CN103409179A - Sec-butyl alcohol gasoline - Google Patents

Sec-butyl alcohol gasoline Download PDF

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Publication number
CN103409179A
CN103409179A CN2013103022722A CN201310302272A CN103409179A CN 103409179 A CN103409179 A CN 103409179A CN 2013103022722 A CN2013103022722 A CN 2013103022722A CN 201310302272 A CN201310302272 A CN 201310302272A CN 103409179 A CN103409179 A CN 103409179A
Authority
CN
China
Prior art keywords
sec
butyl alcohol
gasoline
butyl
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013103022722A
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Chinese (zh)
Inventor
傅兵
邱小勇
李启玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuhai Feiyang Novel Materials Corp ltd
Original Assignee
SHENZHEN FEIYANG JUNYAN TECHNOLOGY DEVELOPMENT Co Ltd
ZHUHAI FEIYANG NOVEL MATERIALS Corp Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHENZHEN FEIYANG JUNYAN TECHNOLOGY DEVELOPMENT Co Ltd, ZHUHAI FEIYANG NOVEL MATERIALS Corp Ltd filed Critical SHENZHEN FEIYANG JUNYAN TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN2013103022722A priority Critical patent/CN103409179A/en
Publication of CN103409179A publication Critical patent/CN103409179A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the technical field of vehicle fuel oil, and concretely relates to a sec-butyl alcohol gasoline. The sec-butyl alcohol gasoline is composed of gasoline and sec-butyl alcohol, and the mass percentage concentration of the sec-butyl alcohol is 10-30%. The highest content of the sec-butyl alcohol in the sec-butyl alcohol gasoline can reach 30% without using an additive or installing an engine, so the pollution problem of automobile tail gas is effectively reduced, and the fuel cost is reduced. The sec-butyl alcohol gasoline formed by mixing 10-30mass% of the sec-butyl alcohol with 93# gasoline can completely substitute 93# gasoline. The sec-butyl alcohol has a branched chain structure, has a high octane number, can be easily biodegraded, has a good environmental protection performance and can improve the anti-knock property of the gasoline. The sec-butyl alcohol is generated by reacting butylene in a low-price refinery cracking gas with water, the production power of the sec-butyl alcohol in China is excess, the price of the sec-butyl alcohol is low, and the highest content of the sec-butyl alcohol in the sec-butyl alcohol gasoline can reach 30%, so the cost of the sec-butyl alcohol gasoline is low.

Description

A kind of sec-butyl alcohol gasoline
Technical field
The present invention relates to the fuel oil for vehicles technical field, be specially a kind of sec-butyl alcohol gasoline.
Background technology
Along with the shortage of petroleum resources, constantly the raising up of oil price, resource, the energy, environmental revolution are carried out in society and expanding economy requirement.The blended gasoline replacing gasoline becomes one of focus of research now as vehicle traction fuel.Existing blended gasoline has methanol gasoline, ethanol petrol, methyl tertiary butyl ether gasoline, butanol vapour wet goods usually.Butanols gasoline usually is in harmonious proportion and forms with biological butanol and gasoline, wherein biological butanol is n-butyl alcohol, 2-butanols and butanols isomer mixture, the butanol vapour oil phase is than methanol gasoline and ethanol petrol, have following advantage: the compatibleness of butanols and gasoline is better, can reach higher ratio of mixture with gasoline; Butanols has higher energy density, has fuel economy preferably; A little less than the butanols wetting ability, can be miscible with gasoline.But, in the preparation process of biological butanol, need to use larger evaporation, heating, the facility such as cooling, so investment cost is high, production cost is high, and easily environment is produced to secondary pollution.Butanols gasoline also be faced with thereupon cost high, easily environment is produced to the challenge such as secondary pollution.
Summary of the invention
The object of the invention is to for overcoming the defect of prior art, and provide a kind of cost low, in the situation that do not need to transform engine and do not need to use additive, the mass percent of sec-butyl alcohol can be up to 30% sec-butyl alcohol gasoline.
For achieving the above object, the present invention by the following technical solutions: a kind of sec-butyl alcohol gasoline, described sec-butyl alcohol gasoline is comprised of gasoline and sec-butyl alcohol, the mass percent concentration of described sec-butyl alcohol is 10-30%.
Described gasoline is No. 93 gasoline.
Described sec-butyl alcohol is 1-butylene in refinery's splitting gas and 2-butylene generate with water generation hydration reaction respectively under the effect of an acidic catalyst sec-butyl alcohol.
The mass percent concentration of described sec-butyl alcohol is 20-30%.
The mass percent concentration of described sec-butyl alcohol is 25-30%.
The mass percent concentration of described sec-butyl alcohol is 30%.
The preparation technology of sec-butyl alcohol gasoline: under normal temperature and pressure, gasoline and sec-butyl alcohol are mixed in proportion, filter and get final product.
Compared with prior art, the invention has the beneficial effects as follows: the present invention is in harmonious proportion and forms sec-butyl alcohol gasoline with sec-butyl alcohol and gasoline, in the situation that do not use additive and do not need refiting engine, the content of sec-butyl alcohol can, up to 30%, can effectively reduce the pollution problem of cost and the reduction vehicle exhaust of fuel.By the sec-butyl alcohol gasoline of sec-butyl alcohol and No. 93 gasoline mediation formation, the mass percent of sec-butyl alcohol is 10-30%, can substitute No. 93 gasoline fully.Because the structure of sec-butyl alcohol is branched chain type, octane value is high, readily biodegradable more, and good environmental protection, and can improve the anti-knocking property of gasoline.The butylene of sec-butyl alcohol in cheap refinery's splitting gas reacts generation with water, and the sec-butyl alcohol production capacity surplus of China, the Costco Wholesale of sec-butyl alcohol is low, and in sec-butyl alcohol gasoline, the content of sec-butyl alcohol is higher than the content of alcohol in other alcohol base gasoline simultaneously, so the cost of sec-butyl alcohol gasoline has more advantage.
Embodiment
In order to more fully understand technology contents of the present invention, below in conjunction with specific embodiment, technical scheme of the present invention is further introduced and explanation.
Embodiment 1
Sec-butyl alcohol is 1-butylene in refinery's splitting gas and 2-butylene generate with water generation hydration reaction respectively under the effect of an acidic catalyst sec-butyl alcohol.
Under normal temperature and pressure, No. 93 gasoline are mixed with sec-butyl alcohol, wherein the mass percentage concentration of No. 93 gasoline and sec-butyl alcohol is respectively: No. 93 gasoline 80%, sec-butyl alcohol 20%; Then removing by filter impurity gets final product.
Embodiment 2
The present embodiment is with the difference of implementing 1, and gasoline is No. 97 gasoline.
Embodiment 3
The present embodiment is with the difference of implementing 1, and gasoline is No. 90 gasoline.
Embodiment 4
The present embodiment is with the difference of implementing 1, and the mass percentage concentration of No. 93 gasoline and sec-butyl alcohol is respectively: No. 93 gasoline 70%, sec-butyl alcohol 30%.
Embodiment 5
The present embodiment is with the difference of implementing 1, and the mass percentage concentration of No. 93 gasoline and sec-butyl alcohol is respectively: No. 93 gasoline 90%, sec-butyl alcohol 10%.
Embodiment 6
The present embodiment is with the difference of implementing 1, and the mass percentage concentration of No. 93 gasoline and sec-butyl alcohol is respectively: No. 93 gasoline 75%, sec-butyl alcohol 25%.
Being compared as follows shown in table of sec-butyl alcohol gasoline and other alcohol base gasoline:
Sample Alcohol content Octane value Compatibility (gasoline)
Gasoline (No. 93) 93
Ethanol petrol (E10) 10% 97 Layering was arranged in four days
Butanols gasoline 10% 98 Ten days without layering
Sec-butyl alcohol gasoline 10% 100 Miscible
The cetane value of methyl alcohol, ethanol, propyl alcohol, butanols, propyl carbinol, sec-butyl alcohol is compared as follows shown in table:
Sample Methyl alcohol Ethanol Propyl alcohol Butanols Sec-butyl alcohol
Cetane value 3 8 10 25 30
The above only further illustrates technology contents of the present invention with embodiment, so that the reader is easier to understand, but does not represent that embodiments of the present invention only limit to this, and any technology of doing according to the present invention is extended or recreation, all is subjected to protection of the present invention.

Claims (7)

1. a sec-butyl alcohol gasoline, is characterized in that, described sec-butyl alcohol gasoline is comprised of gasoline and sec-butyl alcohol, and the mass percent concentration of described sec-butyl alcohol is 10-30%.
2. a kind of sec-butyl alcohol gasoline according to claim 1, is characterized in that, described gasoline is No. 93 gasoline.
3. a kind of sec-butyl alcohol gasoline according to claim 2, is characterized in that, described sec-butyl alcohol is 1-butylene in refinery's splitting gas and 2-butylene generate with water generation hydration reaction respectively under the effect of an acidic catalyst sec-butyl alcohol.
4. according to claim 1 or 2 or 3 described a kind of sec-butyl alcohol gasoline, it is characterized in that, the mass percent concentration of described sec-butyl alcohol is 20-30%.
5. according to claim 1 or 2 or 3 described a kind of sec-butyl alcohol gasoline, it is characterized in that, the mass percent concentration of described sec-butyl alcohol is 25-30%.
6. according to claim 1 or 2 or 3 described a kind of sec-butyl alcohol gasoline, it is characterized in that, the mass percent concentration of described sec-butyl alcohol is 30%.
7. the preparation technology of sec-butyl alcohol gasoline as claimed in claim 1, is characterized in that, under normal temperature and pressure, gasoline and sec-butyl alcohol mixed in proportion, and filters and get final product.
CN2013103022722A 2013-07-18 2013-07-18 Sec-butyl alcohol gasoline Pending CN103409179A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013103022722A CN103409179A (en) 2013-07-18 2013-07-18 Sec-butyl alcohol gasoline

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013103022722A CN103409179A (en) 2013-07-18 2013-07-18 Sec-butyl alcohol gasoline

Publications (1)

Publication Number Publication Date
CN103409179A true CN103409179A (en) 2013-11-27

Family

ID=49602222

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2013103022722A Pending CN103409179A (en) 2013-07-18 2013-07-18 Sec-butyl alcohol gasoline

Country Status (1)

Country Link
CN (1) CN103409179A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000026871A (en) * 1998-07-09 2000-01-25 Yamaoka Masaru Low-pollution fuel composition
CN101981165A (en) * 2008-02-12 2011-02-23 布特马斯先进生物燃料有限责任公司 Use of alcohols in fuels for spark ignition engines
CN102234549A (en) * 2010-04-22 2011-11-09 胡先念 Gasoline composition and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000026871A (en) * 1998-07-09 2000-01-25 Yamaoka Masaru Low-pollution fuel composition
CN101981165A (en) * 2008-02-12 2011-02-23 布特马斯先进生物燃料有限责任公司 Use of alcohols in fuels for spark ignition engines
CN102234549A (en) * 2010-04-22 2011-11-09 胡先念 Gasoline composition and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
尚崇礼: "汽油辛烷值增进剂", 《抚顺石油学院学报》 *
颜丹译: "用含氧化合物提高汽油辛烷值", 《燕山油化》 *

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Address after: 519000 Guangdong province Zhuhai Gaolan Port Economic Zone Petrochemical Zone five North Road Feiyang chemical plant

Applicant after: ZHUHAI FEIYANG NOVEL MATERIALS Corp.,Ltd.

Applicant after: SHENZHEN FEIYANG JUNYAN NEW MATERIAL CO.,LTD.

Address before: 519000 Guangdong province Zhuhai Gaolan Port Economic Zone Petrochemical Zone five North Road Feiyang chemical plant

Applicant before: ZHUHAI FEIYANG NOVEL MATERIALS Corp.,Ltd.

Applicant before: SHENZHEN FEIYANG JUNYAN TECHNOLOGY DEVELOPMENT Co.,Ltd.

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Address after: 519000 Guangdong province Zhuhai Gaolan Port Economic Zone Petrochemical Zone five North Road Feiyang chemical plant

Applicant after: ZHUHAI FEIYANG NOVEL MATERIALS Corp.,Ltd.

Address before: 519000 Guangdong province Zhuhai Gaolan Port Economic Zone Petrochemical Zone five North Road Feiyang chemical plant

Applicant before: ZHUHAI FEIYANG NOVEL MATERIALS Corp.,Ltd.

Applicant before: SHENZHEN FEIYANG JUNYAN NEW MATERIAL CO.,LTD.

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Application publication date: 20131127

RJ01 Rejection of invention patent application after publication