CN103436087A - Ultraviolet curing printing ink - Google Patents
Ultraviolet curing printing ink Download PDFInfo
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- CN103436087A CN103436087A CN2013103403739A CN201310340373A CN103436087A CN 103436087 A CN103436087 A CN 103436087A CN 2013103403739 A CN2013103403739 A CN 2013103403739A CN 201310340373 A CN201310340373 A CN 201310340373A CN 103436087 A CN103436087 A CN 103436087A
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- ultraviolet curing
- methacrylic acid
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Abstract
The invention relates to ultraviolet curing printing ink which comprises the following components in parts by mass: 20-40 parts of oligomerized epoxy acrylate, 10-20 parts of polyurethane methacrylic acid oligomer, 5-20 parts of trimethylolpropane triacrylate, 25-30 parts of polyhydric alcohol acrylic acid activated monomer, 1-2 parts of polyethylene microcrystalline wax, 0.1-0.4 parts of methyl hydroquinone, 6-7 parts of 1,6-dyhydroxyl hexane acrylate, 15-20 parts of methacrylic acid-beta-hydroxyl ethyl ester, 5-10 parts of 2-hydroxyl-2-tolperisone, 0.1-0.7 parts of vinyl tri-(2-methoxyl ethyoxyl)-silicane, and 1-3 parts of antioxidant BHT (butylated hydroxytoluene). The ultraviolet curing printing ink is environment-friendly, energy-saving, free from VOCs (volatile organic compounds), high in drying rate and good in frictional resistance; the equipment floor area is small; ink particles are small; and the ink is oil-proof and solvent-proof, and has excellent glossiness.
Description
Technical field
The present invention relates to a kind of printing ink, relate in particular to a kind of ultraviolet curing ink.
Background technology
The ultraviolet curing principle: it is the photosensitivity of utilizing light trigger (photosensitizers) that ultraviolet (UV) solidifies, light-initiated formation excited ecological molecule under ultraviolet light irradiation, resolve into free radical or ion, make unsaturated compounds carry out polymerization, connect skill, the chemical reaction such as crosslinked reaches curing purpose.
The solidification process of UV printing ink is a photochemically reactive process, under the effect of ultraviolet energy, prepolymer is film-forming within the extremely short time, ultraviolet ray is except the surface cure that causes printing ink, more can permeate and go deep in aqueous ultraviolet curing ink, and stimulate further solidifying of deep layer ink film.Tradition be take the printing ink that oil is main foundation in printing ink and is solidified under oxygenizement, and take solvent or water as basic printing ink be mainly to solidify by the evaporation of water or solvent, part printing ink can infiltrate paper.Therefore with traditional printing ink, compare, the polymerization drying of uv curing ink is more thorough, without any the pollutent of evaporation or solvent borne, and the solidifying of ink film 100%.
Summary of the invention
the technical problem solved:the drawbacks such as contain VOC for printing ink, rate of drying is slow, and rub resistance is bad, provide a kind of environmental protection and energy saving, not containing VOC, and the ultraviolet curing ink that rate of drying is fast and rub resistance is good.
technical scheme:a kind of ultraviolet curing ink, contain following composition in mass parts: propylene oxide acid oligomer resin 20～40 mass parts, urethane methacrylic acid oligopolymer 10～20 mass parts, Viscoat 295 5～20 mass parts, polyvalent alcohol vinylformic acid reactive monomer 25～30 mass parts, polyethylene Microcrystalline Wax 1～2 mass parts, methyl hydroquinone 0.1～0.4 mass parts, 1, 6-dihydroxy-hexane acrylate 6～7 mass parts, methacrylic acid-beta-hydroxy ethyl ester 15～20 mass parts, 2-hydroxyl-2-toluene acetone 5～10 mass parts, vinyl three-(2-methoxy ethoxy)-silane 0.1～0.7 mass parts, antioxidant BHT 1～3 mass parts.
As a preferred technical solution of the present invention: a kind of ultraviolet curing ink, contain following composition in mass parts: propylene oxide acid oligomer resin 20～40 mass parts, urethane methacrylic acid oligopolymer 10～20 mass parts, Viscoat 295 5～20 mass parts, polyvalent alcohol vinylformic acid reactive monomer 25～30 mass parts, polyethylene Microcrystalline Wax 1～2 mass parts, methyl hydroquinone 0.1～0.4 mass parts, 1, 6-dihydroxy-hexane acrylate 6～7 mass parts, methacrylic acid-beta-hydroxy ethyl ester 15～20 mass parts, 2-hydroxyl-2-toluene acetone 5～10 mass parts, vinyl three-(2-methoxy ethoxy)-silane 0.1～0.7 mass parts, antioxidant BHT 1～3 mass parts.
beneficial effect:ultraviolet curing ink provided by the invention, environmental protection and energy saving,, containing VOC, rate of drying is not fast and rub resistance good, and occupation area of equipment is little, and ink particle is little, and oil resistant and anti-solvent, have excellent glossiness.
Embodiment
embodiment 1
The present embodiment provides a kind of ultraviolet curing ink, contain following composition in mass parts: propylene oxide acid oligomer resin 20 mass parts, urethane methacrylic acid oligopolymer 10 mass parts, Viscoat 295 5 mass parts, polyvalent alcohol vinylformic acid reactive monomer 25 mass parts, polyethylene Microcrystalline Wax 1 mass parts, methyl hydroquinone 0.1 mass parts, 1, 6-dihydroxy-hexane acrylate 6 mass parts, methacrylic acid-beta-hydroxy ethyl ester 15 mass parts, 2-hydroxyl-2-toluene acetone 5 mass parts, vinyl three-(2-methoxy ethoxy)-silane 0.1 mass parts, antioxidant BHT 1 mass parts.
embodiment 2
The present embodiment provides a kind of ultraviolet curing ink, contain following composition in mass parts: propylene oxide acid oligomer resin 40 mass parts, urethane methacrylic acid oligopolymer 20 mass parts, Viscoat 295 20 mass parts, polyvalent alcohol vinylformic acid reactive monomer 30 mass parts, polyethylene Microcrystalline Wax 2 mass parts, methyl hydroquinone 0.4 mass parts, 1, 6-dihydroxy-hexane acrylate 7 mass parts, methacrylic acid-beta-hydroxy ethyl ester 20 mass parts, 2-hydroxyl-2-toluene acetone 10 mass parts, vinyl three-(2-methoxy ethoxy)-silane 0.7 mass parts, antioxidant BHT 3 mass parts.
embodiment 3
The present embodiment provides a kind of ultraviolet curing ink, contain following composition in mass parts: propylene oxide acid oligomer resin 20～40 mass parts, urethane methacrylic acid oligopolymer 10～20 mass parts, Viscoat 295 5～20 mass parts, polyvalent alcohol vinylformic acid reactive monomer 25～30 mass parts, polyethylene Microcrystalline Wax 1～2 mass parts, methyl hydroquinone 0.1～0.4 mass parts, 1, 6-dihydroxy-hexane acrylate 6～7 mass parts, methacrylic acid-beta-hydroxy ethyl ester 15～20 mass parts, 2-hydroxyl-2-toluene acetone 5～10 mass parts, vinyl three-(2-methoxy ethoxy)-silane 0.1～0.7 mass parts, antioxidant BHT 1～3 mass parts.
Above-described embodiment is just for content of the present invention is set forth, rather than restriction, therefore in the implication suitable with claims of the present invention and any change in scope, all should think to be included in the scope of claims.
Claims (2)
1. a ultraviolet curing ink, it is characterized in that containing following composition in mass parts: propylene oxide acid oligomer resin 20～40 mass parts, urethane methacrylic acid oligopolymer 10～20 mass parts, Viscoat 295 5～20 mass parts, polyvalent alcohol vinylformic acid reactive monomer 25～30 mass parts, polyethylene Microcrystalline Wax 1～2 mass parts, methyl hydroquinone 0.1～0.4 mass parts, 1, 6-dihydroxy-hexane acrylate 6～7 mass parts, methacrylic acid-beta-hydroxy ethyl ester 15～20 mass parts, 2-hydroxyl-2-toluene acetone 5～10 mass parts, vinyl three-(2-methoxy ethoxy)-silane 0.1～0.7 mass parts, antioxidant BHT 1～3 mass parts.
2. a kind of ultraviolet curing ink according to claim 1, it is characterized in that containing following composition in mass parts: propylene oxide acid oligomer resin 20～40 mass parts, urethane methacrylic acid oligopolymer 10～20 mass parts, Viscoat 295 5～20 mass parts, polyvalent alcohol vinylformic acid reactive monomer 25～30 mass parts, polyethylene Microcrystalline Wax 1～2 mass parts, methyl hydroquinone 0.1～0.4 mass parts, 1, 6-dihydroxy-hexane acrylate 6～7 mass parts, methacrylic acid-beta-hydroxy ethyl ester 15～20 mass parts, 2-hydroxyl-2-toluene acetone 5～10 mass parts, vinyl three-(2-methoxy ethoxy)-silane 0.1～0.7 mass parts, antioxidant BHT 1～3 mass parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103403739A CN103436087A (en) | 2013-08-07 | 2013-08-07 | Ultraviolet curing printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103403739A CN103436087A (en) | 2013-08-07 | 2013-08-07 | Ultraviolet curing printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103436087A true CN103436087A (en) | 2013-12-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013103403739A Withdrawn CN103436087A (en) | 2013-08-07 | 2013-08-07 | Ultraviolet curing printing ink |
Country Status (1)
| Country | Link |
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| CN (1) | CN103436087A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109280369A (en) * | 2018-09-30 | 2019-01-29 | 苏州泛普科技股份有限公司 | The preparation method of intelligent blackboard UV printed material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286230A (en) * | 2011-09-15 | 2011-12-21 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Ultraviolet curable ink and preparation method thereof |
-
2013
- 2013-08-07 CN CN2013103403739A patent/CN103436087A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286230A (en) * | 2011-09-15 | 2011-12-21 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Ultraviolet curable ink and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 凌云星等: "《实用油墨技术指南》", 30 November 2007, 印刷工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109280369A (en) * | 2018-09-30 | 2019-01-29 | 苏州泛普科技股份有限公司 | The preparation method of intelligent blackboard UV printed material |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C04 | Withdrawal of patent application after publication (patent law 2001) | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20131211 |