CN103422152A - Metal wire rod surface treatment device - Google Patents
Metal wire rod surface treatment device Download PDFInfo
- Publication number
- CN103422152A CN103422152A CN2012101490367A CN201210149036A CN103422152A CN 103422152 A CN103422152 A CN 103422152A CN 2012101490367 A CN2012101490367 A CN 2012101490367A CN 201210149036 A CN201210149036 A CN 201210149036A CN 103422152 A CN103422152 A CN 103422152A
- Authority
- CN
- China
- Prior art keywords
- metal wire
- surface treatment
- material surface
- treatment facility
- wire material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Abstract
The invention provides a metal wire rod surface treatment device. A metal wire rod includes a core wire and an oxidation layer coated outside the core wire. The metal wire rod surface treatment device includes: an electrolytic unit, and a film coated unit. The electrolytic unit includes an activating device and a derusting device; through the activating device, the metal wire rod is subjected to anode electrolysis, and the oxidation layer of the metal wire rod is activated; the derusting device removes the oxidation layer of the metal wire rod by an electrolysis mode, and the electrolytic derusting unit adopts an alkaline electrolyte solution. Through the activating device, the oxidation layer of the metal wire rod is activated, and the oxidation layer is initially destroyed, so that the derusting device can more easily remove the oxidation layer, and the quality and the production efficiency are improved; and with the use of the alkaline electrolyte solution, the pollution to the environment is low, and the security is higher.
Description
Technical field
The present invention relates to a kind of metal wire processing units, particularly relate to a kind of metal wire material surface treatment facility.
Background technology
Consult Fig. 1, for No. 168748 " continuous process of wire rod and device " patent of invention case of TaiWan, China patent announcement, the device of the continuous processing that this case discloses, comprise one for line cylinder 11, an electrolysis cells 12, an ablution groove 13, a drying installation 14, and a spool 15.This electrolysis cells 12 has a power supply 121, an anode be electrically connected to this power supply 121 122, a negative electrode 123 be electrically connected to this power supply 121, reach the electrolyzer 124 of accommodating this negative electrode 123 and electrolytic solution, this electrolytic solution is to be mixed by mistake chloric acid, tertiary alcohol, primary alcohol, or is mixed by acetic acid and mistake chloric acid.
One wire rod 16 is sent by this confession line cylinder 11, through this electrolysis cells 12, carrying out this electrochemical reaction makes the surface of this wire rod 16 processed and remove zone of oxidation, next the electrolytic solution on this wire rod 16 by ablution groove 13 wash and remove residual, after this drying installation 14 is dried, finally by this spool 15, this wire rod 16 is furled again.
By above-mentioned processing unit (plant), can remove the zone of oxidation on wire rod 16 surfaces, however above-mentioned processing unit (plant), what use is acid electrolyte, high to the contaminative of environment, therefore for recovery, the aftertreatment of electrolytic solution, are all appreciable expenses, indirectly improve the cost of processing.
Summary of the invention
The object of the present invention is to provide a kind of metal wire material surface treatment facility that can reach the effects such as contaminative is low, working (machining) efficiency raising.
Metal wire material surface treatment facility of the present invention, this metal wire comprises a heart yearn, and a zone of oxidation be coated on outside this heart yearn, and this metal wire material surface treatment facility comprises: an electrolysis cells, and a coating film unit.
This electrolysis cells comprises an activating apparatus, an and rust-removing device, this activating apparatus carries out anode electrolysis to this metal wire, activate the zone of oxidation of this metal wire, this rust-removing device is removed this zone of oxidation to this metal wire in the mode of electrolysis, make this heart yearn exposed, and this electrolytic derusting unit is to use alkaline electrolyte.This coating film unit is to phosphate coating on this core cladding.
The object of the invention to solve the technical problems also can be used in lower technical measures and further realize.
Preferably, aforesaid metal wire material surface treatment facility, wherein the activating apparatus of this electrolysis cells has the activated bath of an accommodating electrolytic solution, two conductive parts of being located at respectively these activated bath two ends, and a washing bath of being located at after this activated bath.
Preferably, aforesaid metal wire material surface treatment facility, wherein the rust-removing device of this electrolysis cells has the rust cleaning groove of an accommodating electrolytic solution, two conductive parts of being located at respectively these rust cleaning groove two ends, a scrub part of being located at after this conductive part, and a washing bath of being located at behind this scrub part.
Preferably, aforesaid metal wire material surface treatment facility, wherein this coating film unit comprises the tunicle groove of an accommodating phosphoric acid saline solution, and a dryer of being located at after this tunicle groove.
Preferably, aforesaid metal wire material surface treatment facility, the alkaline electrolyte that wherein this rust-removing device is used, its pH-value is 8 to 10.
Preferably, aforesaid metal wire material surface treatment facility, the alkaline electrolyte that wherein this rust-removing device is used, its pH-value is 10.
Preferably, aforesaid metal wire material surface treatment facility, wherein the activating apparatus of this electrolysis cells is to use alkaline electrolyte.
Preferably, aforesaid metal wire material surface treatment facility, the alkaline electrolyte that wherein this activating apparatus is used, its pH-value is 8.
Preferably, aforesaid metal wire material surface treatment facility, wherein this metal wire material surface treatment facility also comprises one and is arranged on before this electrolysis cells and, by the straightener of this metal wire aligning, this straightener comprises several rollers that are spaced and wear for this metal wire.
Beneficial effect of the present invention is: the zone of oxidation that activates this metal wire by this activating apparatus, can tentatively destroy this zone of oxidation, allow rust-removing device can remove relatively easily this zone of oxidation, improve quality and production efficiency, and use alkaline electrolytic solution in this rust-removing device, contaminative for environment is low, and security is higher.
The accompanying drawing explanation
Fig. 1 is a schematic diagram, and No. 168748 " continuous process of wire rod and device " patent of invention case of TaiWan, China patent announcement is described;
Fig. 2 is a schematic diagram, and a preferred embodiment of metal wire material surface treatment facility of the present invention is described;
Fig. 3 is a schematic diagram, and the aspect of the metal wire that the present invention uses is described;
Fig. 4 is a partial enlarged drawing, aid illustration Fig. 2.
Embodiment
Below in conjunction with drawings and Examples, the present invention is described in detail.
Consult Fig. 2 and Fig. 3, a preferred embodiment for metal wire material surface treatment facility of the present invention, this metal wire 2 comprises a heart yearn 21, reach one and be coated on the outer zone of oxidation 22 of this heart yearn 21, this metal wire material surface treatment facility sequentially comprises a straightener 3, two electrolysis cells 4, a coating film unit 5, and a collecting machine 6.
It should be noted that, in Fig. 3, the thickness of the zone of oxidation 22 of this metal wire 2 is not substantial proportion, just for convenient, draws and explanation.
This straightener 3 comprises several rollers 31 that are spaced and wear for this metal wire 2, therefore can be by these metal wire 2 alignings.
Consult Fig. 4, each electrolysis cells 4 comprises an activating apparatus 41, and a rust-removing device 42.This activating apparatus 41 comprises that an activated bath 411, two that is equipped with electrolytic solution is located at respectively the conductive part 412 at these activated bath 411 two ends, and a washing bath 413 of being located at after this activated bath 411.
This rust-removing device 42 comprises that a rust cleaning groove 421, two that is equipped with electrolytic solution is located at respectively the scrub part 423 after the conductive part 422, at these rust cleaning groove 421 two ends is located at this conductive part 422, an and washing bath 424 of being located at behind this scrub part 423, the activating apparatus 41 of this electrolysis cells 4, rust-removing device 42 are all to use alkaline electrolyte, in the present embodiment, its pH-value (pH value) is 8 ~ 10, preferably, the electrolytic solution pH-value used in activating apparatus 41 is 8, and the electrolytic solution pH-value used in this rust-removing device 42 is 10, but not as limit.
Consult again Fig. 2 and Fig. 3, this coating film unit 5 comprises the tunicle groove 51 of an accommodating phosphoric acid saline solution, and a dryer 52 after this tunicle groove 51.This heart yearn of 5 pairs of this coating film unit 21 is covered with phosphate coating.
Below explanation is that direction with arrow A in Fig. 2 sequentially explains, after this metal wire 2 is aligned via straightener 3, enter this electrolysis cells 4, be introduced into this activating apparatus 41, by described conductive part 412, this metal wire 2 is become positively charged, make this metal wire 2 carry out anode electrolysis at activated bath 411, activate the zone of oxidation 22 of this metal wire 2, be mainly used in disruptive oxidation layer 22 structure and tentatively remove zone of oxidation 22, partial oxidation layer 22 is formed to metal ion, and accelerate metal ion and form metal hydroxides, enter again this washing bath 413, wash away the electrolytic solution that remains in this metal wire 2.
Next, this metal wire 2 enters this rust-removing device 42, by described conductive part 422, continue to allow this metal wire 2 become positively charged equally, carry out electrochemical reaction while allowing this metal wire 2 enter this rust cleaning groove 421, remove this zone of oxidation 22 in the mode of electrolysis, due to when the activating apparatus 41 by the structure deteriorate of most zone of oxidation 22, so this rust-removing device 42 can remove the zone of oxidation 22 of this metal wire 2 rapidly, make this heart yearn 21 exposed, the mode of more rinsing with mechanical force brushing or water cutter by this scrub part 423 is removed residual zone of oxidation 22, finally enter this washing bath 424, wash away the electrolytic solution remained on this heart yearn 21.
It should be noted that, in the present embodiment, after this metal wire 2 enters this straightener 3, sequentially enter electrolysis cells 4 twice, but with twice, be not limited, can reach on demand the rust cleaning effect only enters once, or the electrolysis cells more than three times 4, also can look metal wire 2 outward appearance demands, conversion Arrays Aluminum Films in Acid Solution, formula, and can utilize electrolytic reaction to reach the effect of polishing, electropolishing is to make heart yearn 21 uneven surface after rust cleaning of metal wire 2 more mild, reaches with naked eyes and watches and can produce brighter effect.
This heart yearn 21 finally enters the tunicle groove 51 of this coating film unit 5, be covered with phosphoric acid salt, form phosphate coating, make the Surface Creation solidity to corrosion phosphate compounds of this heart yearn 21, improve erosion resistance, antirust and lubricated effect arranged, while making follow-up this heart yearn 21 be stretched the line operation, contribute to reduce the grinding loss chance.Then utilize this dryer 52 that residual not dry phosphoric acid salt is toasted, evapotranspires, the heart yearn 21 that will be covered with phosphate coating by this collecting machine 6 furls, for follow-up procedure for processing.
Therefore in the present embodiment, this metal wire 2 is that activating apparatus 41, the rust-removing device 42 at this electrolysis cells 4 carries out respectively the electrochemical reaction of twice use alkaline electrolyte, compared to general use acidity or neutral electrolyte, use alkaline electrolyte to contribute to make metal ion to form metal hydroxides, and then easily form throw out, after electrolytic solution reclaims, can remove throw out in the mode of filtering comparatively easily, just can again recycle; Under electrochemical reaction, alkaline electrolyte can form oxygen fast in addition, the zone of oxidation 22 of this metal wire 2 is destroyed by oxygen, and easily from this heart yearn 21, peel off, therefore, the preliminary zone of oxidation 22 of destroying this metal wire 2 in this activating apparatus 41, allow the zone of oxidation 22 of metal wire 2 in rust-removing device 42 more easily be stripped from, to separate, improve effect and the speed of rust cleaning.
In sum, metal wire 2 surface processing equipments of the present invention, utilize electrolysis cells 4 to carry out respectively twice electrolytic reaction, first one-step electrolysis in activating apparatus 41, the zone of oxidation 22 of activated metal wire rod 2, reach and accelerate the effect that metal ion forms metal hydroxides, destroys these zone of oxidation 22 structures, recycle this rust-removing device 42 and remove effectively, rapidly the zone of oxidation 22 of this metal wire 2, improve the speed of rust cleaning, and in above-mentioned electrolytic reaction, be all to use alkaline electrolyte, contaminative is low, the convenient cycling and reutilization that reclaims.
Claims (9)
1. a metal wire material surface treatment facility, this metal wire comprises a heart yearn, an and zone of oxidation be coated on outside this heart yearn, this metal wire material surface treatment facility comprises the electrolysis cells that at least one removes this zone of oxidation, and a coating film unit to phosphate coating on this core cladding, it is characterized in that:
This electrolysis cells comprises an activating apparatus, an and rust-removing device, this activating apparatus carries out anode electrolysis to this metal wire, activate the zone of oxidation of this metal wire, this rust-removing device is removed this zone of oxidation to this metal wire in the mode of electrolysis, make this heart yearn exposed, and this rust-removing device is to use alkaline electrolyte.
2. metal wire material surface treatment facility according to claim 1, it is characterized in that, the activating apparatus of this electrolysis cells has the activated bath of an accommodating electrolytic solution, two conductive parts of being located at respectively these activated bath two ends, and a washing bath of being located at after this activated bath.
3. metal wire material surface treatment facility according to claim 2, it is characterized in that, the rust-removing device of this electrolysis cells has the rust cleaning groove of an accommodating electrolytic solution, two conductive parts of being located at respectively these rust cleaning groove two ends, a scrub part of being located at after this conductive part, and a washing bath of being located at behind this scrub part.
4. metal wire material surface treatment facility according to claim 3, is characterized in that, this coating film unit comprises the tunicle groove of an accommodating phosphoric acid saline solution, and a dryer of being located at after this tunicle groove.
5. metal wire material surface treatment facility according to claim 1, is characterized in that, the alkaline electrolyte that this rust-removing device is used, and its pH-value is 8 to 10.
6. metal wire material surface treatment facility according to claim 5, is characterized in that, the alkaline electrolyte that this rust-removing device is used, and its pH-value is 10.
7. metal wire material surface treatment facility according to claim 6, is characterized in that, the activating apparatus of this electrolysis cells is to use alkaline electrolyte.
8. metal wire material surface treatment facility according to claim 7, is characterized in that, the alkaline electrolyte that this activating apparatus is used, and its pH-value is 8.
9. according to the described metal wire material surface treatment facility of the arbitrary claim of claim 1 to 8, it is characterized in that, this metal wire material surface treatment facility also comprises one and is arranged on before this electrolysis cells and, by the straightener of this metal wire aligning, this straightener comprises several rollers that are spaced and wear for this metal wire.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101490367A CN103422152A (en) | 2012-05-15 | 2012-05-15 | Metal wire rod surface treatment device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101490367A CN103422152A (en) | 2012-05-15 | 2012-05-15 | Metal wire rod surface treatment device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103422152A true CN103422152A (en) | 2013-12-04 |
Family
ID=49647525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101490367A Pending CN103422152A (en) | 2012-05-15 | 2012-05-15 | Metal wire rod surface treatment device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103422152A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107414649A (en) * | 2017-05-16 | 2017-12-01 | 赵新超 | A kind of metal tube rust-cleaning integrating machine |
| CN107497759A (en) * | 2017-09-11 | 2017-12-22 | 马鞍山市松林刮刀锯有限公司 | A kind of scraper cleaning device |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB245170A (en) * | 1925-03-30 | 1926-01-07 | Seal Company London Ltd | An electrolytic process for the removal of rust and scale from metals |
| JPS58185772A (en) * | 1982-04-21 | 1983-10-29 | Nisshin Steel Co Ltd | Prevention method of discoloration of steel strip in electrolytic cleaning line |
| JPS60228700A (en) * | 1984-04-26 | 1985-11-13 | Citizen Watch Co Ltd | Method for activating stainless steel |
| CN1242439A (en) * | 1998-07-01 | 2000-01-26 | 日本巴可莱新株式会社 | Method and apparatus for quick forming phosphate covering film on steel wire |
| CN202028718U (en) * | 2011-01-04 | 2011-11-09 | 无锡市常欣机电科技有限公司 | Straightener for derusting machine |
-
2012
- 2012-05-15 CN CN2012101490367A patent/CN103422152A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB245170A (en) * | 1925-03-30 | 1926-01-07 | Seal Company London Ltd | An electrolytic process for the removal of rust and scale from metals |
| JPS58185772A (en) * | 1982-04-21 | 1983-10-29 | Nisshin Steel Co Ltd | Prevention method of discoloration of steel strip in electrolytic cleaning line |
| JPS60228700A (en) * | 1984-04-26 | 1985-11-13 | Citizen Watch Co Ltd | Method for activating stainless steel |
| CN1242439A (en) * | 1998-07-01 | 2000-01-26 | 日本巴可莱新株式会社 | Method and apparatus for quick forming phosphate covering film on steel wire |
| CN202028718U (en) * | 2011-01-04 | 2011-11-09 | 无锡市常欣机电科技有限公司 | Straightener for derusting machine |
Non-Patent Citations (1)
| Title |
|---|
| 张允诚 等: "《电镀手册（第四版）》", 31 December 2011, 国防工业出版社, article "钢铁零件的强浸蚀", pages: 84 - 86 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107414649A (en) * | 2017-05-16 | 2017-12-01 | 赵新超 | A kind of metal tube rust-cleaning integrating machine |
| CN107414649B (en) * | 2017-05-16 | 2019-06-07 | 赵新超 | A kind of metal tube rust-cleaning integrating machine |
| CN107497759A (en) * | 2017-09-11 | 2017-12-22 | 马鞍山市松林刮刀锯有限公司 | A kind of scraper cleaning device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102059637A (en) | Mechanical steel wire scale removing method | |
| CN101631427B (en) | Method for plating thick gold layer in circuit board manufacturing process | |
| CN104120460B (en) | A kind of method removing electrolytic copper foil Ni-Ti anode surface scale | |
| CN102061503A (en) | Electrolytic phosphating method for steel wires | |
| CN102586838A (en) | On-line low temperature electrolysis phosphating method for steel wires | |
| CN101275270A (en) | Electrolytic brightening process for martensitic stainless steel holder | |
| CN102899697A (en) | Copper plating process for welding wire | |
| CN103074666B (en) | A kind of electrolytic derusting agent and electrolytic derusting method | |
| CN105543948A (en) | Copper stripping process for dummy plates/corrugated plates for PCB electroplating | |
| CN103361663A (en) | Ultrasonic descaling method of steel wires | |
| CN201873767U (en) | Copperizing device of solder wire | |
| CN102677070A (en) | Surface processing method of bright electrolytic copper foil and device using method | |
| CN102618912A (en) | Surface treatment process method before wiredrawing of welding wire | |
| CN103422152A (en) | Metal wire rod surface treatment device | |
| CN103334109A (en) | Acid pickling method | |
| CN104694937B (en) | A kind of micro- alkalization transitional period heat exchanger electrochemistry induction filming method of recirculated cooling water | |
| CN204434708U (en) | Photovoltaic welding belt is coated with tin device | |
| CN104328476B (en) | A kind of electrolyte and the method removing silverware surface mottle with this electrolyte | |
| CN110735166A (en) | High-speed copper plating process for submerged arc welding wires | |
| CN102732867A (en) | Online phosphatization apparatus of metal wire rods | |
| CN203653724U (en) | High speed electroplating line equipment for IC pins | |
| CN106929907B (en) | A kind of line Pipe surface derusting technique | |
| CN102277600A (en) | Surface treatment method for electroplated copper door | |
| CN107267966A (en) | A kind of continuous chrome-plated process of pin cloth | |
| CN204676184U (en) | Surface of aluminum plate anodic oxidation production line |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20131204 |