CN103380780A - Fluorine chlorine ether pyrethroid smoking paper for mosquito control - Google Patents
Fluorine chlorine ether pyrethroid smoking paper for mosquito control Download PDFInfo
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- CN103380780A CN103380780A CN2013103218032A CN201310321803A CN103380780A CN 103380780 A CN103380780 A CN 103380780A CN 2013103218032 A CN2013103218032 A CN 2013103218032A CN 201310321803 A CN201310321803 A CN 201310321803A CN 103380780 A CN103380780 A CN 103380780A
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Abstract
The invention discloses fluorine chlorine ether pyrethroid smoking paper for mosquito control. The fluorine chlorine ether pyrethroid smoking paper for the mosquito control is formed by 15 to 25 parts of sodium nitrate, 40 to 60 parts of water, 25 to 35 parts of acetone, 5 to 10 parts of essence, 5 to 10 parts of fluorine chlorine ether pyrethroid, 13 to 15 parts of biological prallethrin and 1000 parts of pulp boards. The fluorine chlorine ether pyrethroid smoking paper for the mosquito control has the advantages of being scientific and reasonable in compound design, easy to obtain raw materials, low in cost, good in effect and the like.
Description
Technical field
The invention belongs to a kind of insecticide, relate to a kind of mosquito-repellent incense.
Background technology
Insecticide: English: Pesticide. Insecticide is mainly used in preventing and treating the medicine of pest and urban health insect. use historical long-range, consumption is large, wide in variety.At twentieth century, agriculture develops rapidly, and insecticide makes farm output rise higher.But nearly all insecticide all can seriously change the ecosystem, and most of harmful, other meeting is concentrated in food chain.We must average out in agricultural development and environment and health.Mosquito-repellent incense kind on the market comprises coiled mosquito-repellent incense, sheet type electric mosquito repellent, Electric liquid mosquito-repellent incense etc.The mosquito-repellent incense that [span] is traditional divides two kinds of line spices [span] and incense coils [span], after the liquid or solid electric mosquito repellent appears again.Except above three kinds of mosquito-repellent incenses, based on the fast development of the electronic products such as computer and mobile phone, electric mosquito-repellent incense has appearred.Electric mosquito-repellent incense is different from above said traditional electrical mosquito-repellent incense, and it is the software of developing for computer and cellphone subscriber's mosquito repellent, and the developer claims by hyperacoustic and send, effectively mosquito repellent.
Through Chinese publication retrieval, do not find the scheme identical with present patent application.
Summary of the invention
The object of the invention is to: propose a kind of chlorine fluorine ether chrysanthemum fat kill mosquito smoking paper.
Chlorine fluorine ether chrysanthemum fat kill mosquito smoking paper of the present invention is characterized in that: by weight, by sodium nitrate 15-25 part, water 40-60 part, acetone 25-35 part, essence 5-10 part, chlorine fluorine ether chrysanthemum fat, 5-10 part, biological prallethrin 13-15 part, 1000 parts of paper pulp constitute.Preferably by weight, by 20 parts, sodium nitrate, 50 parts, water, 30 parts, acetone, 10 parts, essence, chlorine fluorine ether chrysanthemum fat, 5 parts, 10 parts of biological prallethrins, 1000 parts of paper pulp constitute.
Chlorine fluorine ether chrysanthemum fat kill mosquito smoking paper preparation method of the present invention is characterized in that: by weight, by sodium nitrate 15-25 part, water 40-60 part, acetone 25-35 part, essence 5-10 part, chlorine fluorine ether chrysanthemum fat, 5-10 part, biological prallethrin 13-15 part, 1000 parts of paper pulp constitute; Preparation process is: 1) by formula, sodium nitrate added the water stirring and dissolving, forms sodium nitrate aqueous solution, and standby; 2) by formula, benzethazet acetofenate, biological prallethrin are added the acetone stirring and dissolving, form the benzethazet acetofenate acetone soln, standby; 3) sodium nitrate aqueous solution evenly is sprayed on paper pulp, after pulp board sucks sodium nitrate aqueous solution, the benzethazet acetofenate acetone soln evenly is sprayed on paper pulp, namely get product after paper pulp sucks benzethazet acetofenate, biological prallethrin acetone soln.Slice packaging can be done the finished product listing and sell.
Raw material:
Chlorine fluorine ether chrysanthemum fat; Chemical name: 2,3,5,6 ,-tetrafluoro-4-methoxymethyl benzyl base (1R, 3S)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester; Molecular formula: C17H17CL2F4O3 molecular weight: 416.22
CAS registration number: 352271-52-4 physicochemical property: for light gray to the light brown solid, fusing point: 72～75 ℃, vapour pressure: 686.2Pa (200 ℃), proportion: 1.2329g/ml, be insoluble in water, be soluble in the organic solvents such as toluene, chloroform, acetone, carrene, dimethyl formamide.Stable under acid and neutrallty condition, but hydrolysis is very fast under alkali condition.Can stablize at normal temperatures and store 2 years.Suck and contact insecticide, the sanitary insect pests such as mosquito, fly are had the remarkable activity of knocking down and kill.
Biological prallethrin; Chemical name: dextrorotation-trans-2,2-diformazan-3-(2-methyl-1-propylene base) cyclopropane-carboxylic acid-S-2 methyl-3-(2-propargyl)-4-oxo-ring penta-2-alkenyl esters molecular formula: C19H24O3 molecular weight: 300.40CAS registration number: 23031-36-9 physicochemical property: outward appearance: limpid yellowish to amber thick liquid content: 90% relative density: 1.021 vapour pressures: 0.013mPa/23.1 ℃ boiling point/flash-point: 313.5 ℃/120 ℃ dissolubilities: be soluble in most of organic solvents; Be insoluble in water (2-3ppm, 25 ℃) stability: unstable under illumination, in first, ethanol; Former medicine is at 60oC, through 6 months or in multiple organic solvent in 40oC, 6 months or stored still stable in the aqua type aerosol of pH4-5 through 9 months.Illumination half-life 2-3 days (similar d-allethrin), unstable in methyl alcohol or ethanol.Rich d-prallethrin product characteristics are identical with beneficial many grams, have strong action of contace poison, and knocking down and kill performance is 4 times of rich_d_transallethrin, and cockroach is had the outstanding effect of driveing.Be mainly used in processing the house pests such as mosquito-repellent incense, electric mosquito repellent, vaporizer mosquito liquid and spray control housefly, mosquito, lice, cockroach.
Sodium nitrate, fusing point are 306.8 ℃, and density is 2.257 g/ccs (20 ℃ time), is water white transparency or the yellow rhomboidan of white little band.Its bitter is salty, and soluble in water and liquefied ammonia is slightly soluble in glycerine and ethanol, easy deliquescence, and when containing the minute quantity sodium chloride as impurity, the sodium nitrate hygroscopy just greatly increases especially.When heating, sodium nitrate easily becomes to resolve into natrium nitrosum and oxygen.Sodium nitrate can be combustion-supporting, must be stored in the place of shady and cool ventilation.
Acetone; Colourless liquid has pleasant smell (pungent sweet taste).Volatile.Can be miscible with water, ethanol, DMF, chloroform, ether and most of oils.Relative density (d25) 0.7845.Fusing point-94.7 ℃.56.05 ℃ of boiling points.Index of refraction (n20D) 1.3588.Flash-point-20 ℃.Inflammable.Median lethal dose (rat, per os) 10.7ml/kg.Irritant.
Paper pulp (paper pulp; Pulp) be take vegetable fiber as raw material, the fibrous material that makes through different processing methods.Can be divided into mechanical pulp, chemical pulp and chemimechanical pulp according to processing method; Also can be divided into wood pulp, straw pulp, jute pulp, reed pulp, sugarcane slurry, bamboo pulp, rag stock etc. according to fibrous raw material used.Can be divided into refined pulp, bleached pulp, unbleached pulp, high-yield pulp, semi-chemical pulp etc. according to different purity again.General multiplex in making paper and cardboard.Refined pulp is except for the manufacture of speciality paper, also usually as the raw material of making the cellulose derivativess such as cellulose esters, cellulose ether.Also be used for the fields such as staple fibre, plastics, coating, film, gunpowder.
The present invention's beneficial effect compared with prior art:The advantages such as it has formula Design science, reasonable, and raw material is easy to get, and cost is low, and is effective.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is further illustrated, but implement
ModeBe not limited only to this.
Embodiment 1
Chlorine fluorine ether chrysanthemum fat kill mosquito smoking paper of the present invention is characterized in that: by weight, by sodium nitrate 15-25 part, water 40-60 part, acetone 25-35 part, essence 5-10 part, chlorine fluorine ether chrysanthemum fat, 5-10 part, biological prallethrin 13-15 part, 1000 parts of paper pulp constitute.Preferably by weight, by 20 parts, sodium nitrate, 50 parts, water, 30 parts, acetone, 10 parts, essence, chlorine fluorine ether chrysanthemum fat, 5 parts, 10 parts of biological prallethrins, 1000 parts of paper pulp constitute.
Embodiment 2
Chlorine fluorine ether chrysanthemum fat kill mosquito smoking paper preparation method of the present invention is characterized in that: by weight, by sodium nitrate 15-25 part, water 40-60 part, acetone 25-35 part, essence 5-10 part, chlorine fluorine ether chrysanthemum fat, 5-10 part, biological prallethrin 13-15 part, 1000 parts of paper pulp constitute; Preparation process is: 1) by formula, sodium nitrate added the water stirring and dissolving, forms sodium nitrate aqueous solution, and standby; 2) by formula, benzethazet acetofenate, biological prallethrin are added the acetone stirring and dissolving, form the benzethazet acetofenate acetone soln, standby; 3) sodium nitrate aqueous solution evenly is sprayed on paper pulp, after pulp board sucks sodium nitrate aqueous solution, the benzethazet acetofenate acetone soln evenly is sprayed on paper pulp, namely get product after paper pulp sucks benzethazet acetofenate, biological prallethrin acetone soln.Slice packaging can be done the finished product listing and sell.
Claims (3)
1. chlorine fluorine ether chrysanthemum fat kill mosquito smoking paper is characterized in that: by weight, by sodium nitrate 15-25 part, water 40-60 part, acetone 25-35 part, essence 5-10 part, chlorine fluorine ether chrysanthemum fat, 5-10 part, biological prallethrin 13-15 part, 1000 parts of pulp boards constitute.
2. chlorine fluorine ether chrysanthemum fat kill mosquito smoking paper according to claim 1, by weight, by 20 parts, sodium nitrate, 50 parts, water, 30 parts, acetone, 10 parts, essence, chlorine fluorine ether chrysanthemum fat, 5 parts, 10 parts of biological prallethrins, 1000 parts of pulp boards
Constitute.
3. chlorine fluorine ether chrysanthemum fat kill mosquito smoking paper preparation method is characterized in that: by weight, by sodium nitrate 15-25 part, water 40-60 part, acetone 25-35 part, essence 5-10 part, chlorine fluorine ether chrysanthemum fat, 5-10 part, biological prallethrin 13-15 part, 1000 parts of pulp boards constitute; Preparation process is: 1) by formula, sodium nitrate added the water stirring and dissolving, forms sodium nitrate aqueous solution, and standby; 2) by formula, benzethazet acetofenate, biological prallethrin are added the acetone stirring and dissolving, form the benzethazet acetofenate acetone soln, standby; 3) sodium nitrate aqueous solution evenly is sprayed on pulp board, after pulp board sucks sodium nitrate aqueous solution, the benzethazet acetofenate acetone soln evenly is sprayed on pulp board, namely get product after pulp board sucks benzethazet acetofenate, biological prallethrin acetone soln.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013103218032A CN103380780A (en) | 2013-07-29 | 2013-07-29 | Fluorine chlorine ether pyrethroid smoking paper for mosquito control |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013103218032A CN103380780A (en) | 2013-07-29 | 2013-07-29 | Fluorine chlorine ether pyrethroid smoking paper for mosquito control |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1700858A (en) * | 2000-08-22 | 2005-11-23 | 雷克特本克斯尔(澳大利亚)有限公司 | Combustible pesticidal products |
| CN101953362A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing meperfluthrin and bifenthrin and application thereof |
| CN102578080A (en) * | 2011-01-07 | 2012-07-18 | 王天桃 | Manufacturing method of aqua electric heating mosquito repellent liquid, mosquito repellent mother liquid and electric heating mosquito repellent sheet dropping liquid |
-
2013
- 2013-07-29 CN CN2013103218032A patent/CN103380780A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1700858A (en) * | 2000-08-22 | 2005-11-23 | 雷克特本克斯尔(澳大利亚)有限公司 | Combustible pesticidal products |
| CN101953362A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing meperfluthrin and bifenthrin and application thereof |
| CN102578080A (en) * | 2011-01-07 | 2012-07-18 | 王天桃 | Manufacturing method of aqua electric heating mosquito repellent liquid, mosquito repellent mother liquid and electric heating mosquito repellent sheet dropping liquid |
Non-Patent Citations (1)
| Title |
|---|
| 赵红良: "《强力灭蚊烟熏纸生产技术》", 《致富之友》 * |
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Application publication date: 20131106 |