CN1034181C - Composite water-proof cold adhesive - Google Patents
Composite water-proof cold adhesive Download PDFInfo
- Publication number
- CN1034181C CN1034181C CN92106618A CN92106618A CN1034181C CN 1034181 C CN1034181 C CN 1034181C CN 92106618 A CN92106618 A CN 92106618A CN 92106618 A CN92106618 A CN 92106618A CN 1034181 C CN1034181 C CN 1034181C
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- natural gum
- polystyrene foam
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- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The present invention relates to a composite cold rubber adhesive, which belongs to the technical field of water-proof materials for buildings. When a colored product is manufactured, the composite cold rubber adhesive has the compositions of 10 to 35% of polystyrene foam, 10 to 20% of rubber, 3 to 10% of antiager, 10 to 35% of petroleum resin, 10 to 25% of gasoline, 10 to 25% of straight-run oil No. 200 and 2 to 5% of pigment. The composite cold rubber adhesive of the present invention has the advantages of no running at high temperature, no brittle fracture at low temperature and no heating during construction; the composite cold rubber adhesive can be directly applied to various base materials.
Description
The present invention relates to building water-proof material technology field, is a kind of cold glue size of rubber and plastic compound.
Present existing building water-proof material, major part be plastic ointment, be coated with plastic cement etc.It is that base-material is made that these sizing materials all adopt plastics, coal tar wet goods, and there is following some deficiency in it: product is paste, need heat during construction and dissolve, and contaminate environment, construction is complicated; Because adopt coal tar to make base-material, product color is black, when being used for waterproof and heat-insulating, it is more to absorb heat, and effect of heat insulation is poor; Performance such as cohesive strength, high-low temperature resistant is all relatively poor, and work-ing life is shorter.
The objective of the invention is, a kind of composite water-proof cold adhesive is provided, make its product be liquid state, can directly be coated on the various base-materials, and make various colored sizing materials, be used for waterproof, anticorrosion, insulation, heat insulation etc. according to the needs of purposes, and has cohesiveness preferably, higher high-and low-temperature resistance performance reduces cost, and is cheap.
The present invention has proposed two kinds of recipe ingredients in order to reach goal of the invention, and a kind of recipe ingredient is used to make black product, and another kind of recipe ingredient is used to make coloured prod.The recipe ingredient that the present invention makes coloured prod is: (each amounts of components of the present invention all is weight percents) polystyrene foam: 10～35%, rubber: 10～20%, anti-aging agent: 3～10%, petroleum resin: 10～35%, gasoline: 10～25%, 200
#Virgin oil: 10～25%, pigment: 2～5%.The recipe ingredient that the present invention makes coloured prod can also be: polystyrene foam: 20～30%, natural gum: 5～10%, synthetical glue: 5～10%, anti-aging agent: 5～9%, petroleum resin: 15～25%, gasoline: 15～20%, 200
#Virgin oil: 15～20%, pigment: 2～5%.
The recipe ingredient that the present invention makes coloured prod can also be: polystyrene foam: natural gum 20%: synthetical glue 10%: petroleum resin 6%: anti-aging agent 20%: gasoline 6%: 15%, 200
#Virgin oil: 20%, pigment 3%.
The recipe ingredient that the present invention makes black product is: polystyrene foam: 10～25%, natural gum: 5～10%, synthetical glue: 5～10%, petroleum pitch: 15～30%, anti-aging agent: 3～10%, 200
#Virgin oil: 10～25%, gasoline: 10～20%, additive: 2～10%.
The recipe ingredient that the present invention makes black product is: polystyrene foam: 15～20%, natural gum: 6～8%, synthetical glue: 6～8%, petroleum pitch: 20～25%, anti-aging agent: 5～8%, 200
#Virgin oil: 15～20%, gasoline: 13～17%, additive: 5～8%.
The recipe ingredient that the present invention makes black product is: polystyrene foam: natural gum 15%: synthetical glue 7%: petroleum pitch 10%: anti-aging agent 22%: 8%, 200
#Virgin oil: gasoline 18%: additive 15%: 5%.
Natural gum described in the above-mentioned recipe ingredient of the present invention can be chosen one wantonly: resin, guayule, blue or green glue, taraxacum glue in following glue class.Described synthetical glue can be chosen one wantonly: styrene-butadiene rubber(SBR), poly-different elastoprene, polybutadiene rubber, isoprene-isobutylene rubber, chloroprene rubber in following glue class.Anti-aging agent described in the recipe ingredient of the present invention is: antioxidant D, phenyl-β-theamin, antioxidant DPPD, N, N-diphenyl-para-phenylene diamine, antioxidant SP and antioxidant BLE.Additive of the present invention is a cobalt naphthenate.
The method that the present invention makes coloured prod is: according to making coloured prod recipe ingredient of the present invention, with polystyrene foam, synthetical glue, petroleum resin, use crusher in crushing, the retort of packing into then is heated to about 200 ℃, react, add natural gum and 200 again
#Virgin oil fully dissolves it.Mixture in the retort is put into ball mill carry out the ball milling first time, and then add anti-aging agent and pigment carries out the ball milling second time.Will be through the mixture of (granularity reaches about 200 orders) behind the secondary ball milling, pour into and add waste vapour oil in the reactor and fully be dissolved to liquid.
The method that the present invention makes black product is: according to the recipe ingredient of making black product of the present invention, with polystyrene foam, synthetical glue, natural gum, each personal crusher is broken separately standby.Petroleum pitch is heated to 250～280 ℃ of fusings, adds broken good natural gum, synthetical glue then, wait to be cooled to 120～80 ℃ after, put into reactor, add polystyrene foam and 200 again
#Straight run is dissolved, and carries out the ball milling first time then.Add anti-aging agent and additive in the mixture behind ball milling, carry out the ball milling second time again.Adding waste vapour oil behind second time ball milling in the mixture of (granularity is about 200 orders) carries out abundant stirring and dissolving and becomes liquid.
Because product of the present invention when not adding petroleum pitch, is transparent liquid, thereby can makes shades of colour.Can according to the construction required, make white, green, redness etc., the present invention after testing, every performance is all better.High temperature resistant: 120 ℃, low temperature resistant :-40 ℃, acid resistance: as in 1% sulphuric acid soln, to soak after 15 days, do not have and peel off foaming.Alkali resistance: in saturated Ca (OH) solution, soak under the normal temperature 32 days waterproof, non-foaming, cohesive strength: 20 * 2 ℃ of cross-lap joint methods detect tensile strength＞0.46MPa, watertightness: moving hydraulic pressure is forced into 0.3MPa, filmed waterproof on 15th, low temperature flexibility :-40 ℃, the coating test specimen is passed through Φ 10mm garden rod, film no reticulate pattern, crackle, nothing peels off elongation: 15%.The present invention has high temperature does not trickle, the advantage of not embrittlement of low temperature, and construction need not heated, and can directly be coated on the various base materials, all can construct under the temperature in four seasons, and cohesive force is strong, and is ageing-resistant, and long service life is with low cost.
Embodiment 1: the recipe ingredient of producing coloured prod according to the present invention, in 100 kilograms of products, get by weight: polystyrene foam: 20 kilograms, natural gum 10 kilograms, styrene-butadiene rubber(SBR): 6 kilograms, antioxidant D: 4 kilograms, petroleum resin: 20 kilograms, gasoline: 20 kilograms, 200
#Virgin oil: 15 kilograms, veridian: 5 kilograms.Produce coloured prod of the present invention according to the method for making coloured prod of the present invention.
Embodiment 2: the recipe ingredient of producing coloured prod according to the present invention, in 100 kilograms of products, get by weight: polystyrene foam: 10 kilograms, guayule: 8 kilograms, chloroprene rubber: 6 kilograms, antioxidant SP: 5 kilograms, petroleum resin: 30 kilograms, gasoline: 16 kilograms, 200
#Virgin oil: 25 kilograms, white pigment: 5 kilograms.Produce coloured prod of the present invention according to the method for making coloured prod of the present invention.
Embodiment 3: the recipe ingredient of producing coloured prod according to the present invention, in 200 kilograms of products, get polystyrene foam: 400 kilograms, blue or green glue: 20 kilograms, 12 kilograms of isoprene-isobutylene rubbers, petroleum resin: 40 kilograms, antioxidant BLE: 30 kilograms of 12 kilograms, gasoline.200
#Virgin oil: 40 kilograms, red pigment: 6 kilograms.Produce coloured prod of the present invention according to the method for making coloured prod of the present invention.
Embodiment 4: according to the recipe ingredient that the present invention produces black product, in 100 kilograms of products, get: polystyrene foam: 12 kilograms, taraxacum glue: 7 kilograms, polybutadiene rubber: 6 kilograms, petroleum pitch: 25 kilograms, antioxidant D: 5 kilograms, and 200
#Virgin oil: 20 kilograms, gasoline: 20 kilograms, cobalt naphthenate: 5 kilograms.Method according to making black product of the present invention is produced.
Embodiment 5: the recipe ingredient of producing black product according to the present invention, in 100 kilograms of products, get polystyrene foam: 25 kilograms, natural gum: 5 kilograms, isoprene-isobutylene rubber: 10 kilograms, petroleum pitch: 25 kilograms, antioxidant DPPD: 5 kilograms, 200# virgin oil: 15 kilograms, gasoline: 10 kilograms, cobalt naphthenate: 5 kilograms.Method according to making black product of the present invention is produced.
Embodiment 6: according to the recipe ingredient that the present invention produces black product, in 50 kilograms of products, get polystyrene foam: 7.5 kilograms, blue or green glue: 3.5 kilograms, polybutadiene rubber: 5 kilograms, petroleum pitch: 11 kilograms, antioxidant D: 4 kilograms, 200
#Virgin oil: 9 kilograms, gasoline: 7.5 kilograms, cobalt naphthenate: 2.5 kilograms, according to making black product of the present invention.
Claims (2)
- One, a kind of colored composite water-proof cold adhesive is characterized in that comprising:Polystyrene foam 20%, natural gum 10%, synthetical glue 6%, petroleum resin 20%, anti-aging agent 6%, gasoline 15%, 200 #Virgin oil 20%, pigment 3%, wherein, natural gum is selected from a kind of in guayule, blue or green glue, the taraxacum glue, and synthetical glue is selected from a kind of in styrene-butadiene rubber(SBR), chloroprene rubber, the isoprene-isobutylene rubber,Anti-aging agent is selected from Phenyl beta naphthylamine.
- Two, a kind of black composite water-proof cold adhesive is characterized in that comprising:Polystyrene foam 15%, natural gum 7%, synthetical glue 10%, petroleum pitch 22%, anti-aging agent 8%, 200 #Virgin oil 18%, gasoline 15%, additive 5%, wherein, natural gum is selected from a kind of in guayule, blue or green glue, taraxacum glue, the natural gum,Synthetical glue is selected from a kind of in isoprene-isobutylene rubber, the polybutadiene rubber,Anti-aging agent is selected from Phenyl beta naphthylamine,Additive is selected from cobalt naphthenate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92106618A CN1034181C (en) | 1992-07-18 | 1992-07-18 | Composite water-proof cold adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92106618A CN1034181C (en) | 1992-07-18 | 1992-07-18 | Composite water-proof cold adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1081457A CN1081457A (en) | 1994-02-02 |
| CN1034181C true CN1034181C (en) | 1997-03-05 |
Family
ID=4942275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92106618A Expired - Fee Related CN1034181C (en) | 1992-07-18 | 1992-07-18 | Composite water-proof cold adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1034181C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1093556C (en) * | 1998-04-17 | 2002-10-30 | 抚顺市辽东合成防水材料厂 | Five-element butyl rubber-asphalt waterproof cold adhering material |
| CN103773021A (en) * | 2014-01-20 | 2014-05-07 | 南通东南公路工程有限公司 | Asphalt roof waterproof material |
-
1992
- 1992-07-18 CN CN92106618A patent/CN1034181C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1081457A (en) | 1994-02-02 |
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| CF01 | Termination of patent right due to non-payment of annual fee |