CN103434300A - Anti-fake bill allowing codes to be changeable - Google Patents
Anti-fake bill allowing codes to be changeable Download PDFInfo
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- CN103434300A CN103434300A CN201310383829XA CN201310383829A CN103434300A CN 103434300 A CN103434300 A CN 103434300A CN 201310383829X A CN201310383829X A CN 201310383829XA CN 201310383829 A CN201310383829 A CN 201310383829A CN 103434300 A CN103434300 A CN 103434300A
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Abstract
An anti-fake bill allowing codes to be changeable comprises an upper bill paper layer 1 and a lower bill paper layer 2, wherein a chip groove 4 and an annular frame groove 5 are formed in the upper portion of the lower bill paper layer 2, a chip 3 is arranged in the chip groove 4, a metal frame 6 is arranged in the frame groove 5, and the space between the frame groove 5 and the metal frame 6 is filled with a glue strip 7. The glue strip 7 is composed of, part by weight, 60-70 parts of methacrylic acid, 5-20 parts of acrylic acid, 20-30 parts of diethylene glycol, 3-6 parts of benzoyl, 0.5-2 parts of methyl toluidine, 0.1-0.3 part of benzoquinone, 2-4 parts of xylopropamine, 1-4 parts of dicumyl peroxide, 0.1-0.5 part of saccharin, 3-6 parts of triethylamine, 0.1-0.3 part of white carbon black, 1-4 parts of ethyl acetate, 0.5-3 parts of propylgallate, 0.3-0.9 part of p-benzoquinone dioxime, 1-3 parts of polysulfone resin and 0.2-0.6 part of 8-hydroxyquinoline. The metal frame serves as a support in the bill, the chip is located in the space defined by the metal frame in an enclosed mode, external force on the bill is resisted, the bill is prevented from being bent to be deformed or damaged, and completeness of the chip is guaranteed.
Description
Technical field
The present invention relates to a kind of ticket, is exactly a kind of variable cipher false proof bill.
Background technology
Password is a kind of important safety anti-fake means of bill, and password is general to be changed according to the human needs that takes ticket.For the ease of the conversion password, insert chip in bill, thereby change password by scan mode read-write chip content.Easily be bent breakage in existing bill in carrying process, thereby chip is destroyed, the antifalse effect of bill disappears, and even can't use; Chip is inserted in bill, will around chip, with glue-line, bond, and existing glue-line adopts heat bonding, and high temperature easily causes certain damage to chip, affects the service life of chip; Gap easily appears in glue-line, and airborne moisture is entered in chip, to the chip corrosion, causes chip to reduce service life.
Summary of the invention
The purpose of this invention is to provide a kind of variable cipher false proof bill, can address the above problem.
The present invention for achieving the above object, be achieved through the following technical solutions: the variable cipher false proof bill, comprise upper strata check paper 1 and lower floor's check paper 2, chip groove 4 and annular skeleton grooves 5 are offered in lower floor's check paper 2 tops, the interior chip 3 that arranges of chip groove 4, the interior metallic framework 6 that arranges of skeleton grooves 5, gum filler 7 between skeleton grooves 5 and metallic framework 6, described adhesive tape 7 is comprised of the raw material of following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part.
In order further to realize purpose of the present invention, can also be by the following technical solutions: the material of described metallic framework 6 be copper, iron, aluminium or alloy.
Described packing 7 manufacturing process comprise the steps: 1. raw material to be prepared to raw material according to following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part, 2. methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part are added in reactor, then add toluene and the concentrated sulfuric acid, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction, add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant, 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 130-140kPa, insulation reaction 1-2h, be cooled to again 30 ℃ in 30min, reaction pressure is 80-90kPa, and insulation reaction 0.5-1h, obtain reactant mixture, 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
Described packing 7 is comprised of the raw material of following weight parts: 60 parts of methacrylic acids, 10 parts, acrylic acid, 30 parts of diglycols, 3 parts of benzoyls, 1 part of dimethylaniline, 0.3 part of benzoquinones, 2 parts of xylopropamines, 3 parts of cumyl peroxides, 0.1 part, asccharin, 4 parts of triethylamines, 0.3 part of white carbon, 1 part, ethyl acetate, 1.5 parts of n-propyl gallates, 0.9 part of parabenzoquinone dioxime, 1 part of polysulfone resin, 0.4 part of oxine.
Described packing 7 is comprised of the raw material of following weight parts: 65 parts of methacrylic acids, 20 parts, acrylic acid, 20 parts of diglycols, 5 parts of benzoyls, 2 parts of dimethylanilines, 0.1 part of benzoquinones, 3 parts of xylopropamines, 4 parts of cumyl peroxides, 0.3 part, asccharin, 6 parts of triethylamines, 0.1 part of white carbon, 3 parts, ethyl acetate, 3 parts of n-propyl gallates, 0.3 part of parabenzoquinone dioxime, 2 parts of polysulfone resins, 0.6 part of oxine.
Described packing 7 is comprised of the raw material of following weight parts: 70 parts of methacrylic acids, 5 parts, acrylic acid, 25 parts of diglycols, 6 parts of benzoyls, 0.5 part of dimethylaniline, 0.2 part of benzoquinones, 4 parts of xylopropamines, 1 part of cumyl peroxide, 0.5 part, asccharin, 3 parts of triethylamines, 0.2 part of white carbon, 4 parts, ethyl acetate, 0.5 part of n-propyl gallate, 0.6 part of parabenzoquinone dioxime, 3 parts of polysulfone resins, 0.2 part of oxine.
Described packing 7 is comprised of the raw material of following weight parts: described packing 7 manufacturing process comprise the steps: 1. raw material to be prepared to raw material according to following weight: methacrylic acid 60g, acrylic acid 10g, diglycol 30g, benzoyl 3g, dimethylaniline 1g, benzoquinones 0.3g, xylopropamine 2g, cumyl peroxide 3g, asccharin 0.1g, triethylamine 4g, white carbon 0.3g, ethyl acetate 1g, n-propyl gallate 1.5g, parabenzoquinone dioxime 0.9g, polysulfone resin 1g, oxine 0.4g, 2. methacrylic acid 60g, acrylic acid 10g, diglycol 30g are added in reactor, then add toluene 100g and concentrated sulfuric acid 30g, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction, add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant, 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 140kPa, insulation reaction 1h, be cooled to again 30 ℃ in 30min, reaction pressure is 80kPa, and insulation reaction 0.5h, obtain reactant mixture, 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
Described packing 7 is comprised of the raw material of following weight parts: described packing 7 manufacturing process comprise the steps: 1. raw material to be prepared to raw material according to following weight: methacrylic acid 65g, acrylic acid 20g, diglycol 20g, benzoyl 5g, dimethylaniline 2g, benzoquinones 0.1g, xylopropamine 3g, cumyl peroxide 4g, asccharin 0.3g, triethylamine 6g, white carbon 0.1g, ethyl acetate 3g, n-propyl gallate 3g, parabenzoquinone dioxime 0.3g, polysulfone resin 2g, oxine 0.6g, 2. methacrylic acid 65g, acrylic acid 20g, diglycol 20g are added in reactor, then add toluene 120g and concentrated sulfuric acid 35g, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction, add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant, 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 130kPa, insulation reaction 2h, be cooled to again 30 ℃ in 30min, reaction pressure is 90kPa, and insulation reaction 1h, obtain reactant mixture, 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
Described packing 7 is comprised of the raw material of following weight parts: described packing 7 manufacturing process comprise the steps: 1. raw material to be prepared to raw material according to following weight: methacrylic acid 70g, acrylic acid 5g, diglycol 25g, benzoyl 6g, dimethylaniline 0.5g, benzoquinones 0.2g, xylopropamine 4g, cumyl peroxide 1g, asccharin 0.5g, triethylamine 3g, white carbon 0.2g, ethyl acetate 4g, n-propyl gallate 0.5g, parabenzoquinone dioxime 0.6g, polysulfone resin 3g, oxine 0.2g, 2. methacrylic acid 70g, acrylic acid 5g, diglycol 25g are added in reactor, then add toluene 130g and concentrated sulfuric acid 40g, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction, add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant, 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 135kPa, insulation reaction 1.5h, be cooled to again 30 ℃ in 30min, reaction pressure is 85kPa, and insulation reaction 0.8h, obtain reactant mixture, 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.。
The invention has the advantages that: bill inside as support, makes chip be positioned at the scope that metallic framework surrounds by metallic framework, keeps out the effect of external force to bill, prevents bill bending distortion or damaged, guarantees the complete of chip.In process, chip and metallic framework are inserted in corresponding groove, gum filler in skeleton grooves, after sealing, push adhesive tape in the environment of Metal Contact and anaerobic, adhesive tape is solidified rapidly by liquid, by upper strata check paper and lower floor's check paper close adhesion, can complete at normal temperatures the work of inserting of chip, keep the stability of chip; Adhesive tape in the environment as for sealing, is avoided chip airborne steam enter in chip chip is corroded, and effectively protects chip, increases the service life.Each component synergy of adhesive tape is pushed adhesive tape under the state with Metal Contact and anaerobic, meets above-mentioned three requirements, and adhesive tape can solidify rapidly, after solidifying, can avoid gas and steam to pass through adhesive tape; Adhesive tape packing and storing material adopts any nonmetallic materials to get final product, and packing and storing is convenient.The present invention also has advantages of compactness simple for structure, cheap for manufacturing cost and easy to use.The manufacture craft of adhesive tape is the fully reaction fusion of each raw material under cryogenic high pressure, adds the speed of fast response, reduces the reaction time; Under the low-temp low-pressure condition, each material performance tends towards stability, and makes the species distribution of having mixed even; Extrusion process ventilation can reduce the activity of adhesive tape, and liquid condition not all the time before guaranteeing to use is easy to use.
The accompanying drawing explanation
Fig. 1 is structural representation of the present invention; Fig. 2 is the structural representation of looking up of Fig. 1.
Reference numeral: 1 upper strata check paper 2 lower floor's check paper 3 chip 4 chip groove 5 skeleton grooves 6 metallic framework 7 adhesive tape.
The specific embodiment
The variable cipher false proof bill, as depicted in figs. 1 and 2, comprise upper strata check paper 1 and lower floor's check paper 2, chip groove 4 and annular skeleton grooves 5 are offered in lower floor's check paper 2 tops, the interior chip 3 that arranges of chip groove 4, the interior metallic framework 6 that arranges of skeleton grooves 5, gum filler 7 between skeleton grooves 5 and metallic framework 6, described adhesive tape 7 is comprised of the raw material of following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part.The material of described metallic framework 6 is copper, iron, aluminium or alloy.
Described adhesive tape 7 is comprised of the raw material of the weight portion of following embodiment:
1. 60 parts of methacrylic acids, 10 parts, acrylic acid, 30 parts of diglycols, 3 parts of benzoyls, 1 part of dimethylaniline, 0.3 part of benzoquinones, 2 parts of xylopropamines, 3 parts of cumyl peroxides, 0.1 part, asccharin, 4 parts of triethylamines, 0.3 part of white carbon, 1 part, ethyl acetate, 1.5 parts of n-propyl gallates, 0.9 part of parabenzoquinone dioxime, 1 part of polysulfone resin, 0.4 part of oxine.
2. 65 parts of methacrylic acids, 20 parts, acrylic acid, 20 parts of diglycols, 5 parts of benzoyls, 2 parts of dimethylanilines, 0.1 part of benzoquinones, 3 parts of xylopropamines, 4 parts of cumyl peroxides, 0.3 part, asccharin, 6 parts of triethylamines, 0.1 part of white carbon, 3 parts, ethyl acetate, 3 parts of n-propyl gallates, 0.3 part of parabenzoquinone dioxime, 2 parts of polysulfone resins, 0.6 part of oxine.
3. 70 parts of methacrylic acids, 5 parts, acrylic acid, 25 parts of diglycols, 6 parts of benzoyls, 0.5 part of dimethylaniline, 0.2 part of benzoquinones, 4 parts of xylopropamines, 1 part of cumyl peroxide, 0.5 part, asccharin, 3 parts of triethylamines, 0.2 part of white carbon, 4 parts, ethyl acetate, 0.5 part of n-propyl gallate, 0.6 part of parabenzoquinone dioxime, 3 parts of polysulfone resins, 0.2 part of oxine.
Packing 7 manufacturing process of described embodiment mono-comprise the steps: 1. raw material to be prepared to raw material according to following weight: methacrylic acid 60g, acrylic acid 10g, diglycol 30g, benzoyl 3g, dimethylaniline 1g, benzoquinones 0.3g, xylopropamine 2g, cumyl peroxide 3g, asccharin 0.1g, triethylamine 4g, white carbon 0.3g, ethyl acetate 1g, n-propyl gallate 1.5g, parabenzoquinone dioxime 0.9g, polysulfone resin 1g, oxine 0.4g; 2. methacrylic acid 60g, acrylic acid 10g, diglycol 30g are added in reactor, then add toluene 100g and concentrated sulfuric acid 30g, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction; Add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant; 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 140kPa, insulation reaction 1h, be cooled to again 30 ℃ in 30min, reaction pressure is 80kPa, and insulation reaction 0.5h, obtain reactant mixture; 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
Packing 7 manufacturing process of described embodiment bis-comprise the steps: 1. raw material to be prepared to raw material according to following weight: methacrylic acid 65g, acrylic acid 20g, diglycol 20g, benzoyl 5g, dimethylaniline 2g, benzoquinones 0.1g, xylopropamine 3g, cumyl peroxide 4g, asccharin 0.3g, triethylamine 6g, white carbon 0.1g, ethyl acetate 3g, n-propyl gallate 3g, parabenzoquinone dioxime 0.3g, polysulfone resin 2g, oxine 0.6g; 2. methacrylic acid 65g, acrylic acid 20g, diglycol 20g are added in reactor, then add toluene 120g and concentrated sulfuric acid 35g, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction; Add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant; 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 130kPa, insulation reaction 2h, be cooled to again 30 ℃ in 30min, reaction pressure is 90kPa, and insulation reaction 1h, obtain reactant mixture; 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
Technical scheme of the present invention is not restricted in the scope of embodiment of the present invention.The present invention not technology contents of detailed description is known technology.
Claims (9)
1. variable cipher false proof bill, it is characterized in that: comprise upper strata check paper (1) and lower floor's check paper (2), chip groove (4) and annular skeleton grooves (5) are offered in lower floor's check paper (2) top, chip (3) is set in chip groove (4), metallic framework (6) is set in skeleton grooves (5), gum filler (7) between skeleton grooves (5) and metallic framework (6), described adhesive tape (7) is comprised of the raw material of following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part.
2. variable cipher false proof bill according to claim 1, it is characterized in that: the material of described metallic framework (6) is copper, iron, aluminium or alloy.
3. variable cipher false proof bill according to claim 1, it is characterized in that: described packing (7) manufacturing process comprises the steps: 1. raw material to be prepared to raw material according to following weight parts: methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part, benzoyl 3-6 part, dimethylaniline 0.5-2 part, benzoquinones 0.1-0.3 part, xylopropamine 2-4 part, cumyl peroxide 1-4 part, asccharin 0.1-0.5 part, triethylamine 3-6 part, white carbon 0.1-0.3 part, ethyl acetate 1-4 part, n-propyl gallate 0.5-3 part, parabenzoquinone dioxime 0.3-0.9 part, polysulfone resin 1-3 part, oxine 0.2-0.6 part, 2. methacrylic acid 60-70 part, acrylic acid 5-20 part, diglycol 20-30 part are added in reactor, then add toluene and the concentrated sulfuric acid, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction, add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant, 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 130-140kPa, insulation reaction 1-2h, be cooled to again 30 ℃ in 30min, reaction pressure is 80-90kPa, and insulation reaction 0.5-1h, obtain reactant mixture, 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
4. variable cipher false proof bill according to claim 1, it is characterized in that: described packing (7) is comprised of the raw material of following weight parts: 60 parts of methacrylic acids, 10 parts, acrylic acid, 30 parts of diglycols, 3 parts of benzoyls, 1 part of dimethylaniline, 0.3 part of benzoquinones, 2 parts of xylopropamines, 3 parts of cumyl peroxides, 0.1 part, asccharin, 4 parts of triethylamines, 0.3 part of white carbon, 1 part, ethyl acetate, 1.5 parts of n-propyl gallates, 0.9 part of parabenzoquinone dioxime, 1 part of polysulfone resin, 0.4 part of oxine.
5. variable cipher false proof bill according to claim 1, it is characterized in that: described packing (7) is comprised of the raw material of following weight parts: 65 parts of methacrylic acids, 20 parts, acrylic acid, 20 parts of diglycols, 5 parts of benzoyls, 2 parts of dimethylanilines, 0.1 part of benzoquinones, 3 parts of xylopropamines, 4 parts of cumyl peroxides, 0.3 part, asccharin, 6 parts of triethylamines, 0.1 part of white carbon, 3 parts, ethyl acetate, 3 parts of n-propyl gallates, 0.3 part of parabenzoquinone dioxime, 2 parts of polysulfone resins, 0.6 part of oxine.
6. variable cipher false proof bill according to claim 1, it is characterized in that: described packing (7) is comprised of the raw material of following weight parts: 70 parts of methacrylic acids, 5 parts, acrylic acid, 25 parts of diglycols, 6 parts of benzoyls, 0.5 part of dimethylaniline, 0.2 part of benzoquinones, 4 parts of xylopropamines, 1 part of cumyl peroxide, 0.5 part, asccharin, 3 parts of triethylamines, 0.2 part of white carbon, 4 parts, ethyl acetate, 0.5 part of n-propyl gallate, 0.6 part of parabenzoquinone dioxime, 3 parts of polysulfone resins, 0.2 part of oxine.
7. variable cipher false proof bill according to claim 4, it is characterized in that: described packing (7) is comprised of the raw material of following weight parts: described packing 7 manufacturing process comprise the steps: 1. raw material to be prepared to raw material according to following weight: methacrylic acid 60g, acrylic acid 10g, diglycol 30g, benzoyl 3g, dimethylaniline 1g, benzoquinones 0.3g, xylopropamine 2g, cumyl peroxide 3g, asccharin 0.1g, triethylamine 4g, white carbon 0.3g, ethyl acetate 1g, n-propyl gallate 1.5g, parabenzoquinone dioxime 0.9g, polysulfone resin 1g, oxine 0.4g, 2. methacrylic acid 60g, acrylic acid 10g, diglycol 30g are added in reactor, then add toluene 100g and concentrated sulfuric acid 30g, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction, add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant, 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 140kPa, insulation reaction 1h, be cooled to again 30 ℃ in 30min, reaction pressure is 80kPa, and insulation reaction 0.5h, obtain reactant mixture, 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
8. variable cipher false proof bill according to claim 5, it is characterized in that: described packing (7) is comprised of the raw material of following weight parts: described packing 7 manufacturing process comprise the steps: 1. raw material to be prepared to raw material according to following weight: methacrylic acid 65g, acrylic acid 20g, diglycol 20g, benzoyl 5g, dimethylaniline 2g, benzoquinones 0.1g, xylopropamine 3g, cumyl peroxide 4g, asccharin 0.3g, triethylamine 6g, white carbon 0.1g, ethyl acetate 3g, n-propyl gallate 3g, parabenzoquinone dioxime 0.3g, polysulfone resin 2g, oxine 0.6g, 2. methacrylic acid 65g, acrylic acid 20g, diglycol 20g are added in reactor, then add toluene 120g and concentrated sulfuric acid 35g, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction, add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant, 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 130kPa, insulation reaction 2h, be cooled to again 30 ℃ in 30min, reaction pressure is 90kPa, and insulation reaction 1h, obtain reactant mixture, 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
9. variable cipher false proof bill according to claim 6, it is characterized in that: described packing (7) is comprised of the raw material of following weight parts: described packing 7 manufacturing process comprise the steps: 1. raw material to be prepared to raw material according to following weight: methacrylic acid 70g, acrylic acid 5g, diglycol 25g, benzoyl 6g, dimethylaniline 0.5g, benzoquinones 0.2g, xylopropamine 4g, cumyl peroxide 1g, asccharin 0.5g, triethylamine 3g, white carbon 0.2g, ethyl acetate 4g, n-propyl gallate 0.5g, parabenzoquinone dioxime 0.6g, polysulfone resin 3g, oxine 0.2g, 2. methacrylic acid 70g, acrylic acid 5g, diglycol 25g are added in reactor, then add toluene 130g and concentrated sulfuric acid 40g, heat temperature raising refluxes, and when being back to acid number and being less than 10mg KOH/g, stops reaction, add NaOH solution to regulate pH=7, static layering, isolate and anhydrate, and retains reactant, 3. the reactant 2. step obtained and surplus stock add agitator to mix, the rotating speed of agitator is 70r/min: be warming up to 70 ℃ in 30min again, reaction pressure is 135kPa, insulation reaction 1.5h, be cooled to again 30 ℃ in 30min, reaction pressure is 85kPa, and insulation reaction 0.8h, obtain reactant mixture, 4. pass into air in the reactant mixture that 3. step is obtained, ventilation limit, limit squeezes out finished product.
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| CN201310383829.XA CN103434300B (en) | 2013-08-29 | 2013-08-29 | Anti-fake bill allowing codes to be changeable |
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| CN201310383829.XA CN103434300B (en) | 2013-08-29 | 2013-08-29 | Anti-fake bill allowing codes to be changeable |
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