CN103396662B - 抗老化pa-par塑料合金 - Google Patents
抗老化pa-par塑料合金 Download PDFInfo
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- CN103396662B CN103396662B CN201310300511.0A CN201310300511A CN103396662B CN 103396662 B CN103396662 B CN 103396662B CN 201310300511 A CN201310300511 A CN 201310300511A CN 103396662 B CN103396662 B CN 103396662B
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- CN
- China
- Prior art keywords
- par
- aging
- polyblend
- mah
- sebs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 230000003712 anti-aging effect Effects 0.000 title claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 239000001273 butane Substances 0.000 claims description 6
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 6
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 claims description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 230000032683 aging Effects 0.000 description 11
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 2
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002656 Distearyl thiodipropionate Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000019305 distearyl thiodipropionate Nutrition 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | |
PA树脂 | 100 | 100 | 100 | 100 |
PAR树脂 | 25 | 25 | 25 | 25 |
相容剂SEBS-g-MAH | 7 | 7 | 7 | 7 |
4,4’-硫代双(6-叔丁基-3-甲基苯酚) | 0.4 | 0.8 | / | 0.5 |
1,1,3-三(2-甲基-4-羟基-5-叔丁苯基)丁烷 | 0.4 | / | 0.8 | 0.5 |
硫代二丙酸双十八醇酯 | 0.2 | 0.2 | 0.2 | / |
拉伸强度保持率,% | 悬臂梁缺口冲击强度保持率,% | |
实施例1 | 82.3 | 81.8 |
实施例2 | 81.2 | 80.2 |
实施例3 | 81.4 | 80.5 |
实施例4 | 81.1 | 80.6 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310300511.0A CN103396662B (zh) | 2013-07-15 | 2013-07-15 | 抗老化pa-par塑料合金 |
Applications Claiming Priority (1)
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---|---|---|---|
CN201310300511.0A CN103396662B (zh) | 2013-07-15 | 2013-07-15 | 抗老化pa-par塑料合金 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103396662A CN103396662A (zh) | 2013-11-20 |
CN103396662B true CN103396662B (zh) | 2015-12-02 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201310300511.0A Expired - Fee Related CN103396662B (zh) | 2013-07-15 | 2013-07-15 | 抗老化pa-par塑料合金 |
Country Status (1)
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CN (1) | CN103396662B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103694678B (zh) * | 2013-12-15 | 2016-11-16 | 上海悦萌环保科技有限公司 | 防鼠蚁pa/par环保塑料 |
CN103756310A (zh) * | 2014-01-08 | 2014-04-30 | 合肥杰事杰新材料股份有限公司 | 一种聚酰胺/聚芳酯合金及其制备方法 |
CN105238038A (zh) * | 2015-09-30 | 2016-01-13 | 滁州优胜高分子材料有限公司 | 一种高耐候pa6/pctg/par复合材料及其制备方法 |
CN109135163A (zh) * | 2018-09-13 | 2019-01-04 | 江南大学 | 一种pi纤维增强par/abs树脂复合材料和其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4804707A (en) * | 1986-05-24 | 1989-02-14 | Unitika Ltd. | Impact resistant resin composition |
US5043385A (en) * | 1987-07-27 | 1991-08-27 | Stamicarbon B.V. | Impact resistant resin composition |
CN102131849A (zh) * | 2007-10-01 | 2011-07-20 | 帝斯曼知识产权资产管理有限公司 | 可热加工的导热性聚合物组合物 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010047631A (ja) * | 2008-08-19 | 2010-03-04 | Unitika Ltd | ガラス繊維強化ポリアミド樹脂組成物 |
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2013
- 2013-07-15 CN CN201310300511.0A patent/CN103396662B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4804707A (en) * | 1986-05-24 | 1989-02-14 | Unitika Ltd. | Impact resistant resin composition |
US5043385A (en) * | 1987-07-27 | 1991-08-27 | Stamicarbon B.V. | Impact resistant resin composition |
CN102131849A (zh) * | 2007-10-01 | 2011-07-20 | 帝斯曼知识产权资产管理有限公司 | 可热加工的导热性聚合物组合物 |
Non-Patent Citations (1)
Title |
---|
"双酚A型聚芳酯/半芳香族聚酰胺共聚物的合成与性能";周丽云等;《高分子材料科学与工程》;20130228;第29卷(第2期);第26-30页 * |
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Inventor after: Wen Bingzhang Inventor before: Huang Meirong |
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Effective date of registration: 20170505 Address after: 528445 Guangdong city of Zhongshan Province high-tech industry Triangle town No. 17 Silicon Valley power Fukuzawa road deep in the demonstration base of A2 building third layer B Patentee after: ZHONGSHAN CITY TONGCAI CHEMICAL TECHNOLOGY CO.,LTD. Address before: Room 271, building 280, Shuguang Road, Shanghai, Minhang District, 201111, China Patentee before: SHANGHAI QIUCHENG NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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