CN103476883B - Water system coating composition - Google Patents
Water system coating composition Download PDFInfo
- Publication number
- CN103476883B CN103476883B CN201280016873.0A CN201280016873A CN103476883B CN 103476883 B CN103476883 B CN 103476883B CN 201280016873 A CN201280016873 A CN 201280016873A CN 103476883 B CN103476883 B CN 103476883B
- Authority
- CN
- China
- Prior art keywords
- coating composition
- water system
- organic solvent
- glycol
- hydroxyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 120
- 239000008199 coating composition Substances 0.000 title claims abstract description 64
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 62
- 239000003960 organic solvent Substances 0.000 claims abstract description 44
- 150000001412 amines Chemical class 0.000 claims abstract description 32
- 229920005989 resin Polymers 0.000 claims abstract description 30
- 239000011347 resin Substances 0.000 claims abstract description 30
- 239000000080 wetting agent Substances 0.000 claims abstract description 21
- KXDHJXZQYSOELW-UHFFFAOYSA-M carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims abstract description 12
- 239000003086 colorant Substances 0.000 claims abstract description 5
- -1 isopropyl Hydramine Chemical compound 0.000 claims description 68
- 239000006185 dispersion Substances 0.000 claims description 40
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 19
- 229940043276 diisopropanolamine Drugs 0.000 claims description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 17
- ZMANZCXQSJIPKH-UHFFFAOYSA-N triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 14
- LVTYICIALWPMFW-UHFFFAOYSA-N 1-(2-hydroxypropylamino)propan-2-ol Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 13
- 238000009835 boiling Methods 0.000 claims description 13
- MTHSVFCYNBDYFN-UHFFFAOYSA-N Diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- WERYXYBDKMZEQL-UHFFFAOYSA-N 1,4-Butanediol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 8
- 229940102253 ISOPROPANOLAMINE Drugs 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- SLCVBVWXLSEKPL-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 7
- 229940117969 NEOPENTYL GLYCOL Drugs 0.000 claims description 7
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 6
- AYDQIZKZTQHYIY-UHFFFAOYSA-N OC(=O)C1(C)CC(C(O)=O)=CC=C1 Chemical compound OC(=O)C1(C)CC(C(O)=O)=CC=C1 AYDQIZKZTQHYIY-UHFFFAOYSA-N 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Tris Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 5
- UAOMVDZJSHZZME-UHFFFAOYSA-N Diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 4
- JJWLVOIRVHMVIS-UHFFFAOYSA-N Isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 4
- UDGSVBYJWHOHNN-UHFFFAOYSA-N N',N'-diethylethane-1,2-diamine Chemical compound CCN(CC)CCN UDGSVBYJWHOHNN-UHFFFAOYSA-N 0.000 claims description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N Triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
- XXMIOPMDWAUFGU-UHFFFAOYSA-N 1,6-Hexanediol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-Amino-2-propanol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 3
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 claims description 3
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N Diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- CRVGTESFCCXCTH-UHFFFAOYSA-N Methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 3
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 3
- WGYKZJWCGVVSQN-UHFFFAOYSA-N Propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 3
- 229940043237 diethanolamine Drugs 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- GLUUGHFHXGJENI-UHFFFAOYSA-N piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 3
- BMRWNKZVCUKKSR-UHFFFAOYSA-N 1,2-Butanediol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 claims description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N 1,2-Diaminopropane Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims description 2
- 229940015975 1,2-hexanediol Drugs 0.000 claims description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N 1,3-Diaminopropane Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 claims description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-Propanediol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 2
- ALQSHHUCVQOPAS-UHFFFAOYSA-N 1,5-Pentanediol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 2
- NCXUNZWLEYGQAH-UHFFFAOYSA-N 1-(dimethylamino)propan-2-ol Chemical compound CC(O)CN(C)C NCXUNZWLEYGQAH-UHFFFAOYSA-N 0.000 claims description 2
- LJDSTRZHPWMDPG-UHFFFAOYSA-N 2-(butylamino)ethanol Chemical compound CCCCNCCO LJDSTRZHPWMDPG-UHFFFAOYSA-N 0.000 claims description 2
- IWSZDQRGNFLMJS-UHFFFAOYSA-N 2-(dibutylamino)ethanol Chemical compound CCCCN(CCO)CCCC IWSZDQRGNFLMJS-UHFFFAOYSA-N 0.000 claims description 2
- FCSBCNYVRIIJFX-UHFFFAOYSA-N 2-(ditert-butylamino)ethanol Chemical compound CC(C)(C)N(C(C)(C)C)CCO FCSBCNYVRIIJFX-UHFFFAOYSA-N 0.000 claims description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N Benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 claims description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N Dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N Diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 2
- IUNMPGNGSSIWFP-UHFFFAOYSA-N Dimethylaminopropylamine Chemical class CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 claims description 2
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N Diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims description 2
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N Dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N Dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- RWLALWYNXFYRGW-UHFFFAOYSA-N Etohexadiol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 claims description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N Hexamethylenediamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 2
- BMVXCPBXGZKUPN-UHFFFAOYSA-N Hexylamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 claims description 2
- QOHMWDJIBGVPIF-UHFFFAOYSA-N N',N'-diethylpropane-1,3-diamine Chemical class CCN(CC)CCCN QOHMWDJIBGVPIF-UHFFFAOYSA-N 0.000 claims description 2
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N N,N-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 claims description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N N-Butylamine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 claims description 2
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-Methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 claims description 2
- GNVRJGIVDSQCOP-UHFFFAOYSA-N N-ethyl-N-methylethanamine Chemical compound CCN(C)CC GNVRJGIVDSQCOP-UHFFFAOYSA-N 0.000 claims description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N Putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 claims description 2
- YBRBMKDOPFTVDT-UHFFFAOYSA-N Tert-Butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 claims description 2
- IMFACGCPASFAPR-UHFFFAOYSA-N Tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N Trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 229940043279 diisopropylamine Drugs 0.000 claims description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N ethyl amine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 2
- 229960005082 etohexadiol Drugs 0.000 claims description 2
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 2
- 229940113083 morpholine Drugs 0.000 claims description 2
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 claims 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-Dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 claims 1
- XHJGXOOOMKCJPP-UHFFFAOYSA-N 2-[tert-butyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(C(C)(C)C)CCO XHJGXOOOMKCJPP-UHFFFAOYSA-N 0.000 claims 1
- 206010008190 Cerebrovascular accident Diseases 0.000 claims 1
- 208000006011 Stroke Diseases 0.000 claims 1
- 235000019437 butane-1,3-diol Nutrition 0.000 claims 1
- PUPZLCDOIYMWBV-UHFFFAOYSA-N butylene glycol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N ethanolamine Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 1
- 229940031098 ethanolamine Drugs 0.000 claims 1
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- 239000000049 pigment Substances 0.000 description 33
- 239000000203 mixture Substances 0.000 description 19
- 238000007792 addition Methods 0.000 description 17
- 239000000243 solution Substances 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 229920005862 polyol Polymers 0.000 description 13
- XBDQKXXYIPTUBI-UHFFFAOYSA-N propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 13
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
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- 150000001875 compounds Chemical class 0.000 description 10
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 10
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- 238000006243 chemical reaction Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
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- RPNUMPOLZDHAAY-UHFFFAOYSA-N DETA Chemical class NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 5
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- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
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- 238000010992 reflux Methods 0.000 description 5
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- 230000002194 synthesizing Effects 0.000 description 5
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- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
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- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
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- TTWHRLANJSQOAT-UHFFFAOYSA-N 2-(2-hexoxypropoxy)propan-1-ol Chemical compound CCCCCCOC(C)COC(C)CO TTWHRLANJSQOAT-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
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- QRLZJWCPSKLFKP-UHFFFAOYSA-N 2-(2-pentoxypropoxy)propan-1-ol Chemical compound CCCCCOC(C)COC(C)CO QRLZJWCPSKLFKP-UHFFFAOYSA-N 0.000 description 1
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- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 1
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- 239000002250 absorbent Substances 0.000 description 1
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
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- NIHJEJFQQFQLTK-UHFFFAOYSA-N butanedioic acid;hexanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)CCCCC(O)=O NIHJEJFQQFQLTK-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- CXLSVMAGOLTCSL-UHFFFAOYSA-J calcium;barium(2+);dicarbonate Chemical compound [Ca+2].[Ba+2].[O-]C([O-])=O.[O-]C([O-])=O CXLSVMAGOLTCSL-UHFFFAOYSA-J 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
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- 235000013985 cinnamic acid Nutrition 0.000 description 1
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- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 239000008079 hexane Substances 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 230000004301 light adaptation Effects 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- FSQQTNAZHBEJLS-UPHRSURJSA-N maleamic acid Chemical compound NC(=O)\C=C/C(O)=O FSQQTNAZHBEJLS-UPHRSURJSA-N 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- UMRZSTCPUPJPOJ-KNVOCYPGSA-N norbornane Chemical compound C1C[C@H]2CC[C@@H]1C2 UMRZSTCPUPJPOJ-KNVOCYPGSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229960001735 pentaerythritol Drugs 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
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- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- ZTHYODDOHIVTJV-UHFFFAOYSA-N propyl 3,4,5-trihydroxybenzoate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 1
- SEPKUNXLGWMPHL-UHFFFAOYSA-N quinoxaline-2,3-dione Chemical class C1=CC=CC2=NC(=O)C(=O)N=C21 SEPKUNXLGWMPHL-UHFFFAOYSA-N 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- HWLCXJRHGUPXJZ-RTLSQWIOSA-K sodium;iron(2+);(1E)-1-oxidoiminonaphthalen-2-one;(1Z)-1-oxidoiminonaphthalen-2-one Chemical compound [Na+].[Fe+2].C1=CC=C2C(=N/[O-])\C(=O)C=CC2=C1.C1=CC=C2C(=N/[O-])\C(=O)C=CC2=C1.C1=CC=C2C(=N/[O-])/C(=O)C=CC2=C1 HWLCXJRHGUPXJZ-RTLSQWIOSA-K 0.000 description 1
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- 150000003512 tertiary amines Chemical class 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910001929 titanium oxide Inorganic materials 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
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- 239000012498 ultrapure water Substances 0.000 description 1
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- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N α-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N γ-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 1
Abstract
The present invention provides a kind of water system coating composition, it is characterized in that, containing coloring agent, water, wetting agent, amines, the organic solvent of hydroxyl and the carbamate resins with Merlon base, utilize this water system coating composition, can easily control the gloss of the coated film being coated on coated article, storage-stable is good, excellent to the wettability of coated article, will not cause spray nozzle clogging and spray excellent in stability continuously.
Description
Technical field
The present invention relates to water system coating composition, relate to easily to control the light of the coated film being coated on coated article
Pool, storage-stable be good, water system coating composition to the wettability ejection excellent in stability excellent, continuous of coated article.
Background technology
In the past, in the coating composition being made up of pigment, adhesive resin, pigment wetting agent, solvent and water, it is proposed that
The coating composition of the various solvent of multiple use.
In the case of using conventional coating composition to make painting object by ink-jet, unstable injection occurs,
Obtain the painting object of the closely sealed difference to coated article, even if it addition, use such coating composition to make painting object, the most sometimes
The gloss difference of film or the display of color are the most abundant.
As produce above-mentioned gloss reduce reason, generally, due to the pigment in coating composition, solvent, resin and
The selection of wetting agent and make the compatibility poor of coating composition, become the reason causing gloss to reduce.In order to prevent this phenomenon,
Use the method (referring for example to patent documentation 1) adding gloss improvers.
It addition, repel or the reason of bleeding as producing, it is generally known that the regulation poor with the interfacial tension of coated article is not filled
Point, in order to solve this problem, use the method adding surface conditioner.
On the other hand, in patent documentation 2, repel and the method for bleeding as improving, disclose interpolation acid-organosilicon crylic acid
Resinoid method, but without providing water system compositions.
Prior art literature
Patent documentation
Patent documentation 1: Japanese Unexamined Patent Application Publication 2007-510017 publication
Patent documentation 2: Japanese Unexamined Patent Publication 10-251573 publication
Summary of the invention
Invent problem to be solved
It is an object of the invention to solve problem as above, it is provided that a kind of water system coating composition, it can control
The gloss of coated film, the storage-stable of coating composition is good, excellent to the wettability of coated article, there is not repulsion and oozes
Color, and spray nozzle clogging will not be caused, spray excellent in stability continuously.
For the method solving problem
Pass through the present invention, it is provided that a kind of water system coating composition, it is characterised in that containing coloring agent, water, wetting agent, amine
Compound, the organic solvent of hydroxyl and there is the carbamate resins of Merlon base.
Invention effect
By means of the invention it is possible to provide a kind of water system coating composition, it can easily control to be coated on coated article
The gloss of coated film, storage-stable is good, excellent to the wettability of coated article, will not cause spray nozzle clogging and spray continuously
Excellent in stability.
Detailed description of the invention
Hereinafter, embodiments of the present invention are described in detail.
The water system coating composition of the present invention is characterised by, containing coloring agent, water, wetting agent, amines, hydroxyl
Organic solvent and there is the carbamate resins of Merlon base.According to the present invention, obtain storage-stable good, to quilt
The wettability of coat is excellent, can easily control the gloss of coated film that is coated on coated article and continuously ejection stability excellent
Good water system coating composition.In the present invention, it is coated with in the water system making gloss reduce owing to adding wetting agent or adhesive resin
In cloth compositions, add the organic solvent of hydroxyl and amines, the film that it is possible to control to be coated on coated article
Gloss.
Coating composition in the present invention is the water system coating composition being added with water.As water, it is possible to use ion is handed over
Change the pure water such as water, distilled water or ultra-pure water.It addition, in the case of long-term preservation water system coating composition, in order to prevent mycete
Or the generation of antibacterial, it is possible to use by the water after the sterilizings such as ultraviolet irradiation.Furthermore it is also possible to according to application during coating
Condition dilute with water water system coating composition.
The coloring agent used in the water system coating composition of the present invention is not particularly limited, it is possible to use common coating group
The pigment used in compound.Such as, as organic pigment, can enumerate:
Pigment Yellow 12,13,14,17,20,24,31,42,53,55,74,83,86,93,109,110,117,120,125,
128、129、137、138、139、147、148、150、151、152、153、154、155、166、168、180、181、184、185、
213、
Pigment orange 16,36,38,43,51,55,59,61,64,65,71,
Pigment Red 9,48,49,52,53,57,97,101,122,123,149,168,177,180,192,202,206,
215、216、217、220、223、224、226、227、228、238、240、244、254、
Pigment violet 19,23,29,30,32,37,40,50,
Pigment blue 15,15:1,15:3,15:4,15:6,22,30,60,64,80,
Pigment Green 7,36,
Bistre 23,25,26,
Pigment black 1,7,26,27 and 28 etc..
It addition, as inorganic pigment, can enumerate: titanium oxide, ferrum oxide, ultramarine, chrome yellow, zinc sulfide, cobalt blue, barium sulfate
And calcium carbonate etc..
The use level of pigment can arbitrarily determine according to the kind etc. of pigment used, preferably water system coating composition
0.5～10 mass %, more preferably 1～5 mass %.
As the wetting agent used in the water system coating composition in the present invention, it is not particularly limited, uses common painting
The wetting agent used in cloth compositions, it is however generally that, use and there is the effect making the interfacial tension between solid and liquid reduce
Anionic based surfactants, cationic based surfactants or nonionic class surfactant.In water system coating composition
Whole organic solvent amounts be more than 35 mass % in the case of, wetting agent is preferably nonionic class surfactant.As non-from
Subclass surfactant, can enumerate such as: polyoxyethylene tridecyl ether, polyoxyethylene lauryl ether, polyoxy alkylene ten
Trialkyl ether, polyoxyethylene isodecyl ether, polyoxyethylene lauryl ether, polyoxy alkylene lauryl ether, polyoxyethylene alkyl ether, poly-
Oxygen ethylene oleyl ether and polyoxyethylene styrene phenyl ether etc..The use level of wetting agent can be appointed according to the kind used etc.
Meaning determines, preferably 0.01～5 mass % of water system coating composition, more preferably 0.5～3 mass %.
As having the carbamate resins of Merlon base, it is not particularly limited, preferably makes polycarbonate polyol
The carbamate resins that alcohol, polyisocyanate and chain extender react and obtain, more preferably mean diameter 30nm～300nm
Urethane dispersion or urethane emulsions.By using the carbamate of mean diameter 30nm～300nm to disperse
Body or urethane emulsions, it is possible to the water system coating composition of the storage-stable that preparation display is good, and can be formed
Show the coated film of excellent scrub resistance.
Polycarbonate polyol is not particularly limited, and can enumerate such as: 1,6-hexanediol polycarbonate polyol, Isosorbide-5-Nitrae-
Butanediol polycarbonate polyol and poly-1,4-cyclohexanedimethyleterephthalate carbonate diol etc..
It addition, be possible not only to add the carbamate resins with Merlon base, it is also possible to add common coating
Use in compositions making polyisocyanate, polyhydric alcohol and chain extender reaction and the carbamate resins that obtains.Gather by making
Isocyanates, polyhydric alcohol and chain extender react and obtain block structure, make carbamate resins dispersion stabilization in water
Improve.
Polisocyanate component is the compound in its compound with at least 2 NCOs, can enumerate example
As: include toluene di-isocyanate(TDI), XDI, methyl diphenylene diisocyanate, naphthalene diisocyanate, 1,3-
Double (isocyanatomethyl) hexamethylene, tetramethylxylene diisocyanate, hexamethylene diisocyanate, isophorone two
The polyisocyanate compounds of isocyanates, dicyclohexyl methyl hydride diisocyanate and norbornene alkyl diisocyanate etc..This
In a little polisocyanate component, preferably XDI, 1,3-double (isocyanatomethyl) hexamethylene, six methylenes
Group diisocyanate, isophorone diisocyanate, 4,4 '-di-2-ethylhexylphosphine oxide (cyclohexyl isocyanate) or norbornane two isocyanide
Acid esters.These polisocyanate component can be used alone one, or can also be applied in combination two or more.
Polyol component is the compound in its compound with at least 2 hydroxyls, can enumerate such as: polyester polyols
Alcohol, polyether polyol and acrylic polyol etc..
As PEPA, it is not particularly limited, can enumerate such as: 10PE27, polyadipate second
Glycol propylene glycol ester, poly adipate succinic acid ester, polyadipate hexanediol ester, polydiethylene glycol adipate, poly-terephthaldehyde
Acid glycol ester, polyethylene glycol isophthalate, poly-M-phthalic acid hexanediol ester, polyethylene glycol succinate, polybutadiene
Acid butanediol ester, polyethylene glycol sebacate, polydiethylene glycol sebacate, poly-'epsilon '-hexanolactam glycol and poly-(adipic acid 3-
Methyl isophthalic acid, 5-pentadiol ester) etc..
As polyether polyol, it is not particularly limited, can enumerate such as: polyoxytetramethylene glycol, polypropylene oxide
Glycol, Polyoxyethylene glycol and polyethylene glycol oxide-propylene oxide glycol etc..
As acrylic polyol, be not particularly limited, can enumerate such as: with (methyl) acrylic acid 2-hydroxy methacrylate,
The acrylic compounds such as (methyl) acrylic acid 3-hydroxy propyl ester, (methyl) acrylic acid 4-hydroxybutyl and these 6-caprolactone addition products
Monomer is as the acrylic polyol of neccessary composition.
These polyol components can be used alone one, additionally can also be applied in combination two or more.
As chain extender, the polyhydric alcohol of such as low-molecular-weight and the polyamine of low-molecular-weight can be enumerated.As low point
Son amount polyhydric alcohol, can enumerate such as: ethylene glycol, diethylene glycol, BDO, 1,6-hexanediol, 3-methyl isophthalic acid, 5-penta
Glycol, neopentyl glycol, trimethylolpropane, tetramethylolmethane, 1,4 cyclohexane dimethanol, dimethylolpropionic acid and dihydroxymethyl
The dimethylolalkanoic acids classes etc. such as propanoic acid.As the polyamine of low-molecular-weight, can enumerate such as: ethylenediamine, propane diamine, fourth two
Amine, hexamethylene diamine, hydrazine, piperazine, isophorone diamine, norbornane diamidogen, diaminodiphenyl-methane, diaminourea cyclohexyl first
Alkane, toluenediamine, dimethylphenylene diamine, diethylenetriamines, trien, tetren and iminobispropylamine
Deng.These chain extenders can be used alone one, additionally can also be applied in combination two or more.
It addition, do not contain only the carbamate resins with Merlon base, it is also possible to containing acrylic resin.Pass through
Containing acrylic resin, the solvent resistance of film improves.As acrylic resin, preferably comprising glass transition temperature Tg is 60
More than DEG C, mean diameter be acrylic acid dispersion or the acrylic emulsion of 50nm～200nm.By making glass transition temperature Tg
It is more than 60 DEG C, obtains excellent scrub resistance and alcohol resistance.It addition, be 50nm～200nm by making mean diameter, it is possible to
Prepare the water system coating composition that storage-stable is good.
As the monomer component of composition acrylic resin, can enumerate: (methyl) acrylic acid methyl ester., (methyl) acrylic acid second
Ester, (methyl) n-propyl, (methyl) isopropyl acrylate, (methyl) n-butyl acrylate, (methyl) i-butyl
Ester, (methyl) amyl acrylate, (methyl) 2-EHA, (methyl) decyl acrylate, (methyl) acrylic acid 12
Alkyl ester, (methyl) stearyl acrylate ester, (methyl) acrylic acid α-chloroethene ester, (methyl) cyclohexyl acrylate, (methyl) acrylic acid
Phenyl ester, (methyl) methoxyethyl acrylate, (methyl) ethoxyethyl acrylate, (methyl) methoxypropyl ester, (first
Base) ethioxy propyl ester, styrene, methyl styrene, chlorostyrene, methoxy styrene, (methyl) acrylic acid, Fructus Crotonis
Acid, itaconic acid, itaconic acid half ester, maleic acid, acid half ester, (methyl) acrylic acid 2-hydroxy methacrylate, (methyl) acrylic acid 2
(3)-hydroxy propyl ester, acrylic acid 4-hydroxybutyl, 1-propenol-3, list (methyl) acrylate of polyhydric alcohol, (methyl) acrylamide,
Maleic amide, (methyl) acrylic acid 2-amino ethyl ester, (methyl) dimethylaminoethyl acrylate, (methyl) acrylic acid 3-aminopropan
Ester, (methyl) acrylic acid 2-butylaminoethyl, vinylpyridine, (methyl) glycidyl acrylate, allyl glycidyl are sweet
Oleyl ether, have the epoxide of more than 2 glycidyls, N hydroxymethyl acrylamide, vinyl acetate, vinyl chloride,
Ethylene, butadiene, acrylonitrile and dialkyl fumarate etc..Wherein, preferably styrene, methyl methacrylate or bag
Containing (methyl) acrylic acid acrylic resin.
In the water system coating composition of the present invention, the organic solvent of hydroxyl can be categorized as the hydroxyl in (A) 1 molecule
Number is organic solvent and the organic solvent that hydroxyl value is more than 2 in (B) 1 molecule of 1.
As the organic solvent of the hydroxyl that hydroxyl value is 1 in (A) 1 molecule, can enumerate:
Ethylene glycol methyl ether, glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol butyl ether, ethylene glycol amyl ether, second two
Alcohol hexyl ether, 1,2-ethanediol cyclohexyl ether, ethylene glycol phenyl ether, ethylene glycol benzyl ether, ethylene glycol isobutyl ether, the ethylene glycol tert-butyl group
Ether,
Diethylene, diethylene glycol ethyl ether, diethylene glycol propyl ether, buiyl diglycol, diethylene glycol
Amyl ether, diethylene glycol hexyl ether, diethylene glycol cyclohexyl ether, diethylene glycol phenyl ether, diethylene glycol benzylic ether, diethylene glycol
Single-butyl ether, diethylene glycol isobutyl ether,
Triethylene glycol methyl ether, triethylene glycol ethylether, triethylene glycol propyl ether, triethylene glycol butyl ether, triethylene glycol
Amyl ether, triethylene glycol hexyl ether, triethylene glycol cyclohexyl ether, triethylene glycol phenyl ether, triethylene glycol benzylic ether and three second two
The gylcol ethers such as alcohol single-butyl ether；And
Methyl proxitol, propylene glycol ethyl ether, propylene glycol propyl ether, propylene glycol butyl ether, propylene glycol amyl ether, the third two
Alcohol hexyl ether, propylene glycol cyclohexyl ether,
Dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol propyl ether, dipropylene glycol butyl ether, dipropylene glycol
Amyl ether, dipropylene glycol hexyl ether, dipropylene glycol cyclohexyl ether,
Tripropylene glycol methyl ether, tripropylene glycol ethylether, tripropylene glycol propyl ether, tripropylene glycol propyl ether, tripropylene glycol
The propylene glycol ethers such as amyl ether, tripropylene glycol hexyl ether and tripropylene glycol cyclohexyl ether；Deng.
Wherein, preferably ethylene glycol monobutyl ether, ethylene glycol isobutyl ether, ethylene glycol tertbutyl ether, diethylene glycol mono butyl base
Ether, diethylene glycol isobutyl ether and triethylene glycol monobutyl base ether.
As the organic solvent of the hydroxyl that hydroxyl value is more than 2 in (B) 1 molecule, can enumerate: ethylene glycol, two
Ethylene glycol, triethylene glycol, 1,2-propylene glycol, 2-methyl-1,3-propanediol, 1,3-propylene glycol, 1,2-butanediol, 1,3-fourth two
Alcohol, 1,4-butanediol, 3-methyl isophthalic acid, 3-butanediol, neopentyl glycol, 1,2-pentanediol, 1,5-pentanediol, 3-methyl isophthalic acid, 5-penta
Glycol, 1,2-hexanediol, 1,6-HD, ethohexadiol, 1,4-butanediol, 1,4 cyclohexane dimethanol, glycerol and three hydroxyls
Methylpropane.Wherein, preferably ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 3-methyl isophthalic acid,
3-butanediol, 2-methyl-1,3-propanediol and glycerol.
In the organic solvent of hydroxyl, from the viewpoint of ejection stability continuously and glossiness, preferably (A) 1 molecule
In the organic solvent that hydroxyl value is 1 and (B) 1 molecule in the ratio of the organic solvent that hydroxyl value is more than 2 be A:B=
100:50～100:170, more preferably 100:50～100:150, even more preferably 100:75～100:150.A is set to 100
Time, if B is less than 50, then moisture retention is deteriorated, and causes spray nozzle clogging when ink-jet application or atomized spray painting etc. sometimes, so that
Ejection stability reduces continuously, on the other hand, when B ultrasonic crosses 170, there is the tendency that the gloss of dry coating declines.
In the water system coating composition of the present invention, from the viewpoint of ejection stability continuously and storage-stable, preferably
All organic solvent amount is 20 mass %～55 mass %, more preferably 30 mass %～50 mass %.All organic solvent amount is less than
During 20 mass %, the dry quickening of water system coating composition, the stifled of nozzle mostly can be caused when ink-jet application or atomized spray painting etc.
Plug, so that ejection stability reduces continuously.On the other hand, during more than 55 mass %, cause the poly-of pigment dispersion and resin
Collection, has the tendency that storage-stable is deteriorated.In the water system coating composition of the present invention, even if being 55 matter in amount of solvent
The most there is not ignition point during amount %, therefore, safety is high compared with dicyandiamide solution.
As the amines used in the water system coating composition of the present invention, can enumerate: primary amine, secondary amine and uncle
Amine.
As primary amine, can enumerate such as: methylamine, ethamine, propylamine, 2-aminopropane., butylamine, tert-butylamine, hexylamine, benzylamine, second
Hydramine, isopropanolamine, butanolamine, hexanol amine, 1,2-propanediamine, 1,3-propanediamine, 1,4-butane diamine, 1,6-hexane two
Amine, pyrrolidine and morpholine etc..
As secondary amine, can enumerate such as: dimethylamine, diethylamine, di-n-propylamine, diisopropylamine, dibutyl amine, diethanolamine,
Diisopropanolamine (DIPA), N-methylethanolamine, N-ehtylethanolamine, N-butylethanolamine, N-butyl isopropanolamine, N-tert-butyl group isopropyl
Hydramine, N, N-diethyl ethylenediamine, N, N-dimethyl-1,3-diaminopropanes, N, N-diethyl-1,3-diaminopropanes and
Piperazine etc..
As tertiary amine, can enumerate such as: trimethylamine, triethylamine, tripropyl amine (TPA), Tris(isopropylamine)., tri-n-butylamine, N-methyl diethyl
Amine, N, N-dimethyl propylamine, triethanolamine, N methyldiethanol amine, N-ethyldiethanolamine, N butyl diethanol amine, uncle N-
Butyl diethanolamine, N, N-dimethylethanolamine, N, N-diethyl ethylene diamine, N, N-dibutylethanolamine, N, N-di-t-butyl
Ethanolamine, triisopropanolamine, N-methyl diisopropanolamine (DIPA), N-ethyl diisopropanolamine (DIPA), N-butyl diisopropanolamine (DIPA), the N-tert-butyl group
Diisopropanolamine (DIPA), N, N-dimethylisopro panolamine, N, N-diethyl isopropanolamine, N, N-dibutylisopropanolamine and N, N-bis-
Tert-butyl group isopropanolamine etc..
Certainly, the invention is not restricted to these amines.These amines can be applied in combination two or more.
In the present invention, in above-mentioned amines, particularly preferably use the amines or water miscible tertiary-aminated of straight chain
Compound.Specifically, triethylamine, triethanolamine, N methyldiethanol amine, N-ethyldiethanolamine, N, N-are particularly preferably used
Dimethylethanolamine or N, N-diethyl ethylene diamine etc..
About the boiling spread of amines used in the present invention, from the glossiness of film and spray stability continuously
From the viewpoint of, using the minimum boiling point solvent in the organic solvent of above-mentioned hydroxyl as benchmark, it is preferably-60 DEG C～+170
DEG C, more preferably-20 DEG C～+170 DEG C, more preferably-10 DEG C～+140 DEG C.The boiling point of amines is for less than-60 DEG C
Temperature time, in the dry run of water system coating composition, amines evaporates earlier than the organic solvent of hydroxyl, resin
Gathering drastically carry out, the gloss of film and continuously ejection stability are easily reduced, and on the other hand, the boiling point of amines is
When being higher than the temperature of+170 DEG C, there is the tendency that drying property is deteriorated.
In the water system coating composition of the present invention, from the viewpoint of glossiness and resistance to water, preferred amines compound is relative
Ratio in the organic solvent of hydroxyl is 0.0005～0.1, more preferably 0.001～0.05.Amines is relative to containing hydroxyl
When the ratio of the organic solvent of base is less than 0.0005, gloss is easily deteriorated, and on the other hand, during more than 0.1, amine remains in film
In, there is the tendency that resistance to water is deteriorated.
As long as the coated article of the water system coating composition of the present invention is suitable to the size of application, thickness, shape, then can make
Use common material, surface process, application can be carried out in advance.As coated article, can enumerate: as hardly picking up water system
The material of coating composition, iron plate, aluminium sheet, corrosion resistant plate, ceramic industry class coated plate and with poly terephthalic acid second two
The resins such as alcohol ester (PET), Merlon, acronitrile-butadiene-styrene (ABS), vinyl chloride, acrylic acid or polyester are as main one-tenth
The resin sheet divided or its formed body.As long as these coated articles, then can obtain good adaptation and gloss.It addition, can
To be coated on absorbefacient paper, cloth and not make it permeate water system coating composition is had.
For the water system coating composition of the present invention, in order to give each function as coated film, can be containing disappearing
The additives such as infusion, surface conditioner, sagging inhibitor, UV absorbent or light stabilizer.
Embodiment
Hereinafter, by embodiment and comparative example, the present invention is given the account in greater detail.It should be noted that about reality
Executing the record of example and comparative example, " part " and " % " is based on quality criteria.
<synthesis of resin 1 (containing the urethane dispersion of Merlon base)>
In the four-hole boiling flask being provided with agitator, reflux condensing tube, thermometer and nitrogen ingress pipe, put into 1,6-oneself two
Alcohol polycarbonate polyol (mean molecule quantity 2000) 100.0 parts, neopentyl glycol 4.0 parts, trimethylolpropane 1.0 parts, 1,4-
Cyclohexanedimethanol 10.0 parts, dihydromethyl propionic acid 8.0 parts, dibutyltin dilaurate 0.001 part and butanone 110.0
Part, mix homogeneously.Then, addition 4,4 '-di-2-ethylhexylphosphine oxide (cyclohexyl isocyanate) 80.0 parts, react 6 hours at 70 DEG C,
Methyl ethyl ketone solution to carboxylic isocyanate-terminated prepolymer.After above-mentioned solution is cooled to less than 40 DEG C, add
Triethylamine 6.0 parts, is neutralized reaction 30 minutes at 40 DEG C.
Then, the solution neutralized is cooled to less than 30 DEG C, uses dispersion machine blade, be slowly added into water
430.0 parts, make the isocyanate-terminated prepolymer corrective dispersion containing Merlon base, obtain dispersion liquid.It addition, will be
The amine aqueous solution dissolving Diethylenetriamine 1.35 parts in 20.0 parts of water is added drop-wise in above-mentioned dispersion liquid, it addition, add 50% hydrazine water
Solution 5.0 parts so that it is react 2 hours.Then, reduce pressure at 30 DEG C, carry out desolventizing process, obtain solid constituent 35%, viscosity
40mPa s, acid number=15, the dispersions of polyurethanes containing Merlon base of mean diameter (d50)=30nm, Tg=45 DEG C.
<synthesis of resin 2 (containing the urethane dispersion of Merlon base)>
In the four-hole boiling flask being provided with agitator, reflux condensing tube, thermometer and nitrogen ingress pipe, put into Isosorbide-5-Nitrae-fourth two
Alcohol polycarbonate polyol (mean molecule quantity 2000) 100.0 parts, neopentyl glycol 4.0 parts, trimethylolpropane 1.0 parts, 1,4-
Cyclohexanedimethanol 10.0 parts, dihydromethyl propionic acid 8.0 parts, dibutyltin dilaurate 0.001 part and butanone 110.0
Part, mix homogeneously.Then, addition 4,4 '-di-2-ethylhexylphosphine oxide (cyclohexyl isocyanate) 80.0 parts, react 6 hours at 70 DEG C,
Methyl ethyl ketone solution to carboxylic isocyanate-terminated prepolymer.After above-mentioned solution is cooled to less than 40 DEG C, add
Triethylamine 6.0 parts, is neutralized reaction 30 minutes at 40 DEG C.
Then, the solution neutralized is cooled to less than 30 DEG C, uses dispersion machine blade, be slowly added into water
430.0 parts, make the isocyanate-terminated prepolymer corrective dispersion containing Merlon base, obtain dispersion liquid.It addition, will be
The amine aqueous solution dissolving Diethylenetriamine 1.35 parts in 20.0 parts of water is added drop-wise in above-mentioned dispersion liquid, it addition, add 50% hydrazine water
Solution 5.0 parts so that it is react 2 hours.Then, reduce pressure at 30 DEG C, carry out desolventizing process, obtain solid constituent 35%, viscosity
46mPa s, acid number=15, the dispersions of polyurethanes containing Merlon base of mean diameter (d50)=34nm, Tg=50 DEG C.
<synthesis of resin 3 (containing the urethane dispersion of Merlon base)>
In the four-hole boiling flask being provided with agitator, reflux condensing tube, thermometer and nitrogen ingress pipe, put into poly-Isosorbide-5-Nitrae-
Cyclohexanedimethyleterephthalate carbonate diol (mean molecule quantity 2000) 100.0 parts, neopentyl glycol 14.0 parts, trimethylolpropane
1.0 parts, dihydromethyl propionic acid 8.0 parts, dibutyltin dilaurate 0.001 part and butanone 110.0 parts, mix homogeneously.
Then, add hexamethylene diisocyanate 31.0 parts, 4,4 '-di-2-ethylhexylphosphine oxide (cyclohexyl isocyanate) 41.0 parts, at 70 DEG C
Lower reaction 6 hours, obtains the methyl ethyl ketone solution of carboxylic isocyanate-terminated prepolymer.Above-mentioned solution is cooled to 40
After below DEG C, add triethylamine 6.0 parts, at 40 DEG C, be neutralized reaction 30 minutes.
Then, the solution neutralized is cooled to less than 30 DEG C, uses dispersion machine blade, be slowly added into water
430.0 parts, make the isocyanate-terminated prepolymer corrective dispersion containing Merlon base, obtain dispersion liquid.It addition, will be
The amine aqueous solution dissolving Diethylenetriamine 1.35 parts in 20.0 parts of water is added drop-wise in above-mentioned dispersion liquid, adds 50% hydrazine water-soluble
Liquid 5.0 parts so that it is react 2 hours.Then, reduce pressure at 30 DEG C, carry out desolventizing process, obtain solid constituent 35%, viscosity
52mPa s, acid number=17, the dispersions of polyurethanes containing Merlon base of mean diameter (d50)=39nm, Tg=40 DEG C.
<synthesis of resin 4 (without the urethane dispersion of Merlon base)>
In the four-hole boiling flask being provided with agitator, reflux condensing tube, thermometer and nitrogen ingress pipe, put into neopentyl glycol
20.0 parts, trimethylolpropane 1.0 parts, 1,4 cyclohexane dimethanol 5.5 parts, dihydromethyl propionic acid 5.5 parts, dibutyltindilaurylmercaptide
Cinnamic acid ester 0.001 part and butanone 110.0 parts, mix homogeneously.Then, add hexamethylene diisocyanate 12.0 parts and
4,4 '-di-2-ethylhexylphosphine oxide (cyclohexyl isocyanate) 82.0 parts, reacts 6 hours at 70 DEG C, obtains carboxylic NCO
The methyl ethyl ketone solution of the prepolymer of end-blocking.After above-mentioned solution is cooled to less than 40 DEG C, add triethylamine 4.2 parts, at 40 DEG C
It is neutralized reaction 30 minutes.
Then, the solution neutralized is cooled to less than 30 DEG C, uses dispersion machine blade, be slowly added into water
250.0 parts, make isocyanate-terminated prepolymer corrective disperse, obtain dispersion liquid.It addition, will dissolve in 20.0 parts of water
The amine aqueous solution that Diethylenetriamine is 1.35 parts is added drop-wise in above-mentioned dispersion liquid, adds 50% hydrazine aqueous solution 5.0 parts, and reaction 2 is little
Time.Then, reduce pressure at 30 DEG C, carry out desolventizing process, obtain solid constituent 35%, viscosity 61mPa s, acid number=20, average
The stable dispersions of polyurethanes without Merlon base of particle diameter (d50)=40nm, Tg=50 DEG C.
<synthesis of resin 5 (acrylic dispersion)>
In the four-hole boiling flask being provided with agitator, reflux condensing tube and thermometer, add 60 parts of water, polyoxyethylene benzene second
Thiazolinyl phenyl ether sulfate ammonium salt 0.6 part and polyoxy alkylene alkyl ether 2 parts, be heated to 70 DEG C, adds potassium peroxydisulfate 0.2 part.
Then, dropping is mixed by butyl acrylate 7.0 parts, 0.8 part of acrylic acid, styrene 24.0 parts and methyl methacrylate 48.2 parts
The mixture closed.Then, add 60 parts of water, prepare in the way of obtaining pH=9 with ammonia.Obtain solid constituent=41%,
Mean diameter (d50)=75nm, Tg=81 DEG C, the good acrylic dispersion of acid number=8.
<coating composition>
As pigment, use:
White carbon black (trade name: ス ペ シ ャ Le Block ラ ッ Network 550, Evonik Degussa Corp.'s system)
C.I. Pigment Blue 15 (trade name: イ Le ガ ラ イ ト Block Le 8700, Ciba's system),
Quinoxalinediones (trade name: ホ ス タ パ system イ エ ロ H5G, Clariant Corporation system),
Dimethylquinacridone (trade name: ス パ マ ゼ Application タ RG, DIC company system),
Titanium dioxide (trade name: TR92, Huntsman Corporation's system),
As wetting agent, use:
Polyoxyethylene styrene phenyl ether (HLB=14,18),
Polyoxyethylene tridecyl ether (HLB=13),
Polyoxyethylene lauryl ether (HLB=14),
Polyoxyethylene isodecyl ether (HLB=16),
As defoamer A, use SN デ Off ォ マ 1312 (company of Sheng Nuopuke Co., Ltd. system),
As defoamer B, use エ Application バ イ Le ジ ェ system AD01 (Air Products Company system),
As surface conditioner A, use TSF4446 (polyether modified silicon oil, Mai Tu company system),
As surface conditioner B, use BYK349 (polyether modified siloxane, PVC ッ グ ケ ミ ジ ャ パ Application company system).
<preparation of coating composition>
(embodiment 1～252)
Defoamer, the organic solvent (having 1 hydroxyl in 1 molecule) of hydroxyl, pigment, wetting agent and ion are exchanged
Water (the 30% of whole water yields of interpolation) mix, use the mixing mean diameter to pigment of ball mill (d50) reach 80nm～
120nm.Then, add by resin 1～5 obtained above, surface conditioner, hydroxy organic solvent (1 molecule has 2 with
Upper hydroxyl), amines and ion exchange water (the 70% of whole water yields of interpolation), use dispersion machine to be sufficiently stirred for, prepare water
It it is coating composition.
(embodiment 253～263)
The organic solvent (having 1 hydroxyl in 1 molecule) of hydroxyl, pigment, wetting agent and ion exchange water (are added
Whole water yields 30%) mixing, use the mixing mean diameter to pigment of ball mill (d50) reach 80nm～120nm.Then,
Add by resin 1 and 5 obtained above, surface conditioner, hydroxy organic solvent (there are in 1 molecule more than 2 hydroxyls), amination
Compound and ion exchange water (the 70% of whole water yields of interpolation), use dispersion machine to be sufficiently stirred for, prepare water system coating compositions
Thing.
(embodiment 264～274)
Defoamer, the organic solvent (having 1 hydroxyl in 1 molecule) of hydroxyl, pigment, wetting agent and ion are exchanged
Water (the 30% of whole water yields of interpolation) mix, use the mixing mean diameter to pigment of ball mill (d50) reach 80nm～
120nm.Then, add by resin 1 and 5 obtained above, hydroxy organic solvent (there are in 1 molecule more than 2 hydroxyls), amination
Compound and ion exchange water (the 70% of whole water yields of interpolation), use dispersion machine to be sufficiently stirred for, prepare water system coating compositions
Thing.
(embodiment 275～285)
The organic solvent (having 1 hydroxyl in 1 molecule) of hydroxyl, pigment, wetting agent and ion exchange water (are added
Whole water yields 30%) mixing, use the mixing mean diameter to pigment of ball mill (d50) reach 80nm～120nm.Then,
Add by resin 1 and 5 obtained above, hydroxy organic solvent (there are in 1 molecule more than 2 hydroxyls), amines and from
Sub-exchanged water (the 70% of whole water yields of interpolation), uses dispersion machine to be sufficiently stirred for, prepares water system coating composition.
(comparative example 1)
Defoamer, the organic solvent (having 1 hydroxyl in 1 molecule) of hydroxyl, pigment, wetting agent and ion are exchanged
Water (the 30% of whole water yields of interpolation) mix, use the mixing mean diameter to pigment of ball mill (d50) reach 80nm～
120nm.Then, add by resin 4 and 5 obtained above, surface conditioner, hydroxy organic solvent (1 molecule has 2 with
Upper hydroxyl), amines and ion exchange water (the 70% of whole water yields of interpolation), use dispersion machine to be sufficiently stirred for, prepare water
It it is coating composition.
(comparative example 2)
Defoamer, the organic solvent (having 1 hydroxyl in 1 molecule) of hydroxyl, pigment, wetting agent and ion are exchanged
Water (the 30% of whole water yields of interpolation) mix, use the mixing mean diameter to pigment of ball mill (d50) reach 80nm～
120nm.Then, add by resin 4 and 5 obtained above, surface conditioner, hydroxy organic solvent (1 molecule has 2 with
Upper hydroxyl) and ion exchange water (the 70% of whole water yields of interpolation), use dispersion machine to be sufficiently stirred for, prepare water system coating group
Compound.
(comparative example 3)
Defoamer, pigment, wetting agent and ion exchange water (the 30% of whole water yields of interpolation) are mixed, uses bead mill
The mixing mean diameter to pigment of machine (d50) reaches 80nm～120nm.Then, add by resin 4 and 5 obtained above, surface
Regulator, hydroxy organic solvent (there are in 1 molecule more than 2 hydroxyls), amines and ion exchange water (interpolation whole
The 70% of the water yield), use dispersion machine to be sufficiently stirred for, prepare water system coating composition.
(comparative example 4)
Defoamer, pigment, wetting agent and ion exchange water (the 30% of whole water yields of interpolation) are mixed, uses bead mill
The mixing mean diameter to pigment of machine (d50) reaches 80nm～120nm.Then, add by resin 1 and 5 obtained above, surface
Regulator, amines and ion exchange water (the 70% of whole water yields of interpolation), use dispersion machine to be sufficiently stirred for, prepare water
It it is coating composition.
(comparative example 5)
Defoamer, the organic solvent (having 1 hydroxyl in 1 molecule) of hydroxyl, pigment and ion exchange water (are added
Whole water yields 30%) mixing, use the mixing mean diameter to pigment of ball mill (d50) reach 80nm～120nm.Then,
Add by resin 1 and 5 obtained above, hydroxy organic solvent (there are in 1 molecule more than 2 hydroxyls), amines and from
Sub-exchanged water (the 70% of whole water yields of interpolation), uses dispersion machine to be sufficiently stirred for, prepares water system coating composition.
The water system coating composition of preparation is evaluated by following method.Show the result in table 1～table 19.
<continuous ejection>
Use ラ ミ レ ス PJ-1304NX, water system coating composition is carried out on vinyl chloride sheet surface the painting of 1m × 4m
Dress, the sheet number bending based on flight and coming off, it is evaluated by following benchmark.
Zero: bend without flight and come off.
△: flight bending and the total tablet number come off are 1～9.
×: flight bending and the total tablet number come off are more than 10.
<storage-stable>
Obtained water system coating composition is stood at 50 DEG C preservation 28 days, by visually, enters based on following benchmark
Row is evaluated.
Zero: unchanged.
△: slightly float.
×: produce precipitation or separate.
<gloss>
Make to use force the ラ ミ レ ス PJ-1304NX of rattan industrial group, application water system coating compositions on vinyl chloride sheet surface
Thing, uses the gloss meter VG2000 of electricity Se industrial group of Japan, is measured the gloss in abundant dried painting face.
<wettability>
Make to use force the ラ ミ レ ス PJ-1304NX of rattan industrial group, by water system coating composition on vinyl chloride sheet surface
Carry out application with the area of 10cm × 10cm, by visually, be evaluated based on following benchmark.
Zero: whole face is printed equably.
△ a: part observes repulsion part.
×: the degree of half observes repulsion part.
Claims (8)
1. a water system coating composition, it is characterised in that containing coloring agent, water, wetting agent, amines, the having of hydroxyl
Machine solvent and the carbamate resins with Merlon base,
Described wetting agent is selected from anionic based surfactants, cationic based surfactants and nonionic class surfactant
In at least one,
Described amines is selected from methylamine, ethamine, propylamine, 2-aminopropane., butylamine, tert-butylamine, hexylamine, benzylamine, ethanolamine, isopropyl
Hydramine, butanolamine, hexanol amine, 1,2-propanediamine, 1,3-propanediamine, 1,4-butane diamine, 1,6-hexane diamine, pyrroles
Alkane, morpholine, dimethylamine, diethylamine, di-n-propylamine, diisopropylamine, dibutyl amine, diethanolamine, diisopropanolamine (DIPA), N-methyl ethanol
Amine, N-ehtylethanolamine, N-butylethanolamine, N-butyl isopropanolamine, N-tert-butyl group isopropanolamine, N, N-diethyl second two
Amine, N, N-dimethyl-1,3-diaminopropanes, N, N-diethyl-1,3-diaminopropanes, piperazine, trimethylamine, triethylamine, three
Propylamine, Tris(isopropylamine)., tri-n-butylamine, N-methyl-diethyl-amine, N, N-dimethyl propylamine, triethanolamine, N methyldiethanol amine, N-second
Base diethanolamine, N butyl diethanol amine, N-tertiarybutyldiethanolamine, N, N-dimethylethanolamine, N, N-diethyl ethylene diamine,
N, N-dibutylethanolamine, N, N-di-t-butyl ethanolamine, triisopropanolamine, N-methyl diisopropanolamine (DIPA), N-ethyl diisopropyl
Hydramine, N-butyl diisopropanolamine (DIPA), N-tert-butyl group diisopropanolamine (DIPA), N, N-dimethylisopro panolamine, N, N-diethyl isopropanol
Amine, N, N-dibutylisopropanolamine and N, at least one in N-di-t-butyl isopropanolamine,
In the organic solvent of described hydroxyl, the organic solvent that hydroxyl value is 1 in (A) 1 molecule and the hydroxyl in (B) 1 molecule
Radix be the quality ratio of the organic solvent of more than 2 be A:B=100:50～100:170,
The organic solvent that hydroxyl value is 1 in described (A) 1 molecule is selected from gylcol ether and propylene glycol apoplexy due to endogenous wind at least
One,
The organic solvent that hydroxyl value is more than 2 in described (B) 1 molecule for selected from ethylene glycol, diethylene glycol, triethylene glycol,
1,2-propylene glycol, 2-methyl-1,3-propanediol, 1,3-propylene glycol, 1,2-butanediol, 1,3 butylene glycol, 1,4-butanediol, 3-first
Base-1,3 butylene glycol, neopentyl glycol, 1,2-pentanediol, 1,5-pentanediol, 3-methyl isophthalic acid, 5-pentanediol, 1,2-hexanediol, 1,
6-hexanediol, ethohexadiol, 1,4-butanediol, 1,4 cyclohexane dimethanol, glycerol, trimethylolpropane, dipropylene glycol and three
At least one in propylene glycol.
2. water system coating composition as claimed in claim 1, it is characterised in that with in the organic solvent of described hydroxyl
Low boiling point solvent is as benchmark, and the boiling spread of described amines is-60 DEG C～+170 DEG C.
3. water system coating composition as claimed in claim 2, it is characterised in that with in the organic solvent of described hydroxyl
Low boiling point solvent is as benchmark, and the boiling spread of described amines is-20 DEG C～+170 DEG C.
4. the water system coating composition as according to any one of claims 1 to 3, it is characterised in that described hydroxyl organic
In solvent, the organic solvent that hydroxyl value is 1 in (A) 1 molecule and the hydroxyl value in (B) 1 molecule are more than 2 organic molten
The quality ratio of agent is 100:50～100:150.
5. the water system coating composition as according to any one of claims 1 to 3, it is characterised in that described amines is relative
Quality ratio in the organic solvent of described hydroxyl is 0.0005～0.1.
6. the water system coating composition as according to any one of claims 1 to 3, it is characterised in that described in there is Merlon
The carbamate resins of base is mean diameter 30nm～the urethane dispersion of 300nm or urethane emulsions.
7. the water system coating composition as according to any one of claims 1 to 3, it is characterised in that possibly together with glass transition
Acrylic acid dispersion or the acrylic emulsion that temperature Tg is more than 60 DEG C, mean diameter is 50nm～200nm.
8. the water system coating composition as according to any one of claims 1 to 3, it is characterised in that described water system coating compositions
Whole organic solvent amounts in thing are 20 mass %～55 mass %.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011080483 | 2011-03-31 | ||
| JP2011-080483 | 2011-03-31 | ||
| PCT/JP2012/058550 WO2012133752A1 (en) | 2011-03-31 | 2012-03-30 | Aqueous coating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103476883A CN103476883A (en) | 2013-12-25 |
| CN103476883B true CN103476883B (en) | 2016-11-30 |
Family
ID=
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5854337A (en) * | 1996-10-30 | 1998-12-29 | Herberts Gesellschaft Mit Beshrankter Haftung | Aqueous binder dispersion for physically drying coating agents and their use |
| CN1649954A (en) * | 2002-04-26 | 2005-08-03 | 三菱化学株式会社 | Polypropylene type aqueous dispersion, polypropylene type composite aqueous emulsion composition and its use |
| CN101638534A (en) * | 2008-07-31 | 2010-02-03 | 精工爱普生株式会社 | Ink composition, recorded material, recording method, and recording apparatus |
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5854337A (en) * | 1996-10-30 | 1998-12-29 | Herberts Gesellschaft Mit Beshrankter Haftung | Aqueous binder dispersion for physically drying coating agents and their use |
| CN1649954A (en) * | 2002-04-26 | 2005-08-03 | 三菱化学株式会社 | Polypropylene type aqueous dispersion, polypropylene type composite aqueous emulsion composition and its use |
| CN101638534A (en) * | 2008-07-31 | 2010-02-03 | 精工爱普生株式会社 | Ink composition, recorded material, recording method, and recording apparatus |
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