CN103483825A - Formula of permanent deformation prevention type buffer block - Google Patents

Formula of permanent deformation prevention type buffer block Download PDF

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Publication number
CN103483825A
CN103483825A CN201310404557.7A CN201310404557A CN103483825A CN 103483825 A CN103483825 A CN 103483825A CN 201310404557 A CN201310404557 A CN 201310404557A CN 103483825 A CN103483825 A CN 103483825A
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China
Prior art keywords
buffer block
formula
permanent deformation
type buffer
prevention type
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Pending
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CN201310404557.7A
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Chinese (zh)
Inventor
王超
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Great River Wuwei County Product Of Rubber And Plastic Co Ltd
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Great River Wuwei County Product Of Rubber And Plastic Co Ltd
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Priority to CN201310404557.7A priority Critical patent/CN103483825A/en
Publication of CN103483825A publication Critical patent/CN103483825A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a formula of a permanent deformation prevention type buffer block. The formula comprises the following components in percentage by mass: 68%-82% of vinyl silicone rubber, 3%-8% of di-tert-butyl peroxide, 4%-10% of silicon dioxide, 3%-6% of zinc oxide and 6%-14% of tetramethyl ethylidene dimethyldialkoxysilane. The formula has the advantages of reasonable matching, low cost, stable performance, good forming quality and the like. When the compression ratio of the permanent deformation prevention type buffer block is 30%, after the permanent deformation prevention type buffer block is compressed for 24-72 hours at the temperature of 150 DEG C, the rate of the permanent deformation of the buffer block is 12%-16% (the common silicon rubber is 20%-30%).

Description

A kind of formula of resistance to permanent deformation type buffer block
Technical field
The present invention relates to the elastomeric material technical field, is a kind of formula of resistance to permanent deformation type buffer block specifically.
Background technology
Buffer block mainly plays and reduces instant impact, protection is used object, reduced the effects such as noise, the vibrations of reduction equipment.Therefore, buffer block has a wide range of applications at aspects such as industry, life, vehicle, mechanical means.The materials of buffer block generally are divided into polystyrene foamed plastics, polyethylene foams, urethane foam, polyvinyl chloride foam and polypropylene foam etc.But viscous deformation, after long-term pressurized, very easily occurs in general buffer block, affects the functional quality of buffer block.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of reasonable ratio, with low cost, stable performance, buffer block formula that Forming Quality is good, i.e. a kind of formula of resistance to permanent deformation type buffer block.
Technical problem to be solved by this invention realizes by the following technical solutions:
A kind of formula of resistance to permanent deformation type buffer block, this formula comprises vinylsiloxane rubber, di-t-butyl peroxide, silicon-dioxide, zinc oxide, tetramethyl-ethylidene dioxy dimethylsilane, the shared mass percent of described each component is as follows:
Figure BDA0000378907050000011
The shared best in quality per-cent of described each component is as follows:
Figure BDA0000378907050000012
Figure BDA0000378907050000021
The performance of described each component and effect are as follows:
Vinylsiloxane rubber: the rubber as silica gel product is used, and anti-deformation nature is good.
Di-t-butyl peroxide: the agent of vinylsiloxane rubber dedicated vulcanization, can decompose rapidly the generation free radical under higher curing temperature, thereby it is crosslinked that ethylene rubber is produced.
Silicon-dioxide: the main raw of the reinforcing filler of silicon rubber claims again white carbon black.Silicon-dioxide can be divided into thermal silica and precipitated silica.Fumed silica is one of the most frequently used strengthening agent of silicon rubber,, good electrical property high by the physical strength of its cross-linked rubber of sizing material of its reinforcement, and can with other strengthening agent or weak strengthening agent use, prepare the sizing material of different service requirementss.
Zinc oxide: weak reinforcing filler, they generally do not use separately in rubber, but with silicon-dioxide use, to regulate the hardness of rubber, improve the processing performance of sizing material and oil resistance and the solvent resistance of cross-linked rubber, reduce the cost of sizing material.
Tetramethyl-ethylidene dioxy dimethylsilane: constitution controller, meeting hardening in the silicone rubber compounds storage process of employing fumed silica reinforcement, plasticity value descends, and loses gradually process industrial art performance, and this phenomenon is called " structurizing " effect.For preventing and weaken that the Synergist S-421 95 that this " structurizing " tendency adds is called " constitution controller ".
The invention has the beneficial effects as follows: the present invention has the advantages such as reasonable ratio, with low cost, stable performance, Forming Quality be good, when rate of compression is 30%, after 150 ℃ of lower compression 24~72h, be permanently deformed to 12%~16% (ordinary silicon rubber is 20%~30%).
Embodiment
For technique means and the creation characteristic that the present invention is realized is easy to understand, below the present invention is further set forth.
Embodiment mono-:
A kind of formula of resistance to permanent deformation type buffer block, this formula comprises vinylsiloxane rubber, di-t-butyl peroxide, silicon-dioxide, zinc oxide, tetramethyl-ethylidene dioxy dimethylsilane, the shared mass percent of described each component is as follows:
Figure BDA0000378907050000022
Figure BDA0000378907050000031
Embodiment bis-:
A kind of formula of resistance to permanent deformation type buffer block, this formula comprises vinylsiloxane rubber, di-t-butyl peroxide, silicon-dioxide, zinc oxide, tetramethyl-ethylidene dioxy dimethylsilane, the shared mass percent of described each component is as follows:
Figure BDA0000378907050000032
Embodiment tri-:
A kind of formula of resistance to permanent deformation type buffer block, this formula comprises vinylsiloxane rubber, di-t-butyl peroxide, silicon-dioxide, zinc oxide, tetramethyl-ethylidene dioxy dimethylsilane, the shared mass percent of described each component is as follows:
Figure BDA0000378907050000033
Above demonstration and described ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what in above-described embodiment and specification sheets, describe is principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.

Claims (2)

1. the formula of a resistance to permanent deformation type buffer block, it is characterized in that: this formula comprises vinylsiloxane rubber, di-t-butyl peroxide, silicon-dioxide, zinc oxide, tetramethyl-ethylidene dioxy dimethylsilane, and the shared mass percent of described each component is as follows:
Figure FDA0000378907040000011
2. a kind of formula of resistance to permanent deformation type buffer block according to claim 1, it is characterized in that: the shared best in quality per-cent of described each component is as follows:
Figure FDA0000378907040000012
CN201310404557.7A 2013-09-08 2013-09-08 Formula of permanent deformation prevention type buffer block Pending CN103483825A (en)

Priority Applications (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH101611A (en) * 1996-06-18 1998-01-06 Shin Etsu Chem Co Ltd Silicone rubber composition and improvement of compression permanent set characteristics of silicone rubber
CN102070905A (en) * 2010-12-09 2011-05-25 平高集团有限公司 Composite silicon rubber and preparation method thereof
CN102775794A (en) * 2012-07-12 2012-11-14 中国恩菲工程技术有限公司 Additional vulcanized rubber
CN103160128A (en) * 2013-04-10 2013-06-19 北京化工大学 Conductive silicon rubber material with ultralow compressive deformation and low hardness and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH101611A (en) * 1996-06-18 1998-01-06 Shin Etsu Chem Co Ltd Silicone rubber composition and improvement of compression permanent set characteristics of silicone rubber
CN102070905A (en) * 2010-12-09 2011-05-25 平高集团有限公司 Composite silicon rubber and preparation method thereof
CN102775794A (en) * 2012-07-12 2012-11-14 中国恩菲工程技术有限公司 Additional vulcanized rubber
CN103160128A (en) * 2013-04-10 2013-06-19 北京化工大学 Conductive silicon rubber material with ultralow compressive deformation and low hardness and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
涂志秀等: "甲基乙烯基硅橡胶加成硫化研究", 《弹性体》 *
黄文润: "《热硫化硅橡胶》", 30 September 2009 *

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Application publication date: 20140101