CN103469191B - A kind of painting dressing automobiles front surface process Phosphating Solution - Google Patents

A kind of painting dressing automobiles front surface process Phosphating Solution Download PDF

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Publication number
CN103469191B
CN103469191B CN201310434327.5A CN201310434327A CN103469191B CN 103469191 B CN103469191 B CN 103469191B CN 201310434327 A CN201310434327 A CN 201310434327A CN 103469191 B CN103469191 B CN 103469191B
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China
Prior art keywords
phosphating solution
front surface
painting dressing
dressing automobiles
surface process
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Expired - Fee Related
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CN201310434327.5A
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Chinese (zh)
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CN103469191A (en
Inventor
杨龙兴
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Zhuhai Newell Industry & Trade Co. Ltd.
Original Assignee
Wuxi Yanggong Machinery Manufacturing Co Ltd
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Priority to CN201310434327.5A priority Critical patent/CN103469191B/en
Publication of CN103469191A publication Critical patent/CN103469191A/en
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Publication of CN103469191B publication Critical patent/CN103469191B/en
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  • Chemical Treatment Of Metals (AREA)

Abstract

The invention discloses a kind of painting dressing automobiles front surface process Phosphating Solution, each component of this Phosphating Solution formula by mass concentration, phosphoric acid 20-25g/L, Secondary ammonium phosphate 5-8g/L, Sodium Fluoride 5-8g/L, nucite six phosphoric acid ester 0.5-4g/L, oxalic acid 1-3g/L, boric acid 0.5-2g/L, starch 0.2-0.5g/L, ammonium molybdate 0.05-0.2g/L.Painting dressing automobiles front surface process Phosphating Solution of the present invention adopts nucite six phosphoric acid ester to replace nickelous nitrate, decreases the pollution of nickel to environment.Meanwhile, after painting dressing automobiles front surface process Phosphating Solution bonderizing provided by the invention, residue is few, enhances the life cycle of Phosphating Solution.In addition, painting dressing automobiles front surface process Phosphating Solution provided by the invention, to after the surface treatment of automobile mechanical parts, can form the phosphatize phosphate coat of one deck evacuation, porous, descend good basis, be more conducive to the process of painting dressing automobiles to follow-up coating process pad.

Description

A kind of painting dressing automobiles front surface process Phosphating Solution
Technical field
The present invention relates to a kind of for the Phosphating Solution in painting dressing automobiles field.
Background technology
Vehicle coating process, generally can be divided into two parts: one is metallic surface process before application, is also pretreatment technology; Two is construction technologies of application.Surface treatment mainly comprises the removing etc. of old dope layer when removing the greasy dirt of workpiece surface, dust, corrosion and carry out repairing work, to improve the condition of surface of workpiece.Comprise, according to various particular case, mechanical workout and chemical treatment are carried out to workpiece surface, as phosphatization, oxidation and Passivation Treatment.Phosphatization is the critical process of pretreatment technology, directly affects the quality of painting dressing automobiles.
At present, for the Phosphating Solution of painting dressing automobiles front surface process, mainly there is the defect of following several respects:
1, nickel content is high, and environmental pollution is serious;
2, the residue in Phosphating Solution is too much;
3, corrosion-resistant.
Summary of the invention
The technical problem to be solved in the present invention overcomes existing defect, provides a kind of gained phosphatize phosphate coat and have the few and free of contamination painting dressing automobiles front surface process Phosphating Solution of strong corrosion resistant, residue.
Object of the present invention carrys out specific implementation by the following technical programs:
A kind of painting dressing automobiles front surface process Phosphating Solution, each component of this Phosphating Solution formula by mass concentration, phosphoric acid 20-25g/L, Secondary ammonium phosphate 5-8g/L, Sodium Fluoride 5-8g/L, nucite six phosphoric acid ester 0.5-4g/L, oxalic acid 1-3g/L, boric acid 0.5-2g/L, starch 0.2-0.5g/L, ammonium molybdate 0.05-0.2g/L.
Preferably, above-mentioned painting dressing automobiles front surface process Phosphating Solution, each component of this Phosphating Solution formula by mass concentration, phosphoric acid 25g/L, Secondary ammonium phosphate 6.5g/L, Sodium Fluoride 5g/L, nucite six phosphoric acid ester 3.5g/L, oxalic acid 2.5g/L, boric acid 1.3g/L, starch 0.4g/L, ammonium molybdate 0.08g/L.
Beneficial effect of the present invention:
Painting dressing automobiles front surface process Phosphating Solution of the present invention adopts nucite six phosphoric acid ester to replace nickelous nitrate, decreases the pollution of nickel to environment.Meanwhile, after painting dressing automobiles front surface process Phosphating Solution bonderizing provided by the invention, residue is few, enhances the life cycle of Phosphating Solution.In addition, painting dressing automobiles front surface process Phosphating Solution provided by the invention, to after the surface treatment of automobile mechanical parts, can form the phosphatize phosphate coat of one deck evacuation, porous, descend good basis, be more conducive to the process of painting dressing automobiles to follow-up coating process pad.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
embodiment 1:
A kind of painting dressing automobiles front surface process Phosphating Solution, each component of this Phosphating Solution formula by mass concentration, phosphoric acid 25g/L, Secondary ammonium phosphate 6.5g/L, Sodium Fluoride 5g/L, nucite six phosphoric acid ester 3.5g/L, oxalic acid 2.5g/L, boric acid 1.3g/L, starch 0.4g/L, ammonium molybdate 0.08g/L.
embodiment 2:
A kind of painting dressing automobiles front surface process Phosphating Solution, each component of this Phosphating Solution formula by mass concentration, phosphoric acid 20g/L, Secondary ammonium phosphate 8g/L, Sodium Fluoride 5g/L, nucite six phosphoric acid ester 4g/L, oxalic acid 1g/L, boric acid 2g/L, starch 0.2g/L, ammonium molybdate 0.2g/L.
embodiment 3:
A kind of painting dressing automobiles front surface process Phosphating Solution, each component of this Phosphating Solution formula by mass concentration, phosphoric acid 25g/L, Secondary ammonium phosphate 5g/L, Sodium Fluoride 8g/L, nucite six phosphoric acid ester 0.5g/L, oxalic acid 3g/L, boric acid 0.5g/L, starch 0.5g/L, ammonium molybdate 0.05g/L.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (1)

1. a painting dressing automobiles front surface process Phosphating Solution, it is characterized in that: each component of this Phosphating Solution formula by mass concentration, phosphoric acid 25g/L, Secondary ammonium phosphate 6.5g/L, Sodium Fluoride 5g/L, nucite six phosphoric acid ester 3.5g/L, oxalic acid 2.5g/L, boric acid 1.3g/L, starch 0.4g/L, ammonium molybdate 0.08g/L.
CN201310434327.5A 2013-09-23 2013-09-23 A kind of painting dressing automobiles front surface process Phosphating Solution Expired - Fee Related CN103469191B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310434327.5A CN103469191B (en) 2013-09-23 2013-09-23 A kind of painting dressing automobiles front surface process Phosphating Solution

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Application Number Priority Date Filing Date Title
CN201310434327.5A CN103469191B (en) 2013-09-23 2013-09-23 A kind of painting dressing automobiles front surface process Phosphating Solution

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CN103469191B true CN103469191B (en) 2016-04-13

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017214780A1 (en) * 2016-06-12 2017-12-21 深圳市恒兆智科技有限公司 Phosphating coating agent, iron piece and method for coating treatment of surface thereof
CN107475758A (en) * 2017-08-11 2017-12-15 江苏富翔汽车科技有限公司 A kind of acid electroplating admiro additive

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1851047A (en) * 2006-05-18 2006-10-25 武汉理工大学 Phosphorizing solution containing soluble starch, and its preparing method
CN101906629A (en) * 2010-08-09 2010-12-08 哈尔滨工业大学 Blue write chromate-free passivation liquid of electrogalvanized layer and method for passivating electrogalvanized layer by adopting same
CN102002699A (en) * 2010-11-19 2011-04-06 浙江英洛华磁业有限公司 Coating method of chromium-free passivating film
CN102703914A (en) * 2012-06-19 2012-10-03 湖南省烟草公司永州市公司 Environment-friendly derusting conditioning fluid for metal equipment of flue-curing barn

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1851047A (en) * 2006-05-18 2006-10-25 武汉理工大学 Phosphorizing solution containing soluble starch, and its preparing method
CN101906629A (en) * 2010-08-09 2010-12-08 哈尔滨工业大学 Blue write chromate-free passivation liquid of electrogalvanized layer and method for passivating electrogalvanized layer by adopting same
CN102002699A (en) * 2010-11-19 2011-04-06 浙江英洛华磁业有限公司 Coating method of chromium-free passivating film
CN102703914A (en) * 2012-06-19 2012-10-03 湖南省烟草公司永州市公司 Environment-friendly derusting conditioning fluid for metal equipment of flue-curing barn

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
植酸在金属表面处理中的应用;周和平;《电镀与环保》;20030330(第02期);24页倒数第4段 *
钢铁表面植酸转化膜研究;亓美玲;《工程科技Ⅰ辑》;20130228;13页第1段,15页最后一段,17页第3段,18页第3段,19页倒数第1段,20页最后一段 *

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Inventor after: Luo Guanghe

Inventor before: Yang Longxing

COR Change of bibliographic data
TR01 Transfer of patent right

Effective date of registration: 20161123

Address after: 519070 Guangdong city of Zhuhai province Rooster Hill Road No. 515 building 14 unit 2 Room 203

Patentee after: Zhuhai Newell Industry & Trade Co. Ltd.

Address before: 214000 Jiangsu city in Wuxi Province Economic Development Zone Huishan Spring Road No. 588

Patentee before: Wuxi Yanggong Machinery Manufacturing Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160413

Termination date: 20190923

CF01 Termination of patent right due to non-payment of annual fee