CN103396092A - Composite ceramic diluent suitable for barren building ceramic formula soil, and application method thereof - Google Patents
Composite ceramic diluent suitable for barren building ceramic formula soil, and application method thereof Download PDFInfo
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- CN103396092A CN103396092A CN2013103324794A CN201310332479A CN103396092A CN 103396092 A CN103396092 A CN 103396092A CN 2013103324794 A CN2013103324794 A CN 2013103324794A CN 201310332479 A CN201310332479 A CN 201310332479A CN 103396092 A CN103396092 A CN 103396092A
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Abstract
The invention discloses a composite ceramic diluent suitable for barren building ceramic formula soil, and an application method thereof. The composite ceramic diluent is prepared by the steps of an inorganic water reducer, a small molecular organic water reducer, a surfactant; optimizing the addition amounts of the above materials; compositing the above materials according to a certain proportion; and mixing the composite materials with the barren building ceramic formula soil uniformly by ball-milling. The prepared composite ceramic diluent is suitable for a barren mud slurry containing relatively many quartz, feldspar, calcined clay (clinker) and fragments of refractory materials, can greatly reduce water content in the mud slurry, meets fluidity required by ceramic production, saves energy consumption of a spray drying tower, and increases output of dry powder. The composite ceramic diluent has the advantages of good universality, wide deflocculation range, convenient use, etc. The composite ceramic diluent is an ideal diluting material for the building ceramic mud slurry.
Description
Technical field
The invention belongs to the building ceramics technical field, be specifically related to a kind ofly be applicable to lean property and build pottery and join composite ceramics thinner and the using method thereof of necromancer.
Background technology
Along with the demand of world market and the development of ceramic industry, the proportion that lean property base glaze accounts for is increasing at present.Its poor material content of system such as mud, fine melt piece glaze slip of making pottery such as the spy are very high.Poor material refers to not have the material of plasticity and stickiness.And its water ratio is less, and therefore in the architectural pottery product, adding of they helps to reduce body drying contraction and distortion, accelerates the work in-process rate of drying, reduces the goods cracking.For optimizing and the improved products performance, improve goods inner quality and even Business Economic Benefit, have irreplaceable purposes.The present invention is intended to announce and is applicable to lean property and builds pottery and join composite ceramics thinner and the using method thereof of necromancer, to improve the processing performance of ceramic mud, production efficiency and the save energy that improves architectural pottery is had important practical significance.
Summary of the invention
The technical problem to be solved in the present invention is to provide that simple, the synthetic cost of a kind of technique is low, the lean property that is applicable to of stable performance is built pottery and joined composite ceramics thinner and the using method thereof of necromancer.
For solving above technical problem, technical scheme of the present invention is: a kind ofly be applicable to lean property and build pottery and join the composite ceramics thinner of necromancer, it is characterized in that including following component by weight percentage:
Inorganic water reducer 52-84%
The organic water reducer 15-45% of small molecules
Tensio-active agent 0.5-3%
Wherein:
Described inorganic water reducer is commercially available Starso, water glass, sodium carbonate, trisodium phosphate, Sodium hexametaphosphate 99, wherein one or more of tripoly phosphate sodium STPP;
The organic water reducer of described small molecules is commercially available Sodium salts humic acids, sodium lignosulfonate, wherein one or more of calcium lignin sulphonate;
Described tensio-active agent is one or more in anion surfactant, cats product, nonionogenic tenside, novel chelate surfactant.
Described anion surfactant is carboxylate salt, sulfonate, sulfuric acid ester salt, phosphoric acid fat salt.
The preferred dodecane sulfonate of described anion surfactant, paratoluenesulfonic acid sodium salt.
Described cats product is quaternary ammonium salt, pyridinium salt.
The preferred bromination hexadecyl of described cats product alkyl pyridine, a kind of in the amino tri alkyl quaternary ammonium salt of dimethyl diallyl ammonium chloride, alkyl dimethyl benzyl quaternary ammonium salt, fatty acyl, Cyprex hydrochloride.
A kind of in described nonionogenic tenside preferred fat polyoxyethylenated alcohol, trolamine, tween, class of department.
A kind of in the described novel preferred N-acyl group of chelate surfactant and N-alkyl ED3A sodium salt.
The using method of above-mentioned composite ceramics thinner, is characterized in that comprising the steps:
The first step: inorganic water reducer, the organic water reducer of small molecules, tensio-active agent are mixed and made into the composite ceramics thinner according to proportioning;
Second step: build the pottery formulated by lean property and build the potter's clay material;
The 3rd step: by weight percentage the composite ceramics thinner of 0.2-0.5% is added to and builds in the potter's clay material, and by ball milling, will build the potter's clay material and the composite ceramics mixing diluents is evenly namely completed modification.
It is Anfu sand 29%, Fengxin sand 16.2%, minute suitable sand 28%, wilkinite 2.8%, kaolinite 7%, white clay 3%, magnesium soil 2%, Fengcheng white clay 7%, Ji'an plaster 2%, high-al clay 3% that described lean property is built the pottery formula optimization;
Described lean property is built the pottery formula optimization and is Yifeng sand 30.8%, upper rich sand 17%, ternary sand 14%, Fuzhou City's sand 22%, white clay 4%, Ji'an white clay 7%, gives birth to talcum 2%, high-al clay 3.2%.
The water ratio that described process composite ceramics thinner modification lean property is later built pottery mud is 33%, and being coated with-4 glasss of flow velocitys is 56 seconds, tails over less than 3%.
Innovation of the present invention is that this composite ceramics thinner uses in lean property and builds during pottery joins necromancer, the water content of mud is significantly reduced, the production efficiency that improves ball mill is full, the required mobility of foot Production of Ceramics, save the spray-drying tower energy consumption, improve dry powder output output, therefore have wide market outlook.
Embodiment
The present invention is further detailed explanation below in conjunction with embodiment.
Embodiment 1
With commercially available non-hydrate sodium metasilicate, Sodium salts humic acids, sodium laurylsulfonate, 80:19:1 carries out proportioning by weight percentage, this composite ceramics thinner 0.35% is added into the more pottery of building of poor material and joins ball milling in necromancer by weight percentage, and it is as follows that this builds Tao Peifang: Anfu sand 29%, Fengxin sand 16.2%, minute should sand 28%, wilkinite 2.8%, kaolinite 7%, white clay 3%, magnesium soil 2%, Fengcheng white clay 7%, Ji'an plaster 2%, high-al clay 3%.Can obtain moisturely approximately 33%, be coated with-4 glasss of flow velocitys mud of 56 seconds, tail over less than 2%.
Embodiment 2
With commercial water glass, sodium lignosulfonate, bromination hexadecyl alkyl pyridine, 65:34.2:0.8 carries out proportioning by weight percentage, this composite ceramics thinner 0.25% is added into the more pottery of building of poor material and joins ball milling in necromancer by weight percentage, build Tao Peifang with embodiment 1, can obtain moisture approximately 33%, be coated with-4 glasss of flow velocitys mud of 56 seconds, tail over less than 2%.
Embodiment 3
With commercially available sodium carbonate, calcium lignin sulphonate, trolamine, 72:26:2 carries out proportioning by weight percentage, this composite ceramics thinner 0.4% is added into lean property and builds pottery and join ball milling in necromancer by mass percentage, and it is as follows that this builds Tao Peifang: Yifeng sand 30.8%, upper rich sand 17%, ternary sand 14%, Fuzhou City's sand 22%, white clay 4%, Ji'an white clay 7%, give birth to talcum 2%, high-al clay 3.2%.Can obtain moisturely approximately 33%, be coated with-4 glasss of flow velocitys mud of 56 seconds, tail over less than 3%.
Embodiment 4
With commercially available tripoly phosphate sodium STPP, Sodium salts humic acids, paratoluenesulfonic acid sodium salt, 59:38:3 carries out proportioning by weight percentage, this composite ceramics thinner 0.45% is added into lean property and builds pottery and join ball milling in necromancer by mass percentage, this builds Tao Peifang with embodiment 3, can obtain moisture approximately 33%, be coated with-4 glasss of flow velocitys mud of 56 seconds, tail over less than 3%.
Claims (10)
1. one kind is applicable to lean property and builds pottery and join the composite ceramics thinner of necromancer, it is characterized in that including following component by weight percentage:
Inorganic water reducer 52-84%
The organic water reducer 15-45% of small molecules
Tensio-active agent 0.5-3%
Wherein:
Described inorganic water reducer is commercially available Starso, water glass, sodium carbonate, trisodium phosphate, Sodium hexametaphosphate 99, wherein one or more of tripoly phosphate sodium STPP;
The organic water reducer of described small molecules is commercially available Sodium salts humic acids, sodium lignosulfonate, wherein one or more of calcium lignin sulphonate;
Described tensio-active agent is one or more in anion surfactant, cats product, nonionogenic tenside, novel chelate surfactant.
2. composite ceramics thinner according to claim 1, it is characterized in that: described anion surfactant is carboxylate salt, sulfonate, sulfuric acid ester salt, phosphoric acid fat salt.
3. composite ceramics thinner according to claim 2, is characterized in that: the preferred dodecane sulfonate of described anion surfactant, paratoluenesulfonic acid sodium salt.
4. composite ceramics thinner according to claim 1, it is characterized in that: described cats product is quaternary ammonium salt, pyridinium salt.
5. composite ceramics thinner according to claim 4, it is characterized in that: the preferred bromination hexadecyl of described cats product alkyl pyridine, a kind of in the amino tri alkyl quaternary ammonium salt of dimethyl diallyl ammonium chloride, alkyl dimethyl benzyl quaternary ammonium salt, fatty acyl, Cyprex hydrochloride.
6. composite ceramics thinner according to claim 1 is characterized in that: a kind of in described nonionogenic tenside preferred fat polyoxyethylenated alcohol, trolamine, tween, class of department.
7. composite ceramics thinner according to claim 1 is characterized in that: a kind of in the described novel preferred N-acyl group of chelate surfactant and N-alkyl ED3A sodium salt.
8. the using method of according to claim 1-7 arbitrary described composite ceramics thinners, is characterized in that comprising the steps:
The first step: inorganic water reducer, the organic water reducer of small molecules, tensio-active agent are mixed and made into the composite ceramics thinner according to proportioning;
Second step: build the pottery formulated by lean property and build the potter's clay material;
The 3rd step: by weight percentage the composite ceramics thinner of 0.2-0.5% is added to and builds in the potter's clay material, and by ball milling, will build the potter's clay material and the composite ceramics mixing diluents is evenly namely completed modification.
9. using method according to claim 8 is characterized in that: described lean property build the pottery formula optimization is Anfu sand 29%, Fengxin sand 16.2%, minute should sand 28%, wilkinite 2.8%, kaolinite 7%, white clay 3%, magnesium soil 2%, Fengcheng white clay 7%, Ji'an plaster 2%, high-al clay 3%;
Described lean property is built the pottery formula optimization and is Yifeng sand 30.8%, upper rich sand 17%, ternary sand 14%, Fuzhou City's sand 22%, white clay 4%, Ji'an white clay 7%, gives birth to talcum 2%, high-al clay 3.2%.
10. using method according to claim 8 is characterized in that: the described water ratio of building pottery mud through composite ceramics thinner modification lean property later is 33%, and being coated with-4 glasss of flow velocitys is 56 seconds, tails over less than 3%.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103952121A (en) * | 2014-04-04 | 2014-07-30 | 湖南省美程陶瓷科技有限公司 | Steatite ceramics composite water reducer and preparation method thereof |
| RU2560048C1 (en) * | 2014-06-06 | 2015-08-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский государственный архитектурно-строительный университет" КГАСУ | Modified low-melting clayey mass |
| CN104987130A (en) * | 2015-04-23 | 2015-10-21 | 张耀辰 | A suspending agent for electric porcelain glaze |
| CN112573929A (en) * | 2020-12-28 | 2021-03-30 | 山东龙港硅业科技有限公司 | Composite ceramic water reducing agent and ceramic application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1821177A (en) * | 2006-03-08 | 2006-08-23 | 桂林工学院 | Method for preparing composite ceramic water reducing agent |
| CN102617154A (en) * | 2012-04-01 | 2012-08-01 | 景德镇陶瓷学院 | Method for preparing environment-friendly building ceramic tile by using high lean material |
| CN103130510A (en) * | 2013-03-22 | 2013-06-05 | 天津大学 | Composite dispersing agent applied to architectural ceramics and application |
-
2013
- 2013-08-02 CN CN2013103324794A patent/CN103396092A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1821177A (en) * | 2006-03-08 | 2006-08-23 | 桂林工学院 | Method for preparing composite ceramic water reducing agent |
| CN102617154A (en) * | 2012-04-01 | 2012-08-01 | 景德镇陶瓷学院 | Method for preparing environment-friendly building ceramic tile by using high lean material |
| CN103130510A (en) * | 2013-03-22 | 2013-06-05 | 天津大学 | Composite dispersing agent applied to architectural ceramics and application |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103952121A (en) * | 2014-04-04 | 2014-07-30 | 湖南省美程陶瓷科技有限公司 | Steatite ceramics composite water reducer and preparation method thereof |
| RU2560048C1 (en) * | 2014-06-06 | 2015-08-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский государственный архитектурно-строительный университет" КГАСУ | Modified low-melting clayey mass |
| CN104987130A (en) * | 2015-04-23 | 2015-10-21 | 张耀辰 | A suspending agent for electric porcelain glaze |
| CN112573929A (en) * | 2020-12-28 | 2021-03-30 | 山东龙港硅业科技有限公司 | Composite ceramic water reducing agent and ceramic application thereof |
| CN112573929B (en) * | 2020-12-28 | 2023-03-10 | 山东龙港硅业科技有限公司 | Composite ceramic water reducing agent and ceramic application thereof |
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Application publication date: 20131120 |