CN101748657A - Ultraviolet cured gloss oil for paper - Google Patents
Ultraviolet cured gloss oil for paper Download PDFInfo
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- CN101748657A CN101748657A CN 201010119195 CN201010119195A CN101748657A CN 101748657 A CN101748657 A CN 101748657A CN 201010119195 CN201010119195 CN 201010119195 CN 201010119195 A CN201010119195 A CN 201010119195A CN 101748657 A CN101748657 A CN 101748657A
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- paper
- gloss oil
- ultraviolet cured
- cured gloss
- oil
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Abstract
The invention provides ultraviolet cured gloss oil for paper and belongs to the field of the gloss oil for paper. The gloss oil comprises a prepolymer, an active thinning agent, a photoinitiator, a chain transfer agent and a polymerization inhibitor, the contents of the components by weight percentage are: the prepolymer accounts for 20-80%, the active thinning agent accounts for 10-40%, the photoinitiator accounts for 1-10%, and the chain transfer agent and the polymerization inhibitor account for 0.5-5%. Through the selection of a formulation monomer, the gloss oil improves the film-forming speed of resins and a uniform film layer is formed after the gloss oil is coated and is not absorbed by a fibrous layer immediately. The gloss oil has low rate of shrinkage and cannot cause the deformation retraction of the paper after film formation so that the stiffness of the paper is maintained well.
Description
Technical field
The invention belongs to paper product and use the oil polish field, especially relate to a kind of high paper of oil absorption exempt to feel secure ultraviolet cured gloss oil for paper of direct glazing that is applicable to.
Background technology
The paper product glazing substantially all is that coating is solidified on the bottoming paper treated with ultraviolet curing varnish, opens for high oil factor uncoated paper, and common oil polish film forming is irregular, and surperficial gloss oil is mostly absorbed by the paper fibre structure, does not have the effect of glazing.
Paper is coated with processing back glazing, or directly buys the coated paper glazing, production cost and use cost increase, and have increased the cost of paper, and the practical value in the reality is not high.
Under the least possible coating cost, realize excellent last light effect for the paper of high oil factor, be the technological difficulties during actual production is used, how realizing reducing the last light effect that is coated with into original realization oilpaper at high quarter is the problem that a needs solves.
Summary of the invention
The embodiment of the invention provides a kind of ultraviolet cured gloss oil for paper, can realize the last light effect of low coating cost to high oil-Absorbing Sheets.
The objective of the invention is to be achieved through the following technical solutions:
The embodiment of the invention provides a kind of ultraviolet cured gloss oil for paper, this oil polish is made up of performed polymer, reactive diluent, light trigger, mercaptan type chain transfer agent and phenolic inhibitor, the weight percentage of each component is as follows: performed polymer 20～90%, reactive diluent 10～70%, light trigger 1～10%, mercaptan type chain transfer agent and phenolic inhibitor 0.5～5%.
Described performed polymer comprises:
Two or more curable crosslinked functional groups, described curable crosslinked functional group are any in carbon-carbon double bond or the epoxide group.
Described carbon-carbon double bond or epoxide group comprise:
Main chain is an acrylate, side chain contain in the acrylate, epoxy acrylate, urethane acrylate of two keys any or several arbitrarily.
Described reactive diluent is reactive monomer or non-reactive solvent.
Described reactive monomer comprises:
In 1,6 hexanediyl ester, tripropylene glycol diacrylate, neopentylglycol diacrylate, PDDA, trimethylolpropane triacrylate, ethyoxyl trimethylolpropane triacrylate, the propoxyl group trimethylolpropane triacrylate any or several arbitrarily.
Described non-reactive solvent comprises:
In ethyl acetate, chlorine benzene,toluene,xylene, acetone, MEK, methyl iso-butyl ketone (MIBK), pentane, hexane, heptane, octane, the dimethyl formamide any or several arbitrarily.
Described light trigger comprises:
Carry the Hydrogen initator, in benzophenone, methyl o-benzoylbenzoate, 2 isopropyl thioxanthones, chloro thioxanthone, nitrato thioxanthone, thiophenyl benzophenone, two benzophenone thio-ether type compounds, the two thiophenyl phenylbenzene ketone compounds any or several arbitrarily.
Described chain-transferring agent is a mercaptan type chain transfer agent; Described polymerization inhibitor is a phenolic inhibitor.
Described mercaptan type chain transfer agent adopts lauryl mercaptan.
Described phenolic inhibitor comprises: any one or two kinds of in hydroquinones, the arylamine.
From the technical scheme that the invention described above provides as can be seen, the embodiment of the invention is passed through performed polymer, reactive diluent, light trigger, chain-transferring agent and polymerization inhibitor organic assembling, form ultraviolet cured gloss oil for paper, by distinctive molecular structure the membrane formation mechanism of oil polish is improved, this oil polish can be realized the last light effect of low coating cost to high oil-Absorbing Sheets.
The specific embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
Present embodiment 1 provides a kind of ultraviolet cured gloss oil for paper, be used in light effect is provided in the paper, this ultraviolet cured gloss oil for paper is formed by performed polymer, reactive diluent, light trigger and by the auxiliary agent that chain-transferring agent and polymerization inhibitor are formed, the weight percentage of each component is as follows: performed polymer accounts for 20～80%, reactive diluent accounts for 10～70%, light trigger accounts for 1～10%, and the auxiliary agent that chain-transferring agent and polymerization inhibitor are formed accounts for 0.5～5%.
Performed polymer in the above-mentioned ultraviolet cured gloss oil for paper is to comprise two or more curable crosslinked functional groups, curable functional group is carbon-carbon double bond or epoxide group, comprise that main chain is an acrylate, side chain contains one or more in the acrylate, epoxy acrylate, urethane acrylate of two keys.
Reactive diluent in the above-mentioned ultraviolet cured gloss oil for paper is reactive monomer or non-reacted solvent; Wherein, reactive monomer can adopt in 1,6 hexanediyl ester, tripropylene glycol diacrylate, neopentylglycol diacrylate, PDDA, trimethylolpropane triacrylate, ethyoxyl trimethylolpropane triacrylate, the propoxyl group trimethylolpropane triacrylate any or several arbitrarily; Non-reactive solvent can adopt in ethyl acetate, chlorine benzene,toluene,xylene, acetone, MEK, methyl iso-butyl ketone (MIBK), pentane, hexane, heptane, octane, the dimethyl formamide any or several arbitrarily.
Light trigger in the above-mentioned ultraviolet cured gloss oil for paper can adopt carries the Hydrogen initator, carries the Hydrogen initator and specifically comprises: any in benzophenone, methyl o-benzoylbenzoate, 2-isopropyl thioxanthone, chloro thioxanthone, nitrato thioxanthone, thiophenyl benzophenone, two benzophenone thio-ether type compounds, the two thiophenyl phenylbenzene ketone compounds or several arbitrarily.
The chain-transferring agent of forming auxiliary agent in the above-mentioned ultraviolet cured gloss oil for paper can adopt mercaptan type chain transfer agent, and this mercaptan type chain transfer agent can adopt lauryl mercaptan; Polymerization inhibitor can adopt phenolic inhibitor, this phenolic inhibitor comprise in hydroquinones, the arylamine any or several arbitrarily.
The ultraviolet cured gloss oil for paper that present embodiment provides is by the selection to formulation monomer, improved the film forming speed of oil polish (resin), make it after coating, have little time by the uniform rete of fibrage absorption promptly formation, the oil polish of present embodiment (being a kind of film-forming resin) shrinkage factor is low, can not cause the Deformation of Paper contraction after the film forming, the maintenance of the paper property endured is good.
Embodiment 2
Present embodiment 2 provides a kind of ultraviolet cured gloss oil for paper, is used in the paper glazing, and this oil polish specifically comprises following raw material:
Formulation weight percentage composition (%)
Urethane acrylate 60
Neopentylglycol diacrylate 25
Ethyl acetate 10
Methyl o-benzoylbenzoate 4.5
Lauryl mercaptan 0.2
Hydroquinones 0.3.
After above-mentioned each raw material mixing, can obtain ultraviolet cured gloss oil for paper.
Embodiment 3
Present embodiment 3 provides a kind of ultraviolet cured gloss oil for paper, is used in the paper glazing, and this oil polish specifically comprises following raw material:
Formulation weight percentage composition (%)
Urethane acrylate 55
Trimethylolpropane triacrylate 15
Propoxyl group trimethylolpropane triacrylate 15
Toluene 8
Hexane 2
Thiophenyl benzophenone 4.2
Lauryl mercaptan 0.2
Arylamine 0.6.
After above-mentioned each raw material mixing, can obtain ultraviolet cured gloss oil for paper.
Embodiment 4
Present embodiment 4 provides a kind of ultraviolet cured gloss oil for paper, is used in the paper glazing, and this oil polish specifically comprises following raw material:
Formulation weight percentage composition (%)
Urethane acrylate 45
Epoxy acrylate 25
Neopentylglycol diacrylate 11
1,6 hexanediyl ester 15
Chloro thioxanthone 3.5
Lauryl mercaptan 0.2
Arylamine 0.3
After above-mentioned each raw material mixing, can obtain ultraviolet cured gloss oil for paper.
Oil polish and commercially available ultraviolet cured gloss oil while glazing with the various embodiments described above provide, carry out the comparison (used paper is the 56g art post paperboard, non-coating handling of paper) of glossiness (30 °) and outward appearance:
Contrast table
| Outward appearance | Glossiness (30 °) | |
| Embodiment 2 | Light does not have distortion | ??87 |
| Embodiment 3 | Light does not have distortion | ??91 |
| Embodiment 4 | Light does not have distortion | ??92 |
| Commercially available oil polish | Paper curls, surface irregularity | ??67 |
In sum, oil polish in the embodiment of the invention is by the selection to formulation monomer, improved the film forming speed of resin, make this oil polish after coating, have little time by the uniform rete of fibrage absorption promptly formation, this oil polish shrinkage factor is low, can not cause the Deformation of Paper contraction after the film forming, can make the very property maintenance of paper good.
The above; only for the preferable specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, and anyly is familiar with those skilled in the art in the technical scope that the present invention discloses; the variation that can expect easily or replacement all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.
Claims (10)
1. ultraviolet cured gloss oil for paper, it is characterized in that, this oil polish is made up of performed polymer, reactive diluent, light trigger, chain-transferring agent and polymerization inhibitor, the weight percentage of each component is as follows: performed polymer 20～90%, reactive diluent 10～70%, light trigger 1～10%, chain-transferring agent and polymerization inhibitor 0.5～5%.
2. the described ultraviolet cured gloss oil for paper of claim 1 is characterized in that, described performed polymer comprises:
Two or more curable crosslinked functional groups, described curable crosslinked functional group are any in carbon-carbon double bond or the epoxide group.
3. the described ultraviolet cured gloss oil for paper of claim 2 is characterized in that, described carbon-carbon double bond or epoxide group comprise:
Main chain is an acrylate, side chain contain in the acrylate, epoxy acrylate, urethane acrylate of two keys any or several arbitrarily.
4. the described ultraviolet cured gloss oil for paper of claim 1 is characterized in that, described reactive diluent is reactive monomer or non-reactive solvent.
5. the described ultraviolet cured gloss oil for paper of claim 4 is characterized in that, described reactive monomer comprises:
In 1,6 hexanediyl ester, tripropylene glycol diacrylate, neopentylglycol diacrylate, PDDA, trimethylolpropane triacrylate, ethyoxyl trimethylolpropane triacrylate, the propoxyl group trimethylolpropane triacrylate any or several arbitrarily.
6. the described ultraviolet cured gloss oil for paper of claim 4 is characterized in that, described non-reactive solvent comprises:
In ethyl acetate, chlorine benzene,toluene,xylene, acetone, MEK, methyl iso-butyl ketone (MIBK), pentane, hexane, heptane, octane, the dimethyl formamide any or several arbitrarily.
7. the described ultraviolet cured gloss oil for paper of claim 1 is characterized in that, described light trigger comprises:
Carry the Hydrogen initator, in benzophenone, methyl o-benzoylbenzoate, 2 isopropyl thioxanthones, chloro thioxanthone, nitrato thioxanthone, thiophenyl benzophenone, two benzophenone thio-ether type compounds, the two thiophenyl phenylbenzene ketone compounds any or several arbitrarily.
8. the described ultraviolet cured gloss oil for paper of claim 1 is characterized in that, described chain-transferring agent is a mercaptan type chain transfer agent; Described polymerization inhibitor is a phenolic inhibitor.
9. the described ultraviolet cured gloss oil for paper of claim 1 is characterized in that, described mercaptan type chain transfer agent adopts lauryl mercaptan.
10. the described ultraviolet cured gloss oil for paper of claim 1 is characterized in that, described phenolic inhibitor comprises: any in hydroquinones, the arylamine or any two kinds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010119195 CN101748657A (en) | 2010-03-05 | 2010-03-05 | Ultraviolet cured gloss oil for paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010119195 CN101748657A (en) | 2010-03-05 | 2010-03-05 | Ultraviolet cured gloss oil for paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101748657A true CN101748657A (en) | 2010-06-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010119195 Pending CN101748657A (en) | 2010-03-05 | 2010-03-05 | Ultraviolet cured gloss oil for paper |
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| CN (1) | CN101748657A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964969A (en) * | 2012-11-14 | 2013-03-13 | 京东方科技集团股份有限公司 | Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen |
| CN103074802A (en) * | 2013-01-24 | 2013-05-01 | 陕西科技大学 | Preparation method for ultraviolet curing water-based paper varnish |
| CN103909753A (en) * | 2013-01-04 | 2014-07-09 | 上海宝钢包装股份有限公司 | Printing and coating method for metal UV (Ultra Violet) color printing products |
| CN104371543A (en) * | 2014-08-20 | 2015-02-25 | 昆山博益鑫成高分子材料有限公司 | Solvent-free cationic light-curable release coating and preparation method thereof |
| CN108300066A (en) * | 2018-02-07 | 2018-07-20 | 温州深奥科技有限公司 | Printed matter protection layer formula |
| CN109135550A (en) * | 2018-08-08 | 2019-01-04 | 深圳市裕同包装科技股份有限公司 | UV-LED curing varnish and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125756A (en) * | 1994-12-26 | 1996-07-03 | 山东省费县化工总厂 | Preparation method of multi-purpose ultraviolet-solidification polish oil |
| CN1472387A (en) * | 2002-07-30 | 2004-02-04 | 四川远见实业有限公司 | Wet transfer special polishing oil for film covering on printed paper |
| CN1556158A (en) * | 2004-01-07 | 2004-12-22 | 汕头市东风印刷厂有限公司 | Ultrariolet rag solidifying printing lustering oil and its preparation method |
| CN101503580A (en) * | 2009-03-06 | 2009-08-12 | 恒昌涂料（惠阳）有限公司 | Ultraviolet light curing oil polish and preparation thereof |
-
2010
- 2010-03-05 CN CN 201010119195 patent/CN101748657A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125756A (en) * | 1994-12-26 | 1996-07-03 | 山东省费县化工总厂 | Preparation method of multi-purpose ultraviolet-solidification polish oil |
| CN1472387A (en) * | 2002-07-30 | 2004-02-04 | 四川远见实业有限公司 | Wet transfer special polishing oil for film covering on printed paper |
| CN1556158A (en) * | 2004-01-07 | 2004-12-22 | 汕头市东风印刷厂有限公司 | Ultrariolet rag solidifying printing lustering oil and its preparation method |
| CN101503580A (en) * | 2009-03-06 | 2009-08-12 | 恒昌涂料（惠阳）有限公司 | Ultraviolet light curing oil polish and preparation thereof |
Non-Patent Citations (2)
| Title |
|---|
| 《合成材料老化与应用》 20060930 张恒 UV固化纸张水性上光油的研究 35、36 1-10 , 第3期 * |
| 《涂料工业》 20030601 唐薰 UV固化纸印品水性上光油的研制 7、8 1-10 第33卷, 第6期 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964969A (en) * | 2012-11-14 | 2013-03-13 | 京东方科技集团股份有限公司 | Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen |
| CN102964969B (en) * | 2012-11-14 | 2014-12-17 | 京东方科技集团股份有限公司 | Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen |
| CN103909753A (en) * | 2013-01-04 | 2014-07-09 | 上海宝钢包装股份有限公司 | Printing and coating method for metal UV (Ultra Violet) color printing products |
| CN103909753B (en) * | 2013-01-04 | 2016-08-10 | 上海宝钢包装股份有限公司 | A kind of metal UV color printing product print coating method |
| CN103074802A (en) * | 2013-01-24 | 2013-05-01 | 陕西科技大学 | Preparation method for ultraviolet curing water-based paper varnish |
| CN104371543A (en) * | 2014-08-20 | 2015-02-25 | 昆山博益鑫成高分子材料有限公司 | Solvent-free cationic light-curable release coating and preparation method thereof |
| CN108300066A (en) * | 2018-02-07 | 2018-07-20 | 温州深奥科技有限公司 | Printed matter protection layer formula |
| CN109135550A (en) * | 2018-08-08 | 2019-01-04 | 深圳市裕同包装科技股份有限公司 | UV-LED curing varnish and preparation method thereof |
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Open date: 20100623 |