CN103468101A - Graphene heat dissipation coating - Google Patents
Graphene heat dissipation coating Download PDFInfo
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- CN103468101A CN103468101A CN2013103695188A CN201310369518A CN103468101A CN 103468101 A CN103468101 A CN 103468101A CN 2013103695188 A CN2013103695188 A CN 2013103695188A CN 201310369518 A CN201310369518 A CN 201310369518A CN 103468101 A CN103468101 A CN 103468101A
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Abstract
The invention discloses a graphene heat dissipation coating, which is composed of the following components in mass part: 50-80 parts of epoxy acrylic resin, 5-10 parts of graphene, 60-80 parts of water, 10-15 parts of coloring agent, and 20-30 parts of auxiliary agent, wherein the coloring agent is one type or a mixture of multiple types from phthalocyanine blue, azo red and azo blue; the auxiliary agent comprises dispersing agent, defoaming agent, curing agent and adhesion promoter. The graphene heat dissipation coating is simple in preparation process and low in production cost, and can be cured at room temperature. The graphene is adopted as the main heat dissipation medium to provide channels for heat transfer, so that heat release is facilitated. The coating is applied onto the surface of a heat dissipation device, so that the heat dissipation area is increased, the heat dissipation effect is improved, and the characteristics of high efficiency and favorable environment friendliness are achieved.
Description
Technical field
The present invention relates to a kind of coating, relate in particular to a kind of Graphene heat radiation coating, belong to the new coating technical field.
Background technology
Coating is as a kind of Industrial products, and its main function is to decorate, and function is comparatively single.Along with scientific and technological development and human living standard's raising, the traditional coating of function singleness can't meet real demand.
Heat radiation coating, as a kind of novel coating, not only has the basic function of decoration, has the effect that improves radiating efficiency simultaneously, obtains paying close attention to widely and studying.Yet current most heat radiation coatings on the market are all to adopt expensive heat-transfer medium as filler, complex manufacturing, cost is higher, is unfavorable for mass production and the mass-producing application of coating.
Summary of the invention
The technical problem solved: the invention provides a kind of Graphene heat radiation coating, adopt cheap Graphene as main heat-eliminating medium, the coating material production cost is lower, and radiating effect is obvious.
Technical scheme: the invention provides a kind of Graphene heat radiation coating, the mass fraction of its each component consists of: epoxy acrylic resin 50-80 part, Graphene 5-10 part, water 60-80 part, tinting material 10-15 part, auxiliary agent 20-30 part.
Described tinting material is one or more mixing in pthalocyanine blue, azophloxine, azo blue; Described auxiliary agent comprises dispersion agent, defoamer, solidifying agent and adhesion promoter.
Described dispersion agent is selected polyethylene wax; Described defoamer is selected polydimethylsiloxane; Described solidifying agent is selected quadrol; Described adhesion promoter is selected aminopropyl trimethylammonium TMOS.
The preparation method of a kind of Graphene heat radiation coating provided by the invention, its preparation process is as follows:
(1) by above-mentioned mass fraction, epoxy acrylic resin, Graphene, water are mixed and adds stirrer, control rotating speed 1000-1500rpm, churning time 1-2h;
(2) add dispersion agent, defoamer, solidifying agent and adhesion promoter successively in stirrer, control rotating speed 800-1000rpm, churning time 0.5-1h;
(3) add tinting material in stirrer, control rotating speed 500-800rpm, after mixing, obtain the Graphene heat radiation coating.
Beneficial effect: Graphene heat radiation coating preparation technology provided by the invention is simple, and low production cost is curable under room temperature.Adopt Graphene as main heat-eliminating medium, for heat transfer provides passage, can increase area of dissipation, be conducive to the release of heat, improving radiating effect, have the characteristics of high-efficiency environment friendly.
Embodiment
Mode below by embodiment further illustrates the present invention, but therefore the present invention is not confined to following embodiment.
Embodiment 1
52 parts of epoxy acrylic resins, 5 parts of Graphenes, 65 parts, water, 11 parts of pthalocyanine blue, 5 parts of polyethylene waxs, 5 parts of polydimethylsiloxanes, 5 parts of quadrols, 5 parts of aminopropyl trimethylammonium TMOSs.
(1) 52 parts of epoxy acrylic resins, 5 parts of Graphenes, 65 water are mixed and add stirrer, control rotating speed 1000rpm, churning time 1h;
(2) add 5 parts of polyethylene waxs, 5 parts of polydimethylsiloxanes, 5 parts of quadrols and 5 parts of aminopropyl trimethylammonium TMOSs successively in stirrer, control rotating speed 800rpm, churning time 0.5h;
(3) add 11 parts of pthalocyanine blue in stirrer, control rotating speed 500rpm, obtain cyan Graphene heat radiation coating after mixing.
Embodiment 2
74 parts of epoxy acrylic resins, 7 parts of Graphenes, 76 parts, water, 13 parts of azophloxines, 7 parts of polyethylene waxs, 6 parts of polydimethylsiloxanes, 8 parts of quadrols, 5 parts of aminopropyl trimethylammonium TMOSs.
(1) 74 parts of epoxy acrylic resins, 7 parts of Graphenes, 76 water are mixed and add stirrer, control rotating speed 1200rpm, churning time 1.5h;
(2) add 7 parts of polyethylene waxs, 6 parts of polydimethylsiloxanes, 8 parts of quadrols and 5 parts of aminopropyl trimethylammonium TMOSs successively in stirrer, control rotating speed 900rpm, churning time 0.7h;
(3) add 13 parts of azophloxines in stirrer, control rotating speed 700rpm, obtain red Graphene heat radiation coating after mixing.
Embodiment 3
80 parts of epoxy acrylic resins, 10 parts of Graphenes, 80 parts, water, 15 parts of azo blues, 7 parts of polyethylene waxs, 8 parts of polydimethylsiloxanes, 8 parts of quadrols, 7 parts of aminopropyl trimethylammonium TMOSs.
(1) 80 parts of epoxy acrylic resins, 10 parts of Graphenes, 80 water are mixed and add stirrer, control rotating speed 1500rpm, churning time 1.8h;
(2) add 7 parts of polyethylene waxs, 8 parts of polydimethylsiloxanes, 8 parts of quadrols and 7 parts of aminopropyl trimethylammonium TMOSs successively in stirrer, control rotating speed 1000rpm, churning time 0.8h;
(3) add 15 parts of azo blues in stirrer, control rotating speed 800rpm, obtain blue Graphene heat radiation coating after mixing.
The various embodiments described above gained Graphene heat radiation coating is sprayed on steel plate, after self-vulcanizing, its performance is detected, result is as table 1.
Table 1 performance test results
By two stainless-steel sheets, (A plate surface scribbles heat radiation coating, B plate surface is not coated with heat radiation coating) be positioned on hot-plate, adjust successively temperature 50 C, 100 ℃, 150 ℃, 200 ℃, 250 ℃, balance 30 minutes, temp.-sensing wire is fixed in to the sheet material center, utilize temperature measurer to record temperature, the results are shown in Table 2.Result shows, scribbles the steel billet temperature of heat radiation coating all lower than the steel plate that is not coated with heat radiation coating, illustrates that Graphene heat radiation coating of the present invention has radiating effect preferably.
Table 2 thermograph result
Claims (5)
1. a Graphene heat radiation coating, is characterized in that the mass fraction of each component consists of: epoxy acrylic resin 50-80 part, Graphene 5-10 part, water 60-80 part, tinting material 10-15 part, auxiliary agent 20-30 part.
2. a kind of Graphene heat radiation coating according to claim 1, it is characterized in that: described tinting material is one or more mixing in pthalocyanine blue, azophloxine, azo blue.
3. a kind of Graphene heat radiation coating according to claim 1, it is characterized in that: described auxiliary agent comprises dispersion agent, defoamer, solidifying agent and adhesion promoter.
4. a kind of Graphene heat radiation coating according to claim 3, it is characterized in that: described dispersion agent is selected polyethylene wax, and defoamer is selected polydimethylsiloxane, and solidifying agent is selected quadrol, and adhesion promoter is selected aminopropyl trimethylammonium TMOS.
5. according to the preparation method of the described a kind of Graphene heat radiation coating of claim 1-4 any one, it is characterized in that preparation process is as follows:
(1) by above-mentioned mass fraction, epoxy acrylic resin, Graphene, water are mixed and adds stirrer, control rotating speed 1000-1500rpm, churning time 1-2h;
(2) add dispersion agent, defoamer, solidifying agent and adhesion promoter successively in stirrer, control rotating speed 800-1000rpm, churning time 0.5-1h;
(3) add tinting material in stirrer, control rotating speed 500-800rpm, after mixing, obtain the Graphene heat radiation coating.
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CN2013103695188A CN103468101A (en) | 2013-08-23 | 2013-08-23 | Graphene heat dissipation coating |
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CN2013103695188A CN103468101A (en) | 2013-08-23 | 2013-08-23 | Graphene heat dissipation coating |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104194631A (en) * | 2014-08-12 | 2014-12-10 | 安徽碳索材料科技有限公司 | Coating on shell of electrolytic capacitor to dissipate heat by taking graphene nanoplatelets as main agent |
CN104194455A (en) * | 2014-08-25 | 2014-12-10 | 鸿纳(东莞)新材料科技有限公司 | Graphene coating as well as preparation method and coating method thereof |
CN104498678A (en) * | 2014-12-11 | 2015-04-08 | 山东大学 | Graphene solid quenching and cooling medium as well as preparation method and application |
CN104592863A (en) * | 2015-01-04 | 2015-05-06 | 林前锋 | Graphene coating and preparation method thereof |
CN104848188A (en) * | 2015-03-30 | 2015-08-19 | 创金美科技(深圳)有限公司 | Method for improving performance of lamp radiator |
CN105131730A (en) * | 2015-08-13 | 2015-12-09 | 蚌埠市时代电子有限公司 | Environmental-protection heat-dissipating coating material and preparation method thereof |
CN105195407A (en) * | 2015-08-22 | 2015-12-30 | 江苏万源新材料有限公司 | Aluminum base-graphene water-based acrylic resin composite material and preparation method thereof |
CN105482435A (en) * | 2014-09-29 | 2016-04-13 | 中国科学院苏州纳米技术与纳米仿生研究所 | Three-dimensional-corrugated-graphene heat dissipating slurry, preparation method therefor and application of three-dimensional-corrugated-graphene heat dissipating slurry |
CN106085377A (en) * | 2016-06-28 | 2016-11-09 | 太仓陶氏电气有限公司 | A kind of CNT thermal conducting agent of computer CPU chip radiator |
CN111334085A (en) * | 2020-04-08 | 2020-06-26 | 德州学院 | Graphene modification method of phthalocyanine blue pigment |
WO2021144508A1 (en) * | 2020-01-16 | 2021-07-22 | Jose Buendia | Quantum polarisation of electrons |
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CN102181212A (en) * | 2011-01-28 | 2011-09-14 | 谢金庚 | Radiating material and preparation method of radiating material |
CN103205149A (en) * | 2012-01-17 | 2013-07-17 | 帛宏兴业股份有限公司 | Heat radiation material, heat radiation structure, and preparation method thereof |
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Patent Citations (2)
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CN102181212A (en) * | 2011-01-28 | 2011-09-14 | 谢金庚 | Radiating material and preparation method of radiating material |
CN103205149A (en) * | 2012-01-17 | 2013-07-17 | 帛宏兴业股份有限公司 | Heat radiation material, heat radiation structure, and preparation method thereof |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104194631A (en) * | 2014-08-12 | 2014-12-10 | 安徽碳索材料科技有限公司 | Coating on shell of electrolytic capacitor to dissipate heat by taking graphene nanoplatelets as main agent |
CN104194631B (en) * | 2014-08-12 | 2016-06-22 | 安徽碳索材料科技有限公司 | It is the coating that host coats that electrochemical capacitor shell produces to dispel the heat by graphene microchip |
CN104194455A (en) * | 2014-08-25 | 2014-12-10 | 鸿纳(东莞)新材料科技有限公司 | Graphene coating as well as preparation method and coating method thereof |
CN105482435A (en) * | 2014-09-29 | 2016-04-13 | 中国科学院苏州纳米技术与纳米仿生研究所 | Three-dimensional-corrugated-graphene heat dissipating slurry, preparation method therefor and application of three-dimensional-corrugated-graphene heat dissipating slurry |
CN105482435B (en) * | 2014-09-29 | 2018-03-20 | 中国科学院苏州纳米技术与纳米仿生研究所 | Three-dimensional drape shape graphene radiating slurry, its preparation method and application |
CN104498678A (en) * | 2014-12-11 | 2015-04-08 | 山东大学 | Graphene solid quenching and cooling medium as well as preparation method and application |
CN104498678B (en) * | 2014-12-11 | 2016-06-22 | 山东大学 | Graphene solid quenching medium and preparation method and application |
CN104592863A (en) * | 2015-01-04 | 2015-05-06 | 林前锋 | Graphene coating and preparation method thereof |
CN104848188A (en) * | 2015-03-30 | 2015-08-19 | 创金美科技(深圳)有限公司 | Method for improving performance of lamp radiator |
CN105131730A (en) * | 2015-08-13 | 2015-12-09 | 蚌埠市时代电子有限公司 | Environmental-protection heat-dissipating coating material and preparation method thereof |
CN105195407A (en) * | 2015-08-22 | 2015-12-30 | 江苏万源新材料有限公司 | Aluminum base-graphene water-based acrylic resin composite material and preparation method thereof |
CN106085377A (en) * | 2016-06-28 | 2016-11-09 | 太仓陶氏电气有限公司 | A kind of CNT thermal conducting agent of computer CPU chip radiator |
WO2021144508A1 (en) * | 2020-01-16 | 2021-07-22 | Jose Buendia | Quantum polarisation of electrons |
CN111334085A (en) * | 2020-04-08 | 2020-06-26 | 德州学院 | Graphene modification method of phthalocyanine blue pigment |
CN111334085B (en) * | 2020-04-08 | 2021-07-23 | 德州学院 | Graphene modification method of phthalocyanine blue pigment |
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Application publication date: 20131225 |