CN103436090B - Printing ink - Google Patents
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- CN103436090B CN103436090B CN201310340667.1A CN201310340667A CN103436090B CN 103436090 B CN103436090 B CN 103436090B CN 201310340667 A CN201310340667 A CN 201310340667A CN 103436090 B CN103436090 B CN 103436090B
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Abstract
The invention discloses printing ink which comprises the following components in parts by weight: 30-50 parts of pigment, 60-80 parts of chlorine acetum resin, 60-70 parts of propyl acetate, 10-20 parts of isopropanol, 2-5 parts of filler, 0.5-1 part of surfactant, 0.5-1.0 part of retarder, 0.5-1.0 part of metal soap drying agent, 1-3 parts of turpentine, 0.5-1.0 part of adhesion accelerant, 20-30 parts of ethanol and 40-60 parts of water. The printing ink is applicable to letterpress printing, intaglio printing and the like; the printing ink takes the water as a thinning agent, so that the use of a volatile organic solvent is reduced; the printing ink is low in cost, environment-friendly, harmless and pollution-free; and the turpentine, the retarder, the adhesion accelerant and the like are added, so that a dry plate, nonuniform printing, shallow flower, ink piling of a printed product, and the like cannot appear in a printing process.
Description
Technical field
The present invention relates to a kind of printing ink, belong to printing technology.
Background technology
Ink is the material for the formation of graph text information in printing process, and therefore ink in press acts on not insignificant, and it directly determines the contrast, color, sharpness etc. of printed matter epigraph.
Ink should have chromatic colour, good printing adaptability, suitable rate of drying.In addition, the application indexes of the aspects such as certain solvent resistant, acid, alkali, water, light, heat should also be had.Along with printing, paper and other requirement etc. are more and more higher, the technical qualification of ink requirements are also increased.As high speed multicolour press and the assorted rotary press in modern age, require that ink is so that a few second, speed was dry even faster.Glass lament and gold and silver lament, enamelled paper require the ink of light.Print plastics film, requires to be combined well with plastic film; Or bond with plastic film the ink be attached together to greatest extent.Print special presswork, requires to use photosensitive ink etc.
In prior art, have diversified printing ink, but great majority are containing volatile organic compounds, the ink especially used in silk screen printing, letterpress, intaglio printing, planography all contains volatile organic compounds.After printing, volatile organic compounds may be penetrated in air, food, medicine, thus be worked the mischief to human body, environment by volatilization, packing material.In addition, in printing process, ink needs the environment in the face of high temperature, phenomenons such as if ink quality is poor, then there will be dry plate, print uneven, shallow flower, printing heap is black.
Summary of the invention
For above-mentioned prior art, the invention provides a kind of printing ink.
The present invention is achieved by the following technical solutions:
A kind of printing ink, is made up of the component of following weight part: pigment 30 ~ 50 parts, vinyl chloride-vinyl acetate resin 60 ~ 80 parts, propyl acetate 60 ~ 70 parts, Virahol 10 ~ 20 parts, filler 2 ~ 5 parts, 0.5 ~ 1 part, tensio-active agent, slow dry agent 0.5 ~ 1.0 part, 0.5 ~ 1.0 part, metallic soap type siccative, 1 ~ 3 part, turps, adhesion promoter 0.5 ~ 1.0 part, ethanol 20 ~ 30 parts, 40 ~ 60 parts, water.
Described pigment, colourless or coloured mineral dye or pigment dyestuff can be used, specifically, the mineral dyes such as titanium dioxide, barium sulfate, calcium carbonate, organobentonite, fumed silica (AEROSIL), ferric oxide, carbon black can be used; The pigment dyestuffs such as azo pigment, pigment lake, phthalocyanine pigment, isoindoline pigment, anthraquinone pigment, quinacridone pigment.These pigment can be used alone or two or more used in combination.Preferred carbon black.
Described filler is barium sulfate, calcium carbonate, calcium hydroxide or kaolin.
Described tensio-active agent is sulforicinoleic acid or NONYL PHENOL POLYOXYETHYLENE.
Described slow dry agent is Diacetylmonoxime or butyraldehyde oxime.
Described metallic soap type siccative, the rare earth metal salt of the metal-salt or cerium etc. of the cobalt, manganese, lead, zinc, copper, iron, calcium, zirconium, aluminium etc. of sad, naphthenic acid, resinous acid, ready denier oil acid, soya fatty acid, hydroxyl higher fatty acid etc. can be used, specifically, can be manganese octoate, cobalt octoate, zirconium caprylate, calcium octoate, iron octoate, cupric octoate, manganese naphthenate, cobalt naphthenate, zirconium naphthenate, calcium naphthenate, iron naphthenate, copper naphthenate etc., can be used alone, or two or more used in combination.Preferably, be manganese octoate, manganese naphthenate or cobalt naphthenate.
Described adhesion promoter is titanic acid ester linking agent.
Can also contain water-based defoamer, drying and volatilizing conditioning agent in described printing ink, its addition is respectively 0.3% ~ 0.8%, 0.5% ~ 1.5% of total amount.
Described water-based defoamer, by preparations such as dimethyl silicone oil, white carbon black, emulsifying agents, adopts the defoamer of water and milk shape dispersiveness that emulsifying technology is made to.All raw materials and link are all nontoxic, have rate of dispersion fast, and froth breaking is fast, press down bubble time length, stablize not stratified feature.For product conventional in prior art.
Described drying and volatilizing conditioning agent is the mixture of propylene-glycol ethyl ether, propanedioic acid acetic ester, is product existing in prior art, commercially can have bought.
Following material can also be suitably added as required: pigment dispersing agent, anti-floating dirt auxiliary agent (whole auxiliary agent), rub resistance activator (rub resistance is agent upwards) etc. in described printing ink.
The preparation method of described printing ink: by pigment, vinyl chloride-vinyl acetate resin, propyl acetate, filler, the mixing of second alcohol and water, stir, grind, be ground to fineness of materials≤10 μm; Then add tensio-active agent, slow dry agent, metallic soap type siccative, turps and adhesion promoter, stir, to obtain final product.
Printing ink of the present invention, is applicable to letterpress, intaglio printing etc.
Printing ink of the present invention, using water as thinner, greatly reduce the use of volatile organic solvent, cost is low, and environmentally friendly pollution-free.In addition, turps, slow dry agent, adhesion promoter etc. is added, phenomenons such as in printing process, there will not be dry plate, print uneven, shallow flower, printing heap is black.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1 prepares printing ink
Formula is: pigment 40 grams, vinyl chloride-vinyl acetate resin 70 grams, propyl acetate 65 grams, Virahol 15 grams, filler 3 grams, 0.8 gram, tensio-active agent, slow dry agent 0.8 gram, 0.8 gram, metallic soap type siccative, 2 grams, turps, adhesion promoter 0.8 gram, ethanol 25 grams, 50 grams, water.
Described pigment is carbon black.
Described filler is barium sulfate.
Described tensio-active agent is sulforicinoleic acid.
Described slow dry agent is Diacetylmonoxime.
Described metallic soap type siccative is manganese octoate.
Described adhesion promoter is titanic acid ester linking agent.
Preparation method is: by pigment, vinyl chloride-vinyl acetate resin, propyl acetate, filler, the mixing of second alcohol and water, stir, grind, be ground to fineness of materials≤10 μm; Then add tensio-active agent, slow dry agent, metallic soap type siccative, turps and adhesion promoter, stir, to obtain final product.
Embodiment 2 prepares printing ink
Formula is: pigment 30 grams, vinyl chloride-vinyl acetate resin 60 grams, propyl acetate 70 grams, Virahol 20 grams, filler 2 grams, 0.5 gram, tensio-active agent, slow dry agent 1.0 grams, 1.0 grams, metallic soap type siccative, 1 gram, turps, adhesion promoter 0.5 gram, ethanol 30 grams, 60 grams, water.
Described pigment is carbon black.
Described filler is calcium carbonate.
Described tensio-active agent is NONYL PHENOL POLYOXYETHYLENE.
Described slow dry agent is butyraldehyde oxime.
Described metallic soap type siccative is manganese naphthenate.
Described adhesion promoter is titanic acid ester linking agent.
Preparation method is: by pigment, vinyl chloride-vinyl acetate resin, propyl acetate, filler, the mixing of second alcohol and water, stir, grind, be ground to fineness of materials≤10 μm; Then add tensio-active agent, slow dry agent, metallic soap type siccative, turps and adhesion promoter, stir, to obtain final product.
Embodiment 3 prepares printing ink
Formula is: pigment 50 grams, vinyl chloride-vinyl acetate resin 80 grams, propyl acetate 60 grams, Virahol 10 grams, filler 5 grams, 1 gram, tensio-active agent, slow dry agent 0.5 gram, 0.5 gram, metallic soap type siccative, 3 grams, turps, adhesion promoter 1.0 grams, ethanol 20 grams, 40 grams, water.
Preparation method is: by pigment, vinyl chloride-vinyl acetate resin, propyl acetate, filler, the mixing of second alcohol and water, stir, grind, be ground to fineness of materials≤10 μm; Then add tensio-active agent, slow dry agent, metallic soap type siccative, turps and adhesion promoter, stir, to obtain final product.
Described pigment is carbon black.
Described filler is calcium hydroxide.
Described tensio-active agent is sulforicinoleic acid.
Described slow dry agent is Diacetylmonoxime.
Described metallic soap type siccative is cobalt naphthenate.
Described adhesion promoter is titanic acid ester linking agent.
Embodiment 4 prepares printing ink
Formula is: pigment 35 grams, vinyl chloride-vinyl acetate resin 75 grams, propyl acetate 62 grams, Virahol 18 grams, filler 3 grams, 0.8 gram, tensio-active agent, slow dry agent 0.6 gram, 0.9 gram, metallic soap type siccative, 2 grams, turps, adhesion promoter 0.7 gram, ethanol 22 grams, 58 grams, water.Described pigment is carbon black.
Described filler is kaolin.
Described tensio-active agent is NONYL PHENOL POLYOXYETHYLENE.
Described slow dry agent is butyraldehyde oxime.
Described metallic soap type siccative is calcium octoate.
Described adhesion promoter is titanic acid ester linking agent.
Preparation method is: by pigment, vinyl chloride-vinyl acetate resin, propyl acetate, filler, the mixing of second alcohol and water, stir, grind, be ground to fineness of materials≤10 μm; Then add tensio-active agent, slow dry agent, metallic soap type siccative, turps and adhesion promoter, stir, to obtain final product.
Embodiment 5 prepares printing ink
Formula is: pigment 45 grams, vinyl chloride-vinyl acetate resin 65 grams, propyl acetate 68 grams, Virahol 12 grams, filler 4 grams, 0.7 gram, tensio-active agent, slow dry agent 0.7 gram, 0.7 gram, metallic soap type siccative, 3 grams, turps, adhesion promoter 0.9 gram, ethanol 28 grams, 50 grams, water.
Described pigment is carbon black.
Described filler is barium sulfate.
Described tensio-active agent is NONYL PHENOL POLYOXYETHYLENE.
Described slow dry agent is butyraldehyde oxime.
Described metallic soap type siccative is iron octoate.
Described adhesion promoter is titanic acid ester linking agent.
Preparation method is: by pigment, vinyl chloride-vinyl acetate resin, propyl acetate, filler, the mixing of second alcohol and water, stir, grind, be ground to fineness of materials≤10 μm; Then add tensio-active agent, slow dry agent, metallic soap type siccative, turps and adhesion promoter, stir, to obtain final product.
Embodiment 6 prepares printing ink
Formula is: pigment 40 grams, vinyl chloride-vinyl acetate resin 75 grams, propyl acetate 65 grams, Virahol 20 grams, filler 4 grams, 0.6 gram, tensio-active agent, slow dry agent 0.6 gram, 0.6 gram, metallic soap type siccative, 1 gram, turps, adhesion promoter 0.6 gram, ethanol 27 grams, 55 grams, water.
Described pigment is carbon black.
Described filler is calcium carbonate.
Described tensio-active agent is sulforicinoleic acid.
Described slow dry agent is Diacetylmonoxime.
Described metallic soap type siccative is cupric octoate.
Described adhesion promoter is titanic acid ester linking agent.
Preparation method is: by pigment, vinyl chloride-vinyl acetate resin, propyl acetate, filler, the mixing of second alcohol and water, stir, grind, be ground to fineness of materials≤10 μm; Then add tensio-active agent, slow dry agent, metallic soap type siccative, turps and adhesion promoter, stir, to obtain final product.
Performance Detection is carried out to product prepared by above-described embodiment:
Fineness detects according to the standard of GB/T13217.1-91, and unit is μm;
Viscosity detects according to the standard of GB/T13217.1-91, and unit is (25 DEG C ± 1) S;
First dryness detects according to the standard of GB/T13217.1-91, and unit is mm;
Tinting strength detects according to the standard of GB/T13217.1-91, and unit is (%);
Attachment fastness detects according to the standard of GB/T13217.1-91, and unit is (%);
Surface tension detects according to the standard of GB/T13217.1-91, and unit is N/cm;
Solvent residual amount detects according to the standard of GB/T13217.1-91, and unit is mg/m
2.
Detected result is as shown in table 1.
Table 1
| Fineness | Viscosity | First dryness | Tinting strength | Attachment fastness | Surface tension | Solvent residual amount | |
| Embodiment 1 | 10 | 40 | 53 | 101 | 98 | 41×10 -5 | 0.3 |
| Embodiment 2 | 10 | 41 | 54 | 100 | 98 | 42×10 -5 | 0.4 |
| Embodiment 3 | 10 | 40 | 53 | 100 | 98 | 41×10 -5 | 0.6 |
| Embodiment 4 | 10 | 39 | 52 | 100 | 98 | 42×10 -5 | 0.5 |
| Embodiment 5 | 9 | 42 | 55 | 102 | 99 | 40×10 -5 | 0.4 |
| Embodiment 6 | 10 | 42 | 56 | 101 | 98 | 42×10 -5 | 0.5 |
The specific embodiment of the present invention is described although above-mentioned in conjunction with the embodiments; but not limiting the scope of the invention; one of ordinary skill in the art should be understood that; on the basis of the technical scheme of type of the present invention, those skilled in the art do not need to pay various amendment or distortion that creative work can make still within protection scope of the present invention.
Claims (6)
1. a printing ink, is characterized in that: be made up of the component of following weight part: carbon black 40 grams, vinyl chloride-vinyl acetate resin 70 grams, propyl acetate 65 grams, Virahol 15 grams, 3 grams, barium sulfate, sulforicinoleic acid 0.8 gram, Diacetylmonoxime 0.8 gram, manganese octoate 0.8 gram, 2 grams, turps, titanic acid ester linking agent 0.8 gram, ethanol 25 grams, 50 grams, water.
2. a printing ink, it is characterized in that: be made up of the component of following weight part: pigment 30 grams, vinyl chloride-vinyl acetate resin 60 grams, propyl acetate 70 grams, Virahol 20 grams, filler 2 grams, 0.5 gram, tensio-active agent, slow dry agent 1.0 grams, 1.0 grams, metallic soap type siccative, 1 gram, turps, adhesion promoter 0.5 gram, ethanol 30 grams, 60 grams, water, described pigment is carbon black, described filler is calcium carbonate, described tensio-active agent is NONYL PHENOL POLYOXYETHYLENE, described slow dry agent is butyraldehyde oxime, described metallic soap type siccative is manganese naphthenate, described adhesion promoter is titanic acid ester linking agent.
3. a printing ink, it is characterized in that: be made up of the component of following weight part: pigment 50 grams, vinyl chloride-vinyl acetate resin 80 grams, propyl acetate 60 grams, Virahol 10 grams, filler 5 grams, 1 gram, tensio-active agent, slow dry agent 0.5 gram, 0.5 gram, metallic soap type siccative, 3 grams, turps, adhesion promoter 1.0 grams, ethanol 20 grams, 40 grams, water, described pigment is carbon black, described filler is calcium hydroxide, described tensio-active agent is sulforicinoleic acid, described slow dry agent is Diacetylmonoxime, described metallic soap type siccative is cobalt naphthenate, described adhesion promoter is titanic acid ester linking agent.
4. a printing ink, it is characterized in that: be made up of the component of following weight part: pigment 35 grams, vinyl chloride-vinyl acetate resin 75 grams, propyl acetate 62 grams, Virahol 18 grams, filler 3 grams, 0.8 gram, tensio-active agent, slow dry agent 0.6 gram, 0.9 gram, metallic soap type siccative, 2 grams, turps, adhesion promoter 0.7 gram, ethanol 22 grams, 58 grams, water, described pigment is carbon black, described filler is kaolin, described tensio-active agent is NONYL PHENOL POLYOXYETHYLENE, described slow dry agent is butyraldehyde oxime, described metallic soap type siccative is calcium octoate, described adhesion promoter is titanic acid ester linking agent.
5. a printing ink, it is characterized in that: be made up of the component of following weight part: pigment 45 grams, vinyl chloride-vinyl acetate resin 65 grams, propyl acetate 68 grams, Virahol 12 grams, filler 4 grams, 0.7 gram, tensio-active agent, slow dry agent 0.7 gram, 0.7 gram, metallic soap type siccative, 3 grams, turps, adhesion promoter 0.9 gram, ethanol 28 grams, 50 grams, water, described pigment is carbon black, described filler is barium sulfate, described tensio-active agent is NONYL PHENOL POLYOXYETHYLENE, described slow dry agent is butyraldehyde oxime, described metallic soap type siccative is iron octoate, described adhesion promoter is titanic acid ester linking agent.
6. a printing ink, it is characterized in that: be made up of the component of following weight part: pigment 40 grams, vinyl chloride-vinyl acetate resin 75 grams, propyl acetate 65 grams, Virahol 20 grams, filler 4 grams, 0.6 gram, tensio-active agent, slow dry agent 0.6 gram, 0.6 gram, metallic soap type siccative, 1 gram, turps, adhesion promoter 0.6 gram, ethanol 27 grams, 55 grams, water, described pigment is carbon black, described filler is calcium carbonate, described tensio-active agent is sulforicinoleic acid, described slow dry agent is Diacetylmonoxime, described metallic soap type siccative is cupric octoate, described adhesion promoter is titanic acid ester linking agent.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310340667.1A CN103436090B (en) | 2013-08-06 | 2013-08-06 | Printing ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310340667.1A CN103436090B (en) | 2013-08-06 | 2013-08-06 | Printing ink |
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| CN103436090A CN103436090A (en) | 2013-12-11 |
| CN103436090B true CN103436090B (en) | 2015-06-10 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107556817A (en) * | 2017-09-25 | 2018-01-09 | 东莞印美涂料有限公司 | A kind of gravure printing ink and its production technology |
| CN107815176B (en) * | 2017-11-01 | 2021-01-19 | 福建省文松彩印有限公司 | Waterproof ink for printing corrugated case and preparation method thereof |
| CN109370304A (en) * | 2018-10-12 | 2019-02-22 | 安徽徽合台智能科技有限公司 | A kind of light diffusion printing ink and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101717596A (en) * | 2009-12-08 | 2010-06-02 | 杭华油墨化学有限公司 | Water-based ink for package printing of high-adhesion film and manufacturing method thereof |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN101942244A (en) * | 2010-09-06 | 2011-01-12 | 东莞市日新传导科技股份有限公司 | Typing printing ink |
| US20120038725A1 (en) * | 2009-04-23 | 2012-02-16 | Konica Minolta Ij Technologies, Inc. | Water-based inkjet ink, method for producing inkjet printed product using the same, and method for producing water-based inkjet ink |
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2013
- 2013-08-06 CN CN201310340667.1A patent/CN103436090B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120038725A1 (en) * | 2009-04-23 | 2012-02-16 | Konica Minolta Ij Technologies, Inc. | Water-based inkjet ink, method for producing inkjet printed product using the same, and method for producing water-based inkjet ink |
| CN101717596A (en) * | 2009-12-08 | 2010-06-02 | 杭华油墨化学有限公司 | Water-based ink for package printing of high-adhesion film and manufacturing method thereof |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN101942244A (en) * | 2010-09-06 | 2011-01-12 | 东莞市日新传导科技股份有限公司 | Typing printing ink |
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