CN103434300B - Anti-fake bill allowing codes to be changeable - Google Patents
Anti-fake bill allowing codes to be changeable Download PDFInfo
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- CN103434300B CN103434300B CN201310383829.XA CN201310383829A CN103434300B CN 103434300 B CN103434300 B CN 103434300B CN 201310383829 A CN201310383829 A CN 201310383829A CN 103434300 B CN103434300 B CN 103434300B
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Abstract
An anti-fake bill allowing codes to be changeable comprises an upper bill paper layer 1 and a lower bill paper layer 2, wherein a chip groove 4 and an annular frame groove 5 are formed in the upper portion of the lower bill paper layer 2, a chip 3 is arranged in the chip groove 4, a metal frame 6 is arranged in the frame groove 5, and the space between the frame groove 5 and the metal frame 6 is filled with a glue strip 7. The glue strip 7 is composed of, part by weight, 60-70 parts of methacrylic acid, 5-20 parts of acrylic acid, 20-30 parts of diethylene glycol, 3-6 parts of benzoyl, 0.5-2 parts of methyl toluidine, 0.1-0.3 part of benzoquinone, 2-4 parts of xylopropamine, 1-4 parts of dicumyl peroxide, 0.1-0.5 part of saccharin, 3-6 parts of triethylamine, 0.1-0.3 part of white carbon black, 1-4 parts of ethyl acetate, 0.5-3 parts of propylgallate, 0.3-0.9 part of p-benzoquinone dioxime, 1-3 parts of polysulfone resin and 0.2-0.6 part of 8-hydroxyquinoline. The metal frame serves as a support in the bill, the chip is located in the space defined by the metal frame in an enclosed mode, external force on the bill is resisted, the bill is prevented from being bent to be deformed or damaged, and completeness of the chip is guaranteed.
Description
Technical field
The present invention relates to a kind of ticket, is exactly a kind of variable cipher false proof bill.
Background technology
Password is a kind of important safety anti-fake means of bill, and password is general to be changed according to the human needs that takes ticket.For the ease of conversion password, in bill, insert chip, by scan mode read-write chip content thus change password.In carrying process, be easily bent breakage in existing bill, chip thus destroyed, the antifalse effect of bill disappears, and even cannot use; Chip is inserted in bill, is bondd by chip circumference glue-line, and existing glue-line adopts heat bonding, and high temperature easily causes certain damage to chip, affects the service life of chip; Easily there is gap in glue-line, makes the moisture in air enter in chip, to chip corrosion, causes chip to reduce service life.
Summary of the invention
The object of this invention is to provide a kind of variable cipher false proof bill, can solve the problem.
The present invention for achieving the above object, be achieved through the following technical solutions: variable cipher false proof bill, comprise upper strata check paper 1 and lower floor's check paper 2, the skeleton grooves 5 of chip groove 4 and annular is offered on lower floor's check paper 2 top, chip 3 is set in chip groove 4, metallic framework 6 is set in skeleton grooves 5, gum filler 7 between skeleton grooves 5 and metallic framework 6, described adhesive tape 7 is made up of the raw material of following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part.
In order to realize object of the present invention further, can also by the following technical solutions: the material of described metallic framework 6 is copper, iron, aluminium or alloy.
Described packing 7 manufacturing process comprises the steps: 1. raw material to be prepared raw material according to following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part, 2. methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part are added in reactor, then add toluene and the concentrated sulfuric acid, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction, add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant, 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 130-140kPa, insulation reaction 1-2h, 30 DEG C are cooled to again in 30min, reaction pressure is 80-90kPa, insulation reaction 0.5-1h, obtains reactant mixture, 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
Described packing 7 is made up of the raw material of following weight parts: methacrylic acid 60 parts, 10 parts, acrylic acid, diglycol 30 parts, benzoyl 3 parts, dimethylaniline 1 part, benzoquinones 0.3 part, xylopropamine 2 parts, cumyl peroxide 3 parts, 0.1 part, asccharin, triethylamine 4 parts, white carbon 0.3 part, 1 part, ethyl acetate, n-propyl gallate 1.5 parts, parabenzoquinone dioxime 0.9 part, polysulfone resin 1 part, oxine 0.4 part.
Described packing 7 is made up of the raw material of following weight parts: methacrylic acid 65 parts, 20 parts, acrylic acid, diglycol 20 parts, benzoyl 5 parts, dimethylaniline 2 parts, benzoquinones 0.1 part, xylopropamine 3 parts, cumyl peroxide 4 parts, 0.3 part, asccharin, triethylamine 6 parts, white carbon 0.1 part, 3 parts, ethyl acetate, n-propyl gallate 3 parts, parabenzoquinone dioxime 0.3 part, polysulfone resin 2 parts, oxine 0.6 part.
Described packing 7 is made up of the raw material of following weight parts: methacrylic acid 70 parts, 5 parts, acrylic acid, diglycol 25 parts, benzoyl 6 parts, dimethylaniline 0.5 part, benzoquinones 0.2 part, xylopropamine 4 parts, cumyl peroxide 1 part, 0.5 part, asccharin, triethylamine 3 parts, white carbon 0.2 part, 4 parts, ethyl acetate, n-propyl gallate 0.5 part, parabenzoquinone dioxime 0.6 part, polysulfone resin 3 parts, oxine 0.2 part.
Described packing 7 is made up of the raw material of following weight parts: described packing 7 manufacturing process comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 60g, acrylic acid 10g, diglycol 30g, benzoyl 3g, dimethylaniline 1g, benzoquinones 0.3g, xylopropamine 2g, cumyl peroxide 3g, asccharin 0.1g, triethylamine 4g, white carbon 0.3g, ethyl acetate 1g, n-propyl gallate 1.5g, parabenzoquinone dioxime 0.9g, polysulfone resin 1g, oxine 0.4g, 2. methacrylic acid 60g, acrylic acid 10g, diglycol 30g are added in reactor, then add toluene 100g and concentrated sulfuric acid 30g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction, add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant, 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 140kPa, insulation reaction 1h, 30 DEG C are cooled to again in 30min, reaction pressure is 80kPa, insulation reaction 0.5h, obtains reactant mixture, 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
Described packing 7 is made up of the raw material of following weight parts: described packing 7 manufacturing process comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 65g, acrylic acid 20g, diglycol 20g, benzoyl 5g, dimethylaniline 2g, benzoquinones 0.1g, xylopropamine 3g, cumyl peroxide 4g, asccharin 0.3g, triethylamine 6g, white carbon 0.1g, ethyl acetate 3g, n-propyl gallate 3g, parabenzoquinone dioxime 0.3g, polysulfone resin 2g, oxine 0.6g, 2. methacrylic acid 65g, acrylic acid 20g, diglycol 20g are added in reactor, then add toluene 120g and concentrated sulfuric acid 35g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction, add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant, 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 130kPa, insulation reaction 2h, 30 DEG C are cooled to again in 30min, reaction pressure is 90kPa, insulation reaction 1h, obtains reactant mixture, 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
Described packing 7 is made up of the raw material of following weight parts: described packing 7 manufacturing process comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 70g, acrylic acid 5g, diglycol 25g, benzoyl 6g, dimethylaniline 0.5g, benzoquinones 0.2g, xylopropamine 4g, cumyl peroxide 1g, asccharin 0.5g, triethylamine 3g, white carbon 0.2g, ethyl acetate 4g, n-propyl gallate 0.5g, parabenzoquinone dioxime 0.6g, polysulfone resin 3g, oxine 0.2g, 2. methacrylic acid 70g, acrylic acid 5g, diglycol 25g are added in reactor, then add toluene 130g and concentrated sulfuric acid 40g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction, add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant, 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 135kPa, insulation reaction 1.5h, 30 DEG C are cooled to again in 30min, reaction pressure is 85kPa, insulation reaction 0.8h, obtains reactant mixture, 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.。
The invention has the advantages that: bill inner by metallic framework as support, the scope making chip be positioned at metallic framework to surround, keeps out the effect of external force to bill, prevents bill from bending distortion or damaged, ensures the complete of chip.In process, chip and metallic framework are inserted in corresponding groove, gum filler in skeleton grooves, after sealing, in the environment of Metal Contact and anaerobic, extrude adhesive tape, adhesive tape by liquid rapid solidification, by upper strata check paper and lower floor's check paper close adhesion, what can complete chip at normal temperatures inserts work, keeps the stability of chip; Adhesive tape is by chip as in the environment sealed, and avoid the steam in air to enter to chip corrosion in chip, available protecting chip, increases the service life.Each component synergy of adhesive tape, with the state of Metal Contact and anaerobic under extrude adhesive tape, meet above-mentioned three requirements, adhesive tape namely can rapid solidification, and gas and steam can be avoided after solidification to pass through adhesive tape; Adhesive tape packing and storing material adopts any nonmetallic materials, and packing and storing is convenient.The present invention also has advantage compact, cheap for manufacturing cost and easy to use simple for structure.Manufacture craft each raw material under cryogenic high pressure of adhesive tape fully reacts fusion, adds the speed of fast response, reduces the reaction time; Under low-temp low-pressure condition, each material performance tends towards stability, and makes the species distribution that mixed even; Extrusion process ventilation can reduce the activity of adhesive tape, non-liquid condition all the time before ensureing to use, easy to use.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention; Fig. 2 be Fig. 1 look up structural representation.
Reference numeral: 1 upper strata check paper 2 lower floor check paper 3 chip 4 chip groove 5 skeleton grooves 6 metallic framework 7 adhesive tape.
Detailed description of the invention
Variable cipher false proof bill, as depicted in figs. 1 and 2, comprise upper strata check paper 1 and lower floor's check paper 2, the skeleton grooves 5 of chip groove 4 and annular is offered on lower floor's check paper 2 top, chip 3 is set in chip groove 4, metallic framework 6 is set in skeleton grooves 5, gum filler 7 between skeleton grooves 5 and metallic framework 6, described adhesive tape 7 is made up of the raw material of following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part.The material of described metallic framework 6 is copper, iron, aluminium or alloy.
Described adhesive tape 7 is made up of the raw material of the weight portion of following embodiment:
1. methacrylic acid 60 parts, 10 parts, acrylic acid, diglycol 30 parts, benzoyl 3 parts, dimethylaniline 1 part, benzoquinones 0.3 part, xylopropamine 2 parts, cumyl peroxide 3 parts, 0.1 part, asccharin, triethylamine 4 parts, white carbon 0.3 part, 1 part, ethyl acetate, n-propyl gallate 1.5 parts, parabenzoquinone dioxime 0.9 part, polysulfone resin 1 part, oxine 0.4 part.
2. methacrylic acid 65 parts, 20 parts, acrylic acid, diglycol 20 parts, benzoyl 5 parts, dimethylaniline 2 parts, benzoquinones 0.1 part, xylopropamine 3 parts, cumyl peroxide 4 parts, 0.3 part, asccharin, triethylamine 6 parts, white carbon 0.1 part, 3 parts, ethyl acetate, n-propyl gallate 3 parts, parabenzoquinone dioxime 0.3 part, polysulfone resin 2 parts, oxine 0.6 part.
3. methacrylic acid 70 parts, 5 parts, acrylic acid, diglycol 25 parts, benzoyl 6 parts, dimethylaniline 0.5 part, benzoquinones 0.2 part, xylopropamine 4 parts, cumyl peroxide 1 part, 0.5 part, asccharin, triethylamine 3 parts, white carbon 0.2 part, 4 parts, ethyl acetate, n-propyl gallate 0.5 part, parabenzoquinone dioxime 0.6 part, polysulfone resin 3 parts, oxine 0.2 part.
Packing 7 manufacturing process of described embodiment one comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 60g, acrylic acid 10g, diglycol 30g, benzoyl 3g, dimethylaniline 1g, benzoquinones 0.3g, xylopropamine 2g, cumyl peroxide 3g, asccharin 0.1g, triethylamine 4g, white carbon 0.3g, ethyl acetate 1g, n-propyl gallate 1.5g, parabenzoquinone dioxime 0.9g, polysulfone resin 1g, oxine 0.4g; 2. methacrylic acid 60g, acrylic acid 10g, diglycol 30g are added in reactor, then add toluene 100g and concentrated sulfuric acid 30g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction; Add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant; 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 140kPa, insulation reaction 1h, 30 DEG C are cooled to again in 30min, reaction pressure is 80kPa, insulation reaction 0.5h, obtains reactant mixture; 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
Packing 7 manufacturing process of described embodiment two comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 65g, acrylic acid 20g, diglycol 20g, benzoyl 5g, dimethylaniline 2g, benzoquinones 0.1g, xylopropamine 3g, cumyl peroxide 4g, asccharin 0.3g, triethylamine 6g, white carbon 0.1g, ethyl acetate 3g, n-propyl gallate 3g, parabenzoquinone dioxime 0.3g, polysulfone resin 2g, oxine 0.6g; 2. methacrylic acid 65g, acrylic acid 20g, diglycol 20g are added in reactor, then add toluene 120g and concentrated sulfuric acid 35g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction; Add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant; 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 130kPa, insulation reaction 2h, 30 DEG C are cooled to again in 30min, reaction pressure is 90kPa, insulation reaction 1h, obtains reactant mixture; 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
Packing 7 manufacturing process of described embodiment three comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 70g, acrylic acid 5g, diglycol 25g, benzoyl 6g, dimethylaniline 0.5g, benzoquinones 0.2g, xylopropamine 4g, cumyl peroxide 1g, asccharin 0.5g, triethylamine 3g, white carbon 0.2g, ethyl acetate 4g, n-propyl gallate 0.5g, parabenzoquinone dioxime 0.6g, polysulfone resin 3g, oxine 0.2g; 2. methacrylic acid 70g, acrylic acid 5g, diglycol 25g are added in reactor, then add toluene 130g and concentrated sulfuric acid 40g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction; Add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant; 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 135kPa, insulation reaction 1.5h, 30 DEG C are cooled to again in 30min, reaction pressure is 85kPa, insulation reaction 0.8h, obtains reactant mixture; 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
Technical scheme of the present invention is not restricted in the scope of embodiment of the present invention.The technology contents of the not detailed description of the present invention is known technology.
Claims (8)
1. variable cipher false proof bill, it is characterized in that: comprise upper strata check paper (1) and lower floor's check paper (2), the skeleton grooves (5) of chip groove (4) and annular is offered on lower floor's check paper (2) top, chip (3) is set in chip groove (4), metallic framework (6) is set in skeleton grooves (5), gum filler (7) between skeleton grooves (5) and metallic framework (6), described adhesive tape (7) is made up of the raw material of following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part, described adhesive tape (7) manufacturing process comprises the steps: 1. raw material to be prepared raw material according to following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part, 2. methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part are added in reactor, then add toluene and the concentrated sulfuric acid, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction, add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant, 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 130-140kPa, insulation reaction 1-2h, 30 DEG C are cooled to again in 30min, reaction pressure is 80-90kPa, insulation reaction 0.5-1h, obtains reactant mixture, 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
2. variable cipher false proof bill according to claim 1, is characterized in that: the material of described metallic framework (6) is copper, iron, aluminium or alloy.
3. variable cipher false proof bill according to claim 1, is characterized in that: described adhesive tape (7) is made up of the raw material of following weight parts: methacrylic acid 60 parts, 10 parts, acrylic acid, diglycol 30 parts, benzoyl 3 parts, dimethylaniline 1 part, benzoquinones 0.3 part, xylopropamine 2 parts, cumyl peroxide 3 parts, 0.1 part, asccharin, triethylamine 4 parts, white carbon 0.3 part, 1 part, ethyl acetate, n-propyl gallate 1.5 parts, parabenzoquinone dioxime 0.9 part, polysulfone resin 1 part, oxine 0.4 part.
4. variable cipher false proof bill according to claim 1, is characterized in that: described adhesive tape (7) is made up of the raw material of following weight parts: methacrylic acid 65 parts, 20 parts, acrylic acid, diglycol 20 parts, benzoyl 5 parts, dimethylaniline 2 parts, benzoquinones 0.1 part, xylopropamine 3 parts, cumyl peroxide 4 parts, 0.3 part, asccharin, triethylamine 6 parts, white carbon 0.1 part, 3 parts, ethyl acetate, n-propyl gallate 3 parts, parabenzoquinone dioxime 0.3 part, polysulfone resin 2 parts, oxine 0.6 part.
5. variable cipher false proof bill according to claim 1, is characterized in that: described adhesive tape (7) is made up of the raw material of following weight parts: methacrylic acid 70 parts, 5 parts, acrylic acid, diglycol 25 parts, benzoyl 6 parts, dimethylaniline 0.5 part, benzoquinones 0.2 part, xylopropamine 4 parts, cumyl peroxide 1 part, 0.5 part, asccharin, triethylamine 3 parts, white carbon 0.2 part, 4 parts, ethyl acetate, n-propyl gallate 0.5 part, parabenzoquinone dioxime 0.6 part, polysulfone resin 3 parts, oxine 0.2 part.
6. variable cipher false proof bill according to claim 3, is characterized in that: described adhesive tape (7) manufacturing process comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 60g, acrylic acid 10g, diglycol 30g, benzoyl 3g, dimethylaniline 1g, benzoquinones 0.3g, xylopropamine 2g, cumyl peroxide 3g, asccharin 0.1g, triethylamine 4g, white carbon 0.3g, ethyl acetate 1g, n-propyl gallate 1.5g, parabenzoquinone dioxime 0.9g, polysulfone resin 1g, oxine 0.4g; 2. methacrylic acid 60g, acrylic acid 10g, diglycol 30g are added in reactor, then add toluene 100g and concentrated sulfuric acid 30g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction; Add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant; 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 140kPa, insulation reaction 1h, 30 DEG C are cooled to again in 30min, reaction pressure is 80kPa, insulation reaction 0.5h, obtains reactant mixture; 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
7. variable cipher false proof bill according to claim 4, is characterized in that: described adhesive tape (7) manufacturing process comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 65g, acrylic acid 20g, diglycol 20g, benzoyl 5g, dimethylaniline 2g, benzoquinones 0.1g, xylopropamine 3g, cumyl peroxide 4g, asccharin 0.3g, triethylamine 6g, white carbon 0.1g, ethyl acetate 3g, n-propyl gallate 3g, parabenzoquinone dioxime 0.3g, polysulfone resin 2g, oxine 0.6g; 2. methacrylic acid 65g, acrylic acid 20g, diglycol 20g are added in reactor, then add toluene 120g and concentrated sulfuric acid 35g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction; Add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant; 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 130kPa, insulation reaction 2h, 30 DEG C are cooled to again in 30min, reaction pressure is 90kPa, insulation reaction 1h, obtains reactant mixture; 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
8. variable cipher false proof bill according to claim 5, is characterized in that: described adhesive tape (7) manufacturing process comprises the steps: 1. raw material to be prepared raw material according to following weight: methacrylic acid 70g, acrylic acid 5g, diglycol 25g, benzoyl 6g, dimethylaniline 0.5g, benzoquinones 0.2g, xylopropamine 4g, cumyl peroxide 1g, asccharin 0.5g, triethylamine 3g, white carbon 0.2g, ethyl acetate 4g, n-propyl gallate 0.5g, parabenzoquinone dioxime 0.6g, polysulfone resin 3g, oxine 0.2g; 2. methacrylic acid 70g, acrylic acid 5g, diglycol 25g are added in reactor, then add toluene 130g and concentrated sulfuric acid 40g, heat temperature raising refluxes, and is back to acid number when being less than 10mg KOH/g, stops reaction; Add NaOH solution and regulate pH=7, static layering, isolates and anhydrates, and retains reactant; 3. reactant step 2. obtained and surplus stock add agitator mixing, the rotating speed of agitator is 70r/min: in 30min, be warming up to 70 DEG C again, reaction pressure is 135kPa, insulation reaction 1.5h, 30 DEG C are cooled to again in 30min, reaction pressure is 85kPa, insulation reaction 0.8h, obtains reactant mixture; 4. in reactant mixture step 3. obtained, pass into air, ventilation limit, limit squeezes out finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310383829.XA CN103434300B (en) | 2013-08-29 | 2013-08-29 | Anti-fake bill allowing codes to be changeable |
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| CN201310383829.XA CN103434300B (en) | 2013-08-29 | 2013-08-29 | Anti-fake bill allowing codes to be changeable |
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| CN103434300A CN103434300A (en) | 2013-12-11 |
| CN103434300B true CN103434300B (en) | 2015-04-15 |
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| JP4495295B2 (en) * | 2000-03-15 | 2010-06-30 | 株式会社日立製作所 | Method for preventing unauthorized use of securities and system for preventing unauthorized use of securities |
| JP2005149360A (en) * | 2003-11-19 | 2005-06-09 | Dainippon Printing Co Ltd | Ic card for sim |
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| CN1560166A (en) * | 2004-03-11 | 2005-01-05 | 萍 刘 | UV solidifying pressure sensitive coating capable of stripping and preparation process thereof |
| CN101768419A (en) * | 2008-12-31 | 2010-07-07 | 上海康达化工有限公司 | Non-solvent polyurethane laminating adhesive with high initial stick force and preparation method and application thereof |
| CN202189391U (en) * | 2011-07-25 | 2012-04-11 | 上海东港安全印刷有限公司 | Automatic identification false proof printing bill |
| CN202650051U (en) * | 2012-06-20 | 2013-01-02 | 郑州东港安全印刷有限公司 | Password bill capable of identifying automatically |
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| CN202685602U (en) * | 2012-07-23 | 2013-01-23 | 北京东港安全印刷有限公司 | Magnetic anti-counterfeiting financial bill |
| CN202995773U (en) * | 2012-12-06 | 2013-06-12 | 合肥进毅智能技术有限公司 | Bank bill voucher possessing anti-fake function |
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