CN103429219A - Process for producing a conditioning cleaning agent - Google Patents
Process for producing a conditioning cleaning agent Download PDFInfo
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- CN103429219A CN103429219A CN201280012285XA CN201280012285A CN103429219A CN 103429219 A CN103429219 A CN 103429219A CN 201280012285X A CN201280012285X A CN 201280012285XA CN 201280012285 A CN201280012285 A CN 201280012285A CN 103429219 A CN103429219 A CN 103429219A
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-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/068—Microemulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Abstract
The invention relates to a process for producing a conditioning cleaning agent, comprising the following steps: a) providing a microemulsion, containing (i) at least one alkyl(oligo)glycoside, (ii) at least one ester of glycerin with at least one C10-C24 fatty acid, (iii) at least one oil which is different from (ii), and (iv) water, and b) mixing the microemulsion with a cosmetic carrier that contains at least one polyhydroxy compound of formula (I), in which the radicals R1, R2, independently of one another, represent a hydrogen atom, a C1-C4 alkyl group or a phenyl group or each of them for alkylene groups, which are constituents of a cyclopentane or a cyclohexane ring, the radicals R3, R4, independently of one another, represent a hydrogen atom, a hydroxyl group, a C1-C4 alkyl group, a hydroxyalkyl group, a phenyl group or each of them for alkylene groups, which are constituents of a cyclopentane or a cyclohexane ring, the radicals R5, R6, independently of one another, represent a hydrogen atom, a C1-C4 alkyl group or a hydroxyalkyl group, or one of the radicals R5, R6 represents a saturated or unsaturated, branched or unbranched C1-C20 alkyl chain which can be interrupted by one or more ester and/or amide groups and can carry one or more hydroxyl groups, with the proviso that the radicals R3, R4 do not simultaneously represent a hydroxyl group.
Description
The invention belongs to cosmetic field, and relate to and prepare the method for nursing one's health cleaning agent, wherein microemulsion is mixed with the cosmetics carrier that comprises special polyol.
The invention further relates to the conditioning cleaning agent that comprises microemulsion and polyol, and described conditioning cleaning agent for strengthening hair structure, improve the hair organoleptic properties and increase the purposes of hair volume.
The cosmetics hair cleanser is known for a long time, and it often is modified or is adapted to the demand that consumer constantly changes.
For example, due to time, cost and environmental problem, that consumer expects on the hair of modern hair cleanser after clean to stay is lasting, sense of touch and perceptible conditioning effect visually, thereby needn't apply the hair post treatment agent.
The clean residue that is generally understood as undesirable abnormal smells from the patient, dirt, the dandruff, sebum deposition and/or the setting agent of removing hair.
Term " sense of touch and visually perceptible conditioning effect " is interpreted as that hair is level and smooth, is easy to combing, softness, glossy and process (clean) after be easy to finalize the design.In addition, the hair after clean should have the volume of increase.
As everyone knows, the hair-conditioning active substance is joined in hair cleanser with conditioning as described in improving as silicone, oil or wax.
Yet the silicone hair cleanser has following shortcoming usually: in the situation that long-time conventional the use, they make trichoesthesia unhappyly thick and heavy.As a result, thin or damaged hair has especially reduced its volume.
Oil and the effect of wax in hair cleanser do not have the effect of silicone so remarkable.In addition, oil can only be stabilized in hair cleanser with relative little amount with wax, and this makes the preparation of this type of reagent more difficult.
Therefore, in order to make oil and wax component (or silicone) stable in the cosmetic cleaning agent, must be through requiring high-octane processing step or synthetic stabilizing agent adds described cleaning agent by other, this makes the preparation of described reagent is disadvantageous from the economy and environment angle.
Therefore, still need the cleaning agent that can obtain by simple preparation method, described cleaning agent provides conditioning benefit for unappealing hair in vision and sense of touch.
The present invention is based on provides a kind of purpose for preparing the uncomplicated method of nursing one's health cleaning agent.
Described detergent package is containing at least one relatively a large amount of hair-conditioning lipid compositions, do not need to stablize lipid composition described in described cleaning agent required require high-octane step as heating, fusing or pre-dispersed.Do not need equally to add polymerization or the crystallization reagent of stablizing described lipid composition.
Particularly due to chemical treatment or over-exposure, damaged the hair of its structure in UV light, will again have been strengthened by using described cleaning agent, and the tactile properties that will demonstrate improvement is as the elasticity that increases and soft sensation.
Very thin, sparse hair will demonstrate the hair volume of increase after using described cleaning agent.
Another object of the present invention is the transparent cleaning agent of preparation.
The invention provides a kind of method of nursing one's health cleaning agent for preparing, it comprises the steps:
A) provide the microemulsion that comprises following component:
(i) at least one alkyl (oligomeric) glucosides,
(ii) glycerol and at least one C
10-C
24At least one ester of fatty acid,
(iii) at least one oil that is different from (ii), and
(iv) water, and
B) described microemulsion is mixed with cosmetics carrier, the polyol that described cosmetics carrier comprises at least one following formula (I),
Wherein
-described radicals R
1, R
2Mean independently of one another hydrogen atom, C
1-C
4Alkyl or phenyl, or in each situation, be the alkylidene of the ingredient of Pentamethylene. ring or cyclohexane ring,
-described radicals R
3, R
4Mean independently of one another hydrogen atom, hydroxyl, C
1-C
4Alkyl, hydroxyalkyl, phenyl or in each situation, be the alkylidene of the ingredient of Pentamethylene. ring or cyclohexane ring,
-described radicals R
5, R
6Mean independently of one another hydrogen atom, C
1-C
4Alkyl or hydroxyalkyl, or described radicals R
5, R
6One of mean saturated or unsaturated, branching or nonbranched C
1-C
20Alkyl chain, described C
1-C
20Alkyl chain can be inserted with one or more esters and/or amide group and can be with one or more hydroxyls,
Condition is described radicals R
3, R
4Mean hydroxyl when different.
Cosmetics carrier preferably is interpreted as aqueous carrier or moisture alcohol carrier.
Described cosmetics carrier preferably comprises the water of at least 40 % by weight.
In addition, described cosmetics carrier can comprise at least one alcohol of 0.01-40 % by weight, preferred 0.05-35 % by weight and particularly 0.1-30 % by weight, and described alcohol can be selected from ethanol, 1-propanol, 2-propanol, isopropyl alcohol, n-butyl alcohol, 2-butanols, 1-amylalcohol, 2-amylalcohol, 1-hexanol, 2-hexanol, benzylalcohol, phenoxyethanol or these pure mixture.
Described water miscible alcohol is preferred.
Particularly preferably be ethanol, 1-propanol, 2-propanol, isopropyl alcohol, benzylalcohol and/or phenoxyethanol and these pure mixture.
According to the method for the invention described component a) and b) mixing in do not require specific order.In principle, can at first the polyol according to formula (I) be provided to suitable carrier, then add wherein described microemulsion.Can be added to described microemulsion according to the carrier of the polyol of formula (I) by comprising at least one equally.
One preferred embodiment in, at first cosmetics carrier as above is provided.Then all optional components of described cleaning agent and at least one are added to described carrier according to the polyol of formula (I), preferably carry out institute in steps by described each component is mixed to (particularly by leniently stirring) with described carrier at ambient temperature.
After adding described microemulsion, enter carrier as above carry out described adding also preferably at ambient temperature by stirring described microemulsion, in each situation by the pH value of described cleaning agent and viscosity adjustment to expected value.
The suitable polyol according to formula (I) preferably with the 0.01-10 % by weight, more preferably the 0.05-7.5 % by weight, particularly preferably the amount of 0.075-5 % by weight and particularly 0.1-3 % by weight is for according to the method for the invention, the gross weight of described quantitative data based on described conditioning cleaning agent.
Preferably according to the polyol of formula (I) be following those, wherein
-described radicals R
1, R
2Mean independently of one another hydrogen atom or methyl,
-described radicals R
3, R
4Mean independently of one another hydrogen atom, hydroxyl or methyl, condition is R
3, R
4Mean hydroxyl when different,
-described radicals R
5, R
6Mean independently of one another hydrogen atom or methyl, or described radicals R
5, R
6One of mean hydrogen atom or methyl, and another group means one of following radicals
Wherein
-R
7Mean hydrogen atom or C
1-4Alkyl,
-R
8Mean hydrogen atom, methyl or hydroxyl,
-n, p, q mean 0 to 10 number independently of one another, and
-described radicals R
9To R
15Mean independently of one another hydrogen atom, C
1-4Alkyl or C
1-4Hydroxyl, condition is each C atom with a hydroxyl at the most.
According in the method for the invention, the particularly preferred polyol according to formula (I) is 1, ammediol, glycerol, erythritol, tetramethylolmethane, Sorbitol, mannitol, xylitol and/or pantothenylol, the mixture that uses the above-mentioned polyol of two or more is particularly preferred equally.
Particularly preferably be pantothenylol, glycerol and/or Sorbitol.
Be applicable to a) preferably have and be less than 3 μ m, be more preferably less than 2 μ m and particularly be less than the particle mean size by volume of 1 μ m according to the microemulsion of the method for the invention.
They preferably comprise, based on its gross weight:
(i) 1-40 % by weight, more preferably at least one general formula R O-[G of 5-30 % by weight and particularly 10-20 % by weight]
xAlkyl (oligomeric) glucosides, wherein R means to have alkyl and/or the thiazolinyl of 4-22 carbon atom, G means that saccharide residue and x with 5 or 6 carbon atoms mean 1 to 10 number,
(ii) 1-15 % by weight, more preferably glycerol and the C of 2-12.5 % by weight and particularly 4-10 % by weight
10-C
24At least one of fatty acid saturated or unsaturated, branching or nonbranched monoesters and/or diester,
(iii) 5-45 % by weight, more preferably at least one oil of 7.5-40 % by weight and particularly 10-30 % by weight, and
(iv) water of 40-80 % by weight.
Specially suitable alkyl (oligomeric) glucosides (i) is derived from the aldose with 5 or 6 carbon atoms and/or ketose, preferably derived from glucose.
Described radicals R particularly preferably means to have the alkyl of 6-20, a particularly 8-18 carbon atom.
At described general formula R O-[G]
xIn subscript x mean oligomeric degree (DP), i.e. described list-and the distribution of oligoglycosides.Described subscript x is the value of 1-6 scope preferably, the value of 1-3 scope particularly preferably, but wherein it can not be integer but the mark of Analysis deterrmination.Particularly preferred alkyl (oligomeric) glucosides has 1.2 to 1.5 oligomeric degree.
Particularly suitable alkyl (oligomeric) glucosides is known, and it can INCI title decyl glucoside, lauryl glucoside and Coco-Glucoside are purchased from different suppliers.
Particularly suitable ester (ii) is the monoesters of glycerol and the alkyl chain length linear fatty acid that is 2-22 carbon atom.The example of particularly suitable ester (ii) is glyceryl monolaurate, monomyristin, glycerol monopalmitate, glyceryl monostearate and/or glycerin mono-fatty acid ester.Glycerin mono-fatty acid ester is particularly suitable.
Applicable oil (iii) can be selected from mineral, natural and synthetic oil ingredient and/or fatty material.
As natural (plant) oil, can use the mixture of triglyceride and triglyceride.Preferred natural oil is Oleum Cocois, (sweet) almond oil, walnut oil, peach kernel oil, almond oil, American Avocado Tree oil, tea tree oil, soybean oil, Oleum sesami, sunflower oil, Camellia oil, Radix Oenotherae erythrosepalae oil, Testa oryzae oil, palm-kernel oil, the awns nut oil, azalea oil, Ji oil, Macadamia nut oil, Oleum Vitis viniferae, the Amaranthus mangostanus L. seed oil, Morocco Ah glycerol, vinifera palm oil, olive oil, Semen Tritici aestivi germ oil, pumpkin seed oil, Radix Malvae sylvestris oil, hazelnut oil, safflower oil, canola oil, the Flos Camelliae Japonicae caul-fat, Jojoba oil, Fructus nephelii topengii oil (rambutan oil), cupu oil and shea butter.
Particularly, mineral oil, paraffin oil, isomeric alkane hydrocarbon ils and synthetic hydrocarbon are as mineral oil.The example of spendable hydrocarbon is for example to can be used as 1 of commodity acquisition, 3-bis--(2-ethylhexyl) cyclohexane extraction (
S).
Silicone (silicone) compound is suitable as artificial oil.
Silicone produces excellent conditioning character on hair.Particularly, they produce hair better cardability under moistening and drying regime, and their actively impacts of pliability generation on trichoesthesia and hair under many circumstances.
Applicable silicone can be selected from:
(i) volatile or nonvolatile, straight chain, branching or ring-type, crosslinked or noncrosslinking poly-alkylsiloxane, poly-aryl siloxanes, polyoxyethylene alkyl aryl radical siloxane;
(ii) polysiloxanes, it comprises and is selected from one or more following organo-functional groups in its formula:
A) replace or unsubstituted amination group;
B) (entirely) fluorinated groups;
C) sulfydryl;
D) carboxylate group;
E) hydroxylating group;
F) alkoxylate group;
G) acyloxy alkyl;
H) amphiprotic group;
I) bisulfite group;
J) alcohol amide base;
K) carboxyl;
I) sulfonic group; With
M) sulfuric ester or thiosulfuric acid ester group;
(iii) (A-B)
nThe block copolymer of the linear polysiloxane of type (A)-polyoxyalkylene (B), wherein n>3;
(iv) there is the grafting silicone polymer that does not contain the Organic substance skeleton of silicone, the Organic substance main chain that described Organic substance skeleton is formed by the organic monomer that does not comprise silicone forms, and on described main chain, at least one polysiloxane macromonomer has been grafted in described chain and optionally has been grafted at least one end of described chain;
(v) there is the grafting silicone polymer of polysiloxanes skeleton, be grafted with the organic monomer that does not contain silicone on the polysiloxanes skeleton, described polysiloxanes skeleton has polysiloxane backbone, and on described polysiloxane backbone, at least one organic large monomer that does not comprise silicone has been grafted in described chain and optionally has been grafted on its at least one end;
Or their mixture (vi).
Dialkyl ether also can be used as oil ingredient.
Spendable dialkyl ether particularly has 12-36 carbon atom altogether, two-alkyl ether of 12-24 carbon atom, two-n-octyl ether for example particularly, two-positive decyl ethers, two-n-nonyl ether, two-n-undecane base ether, two-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-positive decyl ethers, positive decyl-n-undecane base ether, n-undecane base-dodecyl ether and n-hexyl-n-undecane base ether, and two-tertbutyl ether, two-isoamyl ether, two-3-ethyl decyl ethers, the tert-butyl group-n-octyl ether, isopentyl-n-octyl ether and 2-methyl amyl-n-octyl ether.
Particularly preferably be two-n-octyl ether, it can
The title of OE has been bought from the market.
Fatty material will be understood to fatty acid, fatty alcohol and natural and synthetic wax, and it can using solid form and existing as the liquid in aqueous dispersion.
As fatty acid, can use linearity and/or branching, the saturated and/or undersaturated fatty acid with 6-30 carbon atom.The fatty acid that preferably there is 10-22 carbon atom.Among these, should be mentioned in that for example isostearic acid is as commodity
871 Hes
875, and different Palmic acid is as commodity
IP95, and with trade name
(Cognis) all other fatty acids of selling.Other representative instance of these fatty acids is caproic acid, sad, 2 ethyl hexanoic acid, capric acid, lauric acid, different tridecanoic acid, myristic acid, Palmic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselic acid, linoleic acid, linolenic acid, eleostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their industrial grade mixture.
The particularly preferred fatty acid mixt normally obtained from Oleum Cocois or Petiolus Trachycarpi oil; Usually particularly preferably use stearic acid.
As fatty alcohol, can use saturated, single-or polyunsaturated, branching or nonbranched C of having
6-C
30, preferred C
10-C
22C the most particularly preferably
12-C
22The fatty alcohol of carbon atom.For example, can use decanol, capryl alcohol, matsutake alcohol, lanolin alcohol, decenol, octadienol, Pherocon CM, decadinene alcohol, oleyl alcohol, erucyl alcohol, ricinoleyl alcohol, stearyl alcohol, isooctadecanol, spermol, lauryl alcohol, myristyl alcohol, arachidic alcohol, capryl alcohol, decanol, inferior oleyl alcohol, linolenyl alcohol and behenyl alcohol and their Guerbet alcohol (Guerbet alcohols), this is enumerated purpose and is exemplary and non-limiting.Yet described fatty alcohol, preferably derived from natural acid, wherein can think that they are to obtain from the ester of described fatty acid by reduction usually.According to the present invention, also can use those fatty alcohol mixtures that prepare by the fatty acid ester that reduces naturally occurring triglyceride or formed by its ester exchange offspring and corresponding alcohol, described naturally occurring triglyceride is such as Adeps Bovis seu Bubali, Petiolus Trachycarpi oil, Oleum Arachidis hypogaeae semen, Oleum Brassicae campestris, Oleum Gossypii semen, soybean oil, sunflower oil and Semen Lini oil, thereby means the mixture of different fatty alcohol.This class material can below state title and be purchased: for example
As
1618, or
As
O, or
As
As
Or
24.Certainly, according to the present invention, also can use wool wax alcohol, for example can be with title
Or
Be purchased.
As natural or synthetic wax, can use hard paraffin or isoparaffin, Brazil wax, Cera Flava, candelilla wax, ceresine, ceresin, spermaceti, Helianthi wax, wax for waxing fruits as Fructus Mali pumilae wax or mandarin orange wax, the microwax that comprises PE or PP.This class wax can be by for example Kahl& Co., Trittau obtains.
Other fatty material for example
-ester oil.Ester oil will be understood to C
6-C
30Fatty acid and C
2-C
30The esters of fatty alcohol.Preferably fatty acid with there is the monoesters of the alcohol of 2-24 carbon atom.The example that can be used for the fatty acid part of described esters is caproic acid, sad, 2 ethyl hexanoic acid, capric acid, lauric acid, different tridecanoic acid, myristic acid, Palmic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselic acid, linoleic acid, linolenic acid, eleostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their industrial grade mixture.
The example of the fatty alcohol part in described ester oil is isopropyl alcohol, hexanol, capryl alcohol, 2-ethylhexyl alcohol, decanol, lauryl alcohol, different tridecanol, myristyl alcohol, spermol, Palmitoleyl alcohol, stearyl alcohol, isooctadecanol, oleyl alcohol, anti-oleyl alcohol, petroselinum alcohol, inferior oleyl alcohol, linolenyl alcohol, Oleum Verniciae fordii alcohol, arachidic alcohol, cod oleyl alcohol, behenyl alcohol, erucyl alcohol and Ba Wei alcohol (brassidyl alcohol) and their industrial grade mixture.Particularly preferably be isopropyl myristate (
IPM), different n-nonanoic acid C16-18 Arrcostab (
SN), Palmic acid 2-ethyl hexyl ester (
24), stearic acid 2-ethyl hexyl ester (
868), oleic acid cetyl ester, tricaprylin, Cortex cocois radicis fatty alcohol decanoin/caprylate (
LC), n-butyl stearate, oleyl alcohol eruciate (
J600), isopropyl palmitate (
IPP), oleic acid oleic alcohol ester (
), lauric acid hexyl ester (
A), Di-n-butyl Adipate (
B), the myristyl alcohol myristinate (
MM), different n-nonanoic acid cetearyl alcohol alcohol ester (
SN) and the oleic acid decyl ester (
V).
-dicarboxylic ester, as Di-n-butyl Adipate, adipic acid two (2-ethylhexyl) ester, succinic acid two (2-ethylhexyl) ester and different 13 esters of acetic acid two, and diol ester is as two oleic acid glycol esters, the different tridecanoate of ethylene glycol bisthioglycolate, propylene glycol two (2-ethylhexanoate), two isostearic acid propylene glycol esters, two n-nonanoic acid propylene glycol esters, two isostearic acid butanediol esters, two sad DOPCP
The symmetry of-carbonic acid and fatty alcohol, asymmetric or cyclic ester,
-carbonic acid glyceride or dicaprylyl carbonate
CC),
The list of the fatty acid of-saturated and/or undersaturated, linear and/or branching and the ethoxylation of glycerol or non-ethoxylated-, two-and tri-fatty acid ester, for example
90-O18,
90-L12,
HE or
MD.
Described microemulsion another main component a) is water.Described microemulsion a), based on its gross weight, preferably comprises 40-80 % by weight, more preferably 40-70 % by weight and the particularly water of 45-65 % by weight.
Described microemulsion a) can be preferably by under agitation by liquid oil phase (ii) with (iii), with water containing surfactant ((i) and (iv)), mixing to prepare (preferably before carrying out according to the method for the invention).
Perhaps, described microemulsion a) also can be used for according to the method for the invention with ready-made commodity.Commercially available microemulsion example a) be applicable to is can be with title " Plantasil
" the described microemulsion that obtains from Cognis.
Described microemulsion a) preferably with the 0.01-50 % by weight, more preferably the 0.1-30 % by weight, particularly preferably the amount of 0.5-20 % by weight and particularly 1-15 % by weight is for according to the method for the invention, the gross weight of described amount based on described conditioning cleaning agent.
In a particularly preferred embodiment, according to preparation method of the present invention, form transparent conditioning cleaning agent.
Described term " transparent " be interpreted as described conditioning cleaning agent have at the most 100, preferably at the most 50 and 30 NTU (nephelometric turbidity unit) value at the most particularly.
For the application of some cosmetics forms, may preferably prepare and produce excellent spatter property, as mild as a dove and demonstrate the conditioning cleaning agent of particularly preferred foamability.
In order to realize these targets, advantageously according to the method for the invention process, comprise the preparation process that adds other surfactant.
Other surfactant be applicable to can be contained in described microemulsion a), or they can be added to described cosmetics carrier before or after adding described microemulsion.
If described other surfactant is described microemulsion component a), with before described oil phase ((ii) and (iii)) mixes, they are added to the water containing surfactant ((i) and (iv)) of described microemulsion.
Described microemulsion a) preferably comprises other surfactant of 25 % by weight at the most.
Be suitable for can being selected from according to the surfactant of the method for the invention anionic, both sexes/amphoteric ion type and/or the nonionic surfactant of the gentleness with good foaming property.
Applicable anionic surfactant can be preferably with the 0.1-40 % by weight, more preferably the 0.5-30 % by weight, particularly preferably the amount of 1-25 % by weight and particularly 3-20 % by weight is for according to the method for the invention, the gross weight of described quantitative data based on described conditioning cleaning agent.
Described applicable anionic surfactant comprises:
-there is the linearity of 8-30 carbon atom and fatty acid branching (soap),
-Shi R-O-(CH
2-CH
2O)
x-CH
2The ether carboxylic acid of-COOH, wherein R is linearity or branching, the saturated or unsaturated alkyl with 8-30 carbon atom, and x=0 or 1-16,
-there is the acyl sarcosinates of 8-24 carbon atom in acyl group,
-there is the acyl taurine salt of 8-24 carbon atom in acyl group,
-there is the acyl-hydroxyethyl sulfonate of 8-24 carbon atom in acyl group,
-there is the sulfo-succinic acid list of 8-24 carbon atom-and/or dialkyl and there is 8-24 carbon atom and there is the sulfo-succinic acid monoalkyl polyoxy ethyl ester of 1-6 oxygen ethyl in alkyl in alkyl,
-there is the alpha-alkene sulfonate of 8-24 carbon atom,
-Shi R-O (CH
2-CH
2O)
x-OSO
3 -X
+Alkyl sulfate and/or alkyl polyglycol ether sulfate, wherein R preferably has linearity or branching, the saturated or unsaturated alkyl of 8-30 carbon atom, x=0 or 1-12, and X is alkali metal ion or ammonium ion,
-there is the sulphonic acid ester of the unsaturated fatty acid of 8-24 carbon atom and 1-6 two keys,
-tartaric acid and citric acid and pure ester, the addition compound product that it means oxirane and/or the expoxy propane of about 2-15 mole and has the fatty alcohol of 8-22 carbon atom,
The alkyl of-following formula and/or alkene ether phosphate ester or salt,
R wherein
1Preferably mean to have the aliphatic alkyl of 8-30 carbon atom, R
2Mean hydrogen, (CH
2CH
2O)
nR
1Group or X, n means the number of 0-10, X means hydrogen, alkali metal or alkaline-earth metal or NR
3R
4R
5R
6, R wherein
3To R
6Mean independently of one another C
1To C
4Alkyl.
Preferred anionic surfactant be above-mentioned formula the ether carboxylic acid, there is the acyl sarcosinates of 8-24 carbon atom in acyl group, there is the sulfo-succinic acid list of 8-24 carbon atom in alkyl-and/or dialkyl, the alkyl sulfate and/or the alkyl polyglycol ether sulfate that there is 8-24 carbon atom and there is the sulfo-succinic acid monoalkyl polyoxy ethyl ester of 1-6 oxygen ethyl, the alpha-alkene sulfonate with 8-24 carbon atom and/or above-mentioned formula in alkyl.
Particularly preferred anionic surfactant be comprise there is 8-18, the particularly alkyl of 10-16 carbon atom and 1-6, particularly straight chain or the branched-alkyl ether sulfate of 2-4 ethylene oxide unit.
Further particularly preferred anionic surfactant is to comprise to have 8-18 and particularly straight chain or the branched-alkyl sulfonate of the alkyl of 10-16 carbon atom.Particularly preferably be sodium, magnesium and/or the triethanolamine salt of lauryl, tridecyl and/or the myristyl sulfuric ester of the linearity of the ethoxylation degree with 2-4 or branching.
Applicable both sexes/amphoteric ionic surfactant can be preferably with the 0-20 % by weight, more preferably the 0.25-17.5 % by weight, particularly preferably the amount of 0.5-15 % by weight and particularly 1-10 % by weight is for according to the method for the invention, the gross weight of described quantitative data based on described conditioning cleaning agent.
Applicable both sexes/amphoteric ionic surfactant can be selected from the compound of following formula (i) to (v), wherein said radicals R means to have straight chain or branching, saturated or single-or the polyunsaturated alkyl or alkenyl of 8-24 carbon atom in each situation
(i)
(ii)
(iii)
(iv)
(v)
Particularly suitable both sexes/amphoteric ionic surfactant is alkylamidoalkyl alkyl betaine and/or alkyl both sexes (two) acetas of above-mentioned formula (i) to (v).
Described particularly suitable both sexes/amphoteric ionic surfactant comprises with INCI title cocamido propyl betaine and the known surfactant of cocos nucifera oil acyl both sexes base two acetic acid disodium.
Applicable nonionic surfactant (described alkyl (oligomeric) glucosides except described microemulsion in a)) can be preferably with the 0-20 % by weight, more preferably the 0.25-17.5 % by weight, particularly preferably the amount of 0.5-15 % by weight and particularly 1-10 % by weight is for according to the method for the invention, the gross weight of described quantitative data based on described conditioning cleaning agent.
Described applicable nonionic surfactant/emulsifying agent for example comprises:
The C of the oxirane of-1-30 mole and the addition compound product of glycerol
8-C
30The fatty acid list-and diester,
-amine oxide,
The expoxy propane of the oxirane of-2-50 mole and/or 0-5 mole and linearity and fatty alcohol branching with 8-30 carbon atom, and have 8-30 carbon atom fatty acid and with the addition compound product of the alkylphenol that there is 8-15 carbon atom in alkyl,
The addition compound product of-fatty acid esters of sorbitan and oxirane and fatty acid esters of sorbitan is as polysorbate,
The addition compound product of-sugar fatty acid ester and oxirane and sugar fatty acid ester,
The addition compound product of-oxirane and fatty acid alkanol amides and fatty amine, and/or
-alkyl polyglucoside.
If nonionic surfactant is as according to other surfactant in the method for the invention, preferred alkyl oligomeric glucopyranoside, particularly based on hydrogenation C
12/14The oligomeric alkyl glucoside that the DP of cocoanut oil alcohol is 1-3, it can for example have been bought with INCI title " Coco-Glucoside " from the market.
Further preferred nonionic surfactant is the C of the addition compound product of the oxirane of 1-30 mole and glycerol
8-C
30The fatty acid list-and diester.Particularly preferably be the C of the addition compound product of the oxirane of 1-10 mole and glycerol
10-C
16The fatty acid list-and diester.Particularly preferably be the INCI name and be called " PEG-7 glyceryl cocoate ".
, prepare the method for nursing one's health cleaning agent and comprise the steps: particularly preferably in embodiment of the present invention first
A) provide microemulsion, it comprises
(i) at least one alkyl (oligomeric) glucosides,
(ii) glycerol and at least one C
10-C
24At least one ester of fatty acid,
(iii) at least one oil that is different from (ii), and
(iv) water, and
B) described microemulsion is mixed with cosmetics carrier, described cosmetics carrier comprises at least one polyol according to above-mentioned formula (I) and at least one anionic surfactant.
In this embodiment, particularly preferably described cosmetics carrier comprises:
The 1,3-PD of-0.01-10 % by weight, glycerol, erythritol, tetramethylolmethane, Sorbitol, mannitol, xylitol and/or pantothenylol, and
At least one anionic surfactant of-1-25 % by weight, it can be selected from lower group: described ether carboxylic acid, the described acyl sarcosinates that has 8-24 carbon atom in acyl group, describedly at alkyl, have the sulfo-succinic acid list of 8-24 carbon atom-and/or dialkyl, the described sulfo-succinic acid monoalkyl polyoxy ethyl ester that has 8-24 carbon atom and have 1-6 oxygen ethyl in alkyl, alpha-alkene sulfonate and/or described alkyl sulfate and/or the alkyl polyglycol ether sulfate of the described 8-24 of a having carbon atom.
In this embodiment, particularly preferably described cosmetics carrier comprises:
The glycerol of-0.05-7.5 % by weight, Sorbitol and/or pantothenylol, and
Containing of-3-20 % by weight have 8-18, the particularly alkyl of 10-16 carbon atom and 1-6, the particularly straight chain of 2-4 ethylene oxide unit or the alkyl ether sulfate of branching.
, prepare the method for nursing one's health cleaning agent and comprise the steps: particularly preferably in embodiment of the present invention second
A) provide microemulsion, it comprises
(i) at least one alkyl (oligomeric) glucosides,
(ii) glycerol and at least one C
10-C
24At least one ester of fatty acid,
(iii) at least one oil that is different from (ii), and
(iv) water, and
B) described microemulsion is mixed with cosmetics carrier, described cosmetics carrier comprises at least one polyol according to above-mentioned formula (I), at least one anionic surfactant, at least one both sexes/amphoteric ionic surfactant and at least one nonionic surfactant.
In this embodiment, particularly preferably described cosmetics carrier comprises:
The 1,3-PD of-0.01-10 % by weight, glycerol, erythritol, tetramethylolmethane, Sorbitol, mannitol, xylitol and/or pantothenylol,
At least one anionic surfactant of-1-25 % by weight; it can be selected from lower group: the ether carboxylic acid of above-mentioned formula, the described acyl sarcosinates that there is 8-24 carbon atom in acyl group, the described sulfo-succinic acid list that there is 8-24 carbon atom in alkyl-and/or dialkyl, the described sulfo-succinic acid monoalkyl polyoxy ethyl ester that there is 8-24 carbon atom and there is 1-6 oxygen ethyl in alkyl, alpha-alkene sulfonate and/or described alkyl sulfate and/or the alkyl polyglycol ether sulfate of the described 8-24 of a having carbon atom
At least one both sexes/amphoteric ionic surfactant of-0.25-17.5 % by weight, it can be selected from alkylamidoalkyl alkyl betaine and/or alkyl both sexes (two) acetas of above-mentioned formula (i) to (v), and
At least one nonionic surfactant of-0.25-17.5 % by weight, it can be selected from the C of the addition compound product of the oxirane of 1-30 mole and glycerol
8-C
30the fatty acid list-and diester, amine oxide, the expoxy propane of the oxirane of 2-50 mole and/or 0-5 mole and the fatty alcohol with linearity and branching of 8-30 carbon atom, with the fatty acid with 8-30 carbon atom and with the addition compound product of the alkylphenol that there is 8-15 carbon atom in alkyl, the addition compound product of fatty acid esters of sorbitan and oxirane and fatty acid esters of sorbitan is as polysorbate, the addition compound product of sugar fatty acid ester and oxirane and sugar fatty acid ester, the addition compound product of oxirane and fatty acid alkanol amides and fatty amine and/or alkyl polyglucoside.
In this embodiment, particularly preferably described cosmetics carrier comprises:
The glycerol of-0.05-7.5 % by weight, Sorbitol and/or pantothenylol,
The straight chain of-3-20 % by weight or the alkyl ether sulfate of branching, its contain there is 8-18, particularly alkyl and 1-6, a particularly 2-4 ethylene oxide unit of 10-16 carbon atom,
At least one surfactant of-1-10 % by weight, the INCI name is called cocamido propyl betaine and cocos nucifera oil acyl both sexes base two acetic acid disodiums, and
The C of the oxirane of the 1-30 of-1-10 % by weight mole and the addition compound product of glycerol
8-C
30The fatty acid list-and/or addition compound product and/or the alkyl polyglucoside of the oxirane of diester, 2-50 mole and the fatty alcohol of the linearity with 8-30 carbon atom and branching.
Distribute equably and be deposited on hair fiber from the described lipid composition of described microemulsion by making, having realized the conditioning effect of the described conditioning cleaning formulation for preparing according to the method for the invention.As a result, the described hair fiber cunning that flattens, and after processing with described conditioning cleaning formulation, they demonstrate larger elasticity and soft sensation.
Described polyol contributes to the strengthening of the level and smooth and hair structure of hair fiber.
In order to support the deposition of described lipid composition on hair fiber, according to process in the method for the invention, comprising the preparation process that adds cation type polymer, may be favourable.
Applicable cation type polymer can be contained in described microemulsion a), or they can be added to described cosmetics carrier before or after adding described microemulsion.
Applicable cation type polymer preferably is used for according to the method for the invention with the amount of 0.01-10 % by weight, preferred 0.05-5 % by weight and particularly 0.1-3 % by weight, the gross weight of described amount based on described conditioning cleaning agent.
Applicable cation type polymer is for example:
-quaternized cellulose, it can be with title
And Polymer
Bought from the market,
The cellulose derivative of-hydrophobically modified, for example, with trade name
The cation type polymer of selling,
-cationic alkyl poly glucoside,
-cationization Mel, for example commodity
50,
-cationic guar derivative, for example, particularly with trade name
Guar and
Product sold,
The dimethyldiallylammonium salt of-polymerization with and with the ester of acrylic acid and methacrylic acid and the copolymer of amide.The example of these cationic polymers is with title
100 (poly-(dimethyl diallyl ammonium chlorides)) and
550 (dimethyl diallyl ammonium chloride-acrylamide copolymer) commercially available product,
The copolymer of the quaternary ammonium derivative of-vinyl pyrrolidone and dialkyl aminoalkyl acrylate and methacrylate, for example use the copolymer of the quaternised vinyl pyrrolidone-dimethyl amino ethyl methacrylate of dithyl sulfate.This compounds can be with title
734 Hes
755 have bought from the market,
The copolymer of-vinyl pyrrolidone-vinyl imidazole methochloride, for example, with title
Those that FC370, FC550, FC905 and HM552 sell,
-quaternized polyvinyl alcohol, and
The known polymer with described title:
-polyquaternary ammonium salt 2, polyquaternary ammonium salt 17, polyquaternary ammonium salt 18, polyquaternary ammonium salt-24, polyquaternary ammonium salt 27, polyquaternium-32, polyquaternary ammonium salt-37, polyquaternary ammonium salt 74 and polyquaternary ammonium salt 89.
Particularly preferred to can be used for according to the cation type polymer of the method for the invention be quaternized cellulosic polymer, cationic guar derivative and/or acrylic acid (derivant) cationoid type polymer, and it is selected from especially with INCI title guar hydroxypropyl trimonium chloride, polyquaternary ammonium salt-6, polyquaternary ammonium salt-7, Polyquaternium-10, polyquaternary ammonium salt-37 and/or the known polymer of Polyquaternium-67.
, prepare the method for nursing one's health cleaning agent and comprise the steps: particularly preferably in embodiment the of the present invention the 3rd
A) provide microemulsion, it comprises
(i) at least one alkyl (oligomeric) glucosides,
(ii) glycerol and at least one C
10-C
24At least one ester of fatty acid,
(iii) at least one oil that is different from (ii), and
(iv) water, and
B) described microemulsion is mixed with cosmetics carrier, described cosmetics carrier contains at least one protein hydrolysate, at least one anionic surfactant and at least one cation type polymer.
In this embodiment, particularly preferably described cosmetics carrier comprises:
The 1,3-PD of-0.01-10 % by weight, glycerol, erythritol, tetramethylolmethane, Sorbitol, mannitol, xylitol and/or pantothenylol,
At least one anionic surfactant of-1-25 % by weight; it can be selected from lower group: the ether carboxylic acid of above-mentioned formula, the described acyl sarcosinates that there is 8-24 carbon atom in acyl group, the described sulfo-succinic acid list that there is 8-24 carbon atom in alkyl-and/or dialkyl, the described sulfo-succinic acid monoalkyl polyoxy ethyl ester that there is 8-24 carbon atom and there is 1-6 oxygen ethyl in alkyl, alpha-alkene sulfonate and/or described alkyl sulfate and/or the alkyl polyglycol ether sulfate of the described 8-24 of a having carbon atom, and
At least one cation type polymer of-0.01-10 % by weight, it is selected from lower group: described quaternized cellulosic polymer, described cationic guar derivative and/or described acrylic acid (derivant) cationoid polymer.
In this embodiment, particularly preferably described cosmetics carrier comprises:
The glycerol of-0.05-7.5 % by weight, Sorbitol and/or pantothenylol,
The straight chain of-3-20 % by weight or the alkyl ether sulfate of branching, its contain there is 8-18, particularly alkyl and 1-6, a particularly 2-4 ethylene oxide unit of 10-16 carbon atom, and
At least one cationic polymer of-0.05-5 % by weight, it is known with INCI title guar hydroxypropyl trimonium chloride, polyquaternary ammonium salt-6, polyquaternary ammonium salt-7, Polyquaternium-10, polyquaternary ammonium salt-37 and/or Polyquaternium-67.
Above-described cosmetics carrier can also comprise a series of other optional active substances that exist, and described active substance can produce favourable character and not make and become more difficult according to the method for the invention on hair.The preferred optional active substance existed for example comprises:
-vitamin, vitamin derivative and/or previtamin, its can be preferably with the 0.001-10 % by weight, more preferably the amount of 0.005-7.5 % by weight and particularly 0.01-5 % by weight is for according to the method for the invention,
-active dandruff material, its can be preferably with the 0.01-10 % by weight, more preferably the 0.025-7.5 % by weight, particularly preferably the amount of 0.05-5 % by weight and particularly 0.075-3 % by weight is for according to the method for the invention, described quantitative data is the gross weight based on described conditioning cleaning agent in each situation.
Applicable vitamin preferably is interpreted as following vitamin, provitamin and previtamin and their derivant:
Vitamin A: the material group that is called vitamin A comprises retinol (retinol1) and 3,4-, bis-dehydroretinols (dehydroretinol).Beta-carotene is the provitamin of retinol.The component that is suitable as vitamin A is for example retinoic acid and ester, axerophthal and retinol and ester thereof, as cetylate and acetas.
Vitamin B: vitamin(e) B group or vitamin B complex especially comprise:
-vitamin B1 (thiamine)
-vitamin B2 (riboflavin)
-vitamin B3: compound nicotinic acid and nicotiamide (niacin amide) are usually known with this title.
-vitamin B5 (pantothenic acid and pantothenylol).At this apoplexy due to endogenous wind, preferably use pantothenylol.The derivant of spendable pantothenylol is the ester of pantothenylol and the pantothenylol of ether and cation derivatization particularly.Individual typical example is pantothenylol triacetate, pantothenylol list ethylether and monoacetate thereof and cationic pantothenylol derivant in this way.
-vitamin B6 (pyridoxol and pyridoxamine and 2-methyl-3-hydroxy-4-formyl-5-hydroxymethylpyridine .).
Vitamin C (ascorbic acid): can preferably use with the form of cetylate, glucoside or phosphate ester.Also can preferably with tocopherol, combine use.
Vitamin E (tocopherol, particularly alpha-tocopherol).
VitaminF: term " vitaminF " is generally understood as essential fatty acid, particularly linoleic acid, linolenic acid and arachidonic acid.
Biotin: compound (3aS, 4S, 6aR)-2-oxo six hydrogen thienos [3,4-d]-imidazoles-4 valeric acid is called biotin, has nowadays accepted its popular name biotin.
Preferably use described vitamin, provitamin and the previtamin from A, B, E and H class.Nicotiamide, biotin, pantolactone and/or pantothenylol are particularly preferred.
The active dandruff material be applicable to can be selected from piroctone olamine, climbazole, ZPT, ketoconazole, salicylic acid, sulfur, selenium sulfide, tar preparation, endecatylene acid derivative, Radix Arctii extract, Cortex Populi dividianae extract, nettle extract, Endocarpium Juglandis extract, birch extract, Willow bark extract, Herba Rosmarini Officinalis extract and/or arnica montana extract.
Climbazole, ZPT and piroctone olamine salt are preferred.
According to other active substance, auxiliary material and the additive of the method for the invention for example can be used for:
-plant extract,
-wetting agent,
-spice,
-UV screening agent,
-thickening agent, for example gelatin or plant gum are as agar, guar gum, alginate, xanthan gum, Radix Acaciae senegalis, karaya, locust bean gum, Semen Lini glue, glucosan, cellulose derivative is as methylcellulose, hydroxy alkyl cellulose and carboxymethyl cellulose, starch fraction (fraction) and derivant are as amylose, amylopectin and dextrin, clay and phyllosilicate are as bentonite, or fully synthetic hydrocolloid is as polyvinyl alcohol, calcium soap, magnesium soap or zinc soap
-structural agent (structurant), as maleic acid and lactic acid,
-Isosorbide dimethyl ether,
-cyclodextrin,
-improve the active substance of fibre structure, particularly single-, two-and oligosaccharide, for example glucose, galactose, fructose, Fruit candy and lactose,
-make the painted coloring agent of described reagent,
-regulate the material of pH value, for example α-and beta-hydroxycarboxylic acids as citric acid, lactic acid, malic acid and glycolic,
-active substance, as bisabolol,
-chelating agen, as EDTA, NTA, β-alanine, acetoacetic acid and phosphonic acids,
-ceramide: ceramide is interpreted as the synthetic analogues (so-called class ceramide) of N-acyl sphingosine (fatty acid amide of sphingol) or this lipoids,
-propellant, as propane-butane mixture, N
2O, dimethyl ether, CO
2And air,
-antioxidant,
-denseness reinforcing agent, as sugar ester, polyol ester or polyol alkyl ether,
-antiseptic, as sodium benzoate or salicylic acid,
-viscosity modifier, as salt (NaCl).
Preferably being suitable for preparing pH value according to the method for the invention is 1.5-7.5, the preferably conditioning cleaning agent of 2-6.5 and particularly 3-6 scope.
Have advantages of that according to the method for the invention enforcement is simple especially and the energy input requirement is low.Described conditioning component a) and b) can mix with any order, other auxiliary material and active substance can significantly more add described cosmetics carrier under complicated situation not causing described method to become.
In addition, use according to the method for the invention, can prepare and there is the conditioning cleaning agent of lipid (for particularly preferred hair-conditioning) at high proportion, described conditioning cleaning agent also can spume and cleaning effect good, be transparent and stable in addition.
Use can cause having soft feel by the hair treatment of the conditioning cleaning agent that obtains according to the method for the invention, the hair of the strengthening of the elasticity of increase and more volume.
Secondly, the invention provides a kind of conditioning cleaning agent, it comprises in cosmetics carrier:
A) microemulsion, it comprises
(i) at least one alkyl (oligomeric) glucosides,
(ii) glycerol and at least one C
10-C
24At least one ester of fatty acid,
(iii) at least one oil that is different from (ii), and
(iv) water, and
B) polyol of at least one following formula (I),
Wherein
-described radicals R
1, R
2Mean independently of one another hydrogen atom, C
1-C
4Alkyl or phenyl, or in each situation, be the alkylidene of the ingredient of Pentamethylene. ring or cyclohexane ring,
-described radicals R
3, R
4Mean independently of one another hydrogen atom, hydroxyl, C
1-C
4Alkyl, hydroxyalkyl, phenyl or in each situation, be the alkylidene of the ingredient of Pentamethylene. ring or cyclohexane ring,
-described radicals R
5, R
6Mean independently of one another hydrogen atom, C
1-C
4Alkyl or hydroxyalkyl, or described radicals R
5, R
6One of mean saturated or unsaturated, branching or nonbranched C
1-C
20Alkyl chain, described C
1-C
20Alkyl chain can be by one or more esters and/or amide group interval and can be with one or more hydroxyls,
Condition is described radicals R
3, R
4Mean hydroxyl when different.
Again, the invention provides above-described described cosmetic cleaning agent for strengthening hair structure, improving the organoleptic properties of hair and the purposes of increase hair volume.
For according to reagent of the present invention with according to the further preferred implementation of purposes of the present invention, to the explanation made according to the method for the invention, in addition necessary correction is applicable afterwards.
Embodiment:
The conditioning hair shampoo
In above-mentioned hair shampoo, used following commodity:
1INCI title: sodium laureth sulfate; AS68-73%; Cognis
2INCI title: cocamido propyl betaine; AS29-32%; Cognis
3INCI title: cocos nucifera oil acyl both sexes base two acetic acid disodiums; AS approximately 30%; Cognis
4INCI title: Coco-Glucoside; AS51-53%; Cognis
5INCI title: water, dicaprylyl ether, decyl glucoside, glyceryl oleate; Cognis
6INCI title: castor oil hydrogenated; Cognis
7INCI title: PEG-7 glyceryl cocoate; Cognis
8INCI title: Polyquaternium-10; Dow
9INCI title: laureth-2; Cognis
10INCI title: dimethyl polysiloxane; Dow Corning
Conditioning hair shampoo by following method Preparation Example 1-4:
-at ambient temperature, with half water, mix described surfactant, described polyol and the optional nicotiamide existed,
-at ambient temperature, in water, pre-one or more cation type polymers of swelling, then add surfactant mixture to,
-in ambient temperature with under stirring, residual activity material (except citric acid and Arlypon F) is added in batch of material continuously, form transparent Cleasing compositions,
-use the Fructus Citri Limoniae acid for adjusting pH value to about 4.5-5.5,
-be adjusted to desired viscosity with Arlypon F in each situation.
Claims (10)
1. one kind prepares the method for nursing one's health cleaning agent, comprises the steps:
A) provide the microemulsion that comprises following component:
(i) at least one alkyl (oligomeric) glucosides,
(ii) glycerol and at least one C
10-C
24At least one ester of fatty acid,
(iii) at least one oil that is different from (ii), and
(iv) water, and
B) described microemulsion is mixed with cosmetics carrier, the polyol that described cosmetics carrier comprises at least one following formula (I),
Wherein
-described radicals R
1, R
2Mean independently of one another hydrogen atom, C
1-C
4Alkyl or phenyl, or in each situation, be the alkylidene of the ingredient of Pentamethylene. ring or cyclohexane ring,
-described radicals R
3, R
4Mean independently of one another hydrogen atom, hydroxyl, C
1-C
4Alkyl, hydroxyalkyl, phenyl or in each situation, be the alkylidene of the ingredient of Pentamethylene. ring or cyclohexane ring,
-described radicals R
5, R
6Mean independently of one another hydrogen atom, C
1-C
4Alkyl or hydroxyalkyl, or described radicals R
5, R
6One of mean saturated or unsaturated, branching or nonbranched C
1-C
20Alkyl chain, described C
1-C
20Alkyl chain is optionally by one or more esters and/or amide group interval and optionally with one or more hydroxyls,
Condition is described radicals R
3, R
4Mean hydroxyl when different.
2. method according to claim 1, wherein in formula (I)
-described radicals R
1, R
2Mean independently of one another hydrogen atom or methyl,
-described radicals R
3, R
4Mean independently of one another hydrogen atom, hydroxyl or methyl, condition is R
3, R
4Mean hydroxyl when different,
-described radicals R
5, R
6Mean independently of one another hydrogen atom or methyl, or described radicals R
5, R
6One of mean hydrogen atom or methyl, and another group means one of following radicals:
Wherein
-R
7Mean hydrogen atom or C
1-4Alkyl,
-R
8Mean hydrogen atom, methyl or hydroxyl,
-n, p, q mean 0 to 10 number independently of one another, and
-described radicals R
9To R
15Mean independently of one another hydrogen atom, C
1-4Alkyl or hydroxyl, condition is each C atom with a hydroxyl at the most.
3. according to the described method in one of claim 1 or 2, wherein said polyol is selected from 1,3-PD, glycerol, erythritol, tetramethylolmethane, Sorbitol, mannitol, xylitol and/or pantothenylol.
4. according to the described method of one of claims 1 to 3, the gross weight based on the conditioning cleaning agent wherein, described conditioning detergent package is containing 0.01-10 % by weight, preferably 0.05-7.5 % by weight, more preferably at least one polyol of 0.075-5 % by weight and particularly 0.1-3 % by weight.
5. according to the described method of one of claim 1 to 4, wherein said microemulsion a) comprises:
(i) 1-40 % by weight, more preferably at least one general formula R O-[G of 5-30 % by weight and particularly 10-20 % by weight]
xAlkyl (oligomeric) glucosides, wherein R means to have alkyl and/or the thiazolinyl of 4-22 carbon atom, G means that saccharide residue and x with 5 or 6 carbon atoms mean 1 to 10 number,
(ii) 1-15 % by weight, more preferably glycerol and the C of 2-12.5 % by weight and particularly 4-10 % by weight
10-C
24At least one of fatty acid saturated or unsaturated, branching or nonbranched monoesters and/or diester,
(iii) 5-45 % by weight, more preferably at least one oil of 7.5-40 % by weight and particularly 10-30 % by weight, and
(iv) water of 40-80 % by weight,
Described quantitative data is weight a) based on described microemulsion.
6. according to the described method of one of claim 1 to 5, the gross weight based on the conditioning cleaning agent wherein, described conditioning detergent package containing the 0.01-50 % by weight, preferably the 0.1-30 % by weight, more preferably 0.5-20 % by weight and particularly 1-15 % by weight described microemulsion a).
7. according to the described method of one of claim 1 to 6, the gross weight based on the cosmetic cleaning agent wherein, described cosmetic cleaning agent contains the 0.1-40 % by weight, preferred 0.5-30 % by weight, more preferably at least one anionic surfactant of 1-25 % by weight and particularly 3-20 % by weight and 0-20 % by weight, preferred 0.25-17.5 % by weight, more preferably at least one both sexes/amphoteric ionic surfactant of 0.5-15 % by weight and particularly 1-10 % by weight and/or 0-20 % by weight, preferred 0.25-17.5 % by weight, more preferably at least one nonionic surfactant of 0.5-15 % by weight and particularly 1-10 % by weight, described quantitative data does not comprise the nonionic surfactant of described microemulsion in a).
8. according to the described method of one of claim 1 to 7, the gross weight based on the conditioning cleaning agent wherein, described conditioning cleaning agent contains 0.01-10 % by weight, preferably 0.05-5 % by weight and the particularly cation type polymer of 0.1-3 % by weight.
9. a conditioning cleaning agent, it comprises
A) microemulsion, it comprises
(i) at least one alkyl (oligomeric) glucosides,
(ii) glycerol and at least one C
10-C
24At least one ester of fatty acid,
(iii) at least one oil that is different from (ii), and
(iv) water, and
B) polyol of at least one following formula (I),
Wherein
-described radicals R
1, R
2Mean independently of one another hydrogen atom, C
1-C
4Alkyl or phenyl, or in each situation, be the alkylidene of the ingredient of Pentamethylene. ring or cyclohexane ring,
-described radicals R
3, R
4Mean independently of one another hydrogen atom, hydroxyl, C
1-C
4Alkyl, hydroxyalkyl, phenyl or in each situation, be the alkylidene of the ingredient of Pentamethylene. ring or cyclohexane ring,
-described radicals R
5, R
6Mean independently of one another hydrogen atom, C
1-C
4Alkyl or hydroxyalkyl, or described radicals R
5, R
6One of mean saturated or unsaturated, branching or nonbranched C
1-C
20Alkyl chain, described C
1-C
20Alkyl chain is optionally by one or more esters and/or amide group interval and optionally with one or more hydroxyls,
Condition is described radicals R
3, R
4Mean hydroxyl when different.
10. according to the purposes of the cosmetic cleaning agent of claim 9, it is for strengthening hair structure, improve the hair organoleptic properties and increasing hair volume.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102011015192.3 | 2011-03-25 | ||
| DE102011015192A DE102011015192A1 (en) | 2011-03-25 | 2011-03-25 | Process for the preparation of a conditioning detergent |
| PCT/EP2012/054791 WO2012130655A2 (en) | 2011-03-25 | 2012-03-19 | Process for producing a conditioning cleaning agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103429219A true CN103429219A (en) | 2013-12-04 |
Family
ID=45876735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280012285XA Pending CN103429219A (en) | 2011-03-25 | 2012-03-19 | Process for producing a conditioning cleaning agent |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20140023606A1 (en) |
| EP (1) | EP2688545A2 (en) |
| JP (1) | JP2014509610A (en) |
| CN (1) | CN103429219A (en) |
| DE (1) | DE102011015192A1 (en) |
| WO (1) | WO2012130655A2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106821785A (en) * | 2015-11-26 | 2017-06-13 | 株式会社爱茉莉太平洋 | Wash hair composition |
| CN107405269A (en) * | 2014-12-25 | 2017-11-28 | 莱雅公司 | Washing and the composition of conditioning hair |
| CN109475486A (en) * | 2016-04-26 | 2019-03-15 | 莱雅公司 | For handling the composition of keratin fiber |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011015191A1 (en) * | 2011-03-25 | 2012-09-27 | Henkel Ag & Co. Kgaa | Process for the preparation of a conditioned cleaning agent |
| MX352379B (en) | 2013-04-05 | 2017-11-17 | Procter & Gamble | Personal care composition comprising a pre-emulsified formulation. |
| US9101551B2 (en) | 2013-10-09 | 2015-08-11 | The Procter & Gamble Company | Personal cleansing compositions and methods |
| WO2015121101A1 (en) * | 2014-02-13 | 2015-08-20 | Basf Se | Microemulsions, and cosmetic cleansing agents containing microemulsions |
| DE102014210275A1 (en) * | 2014-05-30 | 2015-12-03 | Henkel Ag & Co. Kgaa | Process for the preparation of a conditioning preshave or aftershave agent |
| US10806688B2 (en) | 2014-10-03 | 2020-10-20 | The Procter And Gamble Company | Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation |
| US20160128927A1 (en) | 2014-11-10 | 2016-05-12 | The Procter & Gamble Company | Personal Care Compositions With Two Benefit Phases |
| EP3217948B1 (en) | 2014-11-10 | 2020-09-16 | The Procter and Gamble Company | Personal care compositions with two benefit phases |
| US10966916B2 (en) | 2014-11-10 | 2021-04-06 | The Procter And Gamble Company | Personal care compositions |
| CN107427425A (en) * | 2014-12-26 | 2017-12-01 | 莱雅公司 | For adjusting the composition of hair |
| US9993404B2 (en) | 2015-01-15 | 2018-06-12 | The Procter & Gamble Company | Translucent hair conditioning composition |
| DE102015202971A1 (en) | 2015-02-19 | 2015-12-03 | Henkel Ag & Co. Kgaa | Body cleanser containing a skin care plant milk |
| DE102015213478A1 (en) * | 2015-07-17 | 2017-01-19 | Henkel Ag & Co. Kgaa | stabilizing mixture |
| US20170128658A1 (en) * | 2015-11-11 | 2017-05-11 | CreatiVasc Medical Inc. | Arteriovenous access valve system with separate valve tubes |
| CN108472223A (en) | 2016-01-20 | 2018-08-31 | 宝洁公司 | Include the hair care composition of monoalkyl glyceryl ether |
| MX370963B (en) | 2016-02-19 | 2020-01-10 | Colgate Palmolive Co | Personal care compositions. |
| KR20190005928A (en) * | 2016-05-10 | 2019-01-16 | 바스프 에스이 | A microemulsion concentrate containing an amphoteric surfactant |
| CN111225652A (en) | 2017-10-20 | 2020-06-02 | 宝洁公司 | Aerosol foam skin cleaning agent |
| WO2019079409A1 (en) | 2017-10-20 | 2019-04-25 | The Procter & Gamble Company | Aerosol foam skin cleanser |
| US11096878B2 (en) * | 2018-05-31 | 2021-08-24 | L'oreal | Concentrated rinse-off cleansing composition |
| EP3887824A1 (en) | 2018-11-29 | 2021-10-06 | The Procter & Gamble Company | Methods for screening personal care products |
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2011
- 2011-03-25 DE DE102011015192A patent/DE102011015192A1/en not_active Withdrawn
-
2012
- 2012-03-19 EP EP12710217.6A patent/EP2688545A2/en not_active Withdrawn
- 2012-03-19 JP JP2014500345A patent/JP2014509610A/en active Pending
- 2012-03-19 CN CN201280012285XA patent/CN103429219A/en active Pending
- 2012-03-19 WO PCT/EP2012/054791 patent/WO2012130655A2/en active Application Filing
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- 2013-09-25 US US14/036,090 patent/US20140023606A1/en not_active Abandoned
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| WO2004010958A2 (en) * | 2002-07-31 | 2004-02-05 | Shaklee Corporation | A method for maximizing scalp health and inducing enhanced visual and tactile hair quality |
| CN100464731C (en) * | 2003-05-23 | 2009-03-04 | 宝洁公司 | Clear personal care compositions containing a cationic conditioning polymer and an anionic surfactant system |
| EP1570833A1 (en) * | 2004-03-05 | 2005-09-07 | KPSS-Kao Professional Salon Services GmbH | Hair treatment composition |
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| CN107405269A (en) * | 2014-12-25 | 2017-11-28 | 莱雅公司 | Washing and the composition of conditioning hair |
| CN106821785A (en) * | 2015-11-26 | 2017-06-13 | 株式会社爱茉莉太平洋 | Wash hair composition |
| CN109475486A (en) * | 2016-04-26 | 2019-03-15 | 莱雅公司 | For handling the composition of keratin fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012130655A2 (en) | 2012-10-04 |
| EP2688545A2 (en) | 2014-01-29 |
| DE102011015192A1 (en) | 2012-09-27 |
| WO2012130655A3 (en) | 2013-06-13 |
| US20140023606A1 (en) | 2014-01-23 |
| JP2014509610A (en) | 2014-04-21 |
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Application publication date: 20131204 |