CN103435328B - Pug of bone jade porcelain and preparation method thereof - Google Patents
Pug of bone jade porcelain and preparation method thereof Download PDFInfo
- Publication number
- CN103435328B CN103435328B CN201310360521.3A CN201310360521A CN103435328B CN 103435328 B CN103435328 B CN 103435328B CN 201310360521 A CN201310360521 A CN 201310360521A CN 103435328 B CN103435328 B CN 103435328B
- Authority
- CN
- China
- Prior art keywords
- bone
- mentioned
- porcelain
- bone meal
- kaolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a kind of bone jade porcelain pug and preparation method thereof, bone jade porcelain pug mainly purified by 45-55wt% after bone meal, the Kaolin of 30-40wt% and the potassium albite of 20-25wt% are prepared from, adopt the bone jade porcelain that this pug prepares, in its product structure, existing calcium phosphate, silicon dioxide, the high-stability crystal structure of aluminium oxide, there is again novel substance sodium silicate, potassium silicate, the material of the LMPs such as a small amount of calcium silicates, and the material of these LMPs just fills up the molecular gap of idiosome, thus obtaining the ceramic of fineness, namely there is high whiteness, color and luster is gentle, porcelain is fine and smooth, the bone jade porcelain that light transmission is strong.The inventive method is using the bone of cattle and sheep as main material, resource substantial saving in rare mineral raw material, every ten thousand yuan of output values can economize on resources 90%, every ten thousand yuan of output values can energy efficient 80%, it is the industry of good ecological environment type, resource-conserving, sustainable development, there is the very strong market competitiveness and social synthesis's benefit.
Description
Technical field
The present invention relates to porcelain field, specifically pug of a kind of new-type porcelain-bone jade porcelain and preparation method thereof.
Background technology
China makes the pottery history of existing several thousand, in the formula of Ceramic Material, with support theoretical origin that silicate, aluminium oxide are pottery several thousand, Chinese jade porcelain is gentle with color and luster, porcelain is fine and smooth creates immortal mythology, legend and splendidness at ceramic field, therefore Ceramic Material technology is also gone through among the problem belonging to silicate research in China.
Before about 300 years, it is not uniquely the porcelain kind-bone china being born in China that the ceramic making craftsman of West Europe particularly Britain starts to make in the world today with animal bone ash for raw material, its pottery support in theory, it is then make pottery with calcium phosphate, aluminium oxide, the feature that bone china has whiteness height, light transmission is good, it is subject to, since being appearance, the high-grade porcelain that west noble favors, captures alone the high-end Ceramic Market in the world.
Chinese jade porcelain color and luster is gentle, porcelain is fine and smooth, but whiteness is relatively low, and light transmission is also undesirable；Bone china whiteness is high, light transmission is good, but color and luster is comparatively stiff, porcelain is rougher.Make that a kind of color and luster integrating Chinese jade porcelain is gentle, porcelain is fine and smooth and the height of west bone china is pure white, the porcelain of high light transmittance, is pursuing a goal of ceramic industry.
The basis of the producing principle of Chinese jade porcelain is silicate theoretical system, and the basis of the producing principle of west bone china is phosphatic theoretical system.The theory of two kinds of Ceramic Materials of Chinese and western, also exists qualitative difference, because being more than 1150 DEG C at high operating temperatures, calcium ion and silicon dioxide will produce violent chemical reaction, and product is calcium silicates, and molten point is extremely low, be molten state at normal temperatures.If the bone china raw material of grain of rice size is set on the idiosome that Chinese jade porcelain raw material is made, high-temperature firing then will appear from a solution cavity, otherwise also such.
Keep that the color and luster with Chinese jade porcelain is gentle, porcelain is fine and smooth, whiteness and light transmission are brought up to the level of bone china, then must add substantial amounts of calcium phosphate in the feed；Make bone china have color and luster gentle have again porcelain exquisiteness then must add enough potassium albites in the feed, its main component silicon dioxide, it seems that the Ceramic Material that both can not and be deposited coexists among the idiosome of a Ceramic Material, it is always up the key technology difficult problem in industry.The color and luster integrating Chinese jade porcelain is gentle, porcelain is fine and smooth and the height of west bone china is pure white, the porcelain of high light transmittance is thought in industry to realize, and this has become the technology prejudice in industry.
Summary of the invention
It is an object of the invention to provide a kind of bone jade porcelain pug, adopt the porcelain that this bone jade porcelain pug is made both to have the feature that color and luster is gentle, porcelain is fine and smooth of Chinese jade porcelain, the height simultaneously having again a west bone china is pure white, the feature of high light transmittance.
It is a further object of the present invention to provide a kind of method preparing above-mentioned bone jade porcelain pug.
To achieve these goals, the present invention adopts following scheme:
Bone jade porcelain pug, the potassium albite of bone meal after mainly being purified by 45-55wt%, the Kaolin of 30-40wt% and 20-25wt% is prepared from, and wherein, the granularity of bone meal, Kaolin and potassium albite is 250-300 order.
Above-mentioned bone meal is powder that is purified by Os Bovis seu Bubali or Os Caprae seu Ovis and that pulverize.
The preparation method of bone jade porcelain pug, realizes as follows:
One, bone meal is prepared
A, first the Os Bovis seu Bubali dried or Os Caprae seu Ovis are carried out Conventional calcination, about 1000 DEG C are burnt from room temperature in 4-6 hour, with the reducing flame of 1000-1350 DEG C, Os Bovis seu Bubali or Os Caprae seu Ovis are carried out reduction calcining 1-3 hour again, the ferrous iron in Os Bovis seu Bubali or Os Caprae seu Ovis is reduced into ferric iron, obtains initial bone piece；
B, the initial bone piece of above-mentioned gained is processed into the refinement pulp that granularity is 250-300 order, and refines at this in pulp and add phosphoric acid, regulate to pH value close to neutral；
C, refinement pulp to above-mentioned gained carry out remove impurity, deironing, obtain bone meal after filter pressing；
Two, the mixing of bone meal and Kaolin and potassium albite:
The bone meal of step one gained is mixed with Kaolin and potassium albite, obtain just compound, the usage ratio of three is: bone meal 45-55wt%, Kaolin 30-40wt%, potassium albite 20-25wt%, the granularity of bone meal, Kaolin and potassium albite is 250-300 order；
Three, the mixing of first compound and organic lixiviating solution:
Above-mentioned just compound adds the lixiviating solution of organic matter, accounts for 35-45wt% in organic lixiviating solution, ratio that above-mentioned just compound accounts for 55-65wt% mixes；The lixiviating solution that the organic matter that the lixiviating solution of above-mentioned organic matter adopts weight ratio to be 1:2-4 obtains with water soaking for about 7 days；
Four, ferment old:
The compound that above-mentioned just compound and organic lixiviating solution mix is placed in open containers and ferments old 60-100 days in outdoor elements, namely obtain bone jade porcelain pug.
In the above-mentioned step B preparing bone meal, with ball milling, above-mentioned initial bone piece is processed into the refinement pulp that granularity is 250-300 order by forging.
In the above-mentioned step B preparing bone meal, the pH value adding the refinement pulp after phosphoric acid is 6.8-7.4.
Above-mentioned organic one or more the combination adopted in leaf of Caulis Sacchari sinensis, Folium Bambusae, bamboo stem, Caulis et Folium Oryzae.
Firing of pottery is a complicated chemical reaction process, in this reaction, the component of raw material some played chemical reaction, also new material is had to generate, but also having significant component of material to exist with the starting substance form, sintering procedure is exactly the reaction condition providing necessity for partial reaction material.
First carry out the molecule of Chinese jade porcelain and the various materials of west bone china comprehensively analyzing and understanding, the atom of the material molecule of composition is analyzed one by one, search out the probability coexisted, be made up of following former molecular mixture in whole formula: 1. metallic element: potassium, sodium, calcium, aluminum；2. nonmetalloid: oxygen, phosphorus, silicon etc.；These several elements are among raw material, and they are what kind of form to be present among each molecule with, under what conditions, will play which type of reaction, each what chemical characteristic own, and comprehensively analyze.Wherein, basic anhydride have potassium oxide, calcium oxide and aluminium oxide；Acidic oxidation has phosphorus pentoxide and silicon dioxide.Potassium, sodium belong to first group of race's element respectively, and during composition compound, it easily loses one electronics of outermost electronic shell, reaches Stability Analysis of Structures；Calcium is second group of race's element, and the ability losing two electronics of outermost electronic shell is taken second place.Phosphoric acid is typical middle strong acid, the compound that the compound stability of phosphate radical and metal ion composition forms much stronger than silicic acid, and aluminium oxide will remain stable for structure wherein.
The property analysis of each simple substance: calcium phosphate, middle strong acid, highly basic salt chemical are sufficiently stable, molten o'clock of simple substance is at 1500 DEG C, the stable molten point of covalent bond structure simple substance of silicon oxide is also high, more than 1500 DEG C, aluminium dioxide is also extremely strong covalent bond rock-steady structure, the molten point of simple substance is higher, and more than 1600 DEG C, these are all the good materials as Ceramic Material.nullThe stable again raw material of these three high melting-point coexists among the formula of Ceramic Material，Chemical property according to various materials determines the raw material that various material degree formula among raw material is manufactured，When the idiosome made fires 1270 DEG C to 1310 DEG C，It is the reaction condition that various material provides necessary，Make appropriate potassium oxide、Sodium oxide、Calcium oxide and silicon dioxide react，Generate the silicate of LMP，Under weakly alkaline condition，In the environment that calcium phosphate is excessive，Substantial amounts of calcium phosphate keeps relative steady statue in sintering procedure，Just fill up the intermolecular space among idiosome，Become lenticular，Not only improve the sophistication of ceramic product itself but also improve transparency，Do not interfere with again the support force of idiosome simultaneously，It is thus with aluminium oxide、The birth of calcium phosphate and bone jade porcelain that silicon dioxide is support is laid a good foundation.
The manufacturing process of pottery is the aggregation process of the physical change by many and chemical change process, manufacturing process at idiosome, slip casting, dehydration, the demoulding, dry etc. is all physical phenomenon, and sintering procedure is then the chemical change of series of complex, namely has new material to generate.Moieties carries out chemical reaction, other material then keeps the steady statue of raw material simultaneously, so-called firing is exactly that chemical reaction for this series of complex provides necessary reaction condition and time, this is just related to each element existence form in composition of raw materials and certain proportionate relationship, the form existed according to each element and chemical property determine the ratio of each material essence, in the product structure of bone jade porcelain, should there is calcium phosphate, silicon dioxide, the high-stability crystal structure of aluminium oxide, there is novel substance sodium silicate again, potassium silicate, the material of the LMPs such as a small amount of calcium silicates, and the material of these LMPs just fills up the molecular gap of idiosome, the ceramic of fineness can be produced, namely there is high whiteness, color and luster is gentle, porcelain is fine and smooth, the bone jade porcelain that light transmission is strong.
The bone jade porcelain pug of the present invention, main purified by 45-55wt% after bone meal, the Kaolin of 30-40wt% and the potassium albite of 20-25wt% be prepared from, adopt the bone jade porcelain that this pug prepares, in its product structure, existing calcium phosphate, silicon dioxide, aluminium oxide high-stability crystal structure, there is again the material of the LMPs such as novel substance sodium silicate, potassium silicate, a small amount of calcium silicates, and the material of these LMPs just fills up the molecular gap of idiosome, thus obtaining the ceramic of fineness, namely there is high whiteness, color and luster is gentle, porcelain is fine and smooth, light transmission is strong bone jade porcelain.
The inventive method is using the bone of cattle and sheep as main material, the bone of cattle and sheep derives from sources of three rivers pastoral area, the bone of the cattle and sheep that herdsman arbitrarily abandon after eating at ordinary times, to become morally degenerate at nature, seriously pollute natural environment, applicant is collected to be used, resource substantial saving in rare mineral raw material, every ten thousand yuan of output values can economize on resources 90%, every ten thousand yuan of output values can energy efficient 80%, therefore the production of bone jade porcelain is good ecological environment type, resource-conserving, the industry of sustainable development, there is the very strong market competitiveness and social synthesis's benefit.
Detailed description of the invention
The bone jade porcelain pug of the present invention, the potassium albite of bone meal after mainly being purified by 45-55wt%, the Kaolin of 30-40wt% and 20-25wt% is prepared from, and wherein, the granularity of bone meal, Kaolin and potassium albite is 250-300 order.Wherein, bone meal is powder that is purified by Os Bovis seu Bubali or Os Caprae seu Ovis and that pulverize.
The preparation method of bone jade porcelain pug of the present invention, realizes as follows:
One, bone meal is prepared
A, first the Os Bovis seu Bubali dried or Os Caprae seu Ovis are carried out Conventional calcination, about 1000 DEG C are burnt from room temperature in 4-6 hour, with the reducing flame of 1000-1350 DEG C, Os Bovis seu Bubali or Os Caprae seu Ovis are carried out reduction calcining 1-3 hour again, the ferrous iron in Os Bovis seu Bubali or Os Caprae seu Ovis is reduced into ferric iron, obtains initial bone piece；
B, the initial bone piece of above-mentioned gained first being forged into thin block then the refinement pulp that ball milling becomes granularity to be 250-300 order, and refine at this in pulp and add phosphoric acid, regulate to pH value close to neutral, namely pH is 6.8-7.4；
C, refinement pulp to above-mentioned gained carry out remove impurity, deironing by conventional methods, obtain bone meal after filter pressing；
Two, the mixing of bone meal and Kaolin and potassium albite:
The bone meal of step one gained is mixed with Kaolin and potassium albite, obtain just compound, the usage ratio of three is: bone meal 45-55wt%, Kaolin 30-40wt%, potassium albite 20-25wt%, the granularity of bone meal, Kaolin and potassium albite is 250-300 order；
Three, the mixing of first compound and organic lixiviating solution:
Above-mentioned just compound adds the lixiviating solution of organic matter, accounts for 35-45wt% in organic lixiviating solution, ratio that above-mentioned just compound accounts for 55-65wt% mixes；The lixiviating solution that the organic matter that the lixiviating solution of above-mentioned organic matter adopts weight ratio to be 1:2-4 obtains with water soaking for about 7 days；Wherein, organic one or more the combination adopted in leaf of Caulis Sacchari sinensis, Folium Bambusae, bamboo stem, Caulis et Folium Oryzae；
Four, ferment old:
The compound that above-mentioned just compound and organic lixiviating solution mix is placed in open containers and ferments old 60-100 days in outdoor elements, namely obtain bone jade porcelain pug.
Adopt the bone jade porcelain that the bone jade porcelain pug of the present invention is made, detect according to QB/T1503-1992 " domestic ceramics measuring brightness method ", the testing result of three samples respectively 101.1 degree, 100.7 degree, 100.7 degree, meets the test requirements document of QB/T1503-1992 " domestic ceramics measuring brightness method ".
nullAbout the explanation that Os Bovis seu Bubali or Os Caprae seu Ovis are calcined: mammiferous hemoglobin cell is the cell that in animal body, the life-span is the shortest，The hemoglobin cell life cycle of cattle is 30 days，The hemoglobin cell life cycle of sheep is 28 days，The Functional tissue manufacturing hemoglobin is bone marrow and the spongy bone of animal，So there is substantial amounts of hemoglobin raw material in animal bone spongiosa，Namely main component is ferrous ion，The existence of ferrous ion is the not removable material of general physical method，Ferrous ion is present in the middle of Ceramic Material will have large effect to whiteness and the quality of ceramic，In the present invention，Chemical property according to ferrous ion，In calcining bone process，Take special calcination-temperature profile，Namely at 1000 DEG C-1250 DEG C，It is ferrous ion active period adopt reduction flame，Reduction flame there is substantial amounts of strong reducing property CO (carbon monoxide converter) gas，Reduction of divalent iron ion is become free metal ferrum，Form ferroso-ferric oxide，Deironing can be facilitated，Prepare highly purified bone meal.
nullAbout the explanation that fermenting raw materials is old: selecting materials in process at Ceramic Material，Generally adopt sedimentary clay in thousand as viscosity and plastic auxiliary material，And naturally sedimentary clay majority contains Titanium ion，Aobvious taupe at high operating temperatures，Color and luster and the quality of ceramic product are had a strong impact on，According to sedimentary clay in thousand, there is good viscosity、Plasticity，Come from air slaking、Corrosion this principle of matter，In the present invention，After Raw material processing is become fine particle，Add appropriate organic lixiviating solution (i.e. carbohydrate，Can complete to resolve into the material of carbon dioxide and water within 1000 DEG C) make organic acceleration degenerate，It is placed in outdoor uncovered cement pit，Carry out old 60-100 days in outdoor elements (outdoor natural temperature and humidity) is inner，Reach the old effect of deposition underground，It is greatly enhanced viscosity and the plasticity of raw material，Do not affect again the purity of raw material.
Claims (2)
1. the preparation method of bone jade porcelain pug, it is characterised in that: realize as follows:
One, bone meal is prepared
A, first the Os Bovis seu Bubali dried or Os Caprae seu Ovis are carried out Conventional calcination, 1000 DEG C are burnt from room temperature in 4-6 hour, with the reducing flame of 1000-1350 DEG C, Os Bovis seu Bubali or Os Caprae seu Ovis are carried out reduction calcining 1-3 hour again, the ferrous iron in Os Bovis seu Bubali or Os Caprae seu Ovis is reduced into ferric iron, obtains initial bone piece；
B, the initial bone piece of above-mentioned gained is processed into the refinement pulp that granularity is 250-300 order, and refines at this in pulp and add phosphoric acid, regulate pH value to 6.8-7.4；
C, refinement pulp to above-mentioned gained carry out remove impurity, deironing, obtain bone meal after filter pressing；
Two, the mixing of bone meal and Kaolin and potassium albite:
The bone meal of step one gained is mixed with Kaolin and potassium albite, obtain just compound, the usage ratio of three is: bone meal 45-55wt%, Kaolin 30-40wt%, potassium albite 20-25wt%, and the consumption sum of bone meal, Kaolin and potassium albite is 100wt%；The granularity of bone meal, Kaolin and potassium albite is 250-300 order；
Three, the mixing of first compound and organic lixiviating solution:
Above-mentioned just compound adds the lixiviating solution of organic matter, accounts for 35-45wt% in organic lixiviating solution, ratio that above-mentioned just compound accounts for 55-65wt% mixes；The lixiviating solution that the organic matter that the lixiviating solution of above-mentioned organic matter adopts weight ratio to be 1:2-4 obtains with water soaking for 7 days；Above-mentioned organic one or more the combination adopted in leaf of Caulis Sacchari sinensis, Folium Bambusae, bamboo stem, Caulis et Folium Oryzae；
Four, ferment old:
The compound that above-mentioned just compound and organic lixiviating solution mix is placed in open containers and ferments old 60-100 days in outdoor elements, namely obtain bone jade porcelain pug.
2. the preparation method of bone jade porcelain pug according to claim 1, it is characterised in that: in the above-mentioned step B preparing bone meal, with ball milling, above-mentioned initial bone piece is processed into the refinement pulp that granularity is 250-300 order by forging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310360521.3A CN103435328B (en) | 2013-08-16 | 2013-08-16 | Pug of bone jade porcelain and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310360521.3A CN103435328B (en) | 2013-08-16 | 2013-08-16 | Pug of bone jade porcelain and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103435328A CN103435328A (en) | 2013-12-11 |
| CN103435328B true CN103435328B (en) | 2016-07-06 |
Family
ID=49689078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310360521.3A Active CN103435328B (en) | 2013-08-16 | 2013-08-16 | Pug of bone jade porcelain and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103435328B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104150878B (en) * | 2014-08-25 | 2015-08-05 | 井冈山市恒华陶瓷有限责任公司 | A kind of high whiteness sclerotin pottery |
| CN106187080A (en) * | 2016-07-19 | 2016-12-07 | 陈毅忠 | A kind of preparation method of anti-thermal shock Bone China blank |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045629A (en) * | 2007-03-16 | 2007-10-03 | 江苏高淳陶瓷股份有限公司 | Iolite cellular ceramic and preparation method |
| CN101544491A (en) * | 2008-08-28 | 2009-09-30 | 郑小凌 | Pug formula of bone porcelain and preparation technology thereof |
-
2013
- 2013-08-16 CN CN201310360521.3A patent/CN103435328B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045629A (en) * | 2007-03-16 | 2007-10-03 | 江苏高淳陶瓷股份有限公司 | Iolite cellular ceramic and preparation method |
| CN101544491A (en) * | 2008-08-28 | 2009-09-30 | 郑小凌 | Pug formula of bone porcelain and preparation technology thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103435328A (en) | 2013-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106146027B (en) | Using steel slag as foamed ceramics walling of raw material and preparation method thereof | |
| CN102815965B (en) | Porous ceramsite made of low-silicon iron tailings and preparation method of porous ceramsite | |
| CN107935555B (en) | Nickel iron slag ceramic and preparation method thereof | |
| CN102180659A (en) | Talcum building ceramic brick and manufacturing method thereof | |
| CN107216127A (en) | Dehua pearl white porcelain and its preparation technology | |
| CN102976644B (en) | Moderate-heat silicate cement clinker and production method thereof | |
| CN109279615B (en) | A kind of preparation method of the high whiteness calcination of talc of low cost | |
| CN102701638B (en) | Gypsum retarder and preparation method thereof | |
| CN109133855A (en) | Low temperature light ceramics and its preparation process | |
| CN101481250A (en) | Preparation of light forsterite raw material | |
| CN102531649B (en) | Preparation method for periclase composite spinel brick used for cement kiln clinkering zone | |
| CN102701759B (en) | Pleonaste brick | |
| CN103435328B (en) | Pug of bone jade porcelain and preparation method thereof | |
| CN106565204A (en) | High-performance red-slurry ceramic product and preparation method thereof | |
| CN102674808A (en) | High-toughness composite matte ceramic product and manufacturing method thereof | |
| CN105777069A (en) | Medical stone life-nourishing ceramic mud and method for manufacturing ceramic product from medical stone life-nourishing ceramic mud | |
| CN107902966A (en) | A kind of unburned red mud porcelain granule mixture and preparation method thereof | |
| CN103395817B (en) | Preparation method of high-purity anhydrous calcium sulfate | |
| CN104496433A (en) | High-strength ceramic mainly prepared from tungsten tailings and preparation method of high-strength ceramic | |
| CN102849968A (en) | Method for preparing Portland cement clinker by using vanadium extraction tail-slag | |
| CN102295467A (en) | Method for preparing light ceramic particle from pyrite cinder | |
| JP2013510785A (en) | Secondary synthesis of calcium sulfoaluminate minerals in Portland cement clinker | |
| CN101462837B (en) | Method for producing cement clinker | |
| CN104496231B (en) | A kind of method utilizing red mud and the clay standby high ferro Alite-barium calcium sulphoaluminate of barium | |
| CN103833331B (en) | Method for preparing ceramic tile from high-aluminum fly ash |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |