate and return in bath together with water.From groove 36, recirculation continues by interchanger 38, and returns to the bath of the second encloses container 24 by hole 40.
As raw material, during the water yield in electrolysis reduction system, tank 42 provides make up water in groove 36.Hydrocarbon fuel groove 44 is liquid make-up fuel composition as required also. Solenoid coil 46 and 48 is controlled respectively tank 42 and fuel bath 44.It is that the first encloses container is supplied raw materials that identical source can be used for, as shown in schematic diagram.
Other hole 50 be positioned in the second encloses container 24 on fluid level makes gas be involved in safe bubbler 52, enters subsequently vacuum pump/compressor assembly 54.Vacuum pump/compressor assembly 54 vacuumizes on encloses container 24, and the product of compression sub-fraction gasification becomes liquid and is delivered in groove 56.Extracting vacuum lenitively.When starting, foaming is a problem, and postpones the operation of vacuum pump/compressor 54.Once bathe, moved a little while, foaming reduces and vacuum-pumping.Owing to bathing, be the blend of liquid hydrocarbon, the level of vacuum will affect component volatilization.Used the maximum value of subatmospheric 10 pounds/square inchs.Avoid like this standing in bath removing the raw material liquid hydrocarbon fuel at the bath bottom any raw water of volatilization or flash distillation before certain residence time.Level of vacuum can be used for changing the residence time of volatile hydrocarbon in the second bath, and this is considered to can the required final mixture of impact.The hydrogen that compressor one side can not liquefy and produce during this process, be transported to separately the second groove 58 by hydrogen.Certainly, each in the product of these fractionation all can be guided other device into for processing or be used.
Directly observe this process, the bath (being mainly water) in the first encloses container 10 stands electrolysis, produces hydrogen and oxygen.Guide power supply into electrolytic process, make do not occur overheated, as discussed above.Hydrogen is by fluid level and from the hole 22 of container 10.Due to the thin layer of the liquid hydrocarbon fuels on water surface in encloses container 10, by the anti-block of this barrier, from bathing, overflow.
Be provided to the second encloses container 24 from the hydrogen of encloses container 10 and enter hole 26.The hydrogen that uses ionogen and discharge from encloses container 10, second container 24 carries out electrolysis in having the environment that contains liquid hydrocarbon fuels and the much bigger bath of water ratio.The alternately electrode 30 of opposite polarity that has extended in water by hydrocarbon fuel completes electrolysis.Electrolytic process is approximately moving in 50% circulation of opening with 50% pass.Circulate on every side and control the temperature decline in keeping bathing in this 50% power supply supply, efficiency seems and maximizes.Found that power-cycled makes 30 duration of charging of electrode approximately 50% produce thus larger operational efficiency.
In order further to keep temperature and to be retained in all components in the process of carrying secretly in bath, the component recirculation of bathing is passed through to pump 34 and groove 36.Make cooling being included in this recirculation flow by interchanger 38.Advantageously keep bathing at ambient temperature.As if intermediate hydrocarbon material circulates and is back in bath together with water, so this finally is converted into dark hydrocarbon material (intermediate in conversion process) volatile hydrocarbon of expectation.
By safe bubbler 52, by vacuum pump/compressor 54, in the second encloses container 24 on bathe extracting gases, compression, if necessary, again cooling subsequently, under atmospheric pressure to produce stable liquid.Hydrogen is by the hydrocarbon fuel nature fractionation of such generation.As mentioned above, regulate vacuum, make not gasified raw material water, and allow certain residence time of liquid hydrocarbon fuels.In second container 24 operation of electrolysis reduce hydrocarbon to the component in resulting liquid fuel than the lightweight blend.By in the second bath, controlling the residence time, the resulting blend of the hydrocarbon component of volatilization is considered to change weight.
Therefore, the process that the described producer of gas and fuel generator and use produces reconstituted liquid hydrocarbon fuels is disclosed.Although shown and described embodiments of the present invention and application, to those skilled in the art, in the situation that do not depart from idea of the present invention herein, many further modifications are apparent.Therefore, except in the spirit of claims, the present invention is not limited to this.

Claims (10)

1. the method for the preparation of flammable fluid, described method comprises:
Carry out electrolysis in the bath mainly formed by water, ionogen and liquid hydrocarbon fuels;
Removing gas during electrolysis above bathing;
Make up water and liquid hydrocarbon fuels are provided during described electrolysis.
2. method according to claim 1, wherein, described method also comprises:
Carry out electrolysis in the second bath formed at the main liquid hydrocarbon by water, ionogen and second amount;
To be incorporated into the water of the second bath at the gas of removing from first bath during electrolysis;
Removing gas during electrolysis above the second bath;
Provide make up water and liquid hydrocarbon to the second bath during described electrolysis.
3. method according to claim 1 and 2, wherein, the process of removing gas at least one from first bath and second is bathed comprises uses the vacuum pump extracting gases, vacuum tightness enough hang down with by volatile constituent and raw material moisture from.
4. method according to claim 1 and 2, wherein, in first bath and second is bathed, at least one of electrolysis is to carry out between the electrode with opposite polarity in extending to hydrocarbon fuel and water.
5. method according to claim 1 and 2, wherein, described method also comprises:
The gas that grading liquefaction is removed above first bath at least; With
Therefrom separate hydrogen.
6. method according to claim 1 and 2, wherein, described method also comprises:
Be cooled to envrionment temperature by recirculation at least from the liquid of described bath with by recycled liquid or by intermittent earth pulse for the voltage of electrolysis to keep temperature, make at least first bath remain on envrionment temperature.
7. method according to claim 1 and 2, wherein, in first bath and second is bathed at least one, the amount of liquid hydrocarbon fuels is enough to formation oxygen barrier above the water in described bath.
8. a fuel generator, described fuel generator comprises:
Encloses container;
Water in described encloses container, liquid hydrocarbon and ionogen;
Extend into the electrode with opposite polarity in hydrocarbon and water in encloses container; With,
The vacuum pump be connected with the gas space in water and the encloses container above hydrocarbon.
9. fuel generator according to claim 8, wherein, described fuel generator also comprises:
The second encloses container;
Water, liquid hydrocarbon and ionogen in described the second encloses container;
Extend into the electrode with opposite polarity in hydrocarbon and water in the second encloses container,
The vacuum pump be connected with the gas space in water and the second encloses container above hydrocarbon; With,
The scatterer be connected with vacuum pump at least the first encloses container.
10. fuel generator according to claim 8 or claim 9, wherein, at least one in first bath and second is bathed, the amount of liquid hydrocarbon fuels is enough to formation oxygen barrier above the water in described bath.
CN201180048546.9A 2010-08-12 2011-08-12 Process and apparatus for the preparation of combustible fluid Pending CN103492614A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/855,617 US20120037510A1 (en) 2010-08-12 2010-08-12 Process and apparatus for the preparation of combustible fluid
US12/855,617 2010-08-12
PCT/US2011/047662 WO2012021850A1 (en) 2010-08-12 2011-08-12 Process and apparatus for the preparation of combustible fluid

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CN103492614A true CN103492614A (en) 2014-01-01

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US (1) US20120037510A1 (en)
EP (1) EP2603619A4 (en)
CN (1) CN103492614A (en)
AU (1) AU2011289250A1 (en)
CA (1) CA2812080A1 (en)
WO (1) WO2012021850A1 (en)

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EP2465915B1 (en) * 2010-12-20 2013-02-20 Impara Finanz AG Combustible gas composition
US9267428B2 (en) 2012-02-27 2016-02-23 Deec, Inc. Oxygen-rich plasma generators for boosting internal combustion engines
AU2017229114B2 (en) 2016-03-07 2023-01-12 HyTech Power, Inc. A method of generating and distributing a second fuel for an internal combustion engine
US20190234348A1 (en) 2018-01-29 2019-08-01 Hytech Power, Llc Ultra Low HHO Injection

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US5176809A (en) * 1990-03-30 1993-01-05 Leonid Simuni Device for producing and recycling hydrogen
CN2375642Y (en) * 1998-12-25 2000-04-26 阜新化工设备有限责任公司 Hydrogen generator by electrolysis of water
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US20070080071A1 (en) * 2005-10-12 2007-04-12 All My Relations, Inc. Internal combustion apparatus and method utilizing electrolysis cell
US20090301407A1 (en) * 2006-03-08 2009-12-10 Martinrea International Inc. Electrolyte Delivery System
US20100038236A1 (en) * 2008-08-18 2010-02-18 Alex Rivera Hydrogen-from-water on-demand supplemental vehicle fuel electrolyzer system

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Publication number Priority date Publication date Assignee Title
US5176809A (en) * 1990-03-30 1993-01-05 Leonid Simuni Device for producing and recycling hydrogen
CN2375642Y (en) * 1998-12-25 2000-04-26 阜新化工设备有限责任公司 Hydrogen generator by electrolysis of water
US7191737B2 (en) * 2002-10-22 2007-03-20 Hydrogen Technology Applications, Inc. Hydrogen generator for uses in a vehicle fuel system
US20070080071A1 (en) * 2005-10-12 2007-04-12 All My Relations, Inc. Internal combustion apparatus and method utilizing electrolysis cell
US20090301407A1 (en) * 2006-03-08 2009-12-10 Martinrea International Inc. Electrolyte Delivery System
US20100038236A1 (en) * 2008-08-18 2010-02-18 Alex Rivera Hydrogen-from-water on-demand supplemental vehicle fuel electrolyzer system

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EP2603619A1 (en) 2013-06-19
EP2603619A4 (en) 2014-03-19
CA2812080A1 (en) 2012-02-16
US20120037510A1 (en) 2012-02-16
WO2012021850A1 (en) 2012-02-16
AU2011289250A1 (en) 2013-04-04

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Application publication date: 20140101