CN103408247B - A kind of cement insulation board manufacture method being added with foamable phenolic particle - Google Patents
A kind of cement insulation board manufacture method being added with foamable phenolic particle Download PDFInfo
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- CN103408247B CN103408247B CN201310260660.9A CN201310260660A CN103408247B CN 103408247 B CN103408247 B CN 103408247B CN 201310260660 A CN201310260660 A CN 201310260660A CN 103408247 B CN103408247 B CN 103408247B
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- insulation board
- cement insulation
- foamable phenolic
- particle
- added
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- 239000004568 cement Substances 0.000 title claims abstract description 48
- 238000009413 insulation Methods 0.000 title claims abstract description 39
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 239000002245 particle Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 22
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 239000002002 slurry Substances 0.000 claims abstract description 10
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 10
- 230000008569 process Effects 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 13
- 238000007598 dipping method Methods 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 6
- 235000013539 calcium stearate Nutrition 0.000 claims description 6
- 239000008116 calcium stearate Substances 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 6
- -1 cut Substances 0.000 claims description 4
- 244000198134 Agave sisalana Species 0.000 claims description 3
- 235000011624 Agave sisalana Nutrition 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
- 239000011398 Portland cement Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 230000036541 health Effects 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 238000011112 process operation Methods 0.000 claims 1
- 239000006260 foam Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 3
- 206010000269 abscess Diseases 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
Landscapes
- Building Environments (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
What the present invention proposed is a kind of cement insulation board manufacture method being added with foamable phenolic particle.Through the preparation of foamable phenolic particle, the preparation of cementing Stabilizing Materials, the preparation of base material, slurry, enhanced processes.The cement insulation board adopting the inventive method to make and the greatest advance of common cement insulation board are: reduce thermal conductivity, add toughness, reduce unit weight, reduce use thickness.Be suitable for applying as the manufacture method of wall insulated board.
Description
Technical field
What the present invention proposed is the lagging material of building materials field, specifically a kind of cement insulation board manufacture method being added with foamable phenolic particle.
Background technology
At present, along with country is to the attention of building energy conservation, various wall heat insulation material arises at the historic moment.According to the needs of Building Fire Protection, cement foaming insulation board have also been obtained application.But the shortcoming that current cement foaming insulation board exists is: unit weight is large, poor toughness, water-intake rate are high, thermal conductivity is high, cause volume heavy, carrying is easily damaged, uses thickness thick, takes up room large.The advantage of cement board is not burn, and can realize fire prevention.
Foamable phenolic plate have also been obtained application, but intensity is low, paste difficulty, but thermal conductivity is low, good heat insulating, has not incendivity with metope.
Summary of the invention
In order to improve the performance of cement insulation board, the present invention proposes a kind of cement insulation board manufacture method being added with foamable phenolic particle.The method, by adding foamable phenolic particle in cement insulation board, solves and reduces unit weight and thermal conductivity, increases the technical problem of toughness.
The scheme that technical solution problem of the present invention adopts is:
1, foamable phenolic particle preparation:
Phenolic aldehyde body material through foaming is joined in disk sawtooth nodulizer, makes the particle of 0.1 ~ 5 millimeter.As foamable phenolic particle.
2, cementing Stabilizing Materials preparation: add calcium stearate, polyvinyl formal solution in the polyvinyl formal solution of moisture 50%: calcium stearate mixing ratio 1:1, as cementing Stabilizing Materials.
3, base material: add 4 premium on currency in agitator, add cementing Stabilizing Materials 100 milliliters again, sisal hemp short fibre 50 grams, foamable phenolic particle 1 ~ 3 kilogram, start stirrer fully to stir with the stirring velocity of 400 ~ 500 revs/min, then 5 kilograms of No. 500 ordinary Portland cements are added, abundant stirring 1 minute, finally add the aqueous hydrogen peroxide solution 500 milliliters that content is 28%, stir rapidly, when enlarged volume, be released to mould in agitator immediately, after 5 days aquations, cement insulation board initial set, carries out the demoulding.After the demoulding, health 20 days under envrionment temperature is 20 ~ 30 DEG C and the environment of humidity 20% ~ 80%, becomes cement insulation board blank.
4, cut: after blank drying, by microtome, slice thickness is between 3 ~ 10 centimetres, and length is between 30 ~ 60 centimetres, and width, between 30 ~ 45 centimetres, becomes cement insulation board and becomes material.
5, slurry preparation: by quality, be in the water glass solution of 20 at the degree Beaume of 1 part, adding content is 50% polyvinyl formal solution 1 part, then adds the organosilicon aqueous solution 0.1 part, as slurry after stirring.
6, enhancement process: cement insulation board soaked and carry out dipping enhancement process in the slurry, dipping time is 10 minutes, pulls out after dipping, naturally dries or dries, and becomes the cement insulation board that finished product is added with foamable phenolic particle.
Positively effect, the cement insulation board adopting the inventive method to make and the greatest advance of common cement insulation board are: reduce thermal conductivity, add toughness, reduce unit weight, reduce use thickness.Be suitable for applying as the manufacture method of wall insulated board.
Embodiment
1, foamable phenolic particle preparation:
By the phenolic aldehyde body material through foaming, join in disk sawtooth nodulizer, make the particle of 0.1 ~ 5 millimeter.As foamable phenolic particle.
2, cementing Stabilizing Materials preparation: add calcium stearate, polyvinyl formal solution in the polyvinyl formal solution of moisture 50%: calcium stearate ratio 1:1, as cementing Stabilizing Materials.
3, base material: add 4 premium on currency in agitator, add cementing Stabilizing Materials 100 milliliters again, sisal hemp short fibre 50 grams, foamable phenolic particle 1 ~ 3 kilogram, start stirrer fully to stir with the stirring velocity of 400 ~ 500 revs/min, then 5 kilograms of No. 500 ordinary Portland cements are added, abundant stirring 1 minute, finally add the aqueous hydrogen peroxide solution 500 milliliters that content is 28%, stir rapidly, when enlarged volume, be released to mould in agitator immediately, after 5 days aquations, cement insulation board initial set, carries out the demoulding.After the demoulding, health 20 days under envrionment temperature is 20 ~ 30 DEG C and the environment of humidity 20% ~ 80%, becomes cement insulation board blank.
4, cut: after blank drying, by microtome, slice thickness is between 3 ~ 10 centimetres, and length is between 30 ~ 60 centimetres, and width, between 30 ~ 45 centimetres, becomes cement insulation board and becomes material.
5, slurry preparation: by quality, be in the water glass solution of 20 at the degree Beaume of 1 part, adding content is 50% polyvinyl formal solution 1 part, then adds the organosilicon aqueous solution 0.1 part, as slurry after stirring.
6, enhancement process: cement insulation board soaked and carry out dipping enhancement process in the slurry, dipping time is 10 minutes, pulls out after dipping, naturally dries or dries, and becomes the cement insulation board that finished product is added with foamable phenolic particle.
Performance Detection is tested: selection thickness is that the common cement insulation board of 6 centimetres compares, the cement insulation board selecting 6 cm thicks to be added with the foamable phenolic particle of 2 kilograms makes testing inspection, detect through actual, control board thermal conductivity is 0.068, and test board thermal conductivity is 0.04.
Shown by test data, the cement insulation board and the cement insulation board thermal conductivity that are added with foamable phenolic particle reduce 0.028.
According to detection data analysis, foamable phenolic particle adds to greatest extent in cement insulation board, is conducive to the reduction of thermal conductivity, improves heat-insulating property, improves toughness.
Finished product is observed: by carrying out eye-observation to the finished surface made, foamable phenolic even particulate dispersion, between the micropore of cement board, forms the foam structure body of foamable phenolic particle and foam cement continuously.Analyze the formation of its structure, when in heat conduction process, continue through foam cement abscess-foamable phenolic particle-foam cement abscess-foamable phenolic particle, until to the other end, thermal conductivity values is high and low, high and low change, combine the mean value of foam cement and foamable phenolic, overall thermal conductivity is reduced.
Advantage of the present invention:
1, owing to being added with foamable phenolic particle in cement insulation board, so unit weight is low, thermal conductivity is low, good toughness.
2, because cement insulation board becomes material through dipping sizing agent enhancement process, so surface strength is high, do not fall slag, not efflorescence, carrying and use procedure not damaged, and be conducive to pasting with body of wall.
3, owing to being added with cementing Stabilizing Materials in cement insulation board, add the cohesive force between foam cement and foamable phenolic particle, make foamable phenolic particle can firmly and foam cement bond, can not bulk strength be reduced, and can toughness be increased.
4, because foamable phenolic plate cost is high, and thermal conductivity is low, and cement board cost is low, thermal conductivity is high, after with the addition of foamable phenolic particle in cement board, compared with cement insulation board, thermal conductivity reduces, and though cost is improved, but can reduce thickness, the usable floor area of unit volume increases, so the numerical value that cost increases can be accepted, compared with similar products, the market competitiveness is had more.
Claims (1)
1. one kind is added with the cement insulation board manufacture method of foamable phenolic particle, through the preparation of foamable phenolic particle, the preparation of cementing Stabilizing Materials, base material, cut, slurry preparation and enhancement process operation, wherein made blank is cut, pass through microtome, slice thickness is between 3 ~ 10 centimetres, length is between 30 ~ 60 centimetres, and width, between 30 ~ 45 centimetres, becomes cement insulation board and becomes material; Wherein by the phenolic aldehyde body material through foaming, join in disk sawtooth nodulizer, make the particle of 0.1 ~ 5 millimeter, as foamable phenolic particle;
It is characterized in that:
Foaming insulation board preparation process: add 4 premium on currency in agitator, calcium stearate is added in the polyvinyl formal solution of moisture 50%, polyvinyl formal solution: calcium stearate ratio 1:1 is as cementing Stabilizing Materials 100 milliliters, sisal hemp short fibre 50 grams, foamable phenolic particle 1 ~ 3 kilogram, start stirrer fully to stir with the stirring velocity of 400 ~ 500 revs/min, then 5 kilograms of No. 500 ordinary Portland cements are added, abundant stirring 1 minute, finally add the aqueous hydrogen peroxide solution 500 milliliters that content is 28%, rapid stirring, when enlarged volume, be released to mould in agitator immediately, after 5 days aquations, cement insulation board initial set, carry out the demoulding, health 20 days under envrionment temperature is 20 ~ 30 DEG C and the environment of humidity 20% ~ 80% after the demoulding, become cement insulation board blank, cement insulation board blank is soaked and carries out dipping enhancement process in the slurry, dipping time is 10 minutes, pull out after dipping, naturally dry or dry, becoming cement insulation board,
Described slurry, by quality, be in the water glass solution of 20 at the degree Beaume of 1 part, adding content is 50% polyvinyl formal solution 1 part, then adds the organosilicon aqueous solution 0.1 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310260660.9A CN103408247B (en) | 2013-06-26 | 2013-06-26 | A kind of cement insulation board manufacture method being added with foamable phenolic particle |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310260660.9A CN103408247B (en) | 2013-06-26 | 2013-06-26 | A kind of cement insulation board manufacture method being added with foamable phenolic particle |
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| CN103408247A CN103408247A (en) | 2013-11-27 |
| CN103408247B true CN103408247B (en) | 2015-10-07 |
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| CN201310260660.9A Active CN103408247B (en) | 2013-06-26 | 2013-06-26 | A kind of cement insulation board manufacture method being added with foamable phenolic particle |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107013002A (en) * | 2017-05-11 | 2017-08-04 | 啄木鸟漆业集团有限公司 | Insulation and decoration integrated plate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101941822A (en) * | 2010-08-26 | 2011-01-12 | 无锡吉兴汽车声学部件科技有限公司 | Thermal insulation board |
| CN102173677A (en) * | 2010-11-29 | 2011-09-07 | 杨长文 | Inflaming retarding building heat insulation material and production method thereof |
| CN102953446A (en) * | 2012-12-04 | 2013-03-06 | 山东圣泉化工股份有限公司 | Phenolic foam heat-insulating board made of composite flame-retardant material |
-
2013
- 2013-06-26 CN CN201310260660.9A patent/CN103408247B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101941822A (en) * | 2010-08-26 | 2011-01-12 | 无锡吉兴汽车声学部件科技有限公司 | Thermal insulation board |
| CN102173677A (en) * | 2010-11-29 | 2011-09-07 | 杨长文 | Inflaming retarding building heat insulation material and production method thereof |
| CN102953446A (en) * | 2012-12-04 | 2013-03-06 | 山东圣泉化工股份有限公司 | Phenolic foam heat-insulating board made of composite flame-retardant material |
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| CN103408247A (en) | 2013-11-27 |
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Inventor after: Zhu Jie Inventor after: Zhu Yanmei Inventor before: Chang Shuhui |
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Effective date of registration: 20170509 Address after: 410600, Hunan County, Changsha City, Ningxiang Xia duo town six degrees village ten sets Patentee after: Hunan Zhanjie Technology Co.,Ltd. Address before: 125000, No. 6, unit 22-4, Haixing Road, Longgang District, Liaoning, Huludao, 12 Patentee before: Chang Shuhui |
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Effective date of registration: 20211215 Address after: Room 503, building 3, No. 133, development avenue, Tongxiang Economic Development Zone, Tongxiang City, Jiaxing City, Zhejiang Province Patentee after: ZHEJIANG MAIZHI NETWORK TECHNOLOGY CO.,LTD. Address before: 410600 group 10, liudu'an village, xiaduo Pu town, Ningxiang County, Changsha City, Hunan Province Patentee before: Hunan Zhanjie Technology Co.,Ltd. |
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Effective date of registration: 20221222 Address after: 314500 No.1 Gongnong Road, South Gate, Chongfu Town, Tongxiang City, Jiaxing City, Zhejiang Province Patentee after: Jiaxing Zhuoshi Biotechnology Co.,Ltd. Address before: Room 503, building 3, No. 133, development avenue, Tongxiang Economic Development Zone, Tongxiang City, Jiaxing City, Zhejiang Province Patentee before: ZHEJIANG MAIZHI NETWORK TECHNOLOGY CO.,LTD. |
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