CN103409214B - Cold rolling lubricant for titanium and titanium alloy strips - Google Patents
Cold rolling lubricant for titanium and titanium alloy strips Download PDFInfo
- Publication number
- CN103409214B CN103409214B CN201310375607.3A CN201310375607A CN103409214B CN 103409214 B CN103409214 B CN 103409214B CN 201310375607 A CN201310375607 A CN 201310375607A CN 103409214 B CN103409214 B CN 103409214B
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- CN
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- Prior art keywords
- agent
- compound
- titanium
- mass ratio
- oil
- Prior art date
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000010936 titanium Substances 0.000 title claims abstract description 14
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 13
- 239000000314 lubricant Substances 0.000 title claims abstract description 11
- 238000005097 cold rolling Methods 0.000 title claims abstract description 9
- 229910001069 Ti alloy Inorganic materials 0.000 title claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000003921 oil Substances 0.000 claims abstract description 8
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 3
- 239000002131 composite material Substances 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 18
- -1 phosphamide ester Chemical class 0.000 claims description 12
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 8
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 8
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 6
- 239000002199 base oil Substances 0.000 claims description 6
- SJTOTXNQRUESGY-KVVVOXFISA-N (z)-octadec-9-enoic acid;oxalic acid Chemical compound OC(=O)C(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O SJTOTXNQRUESGY-KVVVOXFISA-N 0.000 claims description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 4
- 235000021314 Palmitic acid Nutrition 0.000 claims description 4
- 229920002367 Polyisobutene Polymers 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 229960004025 sodium salicylate Drugs 0.000 claims description 4
- 239000001384 succinic acid Substances 0.000 claims description 4
- 229960002317 succinimide Drugs 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 2
- 238000001816 cooling Methods 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000000137 annealing Methods 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000013556 antirust agent Substances 0.000 abstract 1
- 239000004359 castor oil Substances 0.000 abstract 1
- 235000019438 castor oil Nutrition 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 3
- LUNUTDXQTSGSJG-LFABVHOISA-N (2S)-2-amino-2-cyclohexyl-N-(1-diphenoxyphosphorylethyl)acetamide Chemical compound C1([C@H](N)C(=O)NC(C)P(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)CCCCC1 LUNUTDXQTSGSJG-LFABVHOISA-N 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000003913 materials processing Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention relates to a cold rolling lubricant for titanium and titanium alloy strips. The lubricant uses combination of #32 total loss oil for a system and refined castor oil as basic oil, and is matched with a plurality of composite additives. The lubricant comprises an antiwear agent, an oiliness agent, an antioxidant preservative, an anti-foaming agent, an antirust agent, a clearing agent, a dispersant and the like. The lubricant has cooling, lubricating and cleaning properties, and can be used for reducing the extent of the roller adhered to titanium and reducing damage caused by adhesion on the surfaces of the plate and strip, so that annealing treatment is conveniently performed to obtain required mechanical properties.
Description
Technical field
The invention belongs to titanium or titanium alloy Strip cold-rolling lubricant field.
Background technology
Titanium material anisotropy is remarkable, and rolling bounce is high, and tensile strength and yield strength increase with working modulus; Elongation increases and reduces with working modulus.The rolling of cold rolling employing minor diameter working roll.Titanium is when cold rolling, and along with the increasing of reduction in pass and roll speed are accelerated, surface smoothness can reduce, the hot sticky phenomenon of Here it is roll and material, and the small abrasion powder at this moment generating is attached on roll or material surface, makes plate surface coarse.To avoid this point completely, consider it is very difficult from rolling efficiency.To this, be generally rolling under more or less hot sticky condition, compared with the stainless steel of same size, draught, roll speed are all lower, and road number of times is also some more; Meanwhile, cold rollingly cause materials processing sclerosis, must just can obtain required mechanical property through anneal.Solve these problems in the titanium material operation of rolling, just must carry out in advance surface treatment to blank, select effective technology lubricant simultaneously, to reduce the sticky titanium degree of roll.
Summary of the invention
The technical problem to be solved in the present invention be to provide a kind of cooling, lubricated, cleaning performance is good, can reduce the sticky titanium of roll degree, reduce the damage on strip surface, be convenient to the titanium or titanium alloy Strip cold-rolling lubricant of anneal.
The present invention solves the problems of the technologies described above using following technical scheme: adopt No. 32 total loss systems compound as base oil with oil and smart Viscotrol C, coordinate multiple composite additive, its component and mass percent are:
| Component | Content (mass percent) |
| Base oil | 78%～85% |
| Anti-wear agent | 5.0%～8.0% |
| Oiliness improver | 7.0%～10.0% |
| Antioxidant preservative | 0.5%～1.0% |
| Kilfoam | 0.001%～0.005% |
| Rust-preventive agent | 0.5%～1.5% |
| Purification agent | 0.5%～1.0% |
| Dispersion agent | 0.8%～1.0% |
Base oil is that No. 32 total loss systems oil of mass ratio 70%～80% is compound with 30%～20% smart Viscotrol C.
Anti-wear agent is that boronation phosphamide ester and 30%～20% the borate of mass ratio 70%～80% is compound.
Oiliness improver is that Palmitic acid and 40%～50% the oleic acid oxalic acid ester of mass ratio 60%～50% is compound.
Antioxidant preservative is that 2,6 ditertiary butyl p cresol and N-phenyl-a-naphthylamines of 40%～50% of mass ratio 60%～50% is compound.
Kilfoam is dimethyl silicone oil.
Rust-preventive agent is that alkenyl succinic acid and 40%～50% the benzotriazole of mass ratio 60%～50% is compound.
Purification agent is alkyl sodium salicylate.
Dispersion agent is polyisobutene succinimide.
The distinguishing feature of titanium or titanium alloy Strip cold-rolling lubricant of the present invention is to have performance cooling, lubricated, that clean, can reduce the degree of the sticky titanium of roll; Reduce the damage that strip surface adhering causes, be convenient to anneal to obtain required mechanical property.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 32 total loss systems of mass ratio 70% are compound with 30% smart Viscotrol C with oil | 78% |
| The boronation phosphamide ester of mass ratio 70% and 30% borate are compound | 8.0% |
| The Palmitic acid of mass ratio 60% and 40% oleic acid oxalic acid ester are compound | 9.5% |
| The 2,6 ditertiary butyl p cresol of mass ratio 60% and 40% N-phenyl-a-naphthylamines are compound | 1.0% |
| Dimethyl silicone oil | 0.005% |
| The alkenyl succinic acid of mass ratio 60% and 40% benzotriazole are compound | 1.495% |
| Alkyl sodium salicylate | 1.0% |
| Polyisobutene succinimide | 1.0% |
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 32 total loss systems of mass ratio 75% are compound with 25% smart Viscotrol C with oil | 82% |
| The boronation phosphamide ester of mass ratio 75% and 25% borate are compound | 6.5% |
| The Palmitic acid of mass ratio 55% and 45% oleic acid oxalic acid ester are compound | 8.0% |
| The 2,6 ditertiary butyl p cresol of mass ratio 55% and 45% N-phenyl-a-naphthylamines are compound | 0.8% |
| Dimethyl silicone oil | 0.004% |
| The alkenyl succinic acid of mass ratio 55% and 45% benzotriazole are compound | 1.296% |
| Alkyl sodium salicylate | 0.6% |
| Polyisobutene succinimide | 0.8% |
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and is formed by mass percentage:
Above component summation is 100%.
Below the main physical and chemical index of embodiment 3 products:
| Project | Quality index |
| Moisture, % is not more than | Vestige |
| 40 DEG C of kinematic viscosity mm 2/s | 33.2 |
| Flash-point (opening) DEG C, is greater than | 150 |
| Mechanical impurity, % is not more than | 0.07 |
| Last non seizure load (Pb), Kg is not less than | 80 |
| Condensation point, DEG C, not higher than | -5 |
| Water soluble acid or alkali | Nothing |
Claims (1)
1. a titanium or titanium alloy Strip cold-rolling lubricant, is characterized in that adopting No. 32 total loss systems compound as base oil with oil and smart Viscotrol C, coordinates multiple composite additive, and its component and mass percent are:
Each component percentage ratio summation is 100% above;
Wherein:
Base oil is that No. 32 total loss systems oil of mass ratio 70% ~ 80% is compound with 30% ~ 20% smart Viscotrol C;
Anti-wear agent is that boronation phosphamide ester and 30% ~ 20% the borate of mass ratio 70% ~ 80% is compound;
Oiliness improver is that Palmitic acid and 40% ~ 50% the oleic acid oxalic acid ester of mass ratio 60% ~ 50% is compound;
Antioxidant preservative is that 2,6 ditertiary butyl p cresol and N-phenyl-a-naphthylamines of 40% ~ 50% of mass ratio 60% ~ 50% is compound;
Kilfoam is dimethyl silicone oil;
Rust-preventive agent is that alkenyl succinic acid and 40% ~ 50% the benzotriazole of mass ratio 60% ~ 50% is compound;
Purification agent is alkyl sodium salicylate;
Dispersion agent is polyisobutene succinimide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310375607.3A CN103409214B (en) | 2013-08-26 | 2013-08-26 | Cold rolling lubricant for titanium and titanium alloy strips |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310375607.3A CN103409214B (en) | 2013-08-26 | 2013-08-26 | Cold rolling lubricant for titanium and titanium alloy strips |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103409214A CN103409214A (en) | 2013-11-27 |
| CN103409214B true CN103409214B (en) | 2014-07-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310375607.3A Expired - Fee Related CN103409214B (en) | 2013-08-26 | 2013-08-26 | Cold rolling lubricant for titanium and titanium alloy strips |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103409214B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666705B (en) * | 2013-12-14 | 2015-02-18 | 广西大学 | Castor-oil-based rust-proof non-stain hydraulic fluid |
| CN106520299A (en) * | 2016-11-04 | 2017-03-22 | 广西大学 | Lubricating agent composition of ordinary brass alloy plate strip foil cold rolling machining technology |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100081591A1 (en) * | 2008-09-30 | 2010-04-01 | Chevron Oronite Company Llc | Lubricating oil compositions |
| CN102977974A (en) * | 2011-09-02 | 2013-03-20 | 中国石油化工股份有限公司 | Hot rolling lubricating oil composition and use thereof |
| CN103194302A (en) * | 2013-04-19 | 2013-07-10 | 上海禾泰特种润滑技术有限公司 | Worm gear oil composition and preparation method thereof |
-
2013
- 2013-08-26 CN CN201310375607.3A patent/CN103409214B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100081591A1 (en) * | 2008-09-30 | 2010-04-01 | Chevron Oronite Company Llc | Lubricating oil compositions |
| CN102977974A (en) * | 2011-09-02 | 2013-03-20 | 中国石油化工股份有限公司 | Hot rolling lubricating oil composition and use thereof |
| CN103194302A (en) * | 2013-04-19 | 2013-07-10 | 上海禾泰特种润滑技术有限公司 | Worm gear oil composition and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103409214A (en) | 2013-11-27 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140716 |