CN103451525A - Corrosion-resistant hot-rolled ribbed steel bar with yield strength not less than 600Mpa and production method thereof - Google Patents

Corrosion-resistant hot-rolled ribbed steel bar with yield strength not less than 600Mpa and production method thereof Download PDF

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CN103451525A
CN103451525A CN2013104086308A CN201310408630A CN103451525A CN 103451525 A CN103451525 A CN 103451525A CN 2013104086308 A CN2013104086308 A CN 2013104086308A CN 201310408630 A CN201310408630 A CN 201310408630A CN 103451525 A CN103451525 A CN 103451525A
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corrosion
steel bar
steel
rolled ribbed
resistant hot
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CN103451525B (en
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徐志
徐志东
范植金
吴杰
周新龙
李婷
张帆
丁礼权
罗国华
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Wuhan Iron and Steel Co Ltd
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Abstract

The invention relates to a corrosion-resistant hot-rolled ribbed steel bar with yield strength not less than 600Mpa. The corrosion-resistant hot-rolled ribbed steel bar comprises the following components in percentage by weight: 0.17-0.28% of C, 0.50-0.90% of Si, 0.70-1.50% of Mn, 0.04-0.009% of P, not more than 0.015% of S, 0.08-0.15% of V and 0.025-0.045% of Nb. A production process comprises the following steps: desulfurizing molten iron; performing top and bottom combined blowing by virtue of a converter; refining by virtue of an argon station; refining by an LF (ladle furnace); performing continuous casting; stacking and cooling to a room temperature; heating a cast blank; performing rough rolling and finish rolling; naturally cooling to the room temperature. Compared with a steel bar with an epoxy resin coating, the corrosion-resistant hot-rolled ribbed steel bar has no defect of acceleration of corrosion rate caused by shedding of the coating; compared with the steel bar made of stainless steel, the corrosion-resistant hot-rolled ribbed steel bar has the advantage that the content of Cr is greatly reduced; compared with the ordinary steel bar, the corrosion-resistant hot-rolled ribbed steel bar has the advantage that the resistance to Cl ion corrosion is above 2 times higher than that of the ordinary steel bar; only the refining by virtue of the LF is additionally performed in an existing 400MPa grade steel bar process line, the increase in per ton of steel does not exceed 30 yuan, and then the production can be met.

Description

Corrosion-resistant hot rolled ribbed steel bar and the production method of yield strength >=600Mpa
Technical field
The present invention relates to a kind of reinforcing bar and production method thereof, belong to particularly a kind of Ribbed Bar and production method thereof, be particularly useful for putting forward by vanadium niobium micro-alloy intensifying technology corrosion-resistant hot rolled ribbed steel bar and the production method of high-intensity yield strength >=600Mpa.
Background technology
Along with the development of domestic construction engineering to maximization, large load direction, the operating efficiency of building structure, energy-conserving and environment-protective problem have caused common concern, more and more higher to the requirement of building iron use properties.The HRB600 corrosion-resistant steel bar is the starting material of manufacturing large project, high strength civil construction project.With a large amount of HRB400 reinforcing bars that use of current domestic construction industry, compare, the HRB600 corrosion-resistant steel bar is in plasticity decline situation by a small margin, and intensity level improves a lot; Yield strength has improved 200MPa, and tensile strength has improved 190MPa.Substitute the HRB400 hot rolled ribbed steel bar with it in engineering construction, but saving steel 28%.Its application, can reduce the amount of reinforcement of construction in a large number, reduces difficulty of construction, improves construction quality, and increase substantially security and the work-ing life of engineering.
Enquiry data shows both at home and abroad, and the reinforcement corrosion of using in civil construction project is serious.The total corrosion loss of iron and steel in U.S. every year accounts for 4.2% of gross national product (GDP).The reinforcing bar of use in Infrastructure, the year financial loss of its corrosion failure just reaches 1,500 hundred million dollars.Japan's transportation economizes 103 the concrete sea port dock situations that check, finds to use the harbour more than 20 years, has sizable along the muscle rust crack.Australia is investigated 62 seashore concrete structures, and the endurance issues of the finding the seashore concrete structure all serious corrosion of reinforcing bar is relevant.The loss that China is caused by reinforcement corrosion is also very serious, in the investigation that 27Zuo harbour, East China, China south China concrete structure is carried out, finds that the structure deteriorate that the corrosion of invar muscle causes accounts for 74%.1981, to the l8 seat, use the result of Reinforced Concrete Dock investigation in 7~25 years to show, steel bar corrosion or non-resistantly account for 89%.What occur that time of corrosion and destruction has is only 5~10 years, and these structures all do not reach the design reference period requirement work-ing life basically.Due to the steel bar corrosion that atmosphere and marine atmosphere cause, make the destruction of concrete structure, be acknowledged as the major cause that causes the coastal engineering destroying concrete structure.
China is in the sixties in last century, just starts to carry out the corrosion resistance nature research of steel, developed so far high weatherproof structure steel, the weathering steel kinds such as weather resisting steel, hull structure and offshore platform steel, steel for container for rail truck.The resistance to atmospheric corrosion of weather-resistant steel plate improves more than 2 times than ordinary steel.Yet corrosion-resistant steel bar for building, application at home and abroad at present seldom.
Through retrieval, the patent documentation that Chinese Patent Application No. is CN200910243828.9, disclose " a kind of high-strength low-alloy steel bar of Cl-corrosion resistant and production method ", but yield strength is the 400MPa level, can not meet the demand of existing market.
The patent documentation that Chinese Patent Application No. is CN200710133597.7, disclose " a kind of containing steel and production technique thereof for the vanadium high-strength corrosion-resistant steel bar ", but yield strength is the 400MPa level, can not meet the demand of existing market.
Summary of the invention
The deficiency of the growth requirement that the present invention is directed to yield strength that prior art exists and be 400 MPa levels and can not satisfying the market, provide a kind of As rolled yield strength more than 600MPa, anti-Cl ion etching ability is strong, and utilize current 400MPa grade reinforcing steel production line, also without corrosion-resistant hot rolled ribbed steel bar and the production method of adding or transform the yield strength >=600Mpa of any equipment.
Realize the measure of above-mentioned purpose:
The corrosion-resistant hot rolled ribbed steel bar of yield strength >=600Mpa, its component and weight percent content are: C:0.17~0.28%, Si:0.50~0.90%, Mn:0.70~1.50%, P:0.04~009%, S<=0.015%, V:0.08~0.15%, Nb:0.025~0.045%, Tb:0.01~1.0%, all the other are Fe and impurity element.
Further: being added with weight percent is Mo≤0.5% or B: 0.0001~0.005% or overall control be no more than these two kinds of elements of 1.0% compound.
The method of the corrosion-resistant hot rolled ribbed steel bar of production yield strength >=600Mpa, its step:
1) desulfurizing iron: adopt spray magnesium powder sulfur removal technology, and control molten steel sulfur content [S]≤0.010%;
2) converter top bottom blowing: when tap to the molten steel gross weight 1/4 the time, add ferro-silico-manganese according to 21~24 kg/tonnes of steel in molten steel, according to 1.3 ~ 1.7 kg/tonnes of steel, add silicon carbide to carry out deoxidation, add 1.8 ~ 2.5 kilograms of vanadium iron, 0.6 ~ 1.0 kilogram of ferro-niobium, 0.1~0.3 kilogram of carbon dust, 10~20 kilograms of ferrochrome, 2.0~18 kilograms of ferro tantalums by the ton steel after deoxidation, and the chrome molybdenum that is no more than 1 kg/tonne of steel, when molten steel measure to the molten steel gross weight 3/4 the time, the alloy that add and carburelant must all add;
3) the argon station is concise: trimming also is blown into argon gas, and argon flow amount is at 7 ~ 10Nm3/ minute, and argon blowing time is 3~15 minutes;
4) LF stove refining: to being blown into pressure in stove, be the argon gas that 0.5~0.8MPa, flow are 7.0~10.0Nm3/Min, argon blowing time is not less than 15 minutes, is not less than 10 minutes heat-up time;
5) carry out continuous casting: adopt large tank long nozzle and crystallizer submersed nozzle to protect cast; Middle bag covering slag adopts basic powder, and crystallizer protecting residue adopts low-carbon steel protecting slag; Middle Baogang water temp is controlled at 1530~1545 ℃; Casting speed is controlled at 1.6~1.8 m/mins;
6) carry out cooling: stacking is cooled to room temperature;
7) strand heating: control the soaking zone temperature at 1150~1300 ℃, be not less than 100 minutes heat-up time;
8) roughing and finish rolling: control the roughing start rolling temperature at 1050~1150 ℃; Control the finish rolling finishing temperature and be no more than 1100 ℃;
9) naturally cool to room temperature.
The effect of each element and master operation in the present invention
C: as a kind of economical strengthening element, be dissolved in matrix, can play the solution strengthening left and right, therefore can not be too low, so the scope of selection C is 0.17~0.28%.
Si: be a kind of displacement strengthening element of cheapness, can significantly improve the intensity of steel, but the Si too high levels can affect the welding property of steel, so the scope of selection Si is 0.5~0.9%.
Mn: significantly reduce the transformation temperature of steel, by the controlled rolling process, crystal grain thinning, comprehensively improve the over-all properties of steel, but the too high meeting of Mn causes weldability and the hot deterioration of welded heat affecting zone, so the scope of selecting Mn is 0.7~1.5%;
P: improve the corrosion resistance nature element of steel, reduce the plasticity of material but too high levels will cause segregation, select the scope 0.04~0.09% of P.
S: as harmful element, require in theory its content more low better, but consider situ production cost reason,, the Fan Wei of selection S<=0.015%.
V: be microalloyed steel the most frequently used be also one of the most effective strengthening element.The effect of vanadium is to affect tissue and the performance of steel by forming VN, V (CN), and it is mainly Precipitation in the ferrite of austenite grain boundary, refinement ferrite crystal grain, the intensity of increase steel.After adding vanadium in steel, more than intensity can increase by 150 MPa.This effect of vanadium, the steel of delivering goods for hot rolling seem particularly important.In the present invention, if the content of vanadium lower than 0.12%, can produce intensity, do not reach the 600MPa rank, if higher than 0.15%, can make the reinforcing bar surplus capacity excessive and cause alloy waste, therefore it is controlled to 0.08~0.15%.
Nb: as crystal grain thinning and precipitation strength element, can improve the intensity of steel, no longer increase but its content surpasses its result a certain amount of the time, so the scope of selecting Nb is 0.025~0.045%.
Cr: improve the element of anti-seawater corrosion ability, easily at interior rusty scale, carry out enrichment, so select Cr≤1.0%;
Cu: improve the corrosion resistance element, too high meeting causes the intergranular segregation and causes embrittlement of grain boundaries, so the scope of selection Cu is 0.3%~0.6%;
Ni: improve the corrosion resistance element, improve the intensity of steel, its too high levels not only raises the cost, and easily enrichment and cause that oxide skin adheres under oxide skin, so the scope of selecting Ni is 0.1%~0.4%;
Mo: improve the corrosion resistance element, but after surpassing certain content, effect no longer increases, therefore select Mo≤0.5;
B: too high meeting causes the intergranular segregation and causes embrittlement of grain boundaries, so the scope of selection B is 0.0001~0.005%;
Tb: improve the corrosion resistance element, improve the intensity of steel, its too high levels not only raises the cost, and range of choice is 0.01~1.0%;
The control reason of main technique: the present invention utilizes the vanadium Nb-microalloying to improve the intensity of reinforcing bar, adds the corrosive nature that corrosion-resistant element improves steel, improves the matrix current potential, by increasing LF stove refinery practice minimizing steel inclusion, reaches the reduction source of corrosion.
The present invention compares with existing Epoxy Resin Coated Steel Bars, without the brushwork epoxy resin coating, does not more have coating shedding and the shortcoming that causes erosion rate to accelerate; With stainless steel rebar, compare, a large amount of minimizing added the cost pressure that precious alloy Cr brings, and just added a small amount of P, Cu, Ni, Cr microalloy element, and its total content<2% improves corrosion resistance nature; With regular reinforcement, compare, its anti-Cl ion etching ability is more than 2 times of regular reinforcement, and, on current 400MPa grade reinforcing steel production line, only attaching the refining of LF stove increases, the increase of ton steel is no more than 30 yuan, just can meet the production of 600MPa level corrosion-resistant steel bar.The present invention forbids water-cooled or get wet.
The accompanying drawing explanation
Accompanying drawing is metallographic structure figure of the present invention.
Embodiment
Below the present invention is described in detail:
The value list that table 1 is various embodiments of the present invention and Comparative Examples;
The main technologic parameters list that table 2 is various embodiments of the present invention and Comparative Examples;
Table 3 is various embodiments of the present invention and the list of Comparative Examples Performance Detection situation.
Various embodiments of the present invention are according to following steps production:
1) desulfurizing iron: adopt spray magnesium powder sulfur removal technology, and control molten steel sulfur content [S]≤0.010%;
2) converter top bottom blowing: when tap to the molten steel gross weight 1/4 the time, add ferro-silico-manganese according to 21~24 kg/tonnes of steel in molten steel, according to 1.3 ~ 1.7 kg/tonnes of steel, add silicon carbide to carry out deoxidation, add 1.8 ~ 2.5 kilograms of vanadium iron, 0.6 ~ 1.0 kilogram of ferro-niobium, 0.1~0.3 kilogram of carbon dust, 10~20 kilograms of ferrochrome, 2.0~18 kilograms of ferro tantalums by the ton steel after deoxidation, and the chrome molybdenum that is no more than 1 kg/tonne of steel, when molten steel measure to the molten steel gross weight 3/4 the time, the alloy that add and carburelant must all add;
3) the argon station is concise: trimming also is blown into argon gas, and argon flow amount is at 7 ~ 10Nm3/ minute, and argon blowing time is 3~15 minutes;
4) LF stove refining: to being blown into pressure in stove, be the argon gas that 0.5~0.8MPa, flow are 7.0~10.0Nm3/Min, argon blowing time is not less than 15 minutes, is not less than 10 minutes heat-up time;
5) carry out continuous casting: adopt large tank long nozzle and crystallizer submersed nozzle to protect cast; Middle bag covering slag adopts basic powder, and crystallizer protecting residue adopts low-carbon steel protecting slag; Middle Baogang water temp is controlled at 1530~1545 ℃; Casting speed is controlled at 1.6~1.8 m/mins;
6) carry out cooling: stacking is cooled to room temperature;
7) strand heating: control the soaking zone temperature at 1150~1300 ℃, be not less than 100 minutes heat-up time;
8) roughing and finish rolling: control the roughing start rolling temperature at 1050~1150 ℃; Control the finish rolling finishing temperature and be no more than 1100 ℃;
9) naturally cool to room temperature.
The chemical composition of table 1 various embodiments of the present invention and Comparative Examples (wt%)
Table 2 various embodiments of the present invention and Comparative Examples technique significant parameter are controlled list ()
Figure 957292DEST_PATH_IMAGE002
Table 2 various embodiments of the present invention and Comparative Examples controlled rolling process significant parameter are controlled (two)
Figure 230141DEST_PATH_IMAGE003
Table 3 various embodiments of the present invention and Comparative Examples mechanical properties test result contrast list
Figure 959063DEST_PATH_IMAGE004
Corrosion rate test conditions in table 3: carry out week soaking experiment, experimental solutions is 3%NaCl, 45 ± 2 ℃ of experimental temperatures, and relative humidity 70 ± 5%, soak wheel speed 1 circle week/60 minutes, and etching time is respectively 216 hours (corrosion rate 1) and 288 hours (corrosion rate 2).
As can be seen from Table 3, the composition of the present invention's design all can meet 600Mpa corrosion-resistant steel bar performance, and the more current common 600Mpa grade reinforcing steel of its corrosion rate has reduced more than 70%, and the drawn test, breaks on mother metal, illustrates that welding property is good.
The present invention forbids with water cooling or touches water.
Above-described embodiment only exemplifies for the best, and is not the restriction to embodiments of the present invention.

Claims (3)

1. the corrosion-resistant hot rolled ribbed steel bar of yield strength >=600Mpa, its component and weight percent content are: C:0.17~0.28%, Si:0.50~0.90%, Mn:0.70~1.50%, P:0.04~009%, S<=0.015%, V:0.08~0.15%, Nb:0.025~0.045%, Tb:0.01~1.0%, all the other are Fe and impurity element.
2. the corrosion-resistant hot rolled ribbed steel bar of yield strength >=600Mpa as claimed in claim 1, it is characterized in that: being added with weight percent is Mo≤0.5% or B: 0.0001~0.005% or total weight percent control the compound of these two kinds of elements of being no more than 1.0%.
3. produce the method for the corrosion-resistant hot rolled ribbed steel bar of yield strength >=600Mpa as claimed in claim 1, its step:
1) desulfurizing iron: adopt spray magnesium powder sulfur removal technology, and control molten steel sulfur content [S]≤0.010%;
2) converter top bottom blowing: when tap to the molten steel gross weight 1/4 the time, add ferro-silico-manganese according to 21~24 kg/tonnes of steel in molten steel, according to 1.3 ~ 1.7 kg/tonnes of steel, add silicon carbide to carry out deoxidation, add 1.8 ~ 2.5 kilograms of vanadium iron, 0.6 ~ 1.0 kilogram of ferro-niobium, 0.1~0.3 kilogram of carbon dust, 10~20 kilograms of ferrochrome, 2.0~18 kilograms of ferro tantalums by the ton steel after deoxidation, and the chrome molybdenum that is no more than 1 kg/tonne of steel, when molten steel measure to the molten steel gross weight 3/4 the time, the alloy that add and carburelant must all add;
3) the argon station is concise: trimming also is blown into argon gas, and argon flow amount is at 7 ~ 10Nm3/ minute, and argon blowing time is 3~15 minutes;
4) LF stove refining: to being blown into pressure in stove, be the argon gas that 0.5~0.8MPa, flow are 7.0~10.0Nm3/Min, argon blowing time is not less than 15 minutes, is not less than 10 minutes heat-up time;
5) carry out continuous casting: adopt large tank long nozzle and crystallizer submersed nozzle to protect cast; Middle bag covering slag adopts basic powder, and crystallizer protecting residue adopts low-carbon steel protecting slag; Middle Baogang water temp is controlled at 1530~1545 ℃; Casting speed is controlled at 1.6~1.8 m/mins;
6) carry out cooling: stacking is cooled to room temperature;
7) strand heating: control the soaking zone temperature at 1150~1300 ℃, be not less than 100 minutes heat-up time;
8) roughing and finish rolling: control the roughing start rolling temperature at 1050~1150 ℃; Control the finish rolling finishing temperature and be no more than 1100 ℃;
9) naturally cool to room temperature.
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CN103898407A (en) * 2014-04-09 2014-07-02 武汉钢铁(集团)公司 600MPa hot-rolled ribbed steel bar and preparation method thereof
CN103981446A (en) * 2014-03-26 2014-08-13 江苏省沙钢钢铁研究院有限公司 Bainite type 700-MPa-grade twisted steel and production method thereof
CN104233096A (en) * 2014-09-20 2014-12-24 唐山市德龙钢铁有限公司 Method used for producing 400 MPa level hot rolled ribbed steel bar and capable of reducing alloy cost
CN104451410A (en) * 2014-12-18 2015-03-25 马钢(集团)控股有限公司 Steel for 600MPa-level high-strength steel bars and thermal mechanical rolling method thereof
CN104946996A (en) * 2015-05-28 2015-09-30 武汉钢铁(集团)公司 Alkali corrosion resistance high strength steel and production method thereof
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CN105543667A (en) * 2016-01-20 2016-05-04 广西丛欣实业有限公司 Corrosion-resistant reinforcing bar
CN107723603A (en) * 2017-11-29 2018-02-23 安徽工业大学 Yield strength 500MPa levels corrosion-resistant steel bar and manufacture method
CN108913990A (en) * 2018-06-20 2018-11-30 河钢股份有限公司承德分公司 A kind of 600MPa grade high-plasticity anchor pole reinforcing bar and production method
CN112195394A (en) * 2020-09-01 2021-01-08 陕钢集团产业创新研究院有限公司 MG600 grade anchor rod steel with yield ratio less than or equal to 0.8 and production method thereof
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CN103981446B (en) * 2014-03-26 2016-03-09 江苏省沙钢钢铁研究院有限公司 A kind of bainite type 700MPa level Twisted Steel and production method thereof
CN103898403B (en) * 2014-04-09 2016-06-29 武汉钢铁(集团)公司 The hot-rolled ribbed anti-seismic steel bar of HRB500 level
CN103898407A (en) * 2014-04-09 2014-07-02 武汉钢铁(集团)公司 600MPa hot-rolled ribbed steel bar and preparation method thereof
CN103898403A (en) * 2014-04-09 2014-07-02 武汉钢铁(集团)公司 HRB500 hot-rolled belt rib antiseismic steel bar and preparation method thereof
CN103898407B (en) * 2014-04-09 2016-07-06 武汉钢铁(集团)公司 600MPa hot rolled ribbed bars and preparation method thereof
CN104233096A (en) * 2014-09-20 2014-12-24 唐山市德龙钢铁有限公司 Method used for producing 400 MPa level hot rolled ribbed steel bar and capable of reducing alloy cost
CN104451410A (en) * 2014-12-18 2015-03-25 马钢(集团)控股有限公司 Steel for 600MPa-level high-strength steel bars and thermal mechanical rolling method thereof
CN104946996B (en) * 2015-05-28 2018-03-27 武汉钢铁有限公司 A kind of high strength steel and its production method of alkali resistance corrosion
CN104946977A (en) * 2015-05-28 2015-09-30 武汉钢铁(集团)公司 Low temperature-resistant high strength anchor bar steel and production method thereof
CN104946996A (en) * 2015-05-28 2015-09-30 武汉钢铁(集团)公司 Alkali corrosion resistance high strength steel and production method thereof
CN105543667A (en) * 2016-01-20 2016-05-04 广西丛欣实业有限公司 Corrosion-resistant reinforcing bar
CN107723603A (en) * 2017-11-29 2018-02-23 安徽工业大学 Yield strength 500MPa levels corrosion-resistant steel bar and manufacture method
CN108913990A (en) * 2018-06-20 2018-11-30 河钢股份有限公司承德分公司 A kind of 600MPa grade high-plasticity anchor pole reinforcing bar and production method
CN112195394A (en) * 2020-09-01 2021-01-08 陕钢集团产业创新研究院有限公司 MG600 grade anchor rod steel with yield ratio less than or equal to 0.8 and production method thereof
CN112195394B (en) * 2020-09-01 2022-02-18 陕钢集团产业创新研究院有限公司 MG600 grade anchor rod steel with yield ratio less than or equal to 0.8 and production method thereof
CN113061805A (en) * 2021-03-12 2021-07-02 盐城市联鑫钢铁有限公司 600 MPa-grade corrosion-resistant rare earth reinforcing steel bar and production method thereof
CN114058770A (en) * 2021-11-02 2022-02-18 阳春新钢铁有限责任公司 Production method of HRB600E high-strength anti-seismic steel bar

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