CN103351509B - A kind of cable insulation compositions and preparation method thereof - Google Patents
A kind of cable insulation compositions and preparation method thereof Download PDFInfo
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- CN103351509B CN103351509B CN201310243554.XA CN201310243554A CN103351509B CN 103351509 B CN103351509 B CN 103351509B CN 201310243554 A CN201310243554 A CN 201310243554A CN 103351509 B CN103351509 B CN 103351509B
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- cable insulation
- antioxidant
- silicon carbide
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- 238000009413 insulation Methods 0.000 title claims abstract description 14
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920001971 elastomer Polymers 0.000 claims abstract description 15
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 12
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 12
- 239000004113 Sepiolite Substances 0.000 claims abstract description 11
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 11
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 11
- 229920001195 polyisoprene Polymers 0.000 claims abstract description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011449 brick Substances 0.000 claims abstract description 7
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000004048 modification Effects 0.000 claims abstract description 7
- 238000012986 modification Methods 0.000 claims abstract description 7
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002893 slag Substances 0.000 claims abstract description 7
- 239000011701 zinc Substances 0.000 claims abstract description 7
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 7
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 6
- 239000012802 nanoclay Substances 0.000 claims abstract description 6
- 239000000779 smoke Substances 0.000 claims abstract description 6
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims abstract description 4
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims abstract description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910007948 ZrB2 Inorganic materials 0.000 claims abstract description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 4
- VWZIXVXBCBBRGP-UHFFFAOYSA-N boron;zirconium Chemical compound B#[Zr]#B VWZIXVXBCBBRGP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052923 celestite Inorganic materials 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 239000012948 isocyanate Substances 0.000 claims abstract description 4
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229910000077 silane Inorganic materials 0.000 claims abstract description 4
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010455 vermiculite Substances 0.000 claims abstract description 4
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 4
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 4
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims description 8
- 229940126062 Compound A Drugs 0.000 claims description 6
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 3
- 229910017083 AlN Inorganic materials 0.000 claims description 3
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- XFBXDGLHUSUNMG-UHFFFAOYSA-N alumane;hydrate Chemical compound O.[AlH3] XFBXDGLHUSUNMG-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- SMNNDVUKAKPGDD-UHFFFAOYSA-N 2-butylbenzoic acid Chemical compound CCCCC1=CC=CC=C1C(O)=O SMNNDVUKAKPGDD-UHFFFAOYSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 235000019504 cigarettes Nutrition 0.000 claims 1
- YGZXCVSWQWFWAA-UHFFFAOYSA-N ethenyl acetate;propanoic acid Chemical compound CCC(O)=O.CC(=O)OC=C YGZXCVSWQWFWAA-UHFFFAOYSA-N 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- -1 inserts Substances 0.000 description 2
- 239000011863 silicon-based powder Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
Landscapes
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Description
Project | Unit | CABLE MATERIALS of the present invention |
Green tensile intensity | MPa is not less than | 15.00 |
Original broken percentage elongation | % is not less than | 460 |
After resistance to 158 DEG C × 168h is aging | ||
Fracture strength | MPa is not less than | 13 |
Elongation at break | % is not less than | 440 |
20 DEG C of specific insulations | Ω·m | 1.0×1014 |
200 DEG C of heat-stable times | Min | 60 |
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310243554.XA CN103351509B (en) | 2013-06-19 | 2013-06-19 | A kind of cable insulation compositions and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310243554.XA CN103351509B (en) | 2013-06-19 | 2013-06-19 | A kind of cable insulation compositions and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN103351509A CN103351509A (en) | 2013-10-16 |
CN103351509B true CN103351509B (en) | 2016-08-10 |
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CN201310243554.XA Active CN103351509B (en) | 2013-06-19 | 2013-06-19 | A kind of cable insulation compositions and preparation method thereof |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103601941B (en) * | 2013-10-22 | 2016-03-16 | 国家电网公司 | A kind of Thermoplastic Elastomer, Olefinic cable jacket material and preparation method thereof |
CN112331418B (en) * | 2020-10-28 | 2022-05-17 | 江苏亿致通信科技有限公司 | Production method for 5G high-frequency anti-interference communication cable |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001055545A (en) * | 1999-08-18 | 2001-02-27 | Toyo Chem Co Ltd | Tape |
CN101070412A (en) * | 2007-06-11 | 2007-11-14 | 黄东东 | Halogen-free expansion fire-retardant cable material and environment-protection type cable made thereby |
CN102911440A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Polytetrafluoroethylene insulated cable material for aviation and method for preparing same |
CN102964668A (en) * | 2012-11-16 | 2013-03-13 | 江苏远洋东泽电缆股份有限公司 | Chemical crosslinking polyolefin insulating rubber for offshore oil gas engineering cable and manufacturing method |
CN102969043A (en) * | 2012-11-16 | 2013-03-13 | 江苏远洋东泽电缆股份有限公司 | High-temperature-resistant soft double-shield instrument cable for maritime oil and gas engineering and manufacturing method thereof |
CN103012885A (en) * | 2012-11-13 | 2013-04-03 | 安徽文峰电子科技集团有限公司 | Flame-retardant type cable sheath insulation material and preparation method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100227966A1 (en) * | 2009-03-06 | 2010-09-09 | Shawcor Ltd. | Moisture-crosslinked polyolefin compositions |
-
2013
- 2013-06-19 CN CN201310243554.XA patent/CN103351509B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001055545A (en) * | 1999-08-18 | 2001-02-27 | Toyo Chem Co Ltd | Tape |
CN101070412A (en) * | 2007-06-11 | 2007-11-14 | 黄东东 | Halogen-free expansion fire-retardant cable material and environment-protection type cable made thereby |
CN102911440A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Polytetrafluoroethylene insulated cable material for aviation and method for preparing same |
CN103012885A (en) * | 2012-11-13 | 2013-04-03 | 安徽文峰电子科技集团有限公司 | Flame-retardant type cable sheath insulation material and preparation method thereof |
CN102964668A (en) * | 2012-11-16 | 2013-03-13 | 江苏远洋东泽电缆股份有限公司 | Chemical crosslinking polyolefin insulating rubber for offshore oil gas engineering cable and manufacturing method |
CN102969043A (en) * | 2012-11-16 | 2013-03-13 | 江苏远洋东泽电缆股份有限公司 | High-temperature-resistant soft double-shield instrument cable for maritime oil and gas engineering and manufacturing method thereof |
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CN103351509A (en) | 2013-10-16 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Cable insulation composition and preparation method thereof Effective date of registration: 20190412 Granted publication date: 20160810 Pledgee: Tianchang Science and Technology Financing Guarantee Co., Ltd. Pledgor: Anhui Cable Co., Ltd. Registration number: 2019340000197 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200415 Granted publication date: 20160810 Pledgee: Tianchang Science and Technology Financing Guarantee Co., Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: 2019340000197 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Cable insulation composition and preparation method thereof Effective date of registration: 20200421 Granted publication date: 20160810 Pledgee: Tianchang Science and Technology Financing Guarantee Co., Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2020980001678 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20210414 Granted publication date: 20160810 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2020980001678 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a cable insulating composition and a preparation method thereof Effective date of registration: 20210416 Granted publication date: 20160810 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2021980002725 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220408 Granted publication date: 20160810 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2021980002725 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a cable insulation composition and a preparation method thereof Effective date of registration: 20220414 Granted publication date: 20160810 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2022980004178 |