CN103351523B - A kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material and preparation method thereof - Google Patents
A kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material and preparation method thereof Download PDFInfo
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- CN103351523B CN103351523B CN201310244080.0A CN201310244080A CN103351523B CN 103351523 B CN103351523 B CN 103351523B CN 201310244080 A CN201310244080 A CN 201310244080A CN 103351523 B CN103351523 B CN 103351523B
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- halogen flame
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- 239000000463 material Substances 0.000 title claims abstract description 25
- 239000003063 flame retardant Substances 0.000 title claims abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229920013636 polyphenyl ether polymer Polymers 0.000 title claims abstract description 12
- 229920001971 elastomer Polymers 0.000 title claims abstract description 11
- 239000000806 elastomer Substances 0.000 title claims abstract description 11
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 11
- 239000000779 smoke Substances 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000019484 Rapeseed oil Nutrition 0.000 claims abstract description 7
- XFBXDGLHUSUNMG-UHFFFAOYSA-N alumane;hydrate Chemical compound O.[AlH3] XFBXDGLHUSUNMG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004927 clay Substances 0.000 claims abstract description 7
- 238000012986 modification Methods 0.000 claims abstract description 7
- 230000004048 modification Effects 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- LRTTZMZPZHBOPO-UHFFFAOYSA-N [B].[B].[Hf] Chemical compound [B].[B].[Hf] LRTTZMZPZHBOPO-UHFFFAOYSA-N 0.000 claims abstract description 4
- XTDAIYZKROTZLD-UHFFFAOYSA-N boranylidynetantalum Chemical compound [Ta]#B XTDAIYZKROTZLD-UHFFFAOYSA-N 0.000 claims abstract description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004327 boric acid Substances 0.000 claims abstract description 4
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920006380 polyphenylene oxide Polymers 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 9
- 229940126062 Compound A Drugs 0.000 claims description 6
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 3
- 229910017083 AlN Inorganic materials 0.000 claims description 3
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims 2
- 229940075507 glyceryl monostearate Drugs 0.000 claims 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims 1
- 235000021355 Stearic acid Nutrition 0.000 abstract description 3
- 125000005456 glyceride group Chemical group 0.000 abstract description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 3
- 239000008117 stearic acid Substances 0.000 abstract description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
- Organic Insulating Materials (AREA)
Abstract
A kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material and preparation method thereof, is characterized in that being made up of the raw material of following weight part: polyphenylene oxide 25-28, ethylene-methyl acrylate copolymer (EMA? 1126AC) 30-34, tantalum boride 5-7, hafnium boride 2-3, boric acid 1-2, stearic acid direactive glyceride 4-6, Zinic stearas 2-3, zinc oxide 1-2, rapeseed oil 4-5, aluminium hydrate powder 12-15, bauxitic clay 26-29, glycerol glycerinate 3-4, methyltrimethoxy silane 2-3, altax? 1-2, modification infusorial earth 6-8.Wire cable material excellent in flame retardance of the present invention, can be tested by VW-1 vertical combustion, and mechanical property, water resistance and electrical insulating property are good, high-low temperature resistant.
Description
Technical field
The invention belongs to CABLE MATERIALS technical field, more particularly, relate to a kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material and preparation method thereof.
Background technology
Wire cable material, primarily of resinous principle, stopping composition, softening agent, anti-aging agent ,] fire retardant, oxidation inhibitor etc. is mixed, formula material mainly concentrates on some conventional compositions, cause the not high or high in cost of production problem of CABLE MATERIALS technical indicator thus, such as volume specific resistance is on the low side, high temperature resistant, low temperature resistant, flame retardant resistance, insulativity etc. can not meet the requirement of cable producer to insulation-grade sheath material more high electrical performance.
Summary of the invention
The object of this invention is to provide a kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material and preparation method thereof,
The technical solution adopted in the present invention is:
A kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material, is characterized in that being made up of the raw material of following weight part: polyphenylene oxide 25-28, ethylene-methyl acrylate copolymer (EMA1126AC) 30-34, tantalum boride 5-7, hafnium boride 2-3, boric acid 1-2, stearic acid direactive glyceride 4-6, Zinic stearas 2-3, zinc oxide 1-2, rapeseed oil 4-5, aluminium hydrate powder 12-15, bauxitic clay 26-29, glycerol glycerinate 3-4, methyltrimethoxy silane 2-3, altax 1-2, modification infusorial earth 6-8.
Described modification infusorial earth is obtained by following methods:
Diatomite is put into 450-500 DEG C of calcining 3-4 hour, take out, cooling, puts into 10-12% hydrochloric acid soln and soaks 1-2 hour, takes out, and cleans with pure water, dries grinding powder; Add the aluminium nitride, the calcium stearate of 2-3%, the Zirconium tetrafluoride of 2-3%, the alum powder of 3-4% that are equivalent to diatomite weight 35-40% again, mixed grinding 30-40 minute, and then spray into the iso-cyanuric acid triallyl ester being equivalent to diatomite weight 12-15%, under 12000-15000 rev/min, stir 60-80 minute, to obtain final product.
The preparation method of described low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material, it is characterized in that comprising the following steps: ethylene-methyl acrylate copolymer (EMA1126AC), rapeseed oil, aluminium hydrate powder, bauxitic clay, glycerol glycerinate are blended in 120-150 DEG C of mixing 12-16 minute, obtain compound A; Again by other mixing of materials, at 160-180 DEG C, mix 10-15 minute, obtain compound B; Again compound A, B are mixed, places after 12-15 hour, mix 10-15 minute at 140-150 DEG C after, feeding twin screw extruder extruding pelletization and get final product at 170-190 DEG C.
The present invention utilizes the rigidity that polyphenyl ether material itself is higher, good electrical insulating property and water tolerance, by adding ethylene-methyl acrylate copolymer, strengthens snappiness.Add the bonding force between methyltrimethoxy silane raising material, improve the comprehensive mechanical performance of blend.Wire cable material excellent in flame retardance of the present invention, can be tested by VW-1 vertical combustion, and mechanical property, water resistance and electrical insulating property are good, high-low temperature resistant.
Embodiment
A kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material, be made up of the raw material of following weight part (kilogram):
Polyphenylene oxide 25, ethylene-methyl acrylate copolymer (EMA1126AC) 34, tantalum boride 7, hafnium boride 2, boric acid 2, stearic acid direactive glyceride 6, Zinic stearas 3, zinc oxide 1, rapeseed oil 5, aluminium hydrate powder 15, bauxitic clay 26, glycerol glycerinate 4, methyltrimethoxy silane 3, altax 2, modification infusorial earth 8.
Described modification infusorial earth is obtained by following methods:
Diatomite is put into 450-500 DEG C of calcining 3-4 hour, take out, cooling, puts into 10-12% hydrochloric acid soln and soaks 1-2 hour, takes out, and cleans with pure water, dries grinding powder; Add again be equivalent to diatomite weight 40% aluminium nitride, 3% calcium stearate, the Zirconium tetrafluoride of 3%, the alum powder of 4%, mixed grinding 30-40 minute, and then spray into the iso-cyanuric acid triallyl ester being equivalent to diatomite weight 15%, under 12000-15000 rev/min, stir 60-80 minute, to obtain final product.
The preparation of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material, comprise the following steps: ethylene-methyl acrylate copolymer (EMA1126AC), rapeseed oil, aluminium hydrate powder, bauxitic clay, glycerol glycerinate are blended in 120-150 DEG C of mixing 12-16 minute, obtain compound A; Again by other mixing of materials, at 160-180 DEG C, mix 10-15 minute, obtain compound B; Again compound A, B are mixed, places after 12-15 hour, mix 10-15 minute at 140-150 DEG C after, feeding twin screw extruder extruding pelletization and get final product at 170-190 DEG C.
CABLE MATERIALS performance of the present invention:
| Project | Unit | CABLE MATERIALS of the present invention |
| Green tensile intensity | MPa is not less than | 25.00 |
| Original broken elongation | % is not less than | 230 |
| After resistance to 158 DEG C × 168h is aging | ||
| Breaking tenacity | MPa is not less than | 21 |
| Elongation at break | % is not less than | 210 |
| 20 DEG C of volume specific resistances | Ω·m | 1.0×1015 |
| 200 DEG C of heat-stable times | Min | 70 |
Claims (2)
1. a low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material, is characterized in that being made up of the raw material of following weight part: polyphenylene oxide 25-28, ethylene-methyl acrylate copolymer EMA1126AC30-34, tantalum boride 5-7, hafnium boride 2-3, boric acid 1-2, glyceryl monostearate 4-6, Zinic stearas 2-3, zinc oxide 1-2, rapeseed oil 4-5, aluminium hydrate powder 12-15, bauxitic clay 26-29, glycerol glycerinate 3-4, methyltrimethoxy silane 2-3, altax 1-2, modification infusorial earth 6-8;
Described modification infusorial earth is obtained by following methods: diatomite is put into 450-500 DEG C of calcining 3-4 hour, take out, cooling, puts into 10-12% hydrochloric acid soln and soak 1-2 hour, takes out, and cleans with pure water, dries grinding powder; Add the aluminium nitride, the calcium stearate of 2-3%, the Zirconium tetrafluoride of 2-3%, the alum powder of 3-4% that are equivalent to diatomite weight 35-40% again, mixed grinding 30-40 minute, and then spray into the iso-cyanuric acid triallyl ester being equivalent to diatomite weight 12-15%, under 12000-15000 rev/min, stir 60-80 minute, to obtain final product.
2. the preparation method of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material according to claim 1, it is characterized in that comprising the following steps: ethylene-methyl acrylate copolymer EMA1126AC, rapeseed oil, aluminium hydrate powder, bauxitic clay, glycerol glycerinate are blended in 120-150 DEG C of mixing 12-16 minute, obtain compound A; Again by other mixing of materials, at 160-180 DEG C, mix 10-15 minute, obtain compound B; Again compound A, B are mixed, places after 12-15 hour, mix 10-15 minute at 140-150 DEG C after, feeding twin screw extruder extruding pelletization and get final product at 170-190 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310244080.0A CN103351523B (en) | 2013-06-19 | 2013-06-19 | A kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310244080.0A CN103351523B (en) | 2013-06-19 | 2013-06-19 | A kind of low-smoke zero-halogen flame-retardant polyphenyl ether elastomer cable material and preparation method thereof |
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| CN103351523A CN103351523A (en) | 2013-10-16 |
| CN103351523B true CN103351523B (en) | 2016-02-10 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805509A (en) * | 2010-03-26 | 2010-08-18 | 北京化工大学 | Polyphenyl ether compound used for solar battery connecting box |
| CN101982500A (en) * | 2010-11-03 | 2011-03-02 | 南通星辰合成材料有限公司 | Polyphenyl ether alloy resin material for processing photovoltaic connector |
| CN102030978A (en) * | 2010-11-26 | 2011-04-27 | 中国蓝星（集团）股份有限公司 | Halogen-free flame retardant polyphenylene oxide polyphenyl ether (PPE) cable material composition and preparation method thereof |
| CN102304279A (en) * | 2011-08-18 | 2012-01-04 | 常熟泓淋电线电缆有限公司 | Modified halogen-free inflaming retarding wire and cable material |
| CN102585428A (en) * | 2012-03-15 | 2012-07-18 | 浙江北化阻燃材料有限公司 | Flexible halogen-free flame-retardant polyphenyl ether electric wire cable shield material and preparation method thereof |
| CN102604361A (en) * | 2012-03-16 | 2012-07-25 | 天津市普立泰高分子科技有限公司 | Low-smoke, halogen-free and flame-retardant polyphenyl ether elastomer cable material and preparation method thereof |
-
2013
- 2013-06-19 CN CN201310244080.0A patent/CN103351523B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805509A (en) * | 2010-03-26 | 2010-08-18 | 北京化工大学 | Polyphenyl ether compound used for solar battery connecting box |
| CN101982500A (en) * | 2010-11-03 | 2011-03-02 | 南通星辰合成材料有限公司 | Polyphenyl ether alloy resin material for processing photovoltaic connector |
| CN102030978A (en) * | 2010-11-26 | 2011-04-27 | 中国蓝星（集团）股份有限公司 | Halogen-free flame retardant polyphenylene oxide polyphenyl ether (PPE) cable material composition and preparation method thereof |
| CN102304279A (en) * | 2011-08-18 | 2012-01-04 | 常熟泓淋电线电缆有限公司 | Modified halogen-free inflaming retarding wire and cable material |
| CN102585428A (en) * | 2012-03-15 | 2012-07-18 | 浙江北化阻燃材料有限公司 | Flexible halogen-free flame-retardant polyphenyl ether electric wire cable shield material and preparation method thereof |
| CN102604361A (en) * | 2012-03-16 | 2012-07-25 | 天津市普立泰高分子科技有限公司 | Low-smoke, halogen-free and flame-retardant polyphenyl ether elastomer cable material and preparation method thereof |
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Denomination of invention: A low smoke halogen free flame retardant polyphenylene ether elastomer cable material and its preparation method Effective date of registration: 20210416 Granted publication date: 20160210 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2021980002725 |
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Denomination of invention: The invention relates to a low smoke halogen-free flame retardant polyphenylene ether elastomer cable material and a preparation method thereof Effective date of registration: 20220414 Granted publication date: 20160210 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2022980004178 |