CN103351043B - Vortex-type mixing sedimentation integrated reactor - Google Patents
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Abstract
本发明公开了一种涡流式混合沉淀一体式反应器,由相互连通的第一柱体,收缩椎体、扩张椎体、第二柱体组成,或者在第二柱体通过导流板连接沉淀区。水流切向进入第一柱体,边旋转边向下流动,在收缩椎体部分,由于截面变小,水的流速变大,进入扩张椎体时,由于截面突然变大,受水的纵向射流卷吸,在扩张椎体和第二柱体的近壁处出现较大的回流区,产生了负压,药物在此过程中随水流一起运动,与水流接触效果极佳,可降低药物的浪费,减少了药剂量。经由第二柱体部分的水流,流速极低,满足进入沉淀池的要求。不采用机械搅拌设备,减少了能源的消耗和维护的困难性,节约了运行费用和维修费用。
The invention discloses a vortex-type mixed-sedimentation integrated reactor, which is composed of a first column connected to each other, a shrinking cone, an expanding cone, and a second column, or the second column is connected to the sedimentation through a deflector district. The water flow enters the first cylinder tangentially, and flows downward while rotating. In the shrinking vertebral body, due to the smaller cross-section, the water flow rate increases. Entrainment, a larger recirculation zone appears near the wall of the expanded vertebral body and the second cylinder, generating negative pressure. During this process, the drug moves with the water flow, and the contact effect with the water flow is excellent, which can reduce the waste of drugs , reducing the dosage. The water flow through the second column part has an extremely low flow rate, which meets the requirements of entering the sedimentation tank. No mechanical stirring equipment is used, which reduces energy consumption and maintenance difficulty, and saves operating and maintenance costs.
Description
技术领域technical field
本发明涉及一种水处理的反应器,特别涉及用于一种加药处理废水的涡流式混合沉淀一体式反应器。不仅可以更加有效加强药物与水的混合效果以及沉淀效果,而且不采用任何电力设备,减少了能源的消耗。The invention relates to a reactor for water treatment, in particular to a vortex-type mixed-sedimentation integrated reactor for treating waste water with medicine. Not only can the mixing effect and precipitation effect of medicine and water be more effectively enhanced, but also no electric equipment is used, which reduces energy consumption.
背景技术Background technique
水的净化处理过程中通过加药使药剂与水中杂质或污染物发生化学反应的工艺很多,涉及污水处理和再生回用、工业废水处理与回用、循环冷却水处理、饮用水处理、特殊行业用水和废水处理、化工领域等。这些水处理工艺的去除效率往往取决于药剂与目标污染物或杂质的混合及分离效果,主要采用的是澄清池工艺和混凝沉淀工艺。In the process of water purification, there are many processes to chemically react chemicals with impurities or pollutants in water by adding drugs, involving sewage treatment and regeneration, industrial wastewater treatment and reuse, circulating cooling water treatment, drinking water treatment, special industries Water and wastewater treatment, chemical industry, etc. The removal efficiency of these water treatment processes often depends on the mixing and separation effects of chemicals and target pollutants or impurities, and the clarifier process and coagulation sedimentation process are mainly used.
澄清池工艺是一种将水和药剂的混合、反应及絮凝体与水的分离三个过程一体化的设备。主要包括有机械搅拌澄清池、水力循环澄清池、悬浮澄清池、脉冲澄清池。目前应用最广泛的是机械搅拌澄清池。机械搅拌澄清池工艺是利用机械使水提升和搅拌,促使泥渣循环,并使水中固体杂质与已形成的泥渣接触絮凝,进而达到分离沉淀的效果。其工作原理主要是:加药混合后的原水进入第一反应室,与几倍于原水的循环泥渣在叶片的搅动下进行接触反应,然后经叶轮提升至第二反应室继续反应,以结成较大的絮粒,再通过导流室进入分离室进行沉淀分离。水力循环澄清池工作原理基本同机械搅拌澄清池,不同处只是不用机械而利用水力在水射器的作用下进行混合和达到泥渣循环回流。The clarifier process is a device that integrates the three processes of mixing, reaction of water and chemicals, and separation of flocs and water. It mainly includes mechanical stirring clarifier, hydraulic circulation clarifier, suspension clarifier, pulse clarifier. At present, the most widely used is the mechanically stirred clarifier. The mechanical agitation clarifier process is to use machinery to lift and stir the water to promote the circulation of sludge, and to make the solid impurities in the water contact with the formed sludge and flocculate, thereby achieving the effect of separation and precipitation. Its working principle is as follows: the raw water after dosing and mixing enters the first reaction chamber, contacts and reacts with the circulating sludge several times larger than the raw water under the agitation of the blades, and then is lifted to the second reaction chamber by the impeller to continue the reaction. into larger flocs, and then enter the separation chamber through the diversion chamber for sedimentation and separation. The working principle of the hydraulic circulation clarifier is basically the same as that of the mechanical agitation clarifier. The difference is that it does not use machinery but uses hydraulic power to mix and achieve sludge circulation under the action of the water ejector.
混凝沉淀工艺包括有混凝过程和沉淀过程。混凝过程包括混合以及絮凝,混合过程主要是利用管式静态混合器使混凝剂和原水进行混合,然后进入絮凝池。絮凝过程是指投加混凝剂并经充分混合后的原水,在水流作用下使微絮粒相互接触碰撞,以形成更大絮粒的过程。絮凝池主要分为隔板絮凝、折板絮凝、网格絮凝、机械絮凝。沉淀池主要分为平流式沉淀池、竖流式沉淀池、辐流式沉淀池、斜管(斜板)沉淀池。目前应用最多的是辐流式沉淀池和斜管沉淀池。辐流式沉淀池多采用圆形,池底做成倾斜,水流从中心流向周边,流速逐渐减小。斜管沉淀池是在平流式或竖流式沉淀池的沉淀区内利用倾斜的平行管或平行管道分割成一系列浅层沉淀层,被处理的和沉降的沉泥在各沉淀浅层中相互运动并分离。The coagulation-sedimentation process includes a coagulation process and a precipitation process. The coagulation process includes mixing and flocculation. The mixing process mainly uses a tubular static mixer to mix the coagulant and raw water, and then enters the flocculation tank. The flocculation process refers to the process of adding a coagulant and fully mixing the raw water, and under the action of the water flow, the micro flocs contact and collide with each other to form larger flocs. The flocculation tank is mainly divided into clapboard flocculation, folding plate flocculation, grid flocculation and mechanical flocculation. Sedimentation tanks are mainly divided into flat flow sedimentation tanks, vertical flow sedimentation tanks, radial flow sedimentation tanks, and inclined tube (slope plate) sedimentation tanks. Radial flow sedimentation tanks and inclined tube sedimentation tanks are the most widely used at present. The radial flow sedimentation tank is mostly circular, and the bottom of the tank is inclined. The water flows from the center to the periphery, and the flow rate gradually decreases. The inclined tube sedimentation tank is divided into a series of shallow sedimentation layers by using inclined parallel pipes or parallel pipes in the sedimentation area of the horizontal flow or vertical flow sedimentation tank, and the treated and settled sediments move with each other in each shallow sedimentation layer and separated.
目前无论是混凝沉淀工艺还是机械搅拌澄清池工艺,都需要机械搅拌设备,存在电力消耗大,运行费用高、维修困难等缺陷。At present, both the coagulation sedimentation process and the mechanical stirring clarifier process require mechanical stirring equipment, which has the disadvantages of large power consumption, high operating costs, and difficult maintenance.
发明内容Contents of the invention
针对上述现有技术存在的缺陷或不足,本发明的目的在于,提供一种涡流式混合沉淀一体式反应器,该反应器采用水力混合方式的混合沉淀池,有别于一般的机械搅拌澄清池和水力循环澄清池,不采用任何机械搅拌设备或者水射器,完全利用水流的重力和初始流速,使水和混凝剂在反应器内部产生涡流以及回流,充分接触絮凝,从而提高了药剂的混合效果,减少了搅拌设备的使用,减少了能源的消耗,降低了运行维护费用,使得维护方便。In view of the defects or deficiencies in the above-mentioned prior art, the object of the present invention is to provide a vortex-type mixed-sedimentation integrated reactor, which adopts a mixed-sedimentation tank in a hydraulic mixing mode, which is different from a general mechanical agitation clarifier And the hydraulic circulation clarifier, without using any mechanical stirring equipment or water ejector, fully utilizes the gravity and initial flow velocity of the water flow, so that the water and coagulant generate vortex and reflux inside the reactor, and fully contact with flocculation, thus improving the chemical efficiency. The mixing effect reduces the use of mixing equipment, reduces energy consumption, reduces operation and maintenance costs, and makes maintenance easy.
为实现上述任务,本发明采用如下的技术解决方案:For realizing above-mentioned task, the present invention adopts following technical solution:
一种涡流式混合反应器,其特征在于,由相互连通的第一柱体,收缩椎体、扩张椎体、第二柱体组成,收缩椎体与扩张椎体之间形成喉口,在第一柱体上设有进水管,第一柱体的顶部有进药口和观察取样口,第二柱体下部设有出水口,主要用于混凝过程;其中:A vortex mixing reactor is characterized in that it is composed of a first cylinder connected to each other, a contraction cone, an expansion cone, and a second cylinder, and a throat is formed between the contraction cone and the expansion cone. There is a water inlet pipe on the first column, the top of the first column has a drug inlet and an observation and sampling port, and the lower part of the second column is provided with a water outlet, which is mainly used for the coagulation process; where:
第一柱体、收缩椎体、扩张椎体、第二柱体的高度尺寸比例为3:5:1:10,第一柱体、喉口、第二柱体的直径比例为15:1:5,收缩锥体的角度为46.97°,扩张椎体的角度为30.96°。The height-dimension ratio of the first cylinder, shrinking vertebral body, expanding vertebral body, and second cylinder is 3:5:1:10, and the diameter ratio of the first cylinder, throat, and second cylinder is 15:1: 5. The angle of contraction cone is 46.97°, and the angle of expansion cone is 30.96°.
本发明的另一种技术解决方案是:Another technical solution of the present invention is:
一种涡流式混合沉淀一体式反应器,其特征在于,由相互连通的第一柱体,收缩椎体、扩张椎体、第二柱体、导流板和沉淀区组成,收缩椎体与扩张椎体之间形成喉口,在第一柱体上设有进水管,第一柱体的顶部有进药口和观察取样口,第二柱体经由导流板连接沉淀区,相比较上述的涡流式混合反应器,其特点主要是混合区后加了沉淀区,主要用于混凝沉淀过程;其中:A vortex-type mixed-sedimentation integrated reactor, characterized in that it is composed of a first column connected to each other, a contraction cone, an expansion cone, a second column, a deflector and a settling area, and the contraction cone and the expansion A throat is formed between the vertebral bodies, and a water inlet pipe is provided on the first column. The top of the first column has a drug inlet and an observation and sampling port. The second column is connected to the sedimentation area through a deflector. Compared with the above-mentioned The vortex mixing reactor is mainly characterized by the addition of a sedimentation zone after the mixing zone, and is mainly used for the coagulation and sedimentation process; among them:
第一柱体、收缩椎体、扩张椎体、第二柱体的高度尺寸比例为3:5:1:10,第一柱体、喉口、第二柱体的直径比例为15:1:5,收缩锥体的角度为46.97°,扩张椎体的角度为30.96°;The height-dimension ratio of the first cylinder, shrinking vertebral body, expanding vertebral body, and second cylinder is 3:5:1:10, and the diameter ratio of the first cylinder, throat, and second cylinder is 15:1: 5. The angle of contraction cone is 46.97°, and the angle of expansion cone is 30.96°;
在沉淀区上有环形集水槽、在环形集水槽下方有出水管,在沉淀区的下方有泥斗和排泥管。An annular sump is arranged on the settling area, an outlet pipe is arranged under the annular sump, and a mud bucket and a mud discharge pipe are arranged below the settling area.
本发明的涡流式混合沉淀一体式反应器,可用于所有涉及液体与药剂、液体与液体混合或混合分离的化工和其他领域。与国内外现有技术相比,具有以下优点:The integrated vortex mixing and sedimentation reactor of the present invention can be used in all chemical and other fields involving the mixing or mixing and separation of liquids and medicaments, liquids and liquids. Compared with the existing technology at home and abroad, it has the following advantages:
1、构造简单。该反应器涡流式混合沉淀一体式分为两部分:涡流混合区和沉淀区,采用水力混合方式,不采用机械搅拌。1. The structure is simple. The integrated vortex mixing and sedimentation reactor is divided into two parts: the vortex mixing area and the sedimentation area, which adopts hydraulic mixing mode and does not use mechanical stirring.
2、混合区产生回流。水流由第一柱体中切向进水,形成旋涡流动,边旋转边向下流动。当水流到喉部,由于截面急剧缩小,水流以很大的竖直向下速度流入扩张段,扩张段由于截面突然变大,受水纵向射流的卷吸,喉部以下局部流动十分复杂,形成了极强的涡流和紊流区,速度梯度大,近壁处出现较大的回流区。2. Backflow occurs in the mixing zone. The water flow enters water tangentially from the first cylinder, forming a vortex flow, and flows downward while rotating. When the water flows to the throat, due to the sharp reduction of the cross-section, the water flows into the expansion section at a large vertical downward speed. Due to the sudden increase in the cross-section, the expansion section is entrained by the water longitudinal jet, and the local flow below the throat is very complicated, forming A very strong eddy current and turbulent flow zone are formed, the velocity gradient is large, and a large recirculation zone appears near the wall.
3、混合区出水速度小,混合时间较常规絮凝池短。由混合区进入沉淀区时,水流速度极小,满足沉淀池进水所要求的速度。水流能在涡流的作用下,与药物充分混合,减少了混合时间。3. The water outlet speed in the mixing zone is small, and the mixing time is shorter than that of conventional flocculation tanks. When entering the sedimentation area from the mixing area, the water flow velocity is extremely small, which meets the speed required by the sedimentation tank. The water flow can be fully mixed with the medicine under the action of the vortex, which reduces the mixing time.
4、混凝效果好、药物用量减少。该涡流式混合沉淀一体式反应器利用涡流原理,将药物与水充分混合,药物随着水流在涡流混合区充分接触絮凝,减少了药物的投加量,节约了药剂费用。4. The coagulation effect is good and the dosage of medicine is reduced. The vortex-type mixed-sedimentation integrated reactor uses the principle of vortex to fully mix the drug with water, and the drug is fully contacted and flocculated in the vortex mixing area with the water flow, which reduces the dosage of the drug and saves the cost of the drug.
5、虹吸管进水。涡流式混合沉淀一体式反应器前接高位水箱,采用虹吸管的方式控制进水,虹吸管的喇叭口设置在高位水箱的最低水位处,当水位高过最低水位时,虹吸管开始吸水;当水位低于最低水位时,虹吸被破坏,则停止供水。采用虹吸管输送流体无需任何外加动力,虹吸管与高位水箱的组合可适度调节水量和进水流速,是的该反应器既可连续式运行,亦可间歇式运行。5. Water enters the siphon. The vortex-type mixed-sedimentation integrated reactor is connected to the high-level water tank in front, and the water intake is controlled by a siphon. The bell mouth of the siphon is set at the lowest water level of the high-level water tank. At the lowest water level, the siphon is destroyed and the water supply is stopped. The use of siphon to transport fluid does not require any external power. The combination of siphon and high-level water tank can moderately adjust the water volume and water flow rate. Yes, the reactor can be operated continuously or intermittently.
6、该涡流式混合沉淀一体式反应器可应用于不同场合。在具备沉淀池的地方,可单独使用涡流式混合反应器作为加药混凝池;在对水质要求不高的场合,可采用该涡流式混合沉淀一体式反应器直接处理污水或者废水等。6. The vortex-type mixed-sedimentation integrated reactor can be applied to different occasions. Where there is a sedimentation tank, the vortex mixing reactor can be used alone as a dosing coagulation tank; where the water quality is not high, the vortex mixing and sedimentation integrated reactor can be used to directly treat sewage or waste water.
7、易管理维护、运行费极低。没有了机械搅拌设备,不仅节约了设备维修费用,减少了维护管理的困难,还节约了能源的消耗。该设备投资造价小,市场推广应用前景广阔。7. It is easy to manage and maintain, and the operation cost is extremely low. There is no mechanical stirring equipment, which not only saves equipment maintenance costs, reduces maintenance and management difficulties, but also saves energy consumption. The investment cost of the equipment is small, and the market popularization and application prospect is broad.
附图说明Description of drawings
图1是本发明的涡流式混合反应器的结构示意图。Fig. 1 is a schematic structural view of the vortex mixing reactor of the present invention.
图中的标记分别表示:1、进水管,2、第一柱体,3、收缩椎体,4、扩张椎体,5、第二柱体,6、出水口,11、进药管,12、观察取样口。The marks in the figure represent respectively: 1. water inlet pipe, 2. first cylinder, 3. contraction vertebral body, 4. expansion vertebral body, 5. second cylinder body, 6. water outlet, 11. drug inlet pipe, 12 , Observe the sampling port.
图2是本发明的涡流式混合沉淀一体式反应器整体结构示意图。其中,混合液通过图1的涡流式混合反应器的出水口后,通过涡流式混合反应器外壁的圆孔,经过导流板进入沉淀区。Fig. 2 is a schematic diagram of the overall structure of the vortex-type mixed-sedimentation integrated reactor of the present invention. Wherein, after the mixed liquid passes through the water outlet of the vortex mixing reactor in Fig. 1, it passes through the circular hole on the outer wall of the vortex mixing reactor, and enters the precipitation area through the deflector.
图3是图2的俯视图。FIG. 3 is a top view of FIG. 2 .
图中的标记分别表示:1、进水管,2、第一柱体,3、收缩椎体,4、扩张椎体,5、第二柱体,6′、圆孔,7、泥斗,8、沉淀区,9、环形集水槽,10、出水管,11、进药管,12、观察取样口,13、排泥管,14、导流板。The marks in the figure represent respectively: 1, water inlet pipe, 2, first cylinder, 3, shrinking vertebral body, 4, expanding vertebral body, 5, second cylinder, 6', round hole, 7, mud bucket, 8 . Sedimentation area, 9. Annular sump, 10. Outlet pipe, 11. Drug inlet pipe, 12. Observation and sampling port, 13. Mud discharge pipe, 14. Baffle plate.
图4是实施例1中经FLUENT模拟的12.3L涡流式混合沉淀一体式反应器中药物随时间的轨迹图。该图中的药物与水流的轨迹一致,即喉口下端所产生的部分回流区域既使药物和水流停留时间延长,增加了药物和水流的混合时间,也强化了涡流与紊流混合作用,提高了混合效果。Fig. 4 is a trace diagram of the drug in the 12.3L vortex mixed-sedimentation integrated reactor simulated by FLUENT in Example 1 over time. The trajectory of the drug and the water flow in this figure is consistent, that is, the partial backflow area generated at the lower end of the throat not only prolongs the residence time of the drug and the water flow, increases the mixing time of the drug and the water flow, but also strengthens the mixing effect of vortex and turbulent flow, improving mixed effect.
图5是实施例1中经FLUENT模拟的12.3L涡流式混合沉淀一体式反应器的压力云图。该图中喉口下端产生负压区,使得该区域的水会产生近壁回流。Fig. 5 is a pressure cloud diagram of the 12.3L vortex mixed-sedimentation integrated reactor simulated by FLUENT in Example 1. In this figure, a negative pressure area is generated at the lower end of the throat, so that the water in this area will generate near-wall backflow.
图6是实施例1中经FLUENT模拟的12.3L涡流式混合沉淀一体式反应器中水的速度矢量图。该图主要表述了水流的运动轨迹。Fig. 6 is the velocity vector diagram of water in the 12.3L vortex mixed-sedimentation integrated reactor simulated by FLUENT in Example 1. This figure mainly expresses the trajectory of water flow.
图7是实施例1中经FLUENT模拟的12.3L涡流式混合沉淀一体式反应器出口处的湍动耗散率图。由λ0=(υ3/ε)1/4可知,当λ0越接近颗粒直径,则说明颗粒间的相互碰撞越强烈。其中υ指的是流体的运动粘度,ε是指湍动耗散率。Fig. 7 is a diagram of the turbulent dissipation rate at the outlet of the 12.3L vortex mixed-sedimentation integrated reactor simulated by FLUENT in Example 1. It can be seen from λ 0 =(υ 3 /ε) 1/4 that when λ 0 is closer to the particle diameter, it means that the collision between particles is stronger. where υ refers to the kinematic viscosity of the fluid and ε refers to the turbulent dissipation rate.
图8是实施例2中经FLUENT模拟的12.3m3涡流式混合沉淀一体式反应器中药物随时间的轨迹图。该图中的药物与水流的轨迹一致,即喉口下端所产生的部分回流区域既使药物和水流停留时间延长,增加了药物和水流的混合时间,也强化了涡流与紊流混合作用,提高了混合效果。Fig. 8 is a trace diagram of the drug in the 12.3m 3 vortex mixed-sedimentation integrated reactor simulated by FLUENT in Example 2 with time. The trajectory of the drug and the water flow in this figure is consistent, that is, the partial backflow area generated at the lower end of the throat not only prolongs the residence time of the drug and the water flow, increases the mixing time of the drug and the water flow, but also strengthens the mixing effect of vortex and turbulent flow, improving mixed effect.
图9是实施例2中经FLUENT模拟的12.3m3涡流式混合沉淀一体式反应器的压力云图。该图中喉口下端产生负压区,使得该区域的水会产生近壁回流。Fig. 9 is the pressure contour of the 12.3m 3 vortex-type mixed-sedimentation integrated reactor simulated by FLUENT in Example 2. In this figure, a negative pressure area is generated at the lower end of the throat, so that the water in this area will generate near-wall backflow.
图10是实施例2中经FLUENT模拟的12.3m3涡流式混合沉淀一体式反应器中水的速度矢量图。该图主要表述了水流的运动轨迹。Fig. 10 is the velocity vector diagram of water in the 12.3m 3 vortex mixed-sedimentation integrated reactor simulated by FLUENT in Example 2. This figure mainly expresses the trajectory of water flow.
图11是实施例2中经FLUENT模拟的12.3m3涡流式混合沉淀一体式反应器出口处的湍动耗散率图。由λ0=(υ3/ε)1/4可知,当λ0越接近颗粒直径,则说明颗粒间的相互碰撞越强烈。其中υ指的是流体的运动粘度,ε是指湍动耗散率。Fig. 11 is a diagram of the turbulent dissipation rate at the outlet of the 12.3m 3 vortex mixed-sedimentation integrated reactor simulated by FLUENT in Example 2. It can be seen from λ 0 =(υ 3 /ε) 1/4 that when λ 0 is closer to the particle diameter, it means that the collision between particles is stronger. where υ refers to the kinematic viscosity of the fluid and ε refers to the turbulent dissipation rate.
下面结合附图及实施例对本发明做进一步详细说明。The present invention will be described in further detail below in conjunction with the accompanying drawings and embodiments.
具体实施方式Detailed ways
按照本发明的技术方案,一种涡流式混合反应器,主要由相互连通的第一柱体2、收缩锥体3、扩张椎体4、第二柱体5四部分组成,收缩椎体3与扩张椎体4之间形成喉口;在第一柱体5上设有进水管1,第一柱体5的顶部有进药口11和观察取样口12;According to the technical scheme of the present invention, a vortex type mixing reactor is mainly composed of four parts: the first cylinder 2, the contraction cone 3, the expansion cone 4, and the second cylinder 5, which are connected to each other. The contraction cone 3 and A throat is formed between the expanded vertebral bodies 4; a water inlet pipe 1 is provided on the first cylinder 5, and the top of the first cylinder 5 has a drug inlet 11 and an observation sampling port 12;
或者在第二柱体5之后经过导流板后进入沉淀池8;其中的第一柱体2、收缩锥体3、扩张椎体4、第二柱体5和喉口各部分的比例参数由FLUENT软件模拟确定,分别通过药物轨迹图、压力云图、湍流强度云图、湍流能耗云图来确定最佳比例,最佳比例的模拟图为:在扩张椎体4部分药物轨迹图中有回流状态;压力云图处有负压区;出口处的湍流强度和湍流能耗最大。Or enter the settling tank 8 after the second cylinder 5 through the deflector; the proportion parameters of the first cylinder 2, the contraction cone 3, the expansion cone 4, the second cylinder 5 and the throat are determined by The FLUENT software simulates and determines the optimal ratio through the drug trajectory diagram, pressure cloud diagram, turbulent intensity cloud diagram, and turbulent energy consumption cloud diagram respectively. The optimal ratio simulation diagram is: there is a reflux state in the drug trajectory diagram of the four parts of the expanded vertebral body; There is a negative pressure area in the pressure cloud map; the turbulence intensity and turbulent energy consumption at the outlet are the largest.
在进行FLUENT模拟之后,根据这三个评价指标进行确定最佳比例,得到了第一柱体2、收缩锥体3、扩张椎体4、第二柱体5的高度最佳比例为3:5:1:10;第一柱体2、喉口、第二柱体5的直径比例为15:1:5;此时收缩锥体3角度为46.97°,扩张椎体4的角度为30.96°;该涡流式混合反应器的规模可随处理水量的不同按照比例进行缩放;进药口11的尺寸经模拟后发现混合效果与进药口11尺寸大小无关,因此采用常用规格的进药口尺寸即可;进水口1的大小应根据不同体积的涡流式混合沉淀一体式反应器模拟结果确定,当涡流式混合反应器的为41.5m3时,进水口1的直径不宜大于300mm。After the FLUENT simulation, the optimal ratio is determined according to these three evaluation indicators, and the optimal ratio of the height of the first cylinder 2, contraction cone 3, expansion cone 4, and second cylinder 5 is 3:5 : 1:10; the diameter ratio of the first cylinder 2, the throat, and the second cylinder 5 is 15:1:5; at this time, the angle of the contracted cone 3 is 46.97°, and the angle of the expanded vertebral body 4 is 30.96°; The scale of the vortex mixing reactor can be scaled proportionally with the amount of treated water; the size of the drug inlet 11 has been simulated and found that the mixing effect has nothing to do with the size of the drug inlet 11, so the commonly used size of the drug inlet is Yes; the size of water inlet 1 should be determined according to the simulation results of vortex mixing and sedimentation integrated reactors of different volumes. When the vortex mixing reactor is 41.5m 3 , the diameter of water inlet 1 should not be greater than 300mm.
沉淀区8采用辐流式沉淀池形式,中心进水周边出水,底部以排泥管的形式进行排泥。该涡流式混合沉淀一体式反应器的反应区进水采用切向进水方式,出水采用环形集水槽出水。The sedimentation zone 8 is in the form of a radial flow sedimentation tank, with water in the center and outlet around the periphery, and mud discharge in the form of a mud discharge pipe at the bottom. The vortex mixed-sedimentation integrated reactor adopts a tangential water inlet method for the water inlet of the reaction zone, and adopts an annular water collection tank for water outlet.
以下是发明人给出的实施例。The following are examples given by the inventors.
实施例1:Example 1:
参照例图1,本实施例给出一种涡流式混合反应器的混合区的具体结构,由第一柱体2,收缩椎体3、扩张椎体4、第二柱体5组成,在第一柱体2上设有进水管1,第一柱体2的顶部有进药口11和观察取样口12,第二柱体5下部设有出水口6。Referring to Fig. 1 of the example, the present embodiment provides a specific structure of the mixing zone of a vortex mixing reactor, which consists of a first cylinder 2, a contraction cone 3, an expansion cone 4, and a second cylinder 5. One cylinder 2 is provided with a water inlet pipe 1 , the top of the first cylinder 2 has a drug inlet 11 and an observation sampling port 12 , and the lower part of the second cylinder 5 is provided with a water outlet 6 .
该涡流式混合反应器的体积为12.3L,采用有机玻璃制作,主要用于小量处理实验室酸性废水,投加的药剂为氢氧化镁。模拟结果参照图4、图5、图6、图7,主要是该涡流式混合反应器内部流场的模拟结果,该涡流式混合反应器各部分尺寸如下:The vortex mixing reactor has a volume of 12.3L and is made of plexiglass. It is mainly used to treat a small amount of acid wastewater in the laboratory, and the dosed agent is magnesium hydroxide. The simulation results refer to Figure 4, Figure 5, Figure 6, and Figure 7, which are mainly the simulation results of the internal flow field of the vortex mixing reactor. The dimensions of each part of the vortex mixing reactor are as follows:
1)第一柱体2的直径为0.3m,高度为0.09m;1) The diameter of the first cylinder 2 is 0.3m and the height is 0.09m;
2)收缩椎体3的上直径为0.3m,下直径为0.02m,高度为0.15m;2) The upper diameter of the contracted vertebral body 3 is 0.3m, the lower diameter is 0.02m, and the height is 0.15m;
3)扩张椎体4的上直径为0.02m,下直径为0.1m,高度为0.03m;3) The upper diameter of the expanded vertebral body 4 is 0.02m, the lower diameter is 0.1m, and the height is 0.03m;
4)第二柱体5的直径为0.1m,高度为0.3m;4) The diameter of the second cylinder 5 is 0.1m and the height is 0.3m;
5)涡流式混合反应器的总高度为0.57m。5) The total height of the vortex mixing reactor is 0.57m.
运行方式为连续运行。采用本实施例制作的涡流式混合反应器,对实验室酸性废水进行处理方法步骤如下:The mode of operation is continuous operation. Using the vortex mixing reactor made in this embodiment, the steps of the treatment method for laboratory acid wastewater are as follows:
1、根据例图1所示的涡流式混合反应器混合区,进水管1前连接一个高位水箱,用于储存实验室所用的实验酸性废水。酸性废水由进水管1切向进入涡流式混合反应器,在第一柱体2内边旋转边向下流动,产生巨大的涡流,此时氢氧化镁同时从进药口11射入酸性废水体中心,受到了涡流的卷吸,随水流一起运动,二者一起由收缩椎体3进入扩张椎体4时,经过收缩椎体3和扩张椎体4构成的喉口部分,由于流体突然进入截面较小部分,因此产生了很大的速度向下流动,当进入扩张椎体4时,由于由于截面又突然变大,受流体纵向射流的卷吸,速度梯度大,在扩张椎体4和第二柱体5的近壁处出现较大的回流区,该处产生了负压,此时氢氧化镁与酸性废水会在这个区域内进行多次的回流运动,进行中和反应,然后流体平稳的从出水口6流出了反应器。1. According to the mixing zone of the vortex mixing reactor shown in Figure 1, a high-level water tank is connected in front of the water inlet pipe 1 to store the experimental acid wastewater used in the laboratory. The acidic wastewater enters the vortex mixing reactor tangentially from the water inlet pipe 1, and flows downward while rotating in the first column 2, generating a huge vortex. At this time, magnesium hydroxide is injected into the acidic wastewater body from the drug inlet 11 at the same time. The center is entrained by the eddy current and moves together with the water flow. When the two enter the expanded vertebral body 4 from the contracted vertebral body 3 together, they pass through the throat part formed by the contracted vertebral body 3 and the expanded vertebral body 4. Because the fluid suddenly enters the section The smaller part thus produces a great velocity downward flow. When entering the expanded vertebral body 4, due to the sudden enlargement of the cross-section, the velocity gradient is large due to the entrainment of the fluid longitudinal jet, between the expanded vertebral body 4 and the second There is a large reflux area near the wall of the second column 5, where negative pressure is generated. At this time, magnesium hydroxide and acidic wastewater will perform multiple reflux movements in this area to carry out neutralization reactions, and then the fluid is stable. The water flows out of the reactor from the water outlet 6.
2、进水管1设在第一柱体2顶端,切向进水,进水管1的直径为25mm,采用蠕动泵控制进水水速,根据流量和扬程,选择泵型号为WT600S,流量为1.8mL/min~2300mL/min,接直径为25mm的胶管,因此采用泵头为YZ1×4,将4根软管并联之后,连接直径为25mm的管道进入涡流式混合沉淀一体式反应器。进水流速设定为0.2m/s,设定进入该反应器中的污水的密度与20℃时水的一致。12.3L涡流式混合反应器的理论水力停留时间根据涡流式混合反应器容积与进水量可算得是125s,而例图4显示该涡流式混合反应器的水力停留时间达到了380s左右,因此延长了碱剂和酸性废水的水力停留时间,也加强了其混合的效果。2. The water inlet pipe 1 is set at the top of the first cylinder 2, tangentially enters the water, the diameter of the water inlet pipe 1 is 25mm, and the water inlet speed is controlled by a peristaltic pump. According to the flow rate and head, the pump model is WT600S, and the flow rate is 1.8 mL/min~2300mL/min, connected to a hose with a diameter of 25mm, so the pump head is YZ1×4. After connecting the 4 hoses in parallel, connect the pipe with a diameter of 25mm to enter the vortex-type mixed-sedimentation integrated reactor. The flow rate of the influent water is set to 0.2m/s, and the density of the sewage entering the reactor is set to be consistent with that of water at 20°C. The theoretical hydraulic retention time of the 12.3L vortex mixing reactor can be calculated as 125s according to the volume of the vortex mixing reactor and the water inflow. However, Figure 4 shows that the hydraulic retention time of the vortex mixing reactor has reached about 380s, so it is extended The hydraulic retention time of alkaline agent and acid wastewater also enhances the mixing effect.
3、进药口11设在第一柱体2顶部中心处,进药口11的直径为25mm,加药方式为固体投加,投加的药物为氢氧化镁,氢氧化镁的颗粒直径为2×10-5m。加药速度为3.4×10-03g/s,采用蠕动泵BJ100-2J控制加药速度,泵流量为0.002~380mL/min。3. The drug inlet 11 is located at the center of the top of the first column body 2. The diameter of the drug inlet 11 is 25 mm. The method of dosing is solid dosing. The drug to be added is magnesium hydroxide, and the particle diameter of magnesium hydroxide is 2×10-5m. The dosing speed is 3.4×10 -03 g/s, and the dosing speed is controlled by a peristaltic pump BJ100-2J, and the pump flow rate is 0.002-380mL/min.
4、根据公式λ0=(υ3/ε)1/4计算所得的涡旋尺度λ0与颗粒直径相近或略大于时,反应混合效果最好。水的运动粘度υ=1.0×10-6m2·s-1,根据例图7可知ε值主要集中在ε=1.6×10-2m2·s-1范围内,故,λ0=9×10-5m,接近药物的颗粒直径2×10-5m,表明颗粒之间的碰撞很强烈,也证明该涡流式混合沉淀一体式反应器混合效率高。4. When the vortex scale λ 0 calculated according to the formula λ 0 =(υ 3 /ε) 1/4 is close to or slightly larger than the particle diameter, the reaction mixing effect is the best. The kinematic viscosity of water υ=1.0×10 -6 m 2 ·s -1 , according to the example in Figure 7, we can see that the value of ε is mainly concentrated in the range of ε=1.6×10 -2 m 2 ·s -1 , so, λ 0 =9 ×10 -5 m, the diameter of particles close to the drug is 2×10 -5 m, which shows that the collision between particles is very strong, and also proves that the mixing efficiency of the vortex mixing and sedimentation integrated reactor is high.
5、由图4、5、6可以看出,该涡流式混合反应器内部产生了极大的涡旋状态区,由图7又可知涡旋尺度接近颗粒的直径时,混凝效果最佳。因此可以判断该涡流式混合沉淀一体式反应器出水已经充分混合。5. It can be seen from Figures 4, 5, and 6 that a huge vortex state area is generated inside the vortex mixing reactor. It can also be seen from Figure 7 that when the vortex scale is close to the diameter of the particle, the coagulation effect is the best. Therefore, it can be judged that the effluent from the integrated vortex mixing and sedimentation reactor has been fully mixed.
6、所选药物的密度大小对模拟的反应结果无影响。因为所处理的实验室酸性废水均为已经稀释过的废水,因此密度与水差异不大,对反应结果也没有影响。由于氢氧化镁与酸反应无沉淀产生,因此无需沉淀分离,中和后可直接排入城市下水道管网。6. The density of the selected drug has no effect on the simulated reaction results. Because the laboratory acid wastewater to be treated is all diluted wastewater, there is little difference between the density and water, and there is no influence on the reaction result. Since magnesium hydroxide reacts with acid without precipitation, there is no need for precipitation separation, and it can be directly discharged into the urban sewer network after neutralization.
7、出水口(6)处连接2个45°弯头,用于接入市政管网或者下一级处理设置之中。在本实施例中,2个45°弯头用于检测水质和流速,弯头接到实验室的出水箱中。7. Two 45° elbows are connected to the water outlet (6), which are used to connect to the municipal pipe network or the next level of treatment settings. In this embodiment, two 45° elbows are used to detect water quality and flow rate, and the elbows are connected to the water outlet tank of the laboratory.
8、运行方式可连续、亦可间歇运行。8. The operation mode can be continuous or intermittent.
实施例2:Example 2:
参照例图2,本实施例给出一种涡流式混合沉淀一体式反应器具体结构,由实施例1的混合区和沉淀区8组成,所不同的是实施例1的涡流式混合沉淀一体式反应器混合区部分中的第二柱体5通过导流板连接沉淀区8形成一体式结构,在沉淀区8上有环形集水槽9、在环形集水槽9下方有出水管10,在沉淀区8的下方有泥斗7和排泥管13。Referring to Figure 2 of the example, this embodiment provides a specific structure of a vortex-type mixed-sedimentation integrated reactor, which is composed of the mixing zone and the sedimentation zone 8 in Example 1. The difference is that the vortex-type mixed-sedimentation integrated reactor in Example 1 The second cylinder 5 in the mixing zone of the reactor is connected to the sedimentation zone 8 through a deflector to form an integrated structure. There is an annular sump 9 on the sedimentation area 8 and an outlet pipe 10 below the annular sump 9. In the sedimentation area The bottom of 8 has mud bucket 7 and mud discharge pipe 13.
本实施例中,实施例1的涡流式混合沉淀一体式反应器的反应设计时间为20分钟,沉淀区8反应设计时间为1.8小时。In this example, the designed reaction time of the integrated vortex mixing and sedimentation reactor in Example 1 is 20 minutes, and the designed reaction time of the precipitation zone 8 is 1.8 hours.
本实施例中的涡流式混合沉淀一体式反应器的体积为12.3m3,主要用于代替饮用水处理或者污水再生回用时混凝沉淀的机械搅拌澄清池。该涡流式混合沉淀一体式反应器采用钢板结构或者钢筋混凝土结构,在涡流式混合沉淀一体式反应器前设高位水箱,水箱出水采用虹吸管出水。加药方式为固体投加或液体投加,投加的药物为聚合氯化铝(PAC)。模拟结果参照例图8、例图9、例图10、例图11,例图主要是反应器混合区流场的模拟结果。The vortex mixed-sedimentation integrated reactor in this embodiment has a volume of 12.3m 3 and is mainly used to replace the mechanical agitation clarifier for coagulation and sedimentation in drinking water treatment or sewage recycling. The vortex-type mixed-sedimentation integrated reactor adopts a steel plate structure or a reinforced concrete structure, and a high-level water tank is installed in front of the vortex-type mixed-sedimentation integrated reactor, and the water outlet of the water tank adopts a siphon to discharge water. The dosing method is solid dosing or liquid dosing, and the dosing medicine is polyaluminum chloride (PAC). For the simulation results, refer to Figure 8, Figure 9, Figure 10, and Figure 11. The examples are mainly the simulation results of the flow field in the mixing zone of the reactor.
本实施例的涡流式混合沉淀一体式反应器各部分尺寸如下:The dimensions of the various parts of the vortex-type mixed-sedimentation integrated reactor of the present embodiment are as follows:
1)第一柱体2的直径为3m,高度为0.9m;1) The diameter of the first cylinder 2 is 3m and the height is 0.9m;
2)收缩椎体3的上直径为3m,下直径为0.2m,高度为1.5m;2) The upper diameter of the contracted vertebral body 3 is 3m, the lower diameter is 0.2m, and the height is 1.5m;
3)扩张椎体4的上直径为0.2m,下直径为1m,高度为0.3m;3) The upper diameter of the expanded vertebral body 4 is 0.2m, the lower diameter is 1m, and the height is 0.3m;
4)第二柱体5直径为1m,高度为3m;混合区总高度为5.7m。4) The diameter of the second cylinder 5 is 1m, and the height is 3m; the total height of the mixing zone is 5.7m.
沉淀区尺寸为:The size of the sedimentation zone is:
1)沉淀区8的总直径为6m,池边高为2.5m,保护高度为0.3m,沉淀区水面低于混合反应器内水面0.2m;1) The total diameter of the sedimentation zone 8 is 6m, the pool side height is 2.5m, the protection height is 0.3m, and the water surface in the sedimentation zone is 0.2m lower than the water surface in the mixing reactor;
2)泥斗7的上直径为2.5m,下直径为0.2m,高度为2m;2) The upper diameter of the mud bucket 7 is 2.5m, the lower diameter is 0.2m, and the height is 2m;
3)环形集水槽9的高度为0.72m;3) The height of the annular sump 9 is 0.72m;
4)排泥管10的直径为100mm;4) The diameter of the mud discharge pipe 10 is 100mm;
5)导流板14距离反应器外壁0.5m,圆孔6′直径为0.5m。5) The guide plate 14 is 0.5m away from the outer wall of the reactor, and the diameter of the circular hole 6' is 0.5m.
6)沉淀区总高为5.5m。6) The total height of the sedimentation zone is 5.5m.
运行方式为间歇运行。采用本实施例制作的涡流式混合沉淀一体式反应器,对污水处理方法步骤如下:The mode of operation is intermittent operation. Using the vortex-type mixed-sedimentation integrated reactor made in this embodiment, the steps of the sewage treatment method are as follows:
1、根据图1所示的涡流式混合沉淀一体式反应器,水流由进水管1切向进入涡流式混合沉淀一体式反应器,在第一柱体2内边旋转边向下流动,产生巨大的涡流,此时药物同时从进药口11射入水体中心,受到了涡流的卷吸,随水流一起运动,二者一起由收缩椎体3进入扩张椎体4时,经过喉口部分,由于流体突然进入截面较小部分,因此产生了很大的速度向下流动,进入扩张椎体4时,由于由于截面突然变大,受流体纵向射流的卷吸,速度梯度大,在扩张椎体4和第二柱体5的近壁处出现较大的回流区,该处产生了负压,此时药物与水会在这个区域内进行多次的回流运动,然后流体平稳的从混合区的出水口经由圆孔6′进入导流区,经导流板14进入沉淀区8进行沉淀,在沉淀区8的设计沉淀时间为1.8h,经过充分沉淀后的水,进入环形集水槽9中,然后经由出水管10进入下一处理设施中。根据图10可知,进入沉淀区8时,混合区水流速度极低,满足进入沉淀池的设计流速,因此沉淀分离效果好。1. According to the vortex-type mixed-sedimentation integrated reactor shown in Figure 1, the water flow enters the vortex-type mixed-sedimentation integrated reactor tangentially from the water inlet pipe 1, and flows downward while rotating in the first column 2, resulting in huge At this time, the medicine is injected into the center of the water body from the drug inlet 11 at the same time, and is entrained by the eddy current, and moves together with the water flow. The fluid suddenly enters the smaller part of the cross section, so it flows downward at a great speed. When it enters the expanded vertebral body 4, due to the sudden enlargement of the cross section, it is entrained by the longitudinal jet of the fluid, and the velocity gradient is large. And the near wall of the second cylinder 5 has a larger recirculation zone, where a negative pressure is generated. At this time, the medicine and water will perform multiple reflux movements in this zone, and then the fluid will smoothly exit the mixing zone. The water inlet enters the diversion area through the round hole 6', and enters the sedimentation area 8 through the deflector 14 for sedimentation. The design sedimentation time in the sedimentation area 8 is 1.8h. After sufficient precipitation, the water enters the annular sump 9, and then Enter the next treatment facility through the water outlet pipe 10. According to Figure 10, it can be seen that when entering the sedimentation zone 8, the water flow velocity in the mixing zone is extremely low, which meets the design flow velocity entering the sedimentation tank, so the sedimentation and separation effect is good.
2、进水管1设在第一柱体2顶端,连接前面的高位水箱的虹吸管,切向进水,进水管1大小为100mm,进水速度为1.5m/s。采用潜污泵控制流量,泵采用QW潜污泵,型号为QW100-100-30-15,扬程为30m,流量为100m3/h。设定进入该涡流式混合沉淀一体式反应器中的污水的密度与20℃时水的一致。该12.3m3的涡流式混合沉淀一体式反应器的理论水力停留时间,根据其容积与进水量之比计算得到为1044s,而图8显示该涡流式混合沉淀一体式反应器的水力停留时间为1400s,因此延长了絮凝剂和废水的水力停留时间,也加强了其混合的效果。2. The water inlet pipe 1 is arranged at the top of the first cylinder 2, connected to the siphon pipe of the high water tank in front, tangentially enters the water, the size of the water inlet pipe 1 is 100mm, and the water inlet speed is 1.5m/s. The flow is controlled by a submersible sewage pump. The pump adopts a QW submersible sewage pump, the model is QW100-100-30-15, the lift is 30m, and the flow rate is 100m 3 /h. The density of the sewage entering the integrated vortex mixing and sedimentation reactor is set to be consistent with that of water at 20°C. The theoretical hydraulic retention time of the 12.3m 3 vortex-type mixed-sedimentation integrated reactor is calculated as 1044s according to the ratio of its volume to the influent, and Figure 8 shows that the hydraulic retention time of the vortex-type mixed-sedimentation integrated reactor is 1400s, so the hydraulic retention time of the flocculant and wastewater is prolonged, and the mixing effect is also strengthened.
1、进药口11设在第一柱体2顶部中心处,加药口大小为25mm,聚合氯化铝颗粒直径为1×10-4m。加药速度为0.42g/s,可采用JY型自动投药装置进行药物投加。1. The drug inlet 11 is located at the center of the top of the first cylinder 2, the size of the drug feeding port is 25 mm, and the diameter of the polyaluminum chloride particles is 1×10 -4 m. The dosing speed is 0.42g/s, and the JY automatic dosing device can be used for dosing.
2、根据公式λ0=(υ3/ε)1/4可计算涡旋尺度λ0与颗粒直径相近或略大于时,反应混合效果是最好的,水的运动粘度υ=1.0×10-6m2·s-1,根据例图11可知ε值主要集中在ε=5×10-4m2·s-1,根据公式计算得到涡旋尺度λ0=2×10-4m,与聚合氯化铝的颗粒直径1×10-4m接近,因此说明颗粒之间的碰撞强烈,絮凝效果好,证明该涡流式混合沉淀一体式反应器的混合效率好。2. According to the formula λ 0 = (υ 3 /ε) 1/4 , the vortex scale λ 0 is close to or slightly larger than the particle diameter, the reaction mixing effect is the best, and the kinematic viscosity of water υ = 1.0×10 - 6 m 2 ·s -1 , according to the example in Figure 11, it can be seen that the ε value is mainly concentrated at ε=5×10 -4 m 2 ·s -1 , and the vortex scale λ 0 =2×10 -4 m is calculated according to the formula, and The particle diameter of polyaluminum chloride is close to 1×10 -4 m, so it shows that the collision between the particles is strong and the flocculation effect is good, which proves that the mixing efficiency of the vortex mixed-sedimentation integrated reactor is good.
3、由图8,9,10可以看出,涡流式混合沉淀一体式反应器内部产生了极大的涡旋状态,由图11又可以知道涡旋尺度接近颗粒的直径,混凝效果最佳。因此可以判断该涡流式混合沉淀一体式反应器出水时的混合效率好。3. It can be seen from Figures 8, 9, and 10 that a huge vortex state is generated inside the vortex-type mixed-sedimentation integrated reactor, and it can be known from Figure 11 that the vortex scale is close to the diameter of the particle, and the coagulation effect is the best . Therefore, it can be judged that the mixing efficiency of the vortex mixing and sedimentation integrated reactor is good when the water is discharged.
4、所选药物的密度大小对模拟的反应结果无影响。因为所处理的主要是城市生活污水,因此密度与水差异不大,对反应结果也没有影响。通过该涡流式混合沉淀一体式反应器处理后水,可直接进入清水池之中。4. The density of the selected drug has no effect on the simulated reaction results. Because the treatment is mainly urban domestic sewage, there is little difference between the density and water, and there is no influence on the reaction result. The water treated by the vortex-type mixed-sedimentation integrated reactor can directly enter the clear water pool.
5、采用连续式运行。5. Adopt continuous operation.
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