CN103483911A - Black ink and preparation method thereof - Google Patents
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- CN103483911A CN103483911A CN201310436279.3A CN201310436279A CN103483911A CN 103483911 A CN103483911 A CN 103483911A CN 201310436279 A CN201310436279 A CN 201310436279A CN 103483911 A CN103483911 A CN 103483911A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000008367 deionised water Substances 0.000 claims abstract description 25
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000000080 wetting agent Substances 0.000 claims abstract description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 30
- 241000283690 Bos taurus Species 0.000 claims description 24
- 241000219991 Lythraceae Species 0.000 claims description 24
- 235000014360 Punica granatum Nutrition 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- 239000004021 humic acid Substances 0.000 claims description 20
- 159000000000 sodium salts Chemical class 0.000 claims description 20
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 11
- 241000628997 Flos Species 0.000 claims description 9
- 235000003599 food sweetener Nutrition 0.000 claims description 9
- 239000003765 sweetening agent Substances 0.000 claims description 9
- 239000004287 Dehydroacetic acid Substances 0.000 claims description 8
- 235000019258 dehydroacetic acid Nutrition 0.000 claims description 8
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 claims description 8
- 229940061632 dehydroacetic acid Drugs 0.000 claims description 8
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 8
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 8
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 7
- 235000010234 sodium benzoate Nutrition 0.000 claims description 7
- 239000004375 Dextrin Substances 0.000 claims description 6
- 229920001353 Dextrin Polymers 0.000 claims description 6
- 235000019425 dextrin Nutrition 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000004299 sodium benzoate Substances 0.000 claims description 6
- 239000000230 xanthan gum Substances 0.000 claims description 6
- 235000010493 xanthan gum Nutrition 0.000 claims description 6
- 229920001285 xanthan gum Polymers 0.000 claims description 6
- 229940082509 xanthan gum Drugs 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- 150000004676 glycans Chemical class 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 229960004418 trolamine Drugs 0.000 claims description 5
- 238000002525 ultrasonication Methods 0.000 claims description 5
- 239000006071 cream Substances 0.000 claims description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 4
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 235000010199 sorbic acid Nutrition 0.000 claims description 4
- 239000004334 sorbic acid Substances 0.000 claims description 4
- 229940075582 sorbic acid Drugs 0.000 claims description 4
- 239000003205 fragrance Substances 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000000049 pigment Substances 0.000 abstract description 4
- 239000003381 stabilizer Substances 0.000 abstract description 3
- 239000000796 flavoring agent Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 235000019634 flavors Nutrition 0.000 abstract 1
- 235000013355 food flavoring agent Nutrition 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 43
- 239000000047 product Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 4
- 210000000795 conjunctiva Anatomy 0.000 description 4
- 230000003292 diminished effect Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 239000013065 commercial product Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 235000019615 sensations Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 1
- 244000223014 Syzygium aromaticum Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
The invention discloses black ink by using sodium humate as pigment and preparation method thereof. The black ink comprises the following ingredients by weight percent: 5-10% of sodium humate pigment, 5-10% of a stabilizer, 5-15% of a wetting agent, 5-10% of a dispersing agent, 0.1-0.3% of an aseptic, 0.2-0.5% of a defoaming agent, 0.5-1.0% of a blackening agent, 0.2-0.4% of a flavoring agent, 50-70% of deionized water. The ink provided by the invention has the advantages of environmental protection, simple technology, low cost, fluency for writing, high stability in performance, richness in color, fragrance in flavor and the like.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, is a kind of black ink that Sodium salts humic acids is colorant and preparation method thereof of take specifically.
Background technology
Ink is a kind of liquid that contains pigment or dyestuff, and ink is used to write or paint.Contain some chemical substances to the human injury in the formula of ink, and the ink marks of most of pigment is easy to fade, is unfavorable for the preservation of manuscript.Burnt black ink is the most popular black ink of present fountain pen, main colorant is carbon black, carbon black is the product of organism incomplete combustion or cracking, main component is carbon, it is a kind of not hydrophilic black powder, even grind very carefully by it, can not make ink after adding water, must be treated or add the auxiliary agent with specific function, just can make ink, this complex process, expense is higher, " three wastes " are serious, and because water solid content is generally higher, it is water insoluble also not from dispersed, the long-time placement easily produces layering and precipitation, also easily cause nib to stop up, usually can add dispersion agent for solving such problem, stablizer, suspension agent, emulsifying agent etc., the carbon black long-term stability is disperseed in water, suspend, complicacy and the cost of technique have been increased.The general existence of burnt black ink is write not smooth, if intermittently write, is easy to the dry phenomenon of consequently stopping up a tool, more can not meet computer graphics.
Pollution-free is the basic demand of modern society to ink, so will reduce poisonous and corrodibility composition in the formula of ink as far as possible.This major embodiment is to the more water-based ink development of environmental protection concept by organic solvent type.Therefore, invent a kind of environmental protection, be difficult for an obstruction tool and Novel black chromatic ink with low cost and extremely be necessary.
Summary of the invention
The object of the invention is to provide a kind of environmental protection, cost performance is high, technique is simple, the black ink of the obstruction of anti-nib, taste delicate fragrance, stable performance, this ink composition and mass percent are: Sodium salts humic acids 5-10%, stablizer 5-15%, wetting agent 5-15%, dispersion agent 5-10%, sanitas 0.1-0.3%, defoamer 0.2-0.5%, deionized water 30-70%.
Wetting agent described in the present invention be in glycerine, ethylene glycol, trolamine one or both arbitrarily than mixture.
Dispersion agent described in the present invention be in water miscible polyacrylate, xanthan gum, dextrin one or both arbitrarily than mixture.
Sanitas described in the present invention is a kind of in dehydroacetic acid (DHA), Sodium Benzoate, Sorbic Acid.
Defoamer described in the present invention be in trimethylammonium silicone oil, dimethyl polysiloxane, silicone cream one or both arbitrarily than mixture.
Can also add the blackening agent of mass percent 0.5-1.0%, the sweetener of mass percent 0.2-0.4% in ink of the present invention, described blackening agent is pomegranate rind juice, sweetener is Flos Caryophylli extract, wherein pomegranate rind juice preparation method is as follows: pomegranate rind is reduced to pulp, the ratio of adding 200-300g water in 100g adds water in slurry, mix and be placed on 50-70 ℃ of ultrasonication 25-30 minute, filter cleaner obtains pomegranate rind juice; Flos Caryophylli extract is conventional commercial product.
The preparation method of black ink of the present invention is as follows:
(1) deionized water of mass percent 50-70% is divided into to two parts, portion is heated to 78-82 ℃, mass percent 5-10% dispersion agent, mass percent 5-15% stablizer are added in the deionized water after heating, stir, speed from slow to fast, control rotating speed 500-1500r/min, be stirred to the water white transparency shape;
(2) add the wetting agent of mass percent 5-15%, continue fully to stir 8-12 minute;
(3) add the Sodium salts humic acids stirring and dissolving of mass percent 5-10% in another part of deionized water, sodium humate solution is added in step (2) solution, mix, then add the defoamer of mass percent 0.2-0.5%, stir 35-45 minute;
(4) finally add the sanitas of mass percent 0.1-0.3%, stir and make system even in 25-30 minute, standing, filtration, obtain black ink.
In preparation method of the present invention, the blackening agent of mass percent 0.5-1.0% adds in step (3), and the sweetener of mass percent 0.2-0.4% adds in step (4).
In the present invention, Sodium salts humic acids is conventional commercial product.
Sodium salts humic acids is pitch-black bright, dodging the indefiniteness particle of beautiful gloss, its solution is ink black, system is by the multifunctional macromolecule compound proposed in the brown coal coal, the similar carbon black color paste of performance but, without water insoluble composition, have very large internal surface area, stronger absorption is arranged, exchange, complexing, sequestering power.Sodium salts humic acids does not have toxicity and corrodibility, and degradable after using is very easily water-soluble, forms solution, standingly can layering not form precipitation for a long time yet, and good stability, make colorant with it and can solve the currently available technology deficiency.Sodium salts humic acids itself just has anticorrosionly in addition, and anti-microbial effect, can reduce the sanitas consumption; Sodium salts humic acids, at the industrial stablizer that is used as water, can reduce stabilizing agent dosage.
Black ink of the present invention is by fountain pen ink industry standard---and non-pigmentary type ink QB/T 1745.1-2011 test method is tested, and all technical all reaches criterion of acceptability.
The present invention has the following advantages:
1, Sodium salts humic acids is nontoxic, very easily water-soluble, saves use solubilizing agent, and Sodium salts humic acids itself just has anticorrosion, and stabilization can reduce sanitas, stabilizing agent dosage;
2, technique is simple, with low cost, and taste delicate fragrance, color are strong;
3, fluent writing is durable, and stable performance can not stopped up nib;
4, used the pomegranate rind of medicine-food two-purpose, cloves, Sodium Benzoates etc. are done raw material, safety, green natural environmental protection, cost performance is high.
Embodiment
Below by embodiment, the present invention is described in further detail, but does not therefore limit the present invention in described content.
embodiment 1:the constituent of this black ink and mass percent are: Sodium salts humic acids 5%, stablizer PEG glycan 5%, wetting agent (glycerine, ethylene glycol) 12.8%, dispersion agent polyacrylate 5%, preservative sodium benzoate 0.3%, defoamer trimethylammonium silicone oil 0.5%, deionized water 70%, blackening agent pomegranate rind juice 1.0%, sweetener Flos Caryophylli extract 0.4%.
The preparation method of this black ink is as follows:
(1) deionized water of mass percent 700g is divided into to two parts, a 500g is heated to 80 ℃, and 50g polyacrylate, 50g PEG glycan are added in the deionized water after heating, stir, speed from slow to fast, is controlled rotating speed 1500r/min, is stirred to the water white transparency shape;
(2) add the wetting agent (80g glycerine, 48g ethylene glycol) of 128g, continue fully to stir 10 minutes;
(3) add 50g Sodium salts humic acids stirring and dissolving in another part of 200g deionized water, sodium humate solution is added to step
(2) in solution, mix, then add 1g pomegranate rind juice, 5g trimethylammonium silicone oil, stir 40 minutes;
(4) finally add 3g Sodium Benzoate, Flos Caryophylli extract 4g, stir and make system even in 30 minutes, standing 24h, filtration under diminished pressure, obtain black ink.
Wherein pomegranate rind juice preparation method is as follows: pomegranate rind reduces to pulp, and adds 300g water in the 100g slurry, mixes and is placed on 70 ℃ of ultrasonication 25 minutes, and filter cleaner obtains pomegranate rind juice.
Product appearance: ink no suspended substance, conjunctiva, layering, deposited phenomenon, color is strong, taste delicate fragrance; This product is used through 20 teachers and students in school, the panesthesia fluent writing, and writing is clear, halo-free dying.
By QB/T 1745.1-2011 test method result contrast: the that tests
embodiment 2:the constituent of this black ink and mass percent are: Sodium salts humic acids 10%, stablizer PEG glycan 13.8%, wetting agent (glycerine, trolamine) 15%, dispersion agent xanthan gum 10%, sanitas Sorbic Acid 0.2%, defoamer trimethylammonium silicone oil 0.3%, deionized water 50%, blackening agent pomegranate rind juice 0.5%, sweetener Flos Caryophylli extract 0.2%.
The preparation method of this black ink is as follows:
(1) deionized water of mass percent 500g is divided into to two parts, a 300g is heated to 82 ℃, and 138g PEG glycan, 100g xanthan gum are added in the deionized water after heating, stir, speed from slow to fast, is controlled rotating speed 1000r/min, is stirred to the water white transparency shape;
(2) add the wetting agent (100g glycerine, 50g ethylene glycol) of 150g, continue fully to stir 12 minutes;
(3) add 100g Sodium salts humic acids stirring and dissolving in another part of 200g deionized water, sodium humate solution is added in step (2) solution, mix, then add 5g pomegranate rind juice, 3g trimethylammonium silicone oil, stir 35 minutes;
(4) finally add 1g Sorbic Acid, 2g Flos Caryophylli extract, stir and make system even in 25 minutes, standing 24h, filtration under diminished pressure, obtain black ink;
Wherein pomegranate rind juice preparation method is as follows: pomegranate rind reduces to pulp, and adds 250g water in the 100g slurry, mixes and is placed on 60 ℃ of ultrasonication 28 minutes, and filter cleaner obtains pomegranate rind juice.
Product appearance: ink no suspended substance, conjunctiva, layering, deposited phenomenon, color is strong, taste delicate fragrance.The present embodiment ink offers 20 teachers and students in school and uses, and the sensation fluent writing, intermittently write, still can be good out of ink, and writing is in sharp contrast, color is glossy.
By the test result contrast of QB/T 1745.1-2011 test method
embodiment 3:the constituent of this black ink and mass percent are: Sodium salts humic acids 8%, stablizer polyvinyl alcohol 15%, wetting agent glycerine 5%, dispersion agent dextrin 8%, preservative sodium benzoate 0.1%, defoamer (trimethylammonium silicone oil, dimethyl polysiloxane) 0.2%, deionized water 62.7%, blackening agent pomegranate rind juice 0.7%, sweetener Flos Caryophylli extract 0.3%.
The preparation method of this black ink is as follows:
(1) deionized water of mass percent 627g is divided into to two parts, a 427g is heated to 78 ℃, and 150g polyvinyl alcohol, 80g dextrin are added in the deionized water after heating, stirs, and speed from slow to fast, is controlled rotating speed 500r/min, is stirred to the water white transparency shape;
(2) add the wetting agent glycerine of 50g, continue fully to stir 8 minutes;
(3) add 80g Sodium salts humic acids stirring and dissolving in another part of 200g deionized water, sodium humate solution is added in step (2) solution, mix, then add 7g pomegranate rind juice, 2g defoamer (1g trimethylammonium silicone oil, 1g dimethyl polysiloxane) 0.2%, stir 45 minutes;
(4) finally add 1g Sodium Benzoate, 3g Flos Caryophylli extract, stir and make system even in 30 minutes, standing 24h, filtration under diminished pressure, obtain black ink;
Wherein pomegranate rind juice preparation method is as follows: pomegranate rind reduces to pulp, and adds 200g water in the 100g slurry, mixes and is placed on 50 ℃ of ultrasonication 30 minutes, and filter cleaner obtains pomegranate rind juice.
Product appearance: ink no suspended substance, conjunctiva, layering, deposited phenomenon, color is strong, taste delicate fragrance; The present embodiment offers 20 teachers and students in school and uses, the sensation fluent writing, and writing is in sharp contrast, and lines are full.
By the test result contrast of QB/T 1745.1-2011 test method
embodiment 4:the constituent of this black ink and mass percent are: Sodium salts humic acids 9%, stablizer polyvinyl alcohol 11.3%, wetting agent (ethylene glycol, trolamine) 14%, dispersion agent 10%(dextrin, xanthan gum), sanitas dehydroacetic acid (DHA) 0.3%, defoamer silicone cream 0.4%, deionized water 55%.
The preparation method of this black ink is as follows:
(1) deionized water of mass percent 550g is divided into to two parts, a 350g is heated to 80 ℃, 100g dispersion agent (DEXTRIN g, xanthan gum 60g), 113g polyvinyl alcohol are added in the deionized water after heating, stir, speed from slow to fast, control rotating speed 800r/min, be stirred to the water white transparency shape;
(2) add the wetting agent (70g ethylene glycol, 70g trolamine) of 140g, continue fully to stir 10 minutes;
(3) add 90g Sodium salts humic acids stirring and dissolving in another part of 200g deionized water, sodium humate solution is added in step (2) solution, mix, then add 4g silicone cream, stir 40 minutes;
(4) finally add the 3g dehydroacetic acid (DHA), stir and make system even in 30 minutes, standing 24h, filtration under diminished pressure, obtain black ink.
Product appearance: ink no suspended substance, conjunctiva, layering, deposited phenomenon, color is strong; This product is used through 20 teachers and students in school, the panesthesia fluent writing, and writing is clear, halo-free dying.
By QB/T 1745.1-2011 test method result contrast: the that tests
Claims (10)
1. a black ink, is characterized in that its constituent and mass percent are: Sodium salts humic acids 5-10%, stablizer 5-15%, wetting agent 5-15%, dispersion agent 5-10%, sanitas 0.1-0.3%, defoamer 0.2-0.5%, deionized water 50-70%.
2. black ink according to claim 1, it is characterized in that: stablizer is PEG glycan or polyvinyl alcohol.
3. black ink according to claim 1 is characterized in that: wetting agent is one or both mixture in glycerine, ethylene glycol, trolamine.
4. black ink according to claim 1 is characterized in that: dispersion agent is one or both mixture in polyacrylate, xanthan gum, dextrin.
5. black ink according to claim 1, it is characterized in that: sanitas is a kind of in dehydroacetic acid (DHA), Sodium Benzoate, Sorbic Acid.
6. black ink according to claim 1 is characterized in that: defoamer is one or both mixture in trimethylammonium silicone oil, dimethyl polysiloxane, silicone cream.
7. black ink according to claim 1, is characterized in that: also comprise the blackening agent of mass percent 0.5-1.0%, the sweetener of mass percent 0.2-0.4% in ink.
8. black ink according to claim 7, it is characterized in that: blackening agent is pomegranate rind juice, sweetener is Flos Caryophylli extract, wherein pomegranate rind juice preparation method is as follows: pomegranate rind is reduced to pulp, the ratio of adding 200-300g water in 100g adds water in slurry, mix and be placed on 50-70 ℃ of ultrasonication 25-30 minute, filter cleaner obtains pomegranate rind juice.
9. the preparation method of the described black ink of claim 1-8 any one is characterized in that concrete operation step is as follows:
(1) deionized water of mass percent 50-70% is divided into to two parts, portion is heated to 78-82 ℃, mass percent 5-10% dispersion agent, mass percent 5-15% stablizer are added in the deionized water after heating, stir, speed from slow to fast, control rotating speed 500-1500r/min, be stirred to the water white transparency shape;
(2) add the wetting agent of mass percent 5-15%, continue fully to stir 8-12 minute;
(3) add the Sodium salts humic acids stirring and dissolving of mass percent 5-10% in another part of deionized water, sodium humate solution is added in step (2) solution, mix, then add the defoamer of mass percent 0.2-0.5%, stir 35-45 minute;
(4) finally add the sanitas of mass percent 0.1-0.3%, stir and make system even in 25-30 minute, standing, filtration, obtain black ink.
10. the preparation method of black ink according to claim 9, it is characterized in that: the blackening agent of mass percent 0.5-1.0% adds in step (3), and the sweetener of mass percent 0.2-0.4% adds in step (4).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310436279.3A CN103483911B (en) | 2013-09-24 | 2013-09-24 | Black ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310436279.3A CN103483911B (en) | 2013-09-24 | 2013-09-24 | Black ink and preparation method thereof |
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| CN103483911A true CN103483911A (en) | 2014-01-01 |
| CN103483911B CN103483911B (en) | 2014-10-01 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104592811A (en) * | 2015-02-04 | 2015-05-06 | 韦棋 | Environment-friendly black ink |
| CN108359311A (en) * | 2018-05-25 | 2018-08-03 | 上海晨光文具股份有限公司 | Aqueous anti-dizzy dye ink |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0148412A1 (en) * | 1983-12-12 | 1985-07-17 | Union Camp Corporation | Use of humates in printing inks |
| JPS61106683A (en) * | 1984-10-30 | 1986-05-24 | Pentel Kk | Water-based ink for ball-point pen |
| CN1504522A (en) * | 2002-11-28 | 2004-06-16 | ������������ʽ���� | Black ink composition, ink set, recording method and recorded matter |
| CN101809100A (en) * | 2007-09-26 | 2010-08-18 | 百乐墨水株式会社 | Water-based ink composition for ballpoint pens |
| CN102190921A (en) * | 2010-03-01 | 2011-09-21 | 富士胶片株式会社 | Ink composition, ink set and image forming method using the same |
-
2013
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0148412A1 (en) * | 1983-12-12 | 1985-07-17 | Union Camp Corporation | Use of humates in printing inks |
| JPS61106683A (en) * | 1984-10-30 | 1986-05-24 | Pentel Kk | Water-based ink for ball-point pen |
| CN1504522A (en) * | 2002-11-28 | 2004-06-16 | ������������ʽ���� | Black ink composition, ink set, recording method and recorded matter |
| CN101809100A (en) * | 2007-09-26 | 2010-08-18 | 百乐墨水株式会社 | Water-based ink composition for ballpoint pens |
| CN102190921A (en) * | 2010-03-01 | 2011-09-21 | 富士胶片株式会社 | Ink composition, ink set and image forming method using the same |
Non-Patent Citations (1)
| Title |
|---|
| 贾维妮: "石榴皮染料的提取及其在真丝绸染色中的应用", 《针织工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104592811A (en) * | 2015-02-04 | 2015-05-06 | 韦棋 | Environment-friendly black ink |
| CN104592811B (en) * | 2015-02-04 | 2016-11-30 | 马健 | A kind of environmental protection black ink |
| CN108359311A (en) * | 2018-05-25 | 2018-08-03 | 上海晨光文具股份有限公司 | Aqueous anti-dizzy dye ink |
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