CN103466939B - A kind of sheen stained glass work and preparation method thereof and specific equipment - Google Patents
A kind of sheen stained glass work and preparation method thereof and specific equipment Download PDFInfo
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- CN103466939B CN103466939B CN201310347711.1A CN201310347711A CN103466939B CN 103466939 B CN103466939 B CN 103466939B CN 201310347711 A CN201310347711 A CN 201310347711A CN 103466939 B CN103466939 B CN 103466939B
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Abstract
The present invention relates to a kind of sheen stained glass work and preparation method thereof and specific equipment, described sheen stained glass work is made up of the raw material of following weight part: ground silica 50 ~ 70 parts, soda ash 10 ~ 16 parts, Feldspar Powder 12 ~ 22 parts, 10 ~ 24 parts, aluminium hydroxide, 1 ~ 12 part, zinc oxide, 4 ~ 24 parts, calcium carbonate, borax 1.4 ~ 12 parts, Sodium Silicofluoride 8 ~ 16 parts, 0.8 ~ 5.8 part, salt of wormwood, SODIUMNITRATE 0.4 ~ 4 part, auxiliary material 6.6 ~ 70 parts, described auxiliary material is selected from titanium dioxide, barium carbonate, red lead, calcium phosphate, barium sulfate, magnesium oxide, fluorite, white arsenic, weisspiessglanz, cobalt oxide, cupric oxide, chromoxide green, sodium antimonate, cadmium yellow, sulphur, uranium oxide, cerium oxide, cadmium red, Cadmium Sulfide, selenium powder, several in yttrium aluminum garnet, its preparation method is as follows: (1) batching is founded, (2) shaping, (3) cut, anneal, check, pack, this sheen stained glass work long service life, desired raw material is contaminate environment not easily, and this sheen stained glass work can be fluorescent tube, lampshade or bulb, for illumination or amusement light fixture.
Description
Technical field
The present invention relates to a kind of sheen stained glass work and preparation method thereof and specific equipment, belong to glasswork formula and preparing technical field.
Background technology
Along with the raising of LED light source technology and universal, led illumination emerges rapidly, but the consequent is blue light contamination problem.The lampshade now commercially having pc material, frosting or dusting glass material two kinds to throw light on for Led and fluorescent tube, but the lampshade of pc material along with duration of service the easy variable color of growth and have potential safety hazard, the easy contaminate environment of mat glass desired raw material, the easy variable color of painting bisque of dusting glass, comes off.In view of above problem, the present invention have developed a kind of sheen stained glass work, and this sheen stained glass work overcomes above-mentioned shortcoming, safety and environmental protection, can not cause mercury, acid pollution, and waste material (comprising finished product) all can be recycled.
Summary of the invention
The object of the invention is to the following deficiency solving prior art: the goods be made up of pc material are easy to change, work-ing life is short; The easy contaminate environment of raw material described in mat glass goods, there is provided a kind of sheen stained glass work, this sheen stained glass work long service life, desired raw material is contaminate environment not easily, this sheen stained glass work can be fluorescent tube, bulb or lampshade, for illumination or amusement light fixture.
Another object of the present invention is to provide a kind of preparation method of sheen stained glass work and realizes the specific equipment of the method, and described preparation method is simple to operate, tooling cost is low.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of sheen stained glass work, the main oxides formation of described sheen stained glass work is by weight percentage: SiO
250 ~ 80%, B
2o
32 ~ 8%, ZnO1 ~ 8%, CaO0.2 ~ 8%, Na
2o8 ~ 16%, K
2o0.1 ~ 2%, Al
2o
36 ~ 15%;
Described sheen stained glass work is made up of the raw material of following weight part: ground silica 50 ~ 70 parts, soda ash 10 ~ 16 parts, Feldspar Powder 12 ~ 22 parts, 10 ~ 24 parts, aluminium hydroxide, 1 ~ 12 part, zinc oxide, 4 ~ 24 parts, calcium carbonate, borax 1.4 ~ 12 parts, Sodium Silicofluoride 8 ~ 16 parts, 0.8 ~ 5.8 part, salt of wormwood, SODIUMNITRATE 0.4 ~ 4 part, auxiliary material 6.6 ~ 70 parts, described auxiliary material is selected from titanium dioxide, barium carbonate, red lead, calcium phosphate, barium sulfate, magnesium oxide, fluorite, white arsenic, weisspiessglanz, cobalt oxide, cupric oxide, chromoxide green, sodium antimonate, cadmium yellow, sulphur, uranium oxide, cerium oxide, cadmium red, Cadmium Sulfide, several in selenium powder and yttrium aluminum garnet,
Its preparation method is as follows:
(1) prepare burden and found: by ground silica, soda ash, Feldspar Powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, Sodium Silicofluoride, salt of wormwood, SODIUMNITRATE and auxiliary material grind in proportion and mix, and obtain admixtion; Described admixtion feeder adds feed bin, at the uniform velocity adds furnace pond, founds 10 ~ 12h is melted into evenly clarification glass metal to compound under the actual temperature of fusion of 1260 ~ 1380 DEG C;
(2) shaping;
(3) cut, anneal, check, pack.
So-called sheen glass, when being the interface utilizing light by two kinds of different medias, will changing former direction and produce refraction, light, through repeatedly reflecting, produces the principle of scattering.The present invention, on the basis of transparent glass, adds emulsifying agent in formula, glass can be made to produce micro crystal, produce refraction when light is injected; Add tinting material simultaneously, namely can produce the sheen stained glass that can carry out scattering to light of different colours, sheen stained glass is processed into glasswork as required, i.e. sheen stained glass work.
As preferably, be constructed as follows with auxiliary material described in parts by weight: titanium dioxide 0.2 ~ 4 part, barium carbonate 0.4 ~ 3.2 part, red lead 0 ~ 2.4 part, 4 ~ 24 parts, calcium phosphate, 1 ~ 4 part, barium sulfate, 0 ~ 3 part, magnesium oxide, 0 ~ 4.4 part, fluorite, white arsenic 0.6 ~ 2.6 part, weisspiessglanz 0.4 ~ 1.2 part, cobalt oxide 0 ~ 4 part, cupric oxide 0 ~ 1 part, chromoxide green 0 ~ 0.8 part, sodium antimonate 0 ~ 1.2 part, cadmium yellow 0 ~ 2 part, 0 ~ 0.08 part, sulphur, uranium oxide 0 ~ 0.08 part, cerium oxide 0 ~ 0.88 part, cadmium red 0 ~ 2.2 part, Cadmium Sulfide 0 ~ 0.8 part, selenium powder 0 ~ 0.15 part, yttrium aluminum garnet 0.3 ~ 8 part.
As preferably, described in step (1), furnace pond comprises fusing one district, melts 2nd district, homogenization zone and workspace, the concrete melting process of described admixtion is as follows: first compound founds 3 ~ 5h in fusing one district in 1380 DEG C, then enter fusing two district and found 3h in 1350 ± 3 DEG C, then enter homogenization zone and found 2h in 1280 ± 3 DEG C, finally enter workspace and found 2h in 1260 ± 3 DEG C.
As preferably, described sheen stained glass work is fluorescent tube, bulb or lampshade, and described fluorescent tube, bulb or lampshade are used for illumination or amusement light fixture.
The present invention with ground silica, soda ash, Feldspar Powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, Sodium Silicofluoride, salt of wormwood, SODIUMNITRATE for main raw material, be equipped with different auxiliary materials, the sheen stained glass work such as oyster white, breast is blue, breast green, milk yellow and breast are red can be made, specifically as shown in table 1:
The proportioning raw materials (with parts by weight) of the various sheen stained glass work of table 1
| Material name | Oyster white | Breast is blue | Breast is green | Milk yellow | Breast is red |
| Ground silica | 50-70 | 50-70 | 50-70 | 50-70 | 50-70 |
| Soda ash | 10-16 | 10 | 16 | 8-12 | 8-12 |
| SODIUMNITRATE | 2-4 | 2-4 | 2-4 | 0.4-2 | 0.4-2 |
| Salt of wormwood | 0.8-2.4 | 0.8-2.4 | 0.8-2.4 | 3.4-5.8 | 3.4-5.8 |
| Feldspar Powder | 12-22 | 12-22 | 12-22 | 6-10 | 6-10 |
| Aluminium hydroxide | 10-15 | 6-12 | 6-12 | 15-24 | 15-24 |
| Zinc oxide | 1-5 | 1-5 | 1-5 | 8-12 | 8-12 |
| Calcium carbonate | 2-5 | 2-5 | 2-5 | 0 | 0 |
| Borax | 1.4-4.4 | 1.4-4.4 | 1.4-4.4 | 8-12 | 8-12 |
| Sodium Silicofluoride | 8-12 | 8-12 | 8-12 | 8-16 | 8-16 |
| Titanium dioxide | 1-4 | 0.8-2.4 | 0.8-2.4 | 0.2-2 | 0.2-2 |
| Barium sulfate | 1-4 | 1-4 | 1-4 | 1-4 | 1-4 |
| Barium carbonate | 0.4-3.2 | 0.4-3.2 | 0.4-3.2 | 0.4-3.2 | 0.4-3.2 |
| Red lead | 0.4-1.2 | 0.5-2.4 | 0.5-2.4 | 0 | 0 |
| Calcium phosphate | 4-24 | 4-24 | 4-24 | 4-24 | 4-24 |
| Magnesium oxide | 0.5-3 | 0.5-3 | 0.5-3 | 0 | 0 |
| Fluorite | 1.4-4.4 | 1.4-4.4 | 1.4-4.4 | 0 | 0 |
| Weisspiessglanz | 0.4-1.2 | 0.5-1.3 | 0.5-1.3 | 0.4-1.2 | 0.4-1.2 |
| White arsenic | 0.6-2.6 | 0.6-2.6 | 0.6-2.6 | 0.6-2.6 | 0.6-2.6 |
| Cobalt oxide | 0 | 0.05-4 | 0 | 0 | |
| Cupric oxide | 0 | 0.5-1 | 0.5-1 | 0 | 0 |
| Chromoxide green | 0 | 0 | 0.2-0.8 | 0 | 0 |
| Sodium antimonate | 0.4-1.2 | 0.4-1.2 | 0.4-1.2 | 0 | 0 |
| Cadmium yellow | 0 | 0 | 0 | 1.2-2 | 0.2-0.4 |
| Sulphur | 0 | 0 | 0 | 0.02-0.08 | 0.02-0.08 |
| Uranium oxide | 0 | 0 | 0 | 0.04-0.08 | 0 |
| Cerium oxide | 0 | 0 | 0 | 0.06-0.08 | 0 |
| Cadmium red | 0 | 0 | 0 | 0 | 1.4-2.2 |
| Cadmium Sulfide | 0 | 0 | 0 | 0 | 0.1-0.8 |
| Selenium powder | 0 | 0 | 0 | 0 | 0.08-0.15 |
| Yttrium aluminum garnet | 0.3-8 | 0.3-8 | 0.3-8 | 0.3-8 | 0.3-8 |
A kind of fusing kiln, comprise kiln body and the some thermopairs for detecting kiln temperature, kiln body is provided with combustion chamber and melting chamber, is fixed with kiln cover plate between described combustion chamber and melting chamber, described thermopair is evenly located on the downside of kiln cover plate, and is positioned at the top of melting chamber.Kiln adds one deck kiln cover plate between melting chamber and combustion chamber, both decreased the volatilization of component in sheen stained glass formula, ensure that again lower floor's temperature of fusion is even, thermopair is located at melting chamber top, and on the downside of kiln cover plate, ensure the accurate and ageing of measuring tempeature.
As preferably, described melting chamber is divided into fusing one district by three road weirs, is melted 2nd district, homogenization zone and workspace, is provided with dog-hole bottom described weir, and the height of described dog-hole is 100 ~ 150mm, described fusing one district is communicated with charging opening, and described workspace is communicated with discharge port.Melting chamber subregion is arranged, and increases furnace space, makes more uniform temperature; Weir and dog-hole are set, make glass metal Uniform Flow, reduce the existence of the motionless bed of material, can melt satisfactory softening stained glass liquid.
As preferably, the side of described combustion chamber is fixed with spray gun, and opposite side is provided with air outlet, and described air outlet is fixed with interchanger.The present invention does not establish chimney, but adds an interchanger at air outlet, and the hot blast exchanged by interchanger enters spray gun, effective save energy.
As preferably, described workspace side is also provided with overflow port, and the height of described overflow port is 40 ~ 60mm.
The invention has the beneficial effects as follows:
(1) sheen stained glass work manufacture craft of the present invention is easy, energy-conserving and environment-protective, safety and sanitation;
(2) sheen stained glass have that temperature of fusion is low, in raw material constituent part again than being easier to volatilization variable color feature, by using the fusing kiln improved in preparation method of the present invention, decrease sheen glass Raw component volatilization; Add an interchanger at air outlet, the hot blast exchanged by interchanger enters spray gun, effective save energy; Multiple tracks weir and dog-hole are set, make glass metal Uniform Flow, reduce the existence of the motionless bed of material, melt the softening stained glass liquid of better quality.
Accompanying drawing explanation
Fig. 1 is the schematic front view melting kiln in the present invention;
Fig. 2 is the schematic top plan view of Fig. 1.
In figure: 1, kiln body, 11, combustion chamber, 111, spray gun, 112, air outlet, 12, melting chamber, 121, weir, 122, a district is melted, 123, melt 2nd district, 124, homogenization zone, 125, workspace, 126, dog-hole, 2, kiln cover plate, 3, charging opening, 4, discharge port, 5, interchanger, 6, overflow port.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in further detail.
Embodiment 1: a kind of oyster white sheen stained glass lampshade, raw material is as shown in Table 2 made:
The preparation method of described oyster white sheen stained glass lampshade is as follows:
(1) prepare burden and found: by the ground silica shown in table 2, soda ash, Feldspar Powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, Sodium Silicofluoride, salt of wormwood, SODIUMNITRATE and auxiliary material grind in proportion and mix, obtain admixtion, admixtion feeder adds feed bin, furnace pond is evenly added with the speed of 15kg/min, first compound is founded 5h in fusing one district in 1380 DEG C and is then entered fusing two district and found 3h in 1350 ± 3 DEG C, then enter homogenization zone and found 2h in 1280 ± 3 DEG C, finally enter workspace and found 2h in 1260 ± 3 DEG C, obtain the glass metal of evenly clarification,
(2) shaping: glass metal flows into feeding machine orifice ring by work pool through hopper, temperature controls at 1160 DEG C, establish above feeding machine one can the revolving sleeve of adjusting rotary speed, rotating speed is 1rpm, to make glass metal color even, glass metal is flowed out uniformly by the orifice ring that can control flow, the flow of every bar production line is 120kg/h, below orifice ring, arrange one can the scissors of governing speed, at the uniform velocity glass metal is cut into glass drop, speed is 80/point, the glass drop sheared enters the parison mo(u)ld of blowing machine along slideway, by cake of press mechanism, glass drop is pressed into circular pie, sagging glass vacuole empty in pie glass is blown out one, under gravity, glass vacuole extends stretching downwards naturally, form just type glass vacuole, after first type glass vacuole enters shaping mould, shaping mould closes, glass vacuole does relative rotary motion with mould in a mold, die temperature controls at 300 DEG C,
(3) cut, anneal, check, pack: after hardened forming obtains work in-process in shaping mould, mold open, work in-process enter material cap division mechanism, material cap is cut away rear feeding waste recovery storehouse, work in-process are sent into travelling belt and are sent to annealing furnace, work in-process are placed in the guipure of annealing furnace, with at the uniform velocity through 40min, temperature controls at 420 DEG C, work in-process are cooled to normal temperature, with laser cutting machine, oral area cutting is carried out to work in-process, after cutting, carry out oral area flame round mouth, form oyster white sheen stained glass lampshade finished product.
Embodiment 2: a kind of oyster white sheen stained glass lampshade, raw material is as shown in Table 2 made, and preparation method is as follows:
(1) prepare burden and found: by the ground silica shown in table 2, soda ash, Feldspar Powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, Sodium Silicofluoride, salt of wormwood, SODIUMNITRATE and auxiliary material grind in proportion and mix, obtain admixtion, admixtion feeder adds feed bin, furnace pond is evenly added with the speed of 15kg/min, first compound founds 3h in fusing one district in 1380 DEG C, then enter fusing two district and found 3h in 1350 ± 3 DEG C, then enter homogenization zone and found 2h in 1280 ± 3 DEG C, finally enter workspace and found 2h in 1260 ± 3 DEG C, obtain the glass metal of evenly clarification,
(2) shaping: glass metal flows into feeding machine orifice ring by work pool through hopper, temperature controls at 1280 DEG C, establish above feeding machine one can the revolving sleeve of adjusting rotary speed, rotating speed is 5rpm, to make glass metal color even, glass metal is flowed out uniformly by the orifice ring that can control flow, the flow of every bar production line is 480kg/h, below orifice ring, arrange one can the scissors of governing speed, at the uniform velocity glass metal is cut into glass drop, speed is 90/point, the glass gob sheared enters the parison mo(u)ld of blowing machine along slideway, by cake of press mechanism, glass gob is pressed into circular pie, sagging glass parison empty in pie glass is blown out one, under gravity, parison extends stretching downwards naturally, form just type glass parison, after first type glass parison enters shaping mould, shaping mould closes, glass parison does relative rotary motion with mould in a mold, die temperature controls at 300 DEG C,
(3) cut, anneal, check, pack: after hardened forming obtains work in-process in shaping mould, mold open, work in-process enter material cap division mechanism, material cap is cut away rear feeding waste recovery storehouse, work in-process are sent into travelling belt and are sent to annealing furnace, work in-process are placed in the guipure of annealing furnace, with at the uniform velocity through 180min, temperature controls at 580 DEG C, then half product is cooled to normal temperature, with laser cutting machine, oral area cutting is carried out to work in-process, after cutting, carry out oral area flame round mouth, form oyster white sheen stained glass lampshade finished product.
Table 2: the oyster white sheen stained glass lampshade raw material composition of embodiment 1 and embodiment 2
Embodiment 3: a kind of newborn blue sheen stained glass fluorescent tube, raw material is as shown in Table 3 made:
The preparation method of described breast blue sheen stained glass fluorescent tube is as follows:
(1) prepare burden and found: by the ground silica shown in table 2, soda ash, Feldspar Powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, Sodium Silicofluoride, salt of wormwood, SODIUMNITRATE and auxiliary material grind in proportion and mix, obtain admixtion, admixtion feeder adds feed bin, furnace pond is evenly added with the speed of 15kg/min, first compound founds 4h in fusing one district in 1380 DEG C, then enter fusing two district and found 3h in 1350 ± 3 DEG C, then enter homogenization zone and found 2h in 1280 ± 3 DEG C, finally enter workspace and found 2h in 1260 ± 3 DEG C, obtain the glass metal of evenly clarification,
(2) shaping: glass metal flows into feeding machine orifice ring by work pool through hopper, temperature controls at 1160 DEG C, above feeding machine, arrange one can the revolving sleeve of adjusting rotary speed, rotating speed is 1rpm, to make glass metal color even, glass metal is flowed out uniformly by the orifice ring that can control flow, the flow of every bar production line is 120kg/h, an admission gear is set above orifice ring, with the Glass tubing making the glass metal of outflow form hollow, Glass tubing progressively hardens along the runway that 25m is long, drawn by tractor and move ahead, the Glass tubing of different lengths is cut into by cutting knife, tractor can governing speed and control load by orifice ring, to produce various outer diameter, wall thickness, the breast blue sheen stained glass fluorescent tube of length.
(3) cut, anneal, check, pack: the Glass tubing of well cutting carries out external diameter, wall thickness detection through laser, conveyer is entered by otherwise limit deviation stepping, be sent to essence and cut circular opening machine, oral area cutting is carried out to Glass tubing, oral area flame round mouth is carried out after cutting, form newborn blue sheen stained glass fluorescent tube, packaging of testing as requested.
Embodiment 4: a kind of newborn blue sheen stained glass fluorescent tube, raw material is as shown in Table 3 made, and preparation method is as follows:
(1) prepare burden and found: by the ground silica shown in table 2, soda ash, Feldspar Powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, Sodium Silicofluoride, salt of wormwood, SODIUMNITRATE and auxiliary material grind in proportion and mix, obtain admixtion, admixtion feeder adds feed bin, furnace pond is evenly added with the speed of 15kg/min, first compound founds 4h in fusing one district in 1380 DEG C, then enter fusing two district and found 3h in 1350 ± 3 DEG C, then enter homogenization zone and found 2h in 1280 ± 3 DEG C, finally enter workspace and found 2h in 1260 ± 3 DEG C, obtain the glass metal of evenly clarification,
(2) shaping: glass metal flows into feeding machine orifice ring by work pool through hopper, temperature controls at 1280 DEG C, above feeding machine, arrange one can the revolving sleeve of adjusting rotary speed, rotating speed is 5rpm, to make glass metal color even, glass metal is flowed out uniformly by the orifice ring that can control flow, the flow of every bar production line is 480kg/h, an admission gear is set above orifice ring, with the Glass tubing making the glass metal of outflow form hollow, Glass tubing progressively hardens along the runway that 30m is long, drawn by tractor and move ahead, the Glass tubing of different lengths is cut into by cutting knife, tractor can governing speed and control load by orifice ring, to produce various outer diameter, wall thickness, the sheen Glass tubing of length.
(3) cut, anneal, check, pack: the Glass tubing of well cutting carries out external diameter, wall thickness detection through laser, conveyer is entered by otherwise limit deviation stepping, be sent to essence and cut circular opening machine, oral area cutting is carried out to Glass tubing, oral area flame round mouth is carried out after cutting, form newborn blue sheen stained glass fluorescent tube, packaging of testing as requested.
Table 3: the raw material composition of the breast blue sheen stained glass fluorescent tube of embodiment 3 and embodiment 4
Embodiment 5: a kind of newborn green sheen stained glass lampshade, raw material is as shown in Table 4 made, preparation method's bucket embodiment 1 of the green sheen stained glass of described breast:
Embodiment 6: a kind of milk yellow sheen stained glass lampshade, raw material is as shown in Table 4 made, and preparation method is with embodiment 2.
Embodiment 7: a kind of newborn red sheen stained glass fluorescent tube, raw material is as shown in Table 5 made, and preparation method is with embodiment 3.
Embodiment 8: a kind of newborn red sheen stained glass fluorescent tube, raw material is as shown in Table 5 made, and preparation method is with embodiment 4.
Table 4: the raw material composition of the sheen stained glass lampshade of embodiment 5 and embodiment 6
Table 5: the raw material composition of the breast red sheen stained glass fluorescent tube of embodiment 7 and embodiment 8
LED lamp is used for the oyster white sheen stained glass lampshade of embodiment 1 and embodiment 2, LED lamp cannot see the luminescent lamp pearl of led after using oyster white sheen stained glass lampshade, the optical throughput of LED lamp after detecting with integrating sphere the light fixture that do not use sheen stained glass lampshade respectively and using sheen stained glass lampshade, calculate its ratio, light transmission rate can reach between 86 ~ 95, meets the technical requirements of LED lamp completely.
LED lamp is used for the breast blue sheen stained glass lampshade of embodiment 3 and embodiment 4, LED lamp cannot see the luminescent lamp pearl of led after using newborn blue sheen stained glass lampshade, the optical throughput of LED lamp after detecting with integrating sphere the light fixture that do not use sheen stained glass lampshade respectively and using sheen stained glass lampshade, calculate its ratio, light transmission rate can reach between 86 ~ 92, meets the technical requirements of LED lamp completely.
Realize specific equipment of the present invention: fusing kiln as depicted in figs. 1 and 2, comprise kiln body 1 and the some thermopairs for detecting kiln temperature, kiln body 1 top is combustion chamber 11, bottom is melting chamber 12, kiln cover plate 2 is equipped with between described combustion chamber 11 and melting chamber 12, the material of described kiln cover plate 2 is corundum, described thermopair is evenly installed on the downside of kiln cover plate 2, and be positioned at melting chamber 12 top, described melting chamber 12 is divided into fusing one district 122 by three road weirs 121, melt two districts 123, homogenization zone 124 and workspace 125, dog-hole 126 is processed with bottom described weir 121, the height of described dog-hole 126 is 100 ~ 150mm, 120mm is adopted in the present invention, described fusing one district 122 is communicated with charging opening 3, described workspace 125 is communicated with discharge port 4, described combustion chamber 11 is provided with spray gun 111 near the side of opening for feed 3, air outlet 112 is provided with near the side of discharge port 4, described air outlet 112 is connected with interchanger 5, described spray gun 111 uses oxygenized air combustion supporting, by electric gas flowrate control valve controlled melting one district 122 respectively, melt two districts 123, the temperature of homogenization zone 124 and workspace 125, described charging opening 3 is provided with liquid level laser detecting apparatus, by liquid level laser detecting apparatus automatic controlling liquid level height together with automatic charging equipment, described workspace 125 side is also processed with overflow port 6, the height of described overflow port 6 is 40 ~ 60mm, 50mm is adopted in the present invention.
Above-described embodiment is one of the present invention preferably scheme, not does any pro forma restriction to the present invention, also has other variant and remodeling under the prerequisite not exceeding the technical scheme described in claim.
Claims (3)
1. a sheen stained glass work, is characterized in that: the main oxides formation of described sheen stained glass work is by weight percentage: SiO
250 ~ 80%, B
2o
32 ~ 8%, ZnO 1 ~ 8%, CaO 0.2 ~ 8%, Na
2o 8 ~ 16%, K
2o 0.1 ~ 2%, Al
2o
36 ~ 15%;
Described sheen stained glass work is made up of the raw material of following weight part: ground silica 50 ~ 70 parts, soda ash 10 ~ 16 parts, Feldspar Powder 12 ~ 22 parts, 10 ~ 24 parts, aluminium hydroxide, 1 ~ 12 part, zinc oxide, 4 ~ 24 parts, calcium carbonate, borax 1.4 ~ 12 parts, Sodium Silicofluoride 8 ~ 16 parts, 0.8 ~ 5.8 part, salt of wormwood, SODIUMNITRATE 0.4 ~ 4 part, auxiliary material 6.6 ~ 70 parts, described auxiliary material is selected from titanium dioxide, barium carbonate, red lead, calcium phosphate, barium sulfate, magnesium oxide, fluorite, white arsenic, weisspiessglanz, cobalt oxide, cupric oxide, chromoxide green, sodium antimonate, cadmium yellow, sulphur, uranium oxide, cerium oxide, cadmium red, Cadmium Sulfide, selenium powder and yttrium aluminum garnet,
Its preparation method is as follows:
(1) prepare burden and found: by ground silica, soda ash, Feldspar Powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, Sodium Silicofluoride, salt of wormwood, SODIUMNITRATE and auxiliary material grind in proportion and mix, and obtain admixtion; Described admixtion feeder adds feed bin, at the uniform velocity adds furnace pond, founds 10 ~ 12h is melted into evenly clarification glass metal to compound under the actual temperature of fusion of 1260 ~ 1380 DEG C;
(2) shaping;
(3) cut, anneal, check, pack;
Be constructed as follows with auxiliary material described in parts by weight: titanium dioxide 0.2 ~ 4 part, barium carbonate 0.4 ~ 3.2 part, red lead 0 ~ 2.4 part, 4 ~ 24 parts, calcium phosphate, 1 ~ 4 part, barium sulfate, 0 ~ 3 part, magnesium oxide, 0 ~ 4.4 part, fluorite, white arsenic 0.6 ~ 2.6 part, weisspiessglanz 0.4 ~ 1.2 part, cobalt oxide 0 ~ 4 part, cupric oxide 0 ~ 1 part, chromoxide green 0 ~ 0.8 part, sodium antimonate 0 ~ 1.2 part, cadmium yellow 0 ~ 2 part, 0 ~ 0.08 part, sulphur, uranium oxide 0 ~ 0.08 part, cerium oxide 0 ~ 0.88 part, cadmium red 0 ~ 2.2 part, Cadmium Sulfide 0 ~ 0.8 part, selenium powder 0 ~ 0.15 part, yttrium aluminum garnet 0.3 ~ 8 part.
2. a kind of sheen stained glass work according to claim 1, it is characterized in that: described in step (1), furnace pond comprises fusing one district, melts 2nd district, homogenization zone and workspace, the concrete melting process of described admixtion is as follows: first compound founds 3 ~ 5h in fusing one district in 1380 DEG C, then enter fusing two district and found 3h in 1350 ± 3 DEG C, then enter homogenization zone and found 2h in 1280 ± 3 DEG C, finally enter workspace and found 2h in 1260 ± 3 DEG C.
3. a kind of sheen stained glass work according to claim 1 and 2, is characterized in that: described sheen stained glass work is fluorescent tube, bulb or lampshade, and described fluorescent tube, bulb or lampshade are used for illumination or amusement light fixture.
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|---|---|---|---|---|
| CN103880284B (en) * | 2014-03-10 | 2016-08-17 | 深圳市粤盾科技特种玻璃有限公司 | A kind of glass containing copper oxide and preparation method thereof |
| CN104692658A (en) * | 2015-02-27 | 2015-06-10 | 武汉理工大学 | Method for fixing CdS and Se in borosilicate glass |
| CN105036548A (en) * | 2015-06-30 | 2015-11-11 | 木林森股份有限公司 | Integrated-forming glass lamp tube and preparation technology thereof |
| CN112679072A (en) * | 2020-12-31 | 2021-04-20 | 河南省中联玻璃有限责任公司 | Energy-saving environment-friendly thick plate glass float production process |
| CN114933411B (en) * | 2022-04-23 | 2023-11-14 | 绵竹市红森玻璃制品有限责任公司 | Cobalt blue porcelain-imitating glass bottle and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4311529A (en) * | 1980-06-17 | 1982-01-19 | Corning Glass Works | Tinted opal glass |
| CN1594161A (en) * | 2004-07-02 | 2005-03-16 | 裕腾集团沈阳玻璃制瓶有限公司 | Emerald green glass and its manufacturing method |
| CN101462823A (en) * | 2007-12-17 | 2009-06-24 | 宋征宇 | Special type lead-less glass, preparation, and use thereof as lamp tube core column material |
-
2013
- 2013-08-09 CN CN201310347711.1A patent/CN103466939B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4311529A (en) * | 1980-06-17 | 1982-01-19 | Corning Glass Works | Tinted opal glass |
| CN1594161A (en) * | 2004-07-02 | 2005-03-16 | 裕腾集团沈阳玻璃制瓶有限公司 | Emerald green glass and its manufacturing method |
| CN101462823A (en) * | 2007-12-17 | 2009-06-24 | 宋征宇 | Special type lead-less glass, preparation, and use thereof as lamp tube core column material |
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| Publication number | Publication date |
|---|---|
| CN103466939A (en) | 2013-12-25 |
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