CN103374455A - Oil product regeneration technology and oil product production system - Google Patents

Oil product regeneration technology and oil product production system Download PDF

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CN103374455A
CN103374455A CN2012101282148A CN201210128214A CN103374455A CN 103374455 A CN103374455 A CN 103374455A CN 2012101282148 A CN2012101282148 A CN 2012101282148A CN 201210128214 A CN201210128214 A CN 201210128214A CN 103374455 A CN103374455 A CN 103374455A
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oil
silica gel
production system
oil product
technology
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CN103374455B (en
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张洋源
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Abstract

The invention particular relates to a technology and a production system for purifying and regenerating recycled oil products such as engine oil, lubricating oil and internal combustion engine oil, and aims at providing a technology and a production system for purifying and regenerating oil products in large scale. The technology comprises the following steps of: a, distilling the oil products to separate solid particles and difficultly-volatile substances; b, cooling gas-phase oil products obtained by distillation to be in a liquid state and separating the moisture; c, removing impurities, such as acids and bases, in the oil products by using destaining silica gel. The production system comprises a distillation device, a fraction cooling device, a water knockout drum, and a destaining device capable of performing destaining by using the silica gel. According to the technology and the production system, the technology operation is easy, the large-scale production is facilitated, a scientific development idea of energy conservation and emission reduction can be met, and the market prospect is wide.

Description

Oil regeneration technique and production system
Technical field
The invention belongs to the oil product processing technology, is exactly to reclaim machine oil, lubricating oil, oil engine wet goods oil product to carry out technique and the production system that purifying regeneration is processed specifically.
Background technology
At present, for example transformer oil, turbine oil, lubricated wet goods grease later can be oxidized or other chemical variation occurs through after a while use, variable color is fouled, bring danger for the use of oil product, for example the oxidation of transformer oil may produce the acid change, acid and alkali substance all has electroconductibility, causes easily transformer short-circuit to burn, and the acid content standard of transformer oil is less than or equal to 0.03% in the native land man standard.
I. C. engine oil sucks the easily aged deteriorations such as insoluble and dissolvable oxides that produce after scrap metal grain that dust, overwear vt. produces, the oxidation because moisture or cooling fluid, fuel, soot, carbonaceous thing are sneaked into.Use the oil product of aged deterioration, can cause the piston ring bonding, oil circuit stops up, and corrosion and settling increase, the wearing and tearing aggravation.
Therefore, in a lot of technical fields, oil product such as all needs in time to filter at the purifying treatment, recovers the use properties of oil product, saves the oily expense of purchasing, and saves oil resource.
And also do not have to be fit to carry out in enormous quantities on a large scale the technology and equipment of oil purification and manipulation of regeneration in the prior art.
Summary of the invention
Main purpose of the present invention provides a kind of technique and production system that is fit to extensive in batches purification and regeneration oil product.
For achieving the above object, the technical solution adopted in the present invention is: a kind of oil regeneration technique, and step comprises:
A, oil product fractionation by distillation solid particulate and volatile-resistant substance;
B, the gas phase oil product that distills are cooled to liquid state and separate moisture;
C, utilization decolouring silica gel remove the impurity such as soda acid in the oil product.
As shown from the above technical solution: oil regeneration technique of the present invention mainly is to add thermal distillation first so that the macromolecular substance of the solid particulate such as dust, grinding and difficult volatilization remains in the water distilling apparatus, carry out the control of suitable temperature by the cut water cooler and can obtain the component basically identical with institute desirable oil product boiling point, this component is just comparatively pure.Then utilize water trap to remove wherein moisture, be convenient to improve the efficient of silica decoloration, also be convenient to control water ratio, oxidized when preventing from reusing.Then utilize the decolouring of decolouring silica gel oil supply product, the microvoid structure of decolouring silica gel can adsorb the impurity such as acid in the oil product, alkali, the oil property that obtains with newly purchase oil product in other words conj.or perhaps desirable oil property be as good as, oil product can the recirculation utilization, greatly reduces production costs.And technological operation technique of the present invention is simple, is convenient to scale operation, meets the scientific development thinking of energy-saving and emission-reduction, has wide market outlook.And because this process using the decolouring silica decoloration, make cut be condensed into liquid getting final product so the cut water cooler also can only be controlled cooling, and need not to collect the cut of specified temp, can guarantee equally the effect of purifying regeneration.
Accordingly, implement the production system of above-mentioned oil regeneration technique, comprise the decoloration device of the water distilling apparatus that arranges by treatment scheme, cut water cooler, water trap, utilization decolouring silica decoloration.
Further, the process furnace that described water distilling apparatus comprises retort and is used for heating to retort, the heating-furnace wall material is followed successively by from inside to outside: high temperature alumina silicate block, ceramic fiber cotton blanket, composite magnesium silicate, steel plate.Such improvement protecting wall structure significantly improves than utilizing alumina silicate block to do the furnace wall effect of heat insulation in the prior art, is fit to fire coal, Sweet natural gas, liquefied petroleum gas (LPG) heating.Under equal heating condition, the temperature of furnace wall of the present invention outside surface all is lower than 40 ℃, significantly reduces more than 30 ℃ than prior art is aobvious, not only reduces calorific loss, and has avoided the furnace wall to cause that the user scalds Occupational safety hidden danger.
Described retort is made by 304 stainless steels.Material thickness is thin, heat transfer is fast, indeformable, and easy burn-out not need not to change retort in 8-10, greatly reduces production cost and maintenance cost.
Described water cooler comprises the many cooling tubes of arranging in turn, and the axial along continuous straight runs of cooling tube is arranged.The heat transferring medium of water cooler utilizes water coolant usually, and cooling tube is horizontally disposed to be convenient to dismantle two ends and to clean dirt in the pipe, improves cooling efficiency.
Described system comprises the silica regeneration unit, the silica regeneration unit comprises silica gel regenerator, described silica gel regenerator top arranges the hot body that hot blast is provided, the silica gel regenerator bottom arranges air draft mechanism, and hot blast is flowed through silica gel from top to bottom by air draft mechanism discharge silica gel regenerator at furnace chamber.Hot gas flow circulates downwards, the impurity Yin Wendu height reduced viscosity such as the oil product that silica gel adheres to and soda acid and flowing downward, discharged a large amount of oil products, part oil product and organism are discharged through the air outlet of lower portion of furnace body with air-flow because of the volatilization of being heated simultaneously, just can reuse after oil content, impurity in silica gel and the micropore thereof all is discharged from, play the effect of decolouring.
The air draft mechanism of described silica gel regenerator is connected with the off gas treatment tank, in the off gas treatment tank active carbon adsorption material is set, and the outlet of off gas treatment tank is connected with the secondary cooling tank.The waste gas of silica gel regenerator can be processed like this, realize non-pollution discharge, avoid environmental pollution.
Improvement core point of the present invention is the optimization of processing set-up, especially turnout is managed the oil that can avoid distilling and is passed through the turnout reason, just directly carried out except acid treatment, avoid causing the waste of decolouring silica gel, also avoid causing decolorizing effect bad and directly have influence on the quality of oil product, avoid oil product to be subject to again oxygen and become color of water capacity effect of acid.It is to utilize carclazyte that the prior art decolouring is processed, and contains a large amount of oil behind the clay treatment oil product, can not recycle, and causes secondary pollution.Process gas by activated carbon treatment, also is not a kind of factor that pollutes.And the clear degree with the oil product after the clay treatment is difficult to improve, because the powder of carclazyte is very thin, general filter core is to solve, only have with filter paper and come removal of impurities, filtering the waste paper of oil product can not process, if burning has a large amount of oil, contain a large amount of oil molecules in the smog, also bad to smoke treated.The present invention utilizes decolouring silica gel, has successfully solved this technical barrier.Technique, equipment as for each processing unit then can be with reference to prior aries, and the present invention also provides corresponding preferred implementation.
Description of drawings
Fig. 1 is the synoptic diagram of production system of the present invention;
Fig. 2 is the structural representation of silica gel regenerator;
Fig. 3 is that A-A among Fig. 1 is to sectional view.
Embodiment
As shown in Figure 1, water distilling apparatus of the present invention comprises retort 19 and is used for the body of heater 20 of heating.Retort 19 is to make of 304 stainless steels, and material thickness is thin, heat transfer is fast, indeformable, and easy burn-out not need not to change retort in 8-10, greatly reduces production cost and maintenance cost; The furnace wall material of body of heater 20 from inside to outside the first layer is alumina silicate block; use temperature is at 1600 ℃; the second layer is 20-30mm ceramic fiber cotton blanket; then use temperature is that the 50mm composite magnesium silicate is two-layer at 1600 ℃, and composite magnesium silicate is the expansion type material; in have a lot of fine close-connected poroid; heat insulation effect is excellent, and the provide protection to lagging material is played with the steel plate sealing of 1mm in the outside.The employing infrared thermometer is measured, and the steel plate hull-skin temperature is no more than 40 ℃.The present invention by three kinds of materials combination so that the furnace wall hull-skin temperature about 40 ℃.In construction process, alumina silicate block must water be dipped into the water surface comprehensively and emerge bubble for this reason, uses high-temperature agglomerant bonding again, makes whole edge joint performance good, does not smolder, and does not cause secondary pollution.
The oil gas that distills is by water cooler 28, water cooler 28 comprises cooling tank body 25,26,27, recirculated cooling water and horizontally disposed cooling tube are set in it, flow through in the cooling tube of oil gas in the uppermost cooling tank body 25 and be cooled, then enter successively cooling tank body 26,27 coolings, usually the flow direction and the oil gas opposite direction of water coolant are conducive to improve heat exchange efficiency like this.Oil gas is cooled to liquid rear to 30 minutes water of water trap, enters decoloration device 40 behind minute water again, the impurity such as the adsorption treatment function removal acid of utilization decolouring silica gel, alkali.Oil after the decolouring enters and stores fuel tank 50, and when oil arrived specified location, oil pump automatically startup pumped into fluid in the oil tank 60; This oil is base oil.The user is being deployed into needed oil product as required, after decolouring silica gel lost efficacy, the silica gel that will decolour is emitted and is carried out manipulation of regeneration, the decoloration device 40 of packing into again after the processing uses, the rate of recovery of each decolouring silica regeneration is between 95-98%, greatly reduce like this use cost of decolouring silica gel, also can not cause for the second time and pollute.The smog that whole equipment operation and silica regeneration produce, we carry naturally cooling to utilize activated carbon adsorption to process by off gas treatment tank 70 by pipeline, after process water treatment tank 80 is crossed water treatment again, are discharged by vacuum fan, the expellant gas colorless and odorless, zero disposal of pollutants.Whole system has all embodied the value of recycling, and making product really reach environmental protection is target, satisfies various users' requirement.
Further, the water distilling apparatus system adopts hermetically sealed, and the gas of distillation can not leak gas; reliable securing system is arranged; the over-temp and over-pressure automatic control alarm system is arranged, over-temp and over-pressure automatic interlock Controlling System is arranged, Controlling System comprises that automatically unloading, mechanical release two portions form.Can automatically control, also can manually operate, ensure safety.
In the production, must confirm moisture content in the waste oil before the retort 19 interior pump oil by oil reservoir 12, moisture content can not surpass 3-5%, excess moisture can be wasted fuel, increases the treatment time, increases the required water yield of water-cooling system, cooling performance is poor, increase the difficulty that oil product divides water, decolouring, affect color and the quality of oil regeneration, also increase the discharge capacity of waste gas simultaneously.When the startup scavenge oil pump pumps into waste oil in the retort, can not add waste oil too much, addition generally be not more than the 50%-70% of the useful volume of retort.Purpose is to add waste oil too much: the oil mass that can only add exactly is volume a greater part of of retort; Prevent fluid boiling effusion, affect follow-up minute water; Simultaneously prevent that also impurity from entering into subsequent handling with liquid oil.Behind the complete waste oil of pump, closeall fuel inlet ball check valve.Start scavenge oil pump after 10 minutes, start the burner heating, start vacuum fan, off gas treatment water pump, cooling-water pump, check whether all energising equipment operation situations are normal.
In refining process, in the time of need to quitting work, first brennschluss burner after temperature drops to below 200 ℃, can stop to provide cooling-water pump, off gas treatment water pump, the vacuum fan of water coolant temporarily.
In refining process, when oil temperature reaches 300 ℃ the firepower of burner reduced, make the oil temperature lift velocity slack-off, continue for some time like this, for example one to three hour, if oil temperature surpasses 360 ℃ then the heating of cease combustion device, make between oil temperature slowly falls back to about 320 ℃, make basically all evaporations of oil; And then continue with being heated to about 600 ℃, when the temperature fast rise and when reporting to the police, close combustion engine, other device requirements continue to run until can all operations of arrestment when drop in temperature puts 150 ℃ of left and right sides in place.Namely slow rear fast first, the middle roughly still-process of constant temperature is with the whole evaporations of the oil in the retort 19.Do not cause simultaneously the pyrometamorphism of oil, needing at last suitable short time high temperature then is in order to promote the coking of waste material, to be convenient to cleaning and not cause environmental pollution.
In oil refining process, must guarantee that the coolant water temperature of cooling water tank 90 can not be above 50 ℃, otherwise bad to the oil gas cooling performance, oil gas directly arrives fuel reserve tank by decoloration device 40, and discharge by venting hole, can cause fluid residence time in decoloration device 40 too short, affect the oil product decolorizing effect, also cause oil gas not cool off and cause the waste and environmental pollution.
In conjunction with shown in Figure 2, the present invention is provided with silica gel regenerator 10, and the decolouring silica gel after using is carried out activating and regenerating.For making those skilled in the art more properly understand technology contents of the present invention and effect, with internal diameter 0.6m, the height 1.35m of body of heater 10, single treatment amount 0.5m 3The regeneration body of heater be example, introduce the concrete operations explanation of silica regeneration:
Open the lower end cover 17 of bottom, check and adjust the conical baffled 14 of the inside, make it be in the position that overlaps with body of heater 10 axle cores, namely keep off the mid-way in inside, body of heater 10 lower end.
Open loam cake 1, the plectane 11 in the body of heater 10 is taken out.
Decolouring silica gel after filling is used fills first particle diameter usually at the thick silica gel of 4~8mm, refills particle diameter at the thin silica gel of 0.25~2mm; Simultaneously preferably top is that thinner Kiselgel A, the bottom of micropore size on the silica gel particle is silochrom, guarantees that oil content circulation downwards is comparatively unobstructed, thus simultaneously Kiselgel A because separate the oil content difficulty greatly from thermal source close to, guarantee regeneration effect.Because itself have a lot of microvoid structures on the silica gel, so also can transmit and realize regeneration even only fill the Kiselgel A heat, just need the heat-up time of regeneration to prolong.Silica gel installs to the top side and is advisable from the about 50MM of orifice plate that places plectane 11, avoids silica gel directly to contact with flame, after installing, plectane 11 is put back to build, and closes loam cake 1.
Build lower end cover 17, upper two or three bolts just with good all right on hand, should not be gone up too tightly, in order to unscrew.
With the inflammable substance such as refuse that oil is arranged fire is ignited first during igniting, add firewood, start simultaneously blower fan 4.Firewood just burns at the plate body of plectane 11 and side, and through hole downwards logical flame and hot gas are set on this plate body and the plectane 11.Firewood once should not add too much, avoids causing a fog in body of heater 10 and burning insufficient.
After burning about 30 minutes, slowly loosening the bolt of lower end cover 17, until lower end cover 17 places still have the slit but not smoke, the oil content outflow is convenient in such slit.
Have soon oil this moment and flow out from lower end cover 17 edges, connect with container, continue heating until lower end cover 17 edges are not fuel-displaced.During lower end cover 17 places are fuel-displaced, there is smog out, then bolt is tightly suitably tightened, but can not tension, flow out in order to avoid affect fluid.
In combustion processes, note adding firewood, observed every 10~15 minutes; Midway can not cease combustion heating, the smog that 17 places are covered in about 1 hour posterior end reduces and becomes that explanation smog mainly is water vapour behind the white colour, does not almost have oil gas; Just can blowing-out machine 4, certainly, proper extension also is fine heat-up time, usually treats body of heater 10 interior firewood after-flames.
After the shutdown, if at that time need not, need to all bolts on the lower end cover 17 be tightened, remaining opening also will seal, and keeps body of heater 10 inner chambers not enter air, avoids silica gel to make moist, and affects decolorizing effect.
Perhaps until opening lower end cover 17 after the silica gel cooling silica gel after regenerating is emitted from the bottom.If directly discharging or treat that temperature suitably is higher than the room temperature discharging then will by instrument, avoid scalding.
Silica gel after the regeneration does not have considerable change with the main performance index of using front product (the new silica gel product when namely not using), meets service requirements, and concrete testing data is as shown in table 1:
Table 1:ZCX-I column layer chromatography silicone rubber product uses the main performance index after front and the regeneration
Figure BDA0000157932770000071
During technical finesse silica gel of the present invention, in the firewood combustion process, oil, acidity, greasy filth, moisture contained in the silica gel decomposes, volatilizees and discharge with smog, thereby reaches the purpose that silica gel reclaims.Can carry out activating and regenerating with existing silica gel with the kin product of silica gel, significantly reduce the product use cost.Have significant economic benefit and environmental benefit.Add thermogenetic ash content as for firewood and be blended in the silica gel then not obviously impact of performance on silica gel, because ash content is mainly the salt of alkaline matter or inertia, and in the oil product decolouring removal process filtration unit is arranged in decolouring, so can not impact oil product and recovery and use.

Claims (7)

1. oil regeneration technique, step comprises:
A, oil product fractionation by distillation solid particulate and volatile-resistant substance;
B, the gas phase oil product that distills are cooled to liquid state and separate moisture;
C, utilization decolouring silica gel remove the impurity such as soda acid in the oil product.
2. a kind of oil regeneration technique according to claim 1, it is characterized in that: described distillation utilizes retort to carry out, and the oil product addition is the useful volume 50%-70% of retort.
3. implement claim 1 or 2 described oil regeneration production systems for one kind, it is characterized in that: the decoloration device that comprises the water distilling apparatus that arranges by treatment scheme, cut water cooler, water trap, utilization decolouring silica decoloration.
4. a kind of oil regeneration production system according to claim 3, it is characterized in that: the process furnace that described water distilling apparatus comprises retort and is used for heating to retort, the heating-furnace wall material is followed successively by from inside to outside: high temperature alumina silicate block, ceramic fiber cotton blanket, composite magnesium silicate, steel plate.
5. a kind of oil regeneration production system according to claim 3 is characterized in that: described water cooler comprises the many cooling tubes of arranging in turn, and the axial along continuous straight runs of cooling tube is arranged.
6. a kind of oil regeneration production system according to claim 3, it is characterized in that: described system comprises the silica regeneration unit, the silica regeneration unit comprises silica gel regenerator, described silica gel regenerator top arranges the hot body that hot blast is provided, the silica gel regenerator bottom arranges air draft mechanism, and hot blast is flowed through silica gel from top to bottom by air draft mechanism discharge silica gel regenerator at furnace chamber.
7. a kind of oil regeneration production system according to claim 6, it is characterized in that: the air draft mechanism of described silica gel regenerator is connected with the off gas treatment tank, in the off gas treatment tank active carbon adsorption material is set, the outlet of off gas treatment tank is connected with the secondary cooling tank.
CN201210128214.8A 2012-04-27 2012-04-27 oil regeneration technique and production system Active CN103374455B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106139641A (en) * 2016-08-25 2016-11-23 广东电网有限责任公司电力科学研究院 The processing method of aminophenazone in a kind of transformer oil
CN110295058A (en) * 2019-06-28 2019-10-01 山东华油新能源科技股份有限公司 The waste oil decoloration process and equipment that can be reused

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN201375899Y (en) * 2009-02-23 2010-01-06 宝山钢铁股份有限公司 Allochroic silicagel regeneration unit
CN201809425U (en) * 2010-09-17 2011-04-27 华南理工大学 Liquid zinc storage tank for hot galvanizing zinc production line
CN202530061U (en) * 2012-04-27 2012-11-14 张洋源 Oil product regeneration system

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN201375899Y (en) * 2009-02-23 2010-01-06 宝山钢铁股份有限公司 Allochroic silicagel regeneration unit
CN201809425U (en) * 2010-09-17 2011-04-27 华南理工大学 Liquid zinc storage tank for hot galvanizing zinc production line
CN202530061U (en) * 2012-04-27 2012-11-14 张洋源 Oil product regeneration system

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邓慧东: "铝箔轧制废油的再生研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》, 15 February 2011 (2011-02-15), pages 18 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106139641A (en) * 2016-08-25 2016-11-23 广东电网有限责任公司电力科学研究院 The processing method of aminophenazone in a kind of transformer oil
CN110295058A (en) * 2019-06-28 2019-10-01 山东华油新能源科技股份有限公司 The waste oil decoloration process and equipment that can be reused

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