CN103342980A - Preparation method for MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube - Google Patents
Preparation method for MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube Download PDFInfo
- Publication number
- CN103342980A CN103342980A CN2013102601573A CN201310260157A CN103342980A CN 103342980 A CN103342980 A CN 103342980A CN 2013102601573 A CN2013102601573 A CN 2013102601573A CN 201310260157 A CN201310260157 A CN 201310260157A CN 103342980 A CN103342980 A CN 103342980A
- Authority
- CN
- China
- Prior art keywords
- mwcnt
- pani
- preparation
- nanotube
- quality
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Carbon And Carbon Compounds (AREA)
Abstract
A preparation method for an MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube, relates to the preparation method for the multilayer wrapped nanotube and aims to solve the problems that a current carbon nanotube of a binary or ternary material system, taking the MWCNT as a main body for wrapping, is poor in microwave absorption ability and bonding force between layers. The method comprises the following steps of: 1, performing ultrasonic dispersion; 2, preparing MWCNT/Fe3O4 composite powder; 3, preparing MWCNT/Fe3O4/PANI material; 4, performing Au in-situ outer layer sediment; 5, preparing the MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube through magnetic separation. The preparation method is mainly used for preparing the MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube.
Description
Technical field
The present invention relates to a kind of preparation method of multilayer parcel nanotube.
Background technology
Carbon nanotube is a kind of open column shape carbon nanomaterial that is curled and formed by the single or multiple lift graphite flake layer, and its good physico-chemical property causes people's attention day by day, all has great application potential at a plurality of sciemtifec and technical spheres.Multi-walled carbon nano-tubes (MWCNT) can be regarded as by a plurality of Single Walled Carbon Nanotube nested, concentric and forms, distance between the tube wall is 0.34nm～0.40nm, because special structure and dielectricity, have simultaneously that quality is light, electroconductibility is adjustable, high-temperature oxidation resistance is strong and characteristics such as good stability, obtained in a lot of fields using well.Existing is that main body is wrapped up and is prepared into binary or ternary material system carbon nanotube with MWCNT, but existing is that main body is wrapped up and is prepared into the problem that there are the microwave absorption capacity difference in binary or ternary material system carbon nanotube, the application of restriction binary or ternary material system carbon nanotube with MWCNT.
Summary of the invention
The objective of the invention is to solve existing is that main body is wrapped up and is prepared into binary or there is the problem of microwave absorption capacity difference and each interlayer bonding force difference in ternary material system carbon nanotube with MWCNT, and a kind of MWCNT/Fe is provided
3O
4The preparation method of/PANI/Au multilayer parcel nanotube.
A kind of MWCNT/Fe
3O
4The preparation method of/PANI/Au multilayer parcel nanotube specifically prepares according to the following steps:
One, ultra-sonic dispersion: at first multi-walled carbon nano-tubes, ferric acetyl acetonade are added in the triglycol, carry out ultra-sonic dispersion then, obtain dispersion liquid; The mass ratio of the multi-walled carbon nano-tubes described in the step 1 and ferric acetyl acetonade is 1:(2～8); The quality of the multi-walled carbon nano-tubes described in the step 1 and the volume ratio of triglycol are 1mg:(0.1mL～1mL);
Two, preparation MWCNT/Fe
3O
4Composite granule: the dispersion liquid that under nitrogen protection step 1 is obtained heats; be that 1 ℃/min～10 ℃/min is heated to boiling with temperature rise rate; utilize magnetism separate method to separate then; separating the solid that obtains washes 2～3 times earlier; ethanol is washed 2～3 times again; be 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtain MWCNT/Fe
3O
4Composite granule;
Three, preparation MWCNT/Fe
3O
4/ PANI material: the MWCNT/Fe that elder generation obtains step 2
3O
4The composite granule ultra-sonic dispersion is in water, under agitation condition, add aniline then, be that 0.05mL/s～0.5mL/s adding concentration is the ammonium persulfate aqueous solution of 0.001g/mL～0.02g/mL with the rate of addition, utilizing concentration for the ammonium persulfate aqueous solution of 0.001g/mL～0.02g/mL the pH value of reaction system to be controlled between 5～6; Be 0～25 ℃ of constant temperature machinery stirring reaction 2h～10h in temperature then, isothermal reaction utilizes magnetism separate method to separate after finishing, and separates the solid that obtains and washes 2～3 times earlier, and ethanol is washed 2～3 times again, be 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtain MWCNT/Fe
3O
4/ PANI material; MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of water are 1mg:(0.1mL～2mL); MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of aniline are 1mg:(0.0001mL～0.001mL);
Four, the outer deposition of Au original position: the MWCNT/Fe that elder generation obtains step 3
3O
4/ PANI material ultra-sonic dispersion is in water, under agitation condition, add polyvinylpyrrolidone then, and mechanical stirring 20min～40min, be that 0.05mL/s～0.5mL/s at the uniform velocity adds the aqueous solution of chloraurate that concentration is 0.25mg/mL～4mg/mL then with the rate of addition, add aniline again, mechanical stirring 8min～12min is 0～25 ℃ of constant temperature mechanical stirring 1h～6h in temperature at last then, obtains reaction product; MWCNT/Fe described in the step 4
3O
4The mass ratio of/PANI material and polyvinylpyrrolidone is 1:(1～20); MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and concentration are that the mass ratio of hydrochloro-auric acid is 1:(0.1～2 in the aqueous solution of chloraurate of 0.25mg/mL～4mg/mL); MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and the volume ratio of aniline are 1mg:(0.005mL～0.05mL);
Five, magnetic separates: utilize magnetism separate method that the reaction product that step 4 obtains is separated, separate the solid that obtains and wash 2～3 times earlier, ethanol is washed 2～3 times again, is 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtains MWCNT/Fe
3O
4/ PANI/Au multilayer parcel nanotube.
Advantage of the present invention: the MWCNT/Fe of the present invention's preparation
3O
4/ PANI/Au multilayer parcel nanotube is the quaternary composite nano materials, and innermost layer is the multi-walled carbon nano-tubes with excellent mechanical performances, and the second layer is Fe
3O
4Magneticsubstance strengthens the interfacial polarization effect, and inferior outer field PANI is conductive polymers, improves bonding force between powder and binding agent simultaneously, and the outermost layer golden nanometer particle has third-order non-linear and plasma effect, and four kinds of materials play a role separately and intercouple; The MWCNT/Fe of the present invention's preparation
3O
4/ PANI/Au multilayer parcel nanotube absorbs about 100% hertzian wave in the minimal reflection loss of 9GHz place for-60dB(), so the MWCNT/Fe that the present invention prepares
3O
4/ PANI/Au multilayer parcel nanotube can be used for inhaling ripple, catalysis, bio-sensing, opto-electronic device and field of semiconductor materials.
Description of drawings
Fig. 1 is the MWCNT/Fe of test one preparation
3O
4The TEM figure of/PANI/Au multilayer parcel nanotube;
Fig. 2 is the MWCNT/Fe of test one preparation
3O
4The HRTEM photo of/PANI/Au multilayer parcel nanotube;
Fig. 3 is the MWCNT/Fe of test one preparation
3O
4/ PANI/Au multilayer parcel nanotube XRD figure,, among the figure ◆ expression Fe
3O
4Characteristic peak, represents the characteristic peak of MWCNT among the figure, ★ represents the characteristic peak of PANI among the figure, ▽ represents the characteristic peak of Au among the figure;
Fig. 4 is the MWCNT/Fe of test one preparation
3O
4/ PANI/Au multilayer parcel nanotube 2～18GHz microwave absorbing figure.
Embodiment
Embodiment one: present embodiment is a kind of MWCNT/Fe
3O
4The preparation method of/PANI/Au multilayer parcel nanotube specifically prepares according to the following steps:
One, ultra-sonic dispersion: at first multi-walled carbon nano-tubes, ferric acetyl acetonade are added in the triglycol, carry out ultra-sonic dispersion then, obtain dispersion liquid; The mass ratio of the multi-walled carbon nano-tubes described in the step 1 and ferric acetyl acetonade is 1:(2～8); The quality of the multi-walled carbon nano-tubes described in the step 1 and the volume ratio of triglycol are 1mg:(0.1mL～1mL);
Two, preparation MWCNT/Fe
3O
4Composite granule: the dispersion liquid that under nitrogen protection step 1 is obtained heats; be that 1 ℃/min～10 ℃/min is heated to boiling with temperature rise rate; utilize magnetism separate method to separate then; separating the solid that obtains washes 2～3 times earlier; ethanol is washed 2～3 times again; be 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtain MWCNT/Fe
3O
4Composite granule;
Three, preparation MWCNT/Fe
3O
4/ PANI material: the MWCNT/Fe that elder generation obtains step 2
3O
4The composite granule ultra-sonic dispersion is in water, under agitation condition, add aniline then, be that 0.05mL/s～0.5mL/s adding concentration is the ammonium persulfate aqueous solution of 0.001g/mL～0.02g/mL with the rate of addition, utilizing concentration for the ammonium persulfate aqueous solution of 0.001g/mL～0.02g/mL the pH value of reaction system to be controlled between 5～6; Be 0～25 ℃ of constant temperature machinery stirring reaction 2h～10h in temperature then, isothermal reaction utilizes magnetism separate method to separate after finishing, and separates the solid that obtains and washes 2～3 times earlier, and ethanol is washed 2～3 times again, be 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtain MWCNT/Fe
3O
4/ PANI material; MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of water are 1mg:(0.1mL～2mL); MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of aniline are 1mg:(0.0001mL～0.001mL);
Four, the outer deposition of Au original position: the MWCNT/Fe that elder generation obtains step 3
3O
4/ PANI material ultra-sonic dispersion is in water, under agitation condition, add polyvinylpyrrolidone then, and mechanical stirring 20min～40min, be that 0.05mL/s～0.5mL/s at the uniform velocity adds the aqueous solution of chloraurate that concentration is 0.25mg/mL～4mg/mL then with the rate of addition, add aniline again, mechanical stirring 8min～12min is 0～25 ℃ of constant temperature mechanical stirring 1h～6h in temperature at last then, obtains reaction product; MWCNT/Fe described in the step 4
3O
4The mass ratio of/PANI material and polyvinylpyrrolidone is 1:(1～20); MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and concentration are that the mass ratio of hydrochloro-auric acid is 1:(0.1～2 in the aqueous solution of chloraurate of 0.25mg/mL～4mg/mL); MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and the volume ratio of aniline are 1mg:(0.005mL～0.05mL);
Five, magnetic separates: utilize magnetism separate method that the reaction product that step 4 obtains is separated, separate the solid that obtains and wash 2～3 times earlier, ethanol is washed 2～3 times again, is 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtains MWCNT/Fe
3O
4/ PANI/Au multilayer parcel nanotube.
Golden nanometer particle has unique optics, electricity and catalysis characteristics, has wide application at numerous areas such as sensor, photoelectric device and catalysis, golden nanometer particle also can be used as absorbing material and is applied to stealthy military field with its excellent third-order non-linear and plasma effect.
Polyaniline more and more receives the concern of scientists as a kind of novel functional high molecule material.This is not only because it has advantages such as synthetic method is simple, mechanism of doping effect is unique, environmental stability is good, and it also has wide development and application prospect.At first it is a kind of high conductive material, and its density and organic polymer are suitable, has the potential intermiscibility of certain workability and other commodity polymer insulating material, thereby might prepare the conducting polymer composite of low conductivity threshold.Organic conjugate polymer has unique light, electricity, magnetic property in very wide range of frequency, make it have potential using value in a lot of occasions,
Fe
3O
4Magnetic nano-particle is as a kind of special nano material, basic material and aspects such as magnetic paint, medicine at magnetic recording material, special catalyst raw material, magnetic fluid demonstrate many specific functions, and the preparation method of relevant nano-magnetic Z 250 and the research of character also are subjected to extensive concern.
The MWCNT/Fe of present embodiment preparation
3O
4/ PANI/Au multilayer parcel nanotube is the quaternary composite nano materials, and innermost layer is the multi-walled carbon nano-tubes with excellent mechanical performances, and the second layer is Fe
3O
4Magneticsubstance strengthens the interfacial polarization effect, and inferior outer field PANI is conductive polymers, improves bonding force between powder and binding agent simultaneously, and the outermost layer golden nanometer particle has third-order non-linear and plasma effect, and four kinds of materials play a role separately and intercouple; The MWCNT/Fe of present embodiment preparation
3O
4/ PANI/Au multilayer parcel nanotube absorbs about 100% hertzian wave in the minimal reflection loss of 9GHz place for-60dB(), so the MWCNT/Fe that present embodiment prepares
3O
4/ PANI/Au multilayer parcel nanotube can be used for inhaling ripple, catalysis, bio-sensing, opto-electronic device and field of semiconductor materials.
Embodiment two: the difference of present embodiment and embodiment one is: the mass ratio of multi-walled carbon nano-tubes and ferric acetyl acetonade is 1:(3～5 in the step 1).Other are identical with embodiment one.
Embodiment three: present embodiment and one of embodiment one or two difference are: the quality of the multi-walled carbon nano-tubes described in the step 1 and the volume ratio of triglycol are 1mg:(0.2mL～1mL).Other are identical with embodiment one or two.
Embodiment four: one of present embodiment and embodiment one to three difference is: the MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of water are 1mg:(0.2mL～0.7mL).Other are identical with embodiment one to three.
Embodiment five: one of present embodiment and embodiment one to four difference is: the MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of aniline are 1mg:(0.0005mL～0.001mL).Other are identical with embodiment one to four.
Embodiment six: one of present embodiment and embodiment one to five difference is: the MWCNT/Fe described in the step 4
3O
4The mass ratio of/PANI material and polyvinylpyrrolidone is 1:(5～10).Other are identical with embodiment one to five.
Embodiment seven: one of present embodiment and embodiment one to six difference is: the MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and concentration are that the mass ratio of hydrochloro-auric acid is 1:(0.5～1.5 in the aqueous solution of chloraurate of 0.25mg/mL～4mg/mL).Other are identical with embodiment one to six.
Embodiment eight: one of present embodiment and embodiment one to seven difference is: the MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and the volume ratio of aniline are 1mg:(0.01mL～0.02mL).Other are identical with embodiment one to seven.
Adopt following verification experimental verification effect of the present invention:
Test one: a kind of MWCNT/Fe
3O
4The preparation method of/PANI/Au multilayer parcel nanotube specifically prepares according to the following steps:
One, ultra-sonic dispersion: at first the multi-walled carbon nano-tubes of 100mg, the ferric acetyl acetonade of 400mg are added in the triglycol of 25mL, carry out ultra-sonic dispersion then, obtain dispersion liquid;
Two, preparation MWCNT/Fe
3O
4Composite granule: the dispersion liquid that under nitrogen protection step 1 is obtained heats; be that 4 ℃/min is heated to boiling with temperature rise rate; utilize magnetism separate method to separate then; separating the solid that obtains washes 2 times earlier; ethanol is washed 2 times again; be 40 ℃ of dry 12h in temperature at last, obtain MWCNT/Fe
3O
4Composite granule;
Three, preparation MWCNT/Fe
3O
4/ PANI material: elder generation is with the MWCNT/Fe of 50mg
3O
4The composite granule ultra-sonic dispersion is in 25mL water, under agitation condition, add 0.04mL aniline then, be that 0.1mL/s adding concentration is the ammonium persulfate aqueous solution of 0.018g/mL with the rate of addition, utilizing concentration for the ammonium persulfate aqueous solution of 0.018g/mL the pH value of reaction system to be controlled between 5～6; Be 4 ℃ of constant temperature machinery stirring reaction 6h in temperature then, isothermal reaction utilizes magnetism separate method to separate after finishing, and separates the solid that obtains and washes 2 times earlier, and ethanol is washed 2 times again, is 40 ℃ of dry 12h in temperature at last, obtains MWCNT/Fe
3O
4/ PANI material;
Four, the outer deposition of Au original position: elder generation is with the MWCNT/Fe of 0.5mg
3O
4/ PANI material ultra-sonic dispersion is in 10mL water, the polyvinylpyrrolidone that under agitation condition, adds 40mg then, and mechanical stirring 30min, be that 0.05mL/s at the uniform velocity adds the aqueous solution of chloraurate that 5mL concentration is 1mg/mL then with the rate of addition, add 0.04mL aniline again, mechanical stirring 10min is 25 ℃ of constant temperature mechanical stirring 6h in temperature at last then, obtains reaction product;
Five, magnetic separates: utilize magnetism separate method that the reaction product that step 4 obtains is separated, separate the solid that obtains and wash 2 times earlier, ethanol is washed 2 times again, is 40 ℃ of dry 12h in temperature at last, obtains MWCNT/Fe
3O
4/ PANI/Au multilayer parcel nanotube.
Fig. 1 is the MWCNT/Fe of test one preparation
3O
4The TEM figure of/PANI/Au multilayer parcel nanotube can see Fe by Fig. 1
3O
4, PANI, Au can be coated on the MWCNT surface uniformly, covered effect is good, no particle obscission.
Fig. 2 is the MWCNT/Fe of test one preparation
3O
4The HRTEM photo of/PANI/Au multilayer parcel nanotube can be clearly seen that MWCNT/Fe by Fig. 2
3O
4The lattice of material in four in the/PANI/PVP/Au multilayered structure proves the MWCNT/Fe of preparation
3O
4/ PANI/PVP/Au mixture is four-layer structure.
Fig. 3 is the MWCNT/Fe of test one preparation
3O
4/ PANI/Au multilayer parcel nanotube XRD figure is among the figure ◆ expression Fe
3O
4Characteristic peak, represents the characteristic peak of MWCNT among the figure, ★ represents the characteristic peak of PANI among the figure, ▽ represents the characteristic peak of Au among the figure, can see MWCNT, Fe by Fig. 3
3O
4, PANI, four kinds of materials of Au characteristic peak, illustrate and synthesized MWCNT/Fe
3O
4/ PANI/Au tetraplex.
MWCNT/Fe to this test preparation
3O
4/ PANI/Au multilayer parcel nanotube carries out Performance Detection, and Fig. 4 is the MWCNT/Fe of this test preparation
3O
4/ PANI/Au multilayer parcel nanotube 2～18GHz microwave absorbing figure, the MWCNT/Fe of this test preparation as shown in Figure 4
3O
4/ PANI/Au multilayer parcel nanotube in the minimal reflection loss of 9GHz place is-60dB(absorbs about 100% hertzian wave).
Claims (8)
1. MWCNT/Fe
3O
4The preparation method of/PANI/Au multilayer parcel nanotube is characterized in that MWCNT/Fe
3O
4The preparation method of/PANI/Au multilayer parcel nanotube prepares according to the following steps:
One, ultra-sonic dispersion: at first multi-walled carbon nano-tubes, ferric acetyl acetonade are added in the triglycol, carry out ultra-sonic dispersion then, obtain dispersion liquid; The mass ratio of the multi-walled carbon nano-tubes described in the step 1 and ferric acetyl acetonade is 1:(2～8); The quality of the multi-walled carbon nano-tubes described in the step 1 and the volume ratio of triglycol are 1mg:(0.1mL～1mL);
Two, preparation MWCNT/Fe
3O
4Composite granule: the dispersion liquid that under nitrogen protection step 1 is obtained heats; be that 1 ℃/min～10 ℃/min is heated to boiling with temperature rise rate; utilize magnetism separate method to separate then; separating the solid that obtains washes 2～3 times earlier; ethanol is washed 2～3 times again; be 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtain MWCNT/Fe
3O
4Composite granule;
Three, preparation MWCNT/Fe
3O
4/ PANI material: the MWCNT/Fe that elder generation obtains step 2
3O
4The composite granule ultra-sonic dispersion is in water, under agitation condition, add aniline then, be that 0.05mL/s～0.5mL/s adding concentration is the ammonium persulfate aqueous solution of 0.001g/mL～0.02g/mL with the rate of addition, utilizing concentration for the ammonium persulfate aqueous solution of 0.001g/mL～0.02g/mL the pH value of reaction system to be controlled between 5～6; Be 0～25 ℃ of constant temperature machinery stirring reaction 2h～10h in temperature then, isothermal reaction utilizes magnetism separate method to separate after finishing, and separates the solid that obtains and washes 2～3 times earlier, and ethanol is washed 2～3 times again, be 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtain MWCNT/Fe
3O
4/ PANI material; MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of water are 1mg:(0.1mL～2mL); MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of aniline are 1mg:(0.0001mL～0.001mL);
Four, the outer deposition of Au original position: the MWCNT/Fe that elder generation obtains step 3
3O
4/ PANI material ultra-sonic dispersion is in water, under agitation condition, add polyvinylpyrrolidone then, and mechanical stirring 20min～40min, be that 0.05mL/s～0.5mL/s at the uniform velocity adds the aqueous solution of chloraurate that concentration is 0.25mg/mL～4mg/mL then with the rate of addition, add aniline again, mechanical stirring 8min～12min is 0～25 ℃ of constant temperature mechanical stirring 1h～6h in temperature at last then, obtains reaction product; MWCNT/Fe described in the step 4
3O
4The mass ratio of/PANI material and polyvinylpyrrolidone is 1:(1～20); MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and concentration are that the mass ratio of hydrochloro-auric acid is 1:(0.1～2 in the aqueous solution of chloraurate of 0.25mg/mL～4mg/mL); MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and the volume ratio of aniline are 1mg:(0.005mL～0.05mL);
Five, magnetic separates: utilize magnetism separate method that the reaction product that step 4 obtains is separated, separate the solid that obtains and wash 2～3 times earlier, ethanol is washed 2～3 times again, is 30 ℃～40 ℃ dry 8h～15h in temperature at last, obtains MWCNT/Fe
3O
4/ PANI/Au multilayer parcel nanotube.
2. a kind of MWCNT/Fe according to claim 1
3O
4The preparation method of/PANI/Au multilayer parcel nanotube is characterized in that the mass ratio of multi-walled carbon nano-tubes and ferric acetyl acetonade is 1:(3～5 in the step 1).
3. a kind of MWCNT/Fe according to claim 1 and 2
3O
4The preparation method of/PANI/Au multilayer parcel nanotube, the volume ratio that it is characterized in that the quality of the multi-walled carbon nano-tubes described in the step 1 and triglycol are 1mg:(0.2mL～1mL).
4. a kind of MWCNT/Fe according to claim 1
3O
4The preparation method of/PANI/Au multilayer parcel nanotube is characterized in that the MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of water are 1mg:(0.2mL～0.7mL).
5. according to claim 1 or 4 described a kind of MWCNT/Fe
3O
4The preparation method of/PANI/Au multilayer parcel nanotube is characterized in that the MWCNT/Fe described in the step 3
3O
4The quality of composite granule and the volume ratio of aniline are 1mg:(0.0005mL～0.001mL).
6. a kind of MWCNT/Fe according to claim 1
3O
4The preparation method of/PANI/Au multilayer parcel nanotube is characterized in that the MWCNT/Fe described in the step 4
3O
4The mass ratio of/PANI material and polyvinylpyrrolidone is 1:(5～10).
7. a kind of MWCNT/Fe according to claim 6
3O
4The preparation method of/PANI/Au multilayer parcel nanotube is characterized in that the MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and concentration are that the mass ratio of hydrochloro-auric acid is 1:(0.5～1.5 in the aqueous solution of chloraurate of 0.25mg/mL～4mg/mL).
8. according to claim 1,6 or 7 described a kind of MWCNT/Fe
3O
4The preparation method of/PANI/Au multilayer parcel nanotube is characterized in that the MWCNT/Fe described in the step 4
3O
4The quality of/PANI material and the volume ratio of aniline are 1mg:(0.01mL～0.02mL).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310260157.3A CN103342980B (en) | 2013-06-26 | 2013-06-26 | Preparation method for MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310260157.3A CN103342980B (en) | 2013-06-26 | 2013-06-26 | Preparation method for MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103342980A true CN103342980A (en) | 2013-10-09 |
| CN103342980B CN103342980B (en) | 2014-06-18 |
Family
ID=49277811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310260157.3A Active CN103342980B (en) | 2013-06-26 | 2013-06-26 | Preparation method for MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103342980B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103558271A (en) * | 2013-10-17 | 2014-02-05 | 宁波大学 | Electrochemical biosensor for detecting penicillin and preparation method and application thereof |
| CN104388045A (en) * | 2014-09-26 | 2015-03-04 | 南京大学 | One-step method for preparing CNTs/Fe nanometer composite material |
| CN105273689A (en) * | 2014-07-18 | 2016-01-27 | 广东工业大学 | Novel multi-element structure composite conductive filling material |
| CN106832272A (en) * | 2017-03-03 | 2017-06-13 | 深圳市佩成科技有限责任公司 | The preparation method of PANI/Fe3O4/MWCNTs paraffin composites |
| CN107584111A (en) * | 2017-09-04 | 2018-01-16 | 哈尔滨工业大学 | The preparation of liquid metal composite and flexible nanotube and its application as nano-motor |
| WO2018157399A1 (en) * | 2017-03-03 | 2018-09-07 | 深圳市佩成科技有限责任公司 | Preparation method for fe3o4/mwcnts-paraffin composite material |
| CN112326749A (en) * | 2020-10-26 | 2021-02-05 | 中国科学院重庆绿色智能技术研究院 | Preparation method of novel coronavirus electrochemical immunoassay kit, product and use method of novel coronavirus electrochemical immunoassay kit |
| CN113351169A (en) * | 2021-06-23 | 2021-09-07 | 中国农业科学院蔬菜花卉研究所 | Magnetic MOFs/nano-gold composite material and preparation method and application thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070272901A1 (en) * | 2005-12-09 | 2007-11-29 | Pelagia-Irene Gouma | Poly-vinylpyrrolidone electrospun composites and Bio-composite sensing materials |
| CN101161725A (en) * | 2007-09-29 | 2008-04-16 | 复旦大学 | Polyaniline coated magnetic carbon-nano tube composite material and preparation method thereof |
| KR20090123169A (en) * | 2008-05-27 | 2009-12-02 | 울산대학교 산학협력단 | Synthetic method of conducting polymer functionalized multi-walled carbon nanotube composites with noble metal nanoparticles |
| CN102033088A (en) * | 2009-09-25 | 2011-04-27 | 华东师范大学 | Preparation method of gold nano-particle/carbon nano tube composite material and application thereof |
| US20120149547A1 (en) * | 2010-12-08 | 2012-06-14 | Hon Hai Precision Industry Co., Ltd. | Method for making carbon nanotube based composite |
| CN102746667A (en) * | 2012-07-12 | 2012-10-24 | 新疆大学 | Polyaniline/nanogold composite material synthesized by solid-phase method |
| CN103113580A (en) * | 2013-03-12 | 2013-05-22 | 哈尔滨工业大学 | Preparation method of coaxial cable structure MWCNT/Fe3O4/ZnO/PANI microwave absorbant |
| CN103151129A (en) * | 2013-03-26 | 2013-06-12 | 哈尔滨工业大学 | Preparation method of multiwalled carbon nanotube (MWCNT)/ ferroferric oxide (Fe3O4)/zinc oxide (ZnO) ternary heterogeneous nanocomposite |
-
2013
- 2013-06-26 CN CN201310260157.3A patent/CN103342980B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070272901A1 (en) * | 2005-12-09 | 2007-11-29 | Pelagia-Irene Gouma | Poly-vinylpyrrolidone electrospun composites and Bio-composite sensing materials |
| CN101161725A (en) * | 2007-09-29 | 2008-04-16 | 复旦大学 | Polyaniline coated magnetic carbon-nano tube composite material and preparation method thereof |
| KR20090123169A (en) * | 2008-05-27 | 2009-12-02 | 울산대학교 산학협력단 | Synthetic method of conducting polymer functionalized multi-walled carbon nanotube composites with noble metal nanoparticles |
| CN102033088A (en) * | 2009-09-25 | 2011-04-27 | 华东师范大学 | Preparation method of gold nano-particle/carbon nano tube composite material and application thereof |
| US20120149547A1 (en) * | 2010-12-08 | 2012-06-14 | Hon Hai Precision Industry Co., Ltd. | Method for making carbon nanotube based composite |
| CN102746667A (en) * | 2012-07-12 | 2012-10-24 | 新疆大学 | Polyaniline/nanogold composite material synthesized by solid-phase method |
| CN103113580A (en) * | 2013-03-12 | 2013-05-22 | 哈尔滨工业大学 | Preparation method of coaxial cable structure MWCNT/Fe3O4/ZnO/PANI microwave absorbant |
| CN103151129A (en) * | 2013-03-26 | 2013-06-12 | 哈尔滨工业大学 | Preparation method of multiwalled carbon nanotube (MWCNT)/ ferroferric oxide (Fe3O4)/zinc oxide (ZnO) ternary heterogeneous nanocomposite |
Non-Patent Citations (2)
| Title |
|---|
| HUI ZHANG,等: "Fe3O4/Polypyrrole/Au Nanocomposites with Core/Shell/Shell Structure:Synthesis, Characterization, and Their Electrochemical Properties", 《LANGMUIR》 * |
| ZHIJIANG WANG,等: "Magnetite Nanocrystals on Multiwalled Carbon Nanotubes as a Synergistic Microwave Absorber", 《J.PHYS.CHEM.C》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103558271A (en) * | 2013-10-17 | 2014-02-05 | 宁波大学 | Electrochemical biosensor for detecting penicillin and preparation method and application thereof |
| CN105273689A (en) * | 2014-07-18 | 2016-01-27 | 广东工业大学 | Novel multi-element structure composite conductive filling material |
| CN104388045A (en) * | 2014-09-26 | 2015-03-04 | 南京大学 | One-step method for preparing CNTs/Fe nanometer composite material |
| CN106832272A (en) * | 2017-03-03 | 2017-06-13 | 深圳市佩成科技有限责任公司 | The preparation method of PANI/Fe3O4/MWCNTs paraffin composites |
| WO2018157399A1 (en) * | 2017-03-03 | 2018-09-07 | 深圳市佩成科技有限责任公司 | Preparation method for fe3o4/mwcnts-paraffin composite material |
| CN107584111A (en) * | 2017-09-04 | 2018-01-16 | 哈尔滨工业大学 | The preparation of liquid metal composite and flexible nanotube and its application as nano-motor |
| CN107584111B (en) * | 2017-09-04 | 2019-08-09 | 哈尔滨工业大学 | Liquid metal composite and flexible nanotube preparation and its as nano-motor application |
| CN112326749A (en) * | 2020-10-26 | 2021-02-05 | 中国科学院重庆绿色智能技术研究院 | Preparation method of novel coronavirus electrochemical immunoassay kit, product and use method of novel coronavirus electrochemical immunoassay kit |
| CN112326749B (en) * | 2020-10-26 | 2022-10-11 | 中国科学院重庆绿色智能技术研究院 | Preparation method of novel coronavirus kit for electrochemical immunodetection, product and use method of novel coronavirus kit |
| CN113351169A (en) * | 2021-06-23 | 2021-09-07 | 中国农业科学院蔬菜花卉研究所 | Magnetic MOFs/nano-gold composite material and preparation method and application thereof |
| CN113351169B (en) * | 2021-06-23 | 2023-03-14 | 中国农业科学院蔬菜花卉研究所 | Magnetic MOFs/nano-gold composite material and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103342980B (en) | 2014-06-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103342980B (en) | Preparation method for MWCNT/Fe3O4/PANI/Au multilayer wrapped nanotube | |
| Wei et al. | Multifunctions of polymer nanocomposites: environmental remediation, electromagnetic interference shielding, and sensing applications | |
| Yan et al. | Polypyrrole-based composite materials for electromagnetic wave absorption | |
| Abdiryim et al. | A facile solid-state heating method for preparation of poly (3, 4-ethelenedioxythiophene)/ZnO nanocomposite and photocatalytic activity | |
| Rahman et al. | Insight into metallic oxide semiconductor (SnO2, ZnO, CuO, α-Fe2O3, WO3)-carbon nitride (g-C3N4) heterojunction for gas sensing application | |
| Husain et al. | Synthesis, characterisation and ethanol sensing application of polythiophene/graphene nanocomposite | |
| Cao et al. | Ferroferric oxide/multiwalled carbon nanotube vs polyaniline/ferroferric oxide/multiwalled carbon nanotube multiheterostructures for highly effective microwave absorption | |
| Yao et al. | Fe3O4@ C@ polyaniline trilaminar core–shell composite microspheres as separable adsorbent for organic dye | |
| CN101525435B (en) | Polyaniline/carbon nano tube/nanometer silver particle conductive composite material and preparation method thereof | |
| CN110813376B (en) | Polypyrrole-modified nano bismuth oxybromide photocatalytic material and preparation method and application thereof | |
| Kaur et al. | A convenient electrolytic assembly of graphene-MOF composite thin film and its photoanodic application | |
| Li et al. | Core-shell structured iron nanoparticles for the generation of COx-free hydrogen via ammonia decomposition | |
| Zhang et al. | High sensitivity self-recovery ethanol sensor based on polyporous graphene oxide/melamine composites | |
| Reddy et al. | Organic conjugated polymer-based functional nanohybrids: synthesis methods, mechanisms and its applications in electrochemical energy storage supercapacitors and solar cells | |
| CN106582562A (en) | Magnetic graphene oxide composite nanomaterial and preparation method thereof | |
| CN101200290A (en) | Method for preparing carbon nanotube supported magnetic ferroferric oxide nano-particles | |
| CN103971942B (en) | Graphene/polyaniline/ferric oxide composite material applied to supercapacitor and manufacturing method thereof | |
| Du et al. | Highly sensitive single-walled carbon nanotube/polypyrrole/phenylalanine core–shell nanorods for ammonia gas sensing | |
| Nazir et al. | Electromagnetic interference shielding properties of ferrocene-based polypyrrole/carbon material composites | |
| Jiao et al. | Self-assembly and headgroup effect in nanostructured organogels via cationic amphiphile-graphene oxide composites | |
| Fuentes-Pérez et al. | Influence of the FeO (OH) nanoparticles concentration in the in-situ synthesis of P3HT | |
| Mutharani et al. | Ultrasound-induced radicals initiated the formation of inorganic–organic Pr2O3/polystyrene hybrid composite for electro-oxidative determination of chemotherapeutic drug methotrexate | |
| Reddy et al. | CeO2 nano-hexagons decorated rGO/CNT heterostructure for high-performance LPG sensing | |
| Husain et al. | Preparation and applications of polythiophene nanocomposites | |
| Zhang et al. | Preparation and conductive and electromagnetic properties of Fe3O4/PANI nanocomposite via reverse in situ polymerization |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190222 Address after: 024000 Hongshan High-tech Industrial Development Zone, Chifeng City, Inner Mongolia Autonomous Region Patentee after: Inner Mongolia Yuanqi New Material Technology Co., Ltd. Address before: 150001 No. 92 West straight street, Nangang District, Heilongjiang, Harbin Patentee before: Harbin Institute of Technology |