CN103435964A - Wear-resistant reinforced POM and preparation method thereof - Google Patents
Wear-resistant reinforced POM and preparation method thereof Download PDFInfo
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- CN103435964A CN103435964A CN2013103521504A CN201310352150A CN103435964A CN 103435964 A CN103435964 A CN 103435964A CN 2013103521504 A CN2013103521504 A CN 2013103521504A CN 201310352150 A CN201310352150 A CN 201310352150A CN 103435964 A CN103435964 A CN 103435964A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229920006324 polyoxymethylene Polymers 0.000 claims abstract description 49
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 37
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004917 carbon fiber Substances 0.000 claims abstract description 13
- 239000007822 coupling agent Substances 0.000 claims abstract description 13
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002250 absorbent Substances 0.000 claims abstract description 9
- 230000002745 absorbent Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 230000002708 enhancing effect Effects 0.000 claims description 26
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 12
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 9
- 239000003112 inhibitor Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 8
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 238000010008 shearing Methods 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 abstract description 5
- 230000003078 antioxidant effect Effects 0.000 abstract description 5
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 230000005855 radiation Effects 0.000 abstract description 3
- BOYPAYBWCQZOGC-UHFFFAOYSA-N 2-[4,6-bis(4-butoxy-2-hydroxyphenyl)-1,3,5-triazin-2-yl]-5-butoxyphenol Chemical compound CCCCOc1ccc(c(O)c1)-c1nc(nc(n1)-c1ccc(OCCCC)cc1O)-c1ccc(OCCCC)cc1O BOYPAYBWCQZOGC-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004566 building material Substances 0.000 abstract description 2
- 239000002861 polymer material Substances 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 238000004870 electrical engineering Methods 0.000 abstract 1
- 229910052901 montmorillonite Inorganic materials 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
- B29B9/14—Making granules characterised by structure or composition fibre-reinforced
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
- B29B2009/125—Micropellets, microgranules, microparticles
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to wear-resistant reinforced POM (polyformaldehyde) and a preparation method thereof, and belongs to the technical field of a high polymer material. The wear-resistant reinforced POM comprises the following raw materials in part by weight: 80 to 100 parts of polyformaldehyde, 12 to 18 parts of carbon fibers, 1 to 5 parts of polytetrafluoroethylene, 2 to 5 parts of nano-montmorillonite, 0.2 to 0.5 part of nano zinc oxide, 2 to 5 parts of antioxidant, 1 to 2 parts of polypropylene maleic anhydride, 0.2 to 0.4 part of ethylene bis stearamide, 0.5 to 1.2 parts of formaldehyde absorbent, 1 to 2 parts of titanate coupling agent and 0.5 to 1.2 parts of 2,4,6-tri(2-hydroxy-4-butoxy-phenyl)-1,3,5-triazine. The preparation method disclosed by the invention is simple; the prepared wear-resistant reinforced POM has excellent mechanical performance, excellent wear resistance and excellent resistance to ultraviolet radiation, also has a certain antibacterial capacity and can be widely used in the fields of electronic and electrical engineering, machinery, instruments, daily light industry, automobile, building materials, agriculture and the like.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to wear-resisting enhancing POM and preparation method thereof.
Background technology
Polyoxymethylene, english abbreviation is POM, is a kind of thermoplasticity crystalline polymer, is described as " supersteel " or " match steel ", claims again polyoxymethylene.POM has hardness, intensity and the rigidity of metalloid, all there is good self lubricity, good resistance to fatigue in very wide temperature and humidity scope, and springiness, it also has chemical-resistant preferably in addition, but it has the shortcoming of not anti-solar ultraviolet radiation.
POM is with the cost lower than other many engineering plastics, substituting some traditionally by market that metal captured, as instead of zinc, brass, aluminium and steel are made many parts, since coming out, the fields such as that POM has been widely used in is electric, mechanical, instrument, daily light industry, automobile, building materials, agricultural.In the application of a lot of frontiers, as aspects such as medical skill, sports equipment, POM also shows growing trend preferably.
Due to the development of POM in each field, people have higher requirement to its toughness, rigidity, thermotolerance, dimensional stability, friction and abrasion etc.Yet, for the enhancing modified of POM, because the high crystalline of POM causes resin and glass to be difficult to reach compatible preferably, thereby do not have obvious reinforced effects.Therefore how overcoming the deficiencies in the prior art is problems that current technical field of macromolecules is needed solution badly.
Summary of the invention
The objective of the invention is, in order to solve the deficiencies in the prior art, provides wear-resisting enhancing POM and preparation method thereof, and wear-resisting enhancing POM of the present invention has good toughness and wear resistance, simultaneously can UV resistant.
The technical solution used in the present invention is as follows:
Wear-resisting enhancing POM, comprise the following raw material according to the parts by weight meter: 1 ~ 2 part of 80 ~ 100 parts of polyoxymethylene, 12 ~ 18 parts, carbon fiber, 1 ~ 5 part of tetrafluoroethylene, 2 ~ 5 parts of nano imvites, 0.2 ~ 0.5 part of nano zine oxide, 2 ~ 5 parts, oxidation inhibitor, 1 ~ 2 part of polypropylene maleic anhydride, 0.2 ~ 0.4 part of ethylene bis stearamide, 0.5 ~ 1.2 part of formaldehyde absorbent, titanate coupling agent, 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,0.5 ~ 1.2 part of 3,5-triazine.
Further preferred described oxidation inhibitor is antioxidant 264.
Further preferred described formaldehyde absorbent is poly cyanamid or urea.
The present invention also provides the preparation method of a kind of wear-resisting enhancing POM, comprise the steps: polyoxymethylene, tetrafluoroethylene, nano imvite, nano zine oxide, oxidation inhibitor, the polypropylene maleic anhydride, ethylene bis stearamide, formaldehyde absorbent, titanate coupling agent and 2, 4, 6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1, 3, the 5-triazine is placed in mixing machine, mix, in the screw combinations situation that mixed material is sheared in medium tenacity through twin screw extruder, by side, add carbon fiber to carry out mixing extrusion, the water cooling bracing pelletizing makes wear-resisting enhancing POM.
compared with prior art, its beneficial effect is in the present invention:(1) add tetrafluoroethylene and nano imvite in raw material of the present invention, added the consistency that the polypropylene maleic anhydride strengthens they and POM simultaneously, made the wear-resisting enhancing POM of the present invention to there is excellent mechanical property and good wear resistance; (2) with 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,3,5-triazines for uv-absorbing agent, and carry out scatters ultraviolet with nano zine oxide, make product of the present invention there is the ability of good UV resistant radiation; (3) owing to having added nano zine oxide, not only strengthen the weathering resistance of product of the present invention, also made product of the present invention there is certain germ resistance; (4) preparation method is simple, is easy to apply.
Specific embodiment
Wear-resisting enhancing POM, comprise the following raw material according to the parts by weight meter: 1 ~ 2 part of 80 ~ 100 parts of polyoxymethylene, 12 ~ 18 parts, carbon fiber, 1 ~ 5 part of tetrafluoroethylene, 2 ~ 5 parts of nano imvites, 0.2 ~ 0.5 part of nano zine oxide, 2 ~ 5 parts, oxidation inhibitor, 1 ~ 2 part of polypropylene maleic anhydride, 0.2 ~ 0.4 part of ethylene bis stearamide, 0.5 ~ 1.2 part of formaldehyde absorbent, titanate coupling agent, 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,0.5 ~ 1.2 part of 3,5-triazine.
The preparation method of this wear-resisting enhancing POM, comprise the steps: polyoxymethylene, tetrafluoroethylene, nano imvite, nano zine oxide, oxidation inhibitor, polypropylene maleic anhydride, ethylene bis stearamide, formaldehyde absorbent, titanate coupling agent and 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,3, the 5-triazine is placed in mixing machine, mix, in the screw combinations situation that mixed material is sheared in medium tenacity through twin screw extruder, by side, add carbon fiber to carry out mixing extrusion, the water cooling bracing pelletizing makes wear-resisting enhancing POM.
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1
Wear-resisting enhancing POM, comprise the following raw material according to the parts by weight meter: 1 part of 80 parts of polyoxymethylene, 12 parts, carbon fiber, 1 part of tetrafluoroethylene, 2 parts of nano imvites, 0.2 part of nano zine oxide, 2 parts of antioxidant 264s, 1 part of polypropylene maleic anhydride, 0.2 part of ethylene bis stearamide, 0.5 part of poly cyanamid, titanate coupling agent, 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,0.5 part of 3,5-triazine.
The preparation method of this wear-resisting enhancing POM, comprise the steps: polyoxymethylene, tetrafluoroethylene, nano imvite, nano zine oxide, antioxidant 264, polypropylene maleic anhydride, ethylene bis stearamide, poly cyanamid, titanate coupling agent and 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,3, the 5-triazine is placed in mixing machine, mix, in the screw combinations situation that mixed material is sheared in medium tenacity through twin screw extruder, by side, add carbon fiber to carry out mixing extrusion, the water cooling bracing pelletizing makes wear-resisting enhancing POM.
Embodiment 2
Wear-resisting enhancing POM, comprise the following raw material according to the parts by weight meter: 2 parts of 100 parts of polyoxymethylene, 18 parts, carbon fiber, 5 parts of tetrafluoroethylene, 5 parts of nano imvites, 0.5 part of nano zine oxide, 5 parts of antioxidant 264s, 2 parts of polypropylene maleic anhydrides, 0.4 part of ethylene bis stearamide, 1.2 parts of poly cyanamids, titanate coupling agent, 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,1.2 parts of 3,5-triazines.
The preparation method of the wear-resisting enhancing of the present embodiment POM is identical with embodiment 1.
Embodiment 3
Wear-resisting enhancing POM, comprise the following raw material according to the parts by weight meter: 1.5 parts of 90 parts of polyoxymethylene, 15 parts, carbon fiber, 3 parts of tetrafluoroethylene, 4 parts of nano imvites, 0.3 part of nano zine oxide, 4 parts of antioxidant 264s, 1.2 parts of polypropylene maleic anhydrides, 0.3 part of ethylene bis stearamide, 0.8 part of poly cyanamid, titanate coupling agent, 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,0.9 part of 3,5-triazine.
The preparation method of the wear-resisting enhancing of the present embodiment POM is identical with embodiment 1.
Embodiment 4
Wear-resisting enhancing POM, comprise the following raw material according to the parts by weight meter: 1.6 parts of 95 parts of polyoxymethylene, 16 parts, carbon fiber, 4 parts of tetrafluoroethylene, 3 parts of nano imvites, 0.33 part of nano zine oxide, 3.5 parts of antioxidant 264s, 1.8 parts of polypropylene maleic anhydrides, 0.28 part of ethylene bis stearamide, 1 part, urea, titanate coupling agent, 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,1 part of 3,5-triazine.
The preparation method of this wear-resisting enhancing POM, comprise the steps: polyoxymethylene, tetrafluoroethylene, nano imvite, nano zine oxide, antioxidant 264, polypropylene maleic anhydride, ethylene bis stearamide, urea, titanate coupling agent and 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,3, the 5-triazine is placed in mixing machine, mix, in the screw combinations situation that mixed material is sheared in medium tenacity through twin screw extruder, by side, add carbon fiber to carry out mixing extrusion, the water cooling bracing pelletizing makes wear-resisting enhancing POM.
performance test
Performance to the embodiment of the present invention 1 ~ 4 product is tested, and test result is in Table 1.
The performance test data of table 1 embodiment 1 ~ 4 product
, the antibacterial ability of product of the present invention is detected simultaneously, detected data as shown in table 2.
Table 2 embodiment of the present invention 1 ~ 3 product antibacterial effect detected result
Claims (4)
1. wear-resisting enhancing POM, it is characterized in that comprising the following raw material according to the parts by weight meter: 1 ~ 2 part of 80 ~ 100 parts of polyoxymethylene, 12 ~ 18 parts, carbon fiber, 1 ~ 5 part of tetrafluoroethylene, 2 ~ 5 parts of nano imvites, 0.2 ~ 0.5 part of nano zine oxide, 2 ~ 5 parts, oxidation inhibitor, 1 ~ 2 part of polypropylene maleic anhydride, 0.2 ~ 0.4 part of ethylene bis stearamide, 0.5 ~ 1.2 part of formaldehyde absorbent, titanate coupling agent, 2,4,6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1,0.5 ~ 1.2 part of 3,5-triazine.
2. wear-resisting enhancing POM according to claim 1, is characterized in that described oxidation inhibitor is antioxidant 264.
3. wear-resisting enhancing POM according to claim 1, is characterized in that described formaldehyde absorbent is poly cyanamid or urea.
4. based on the wear-resisting preparation method who strengthens POM claimed in claim 1, it is characterized in that comprising the steps: by polyoxymethylene, tetrafluoroethylene, nano imvite, nano zine oxide, oxidation inhibitor, the polypropylene maleic anhydride, ethylene bis stearamide, formaldehyde absorbent, titanate coupling agent and 2, 4, 6-tri-(2 '-hydroxyl-4 '-n-butoxy phenyl)-1, 3, the 5-triazine is placed in mixing machine, mixing in the screw combinations situation of shearing in medium tenacity by twin screw extruder adds carbon fiber to carry out mixing extrusion by side, the water cooling bracing pelletizing makes wear-resisting enhancing POM.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104356589A (en) * | 2014-11-05 | 2015-02-18 | 上海交通大学 | Carbon fiber reinforced friction-resistant polyoxymethylene (POM) composite material and preparation method thereof |
| CN104499086A (en) * | 2014-12-04 | 2015-04-08 | 江苏苏博特新材料股份有限公司 | Preparation method of polyoxymethylene crude fiber for toughening concrete |
| CN104650531A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Carbon fiber reinforced polyoxymethylene composite with high corrosion resistance and preparation method of composite |
| CN104650529A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Carbon fiber reinforced polyformaldehyde composite material having good weather fastness and preparation method of carbon fiber reinforced polyformaldehyde composite material |
| CN104650532A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Toughness-enhanced carbon fiber reinforced polyformaldehyde composite material and preparation method thereof |
| CN104650533A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Scratch-resistant carbon fiber reinforced polyacetal composite material and preparation method thereof |
| CN104650528A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Carbon fiber reinforced polyformaldehyde composite material with excellent comprehensive properties and preparation method thereof |
| CN104672775A (en) * | 2015-02-06 | 2015-06-03 | 合肥康龄养生科技有限公司 | Carbon fiber reinforced polyformaldehyde composite material with high UV resistance and preparation method thereof |
| CN105237943A (en) * | 2015-10-12 | 2016-01-13 | 神华集团有限责任公司 | Rigidity-reinforced polyformaldehyde composite material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101343409A (en) * | 2008-08-27 | 2009-01-14 | 毛惠敏 | Carbon fiber reinforced composite and preparation thereof |
| CN101759955A (en) * | 2009-11-26 | 2010-06-30 | 苏州市科创聚合物有限公司 | High wear-resistant self-lubricating polyoxymethylene and process for preparing same |
| CN102382418A (en) * | 2010-09-06 | 2012-03-21 | 苏州工业园区鑫丰林塑料科技有限公司 | High wear-resistant lubricating plastic |
-
2013
- 2013-08-14 CN CN201310352150.4A patent/CN103435964B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101343409A (en) * | 2008-08-27 | 2009-01-14 | 毛惠敏 | Carbon fiber reinforced composite and preparation thereof |
| CN101759955A (en) * | 2009-11-26 | 2010-06-30 | 苏州市科创聚合物有限公司 | High wear-resistant self-lubricating polyoxymethylene and process for preparing same |
| CN102382418A (en) * | 2010-09-06 | 2012-03-21 | 苏州工业园区鑫丰林塑料科技有限公司 | High wear-resistant lubricating plastic |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104356589A (en) * | 2014-11-05 | 2015-02-18 | 上海交通大学 | Carbon fiber reinforced friction-resistant polyoxymethylene (POM) composite material and preparation method thereof |
| CN104499086A (en) * | 2014-12-04 | 2015-04-08 | 江苏苏博特新材料股份有限公司 | Preparation method of polyoxymethylene crude fiber for toughening concrete |
| CN104499086B (en) * | 2014-12-04 | 2016-09-14 | 江苏苏博特新材料股份有限公司 | A kind of concrete coarse-fibred preparation method of toughness reinforcing polyoxymethylene |
| CN104650531A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Carbon fiber reinforced polyoxymethylene composite with high corrosion resistance and preparation method of composite |
| CN104650529A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Carbon fiber reinforced polyformaldehyde composite material having good weather fastness and preparation method of carbon fiber reinforced polyformaldehyde composite material |
| CN104650532A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Toughness-enhanced carbon fiber reinforced polyformaldehyde composite material and preparation method thereof |
| CN104650533A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Scratch-resistant carbon fiber reinforced polyacetal composite material and preparation method thereof |
| CN104650528A (en) * | 2015-02-06 | 2015-05-27 | 合肥康龄养生科技有限公司 | Carbon fiber reinforced polyformaldehyde composite material with excellent comprehensive properties and preparation method thereof |
| CN104672775A (en) * | 2015-02-06 | 2015-06-03 | 合肥康龄养生科技有限公司 | Carbon fiber reinforced polyformaldehyde composite material with high UV resistance and preparation method thereof |
| CN105237943A (en) * | 2015-10-12 | 2016-01-13 | 神华集团有限责任公司 | Rigidity-reinforced polyformaldehyde composite material and preparation method thereof |
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