CN103333567B - Anti-aging sun-proof protective material of a kind of air brushing colour painting and preparation method thereof - Google Patents
Anti-aging sun-proof protective material of a kind of air brushing colour painting and preparation method thereof Download PDFInfo
- Publication number
- CN103333567B CN103333567B CN201310264599.5A CN201310264599A CN103333567B CN 103333567 B CN103333567 B CN 103333567B CN 201310264599 A CN201310264599 A CN 201310264599A CN 103333567 B CN103333567 B CN 103333567B
- Authority
- CN
- China
- Prior art keywords
- organosilicon
- air brushing
- colour painting
- protective material
- aging
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses anti-aging sun-proof protective material of a kind of air brushing colour painting and preparation method thereof, belongs to color painting technical field, and the color stability solving existing color painting goods is poor, the problem that the quality guaranteed period is shorter.It is made up of following raw material: turn light rare earth, oxidation inhibitor, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent, and the described light rare earth that turns is Europium trichloride; Oxidation inhibitor is monothioester kind antioxidant or phosphite ester kind antioxidant 168; Photostabilizer is hindered amine light stabilizer, and free radical blocker is BHT; Organosilicon modified crylic acid resin is that dimethyl is silica-based acrylic resin modified, and organosilicon coupling solidifying agent is silane coupling agent Si-69 and Silane coupling agent KH550.This anti-aging sun-proof protective material has lighter color, high-low temperature resistant, curing speed is fast, ageing-resistant performance is high feature.
Description
Technical field
The present invention relates to color painting technical field, anti-aging sun-proof protective material of especially a kind of air brushing colour painting and preparation method thereof.
Background technology
Color painting is a new technology, also be develop technology faster, have the irreplaceable feature of other technique of expression and superiority: other Freehandhand-drawing skill and technique relative, its performance is more truly fine and smooth, can super realistic performance image, reach the picture effect of mixing the spurious with the genuine; The modern skill and technique such as relative computer, photography, the image that it shows is more natural, and vividly, and not by breadth and batch restriction, making method variation, cost is low, and fabrication cycle is short.So spray drawing machine releases short several years, fashionable various places, special standby applicable outdoor large advertisement etc.
But, oxygen, ultraviolet etc. are to the stability of air brushing goods, and especially the color stability etc. of color painting goods affects huge, and the existing color painting goods quality guaranteed period was difficult to more than 2 years.If be used in open space, be especially used in long day area, highlands, area that temperature is high, tan by the sun two, three months just aging.Air brushing goods aging, be the complex process occurred by multiple composite factor effect, the photooxidation resistance of its first stage is called the aging step at initial stage, and this stage advance is slow, and naked eyes be can not see.First be going out due to photon, create high molecular radical, the rupture crosslinks of molecular chain occurs subsequently, at this moment because oxygenizement creates the typical degraded product such as carbonyl, hydroxyl.Subordinate phase is called the aging step in later stage, and degraded product is oxidized further and causes producing colored group in a large number in this stage, and serious degraded occurs, and occurs the proterties such as look change, brisement, electromechanical properties reduction.The aging grade of color painting goods is main relevant with the UV-light in air, oxygen etc.Oxygen can react with air brushing goods, causes degraded or crosslinked, especially when sun exposure, oxidation rate is accelerated, and the oxidation of superpolymer is a kind of radical chain reaction, and the ultraviolet in sunlight is outstanding large on its impact, can occur rapidly aging, occur that gloss disappears, become fragile, the phenomenons such as fission, variable color; Thus cause air brushing goods image quality obviously to reduce, affect its perception and value for preservation, therefore, the sun-proof anti-aging protective material of research color painting goods is of great immediate significance.
Summary of the invention
The object of the present invention is to provide anti-aging sun-proof protective material of a kind of air brushing colour painting and preparation method thereof; have employed turn light rare earth, oxidation inhibitor, photostabilizer, free radical blocker work in coordination with stabilization protective mechanism, be aided with organosilicon modified crylic acid resin, organosilicon coupling solidifying agent be composited.This anti-aging sun-proof protective material has lighter color, high-low temperature resistant, curing speed is fast, ageing-resistant performance is high feature.
The technical solution adopted in the present invention is:
The anti-aging sun-proof protective material of a kind of air brushing colour painting; it is characterized in that, be made up of the raw material of following weight: turn light rare earth 0.5 ~ 5 part, 0 ~ 20 part, oxidation inhibitor, photostabilizer 1 ~ 20 part, free radical blocker 1 ~ 20 part, organosilicon modified crylic acid resin 5 ~ 90 parts, 1 ~ 50 part, organosilicon coupling solidifying agent.
Preferably, be made up of the raw material of following weight: turn light rare earth 1 part, 5 parts, oxidation inhibitor, photostabilizer 10 parts, free radical blocker 10 parts, organosilicon modified crylic acid resin 39 parts, 35 parts, organosilicon coupling solidifying agent.
Preferably, the described light rare earth that turns is Europium trichloride; Turn light rare earth and can absorb 300 ~ 360nm UV-light, change and send that 591.8nm, 614.1nm, 621.2nm, 701.8nm are red, gold-tinted, thus reduce ultraviolet and reduce its destructive force, reach the age inhibiting effect of sun-proof.
Wherein, oxidation inhibitor is monothioester kind antioxidant or phosphite ester kind antioxidant 168; Described photostabilizer is hindered amine light stabilizer, described free radical blocker is BHT, described organosilicon modified crylic acid resin is that dimethyl is silica-based acrylic resin modified, described organosilicon coupling solidifying agent is silane coupling agent Si-69 and Silane coupling agent KH550 mixture, described silane coupling agent Si-69: the mass ratio of Silane coupling agent KH550 is 0.5 ~ 1.5:1.
Wherein, monothioester kind antioxidant is the two dodecane ester of thio-2 acid, and CAS is: 123-28-4, and being called for short DLTDP, is a kind of thioesters class auxiliary antioxidant of good performance.
Phosphite ester kind antioxidant 168 is three (2,4-di-t-butyl) phenyl-phosphite, and CAS is: 31570-04-4, and being called for short IRGAFOS168, is a kind of processing stabilizers of phosphorous acid esters.
Hindered amine light stabilizer is the organic amine compound with steric restriction, and to superpolymer, (superpolymer refers to that the high molecular being repeated to be formed by connecting by covalent linkage by many identical, simple structural units (can reach 10 usually
4~ 10
6) compound) and organic compound photooxidation droping reaction (high-molecular optical degrade, the Degradation that polymer occurs under light action.Wherein, polymer absorbs luminous energy and disintegrate under the irradiation of light, claims photolysis; Oxidation is there is and claims photoxidation in polymer under the existence of light and oxygen or air.) there is good inhibition, be the photostabilizer of a class excellent property; Described hindered amine light stabilizer can be Tnuvin123; (can purchased from Hua Xin industrial chemicals marketing center, Shanghai) Tnuvin123 is a kind of liquid hindered amine stablizer containing amino ethers group for coatings industry; this product has lower alkalescence; can farthest avoid and the acidic component reaction in coating; effectively can prevent cracking, loss of gloss, efflorescence etc. from painting sick, thus improve the work-ing life of coating.
BHT is 2,6 ditertiary butyl p cresol, and CAS is: 128-37-0, is called for short BHT.
Silane coupling agent Si-69 is two-[γ-(triethoxysilicane) propyl group] tetrasulfide, and Silane coupling agent KH550 is γ-aminopropyl triethoxysilane.
Preferably, described oxidation inhibitor is monothioester kind antioxidant.
Preferably, the acrylic resin modified molecular weight of described dimethyl-silicon is 6000 ~ 8000.
Preferably, the mass content of the organosilicon radical part of described organosilicon modified crylic acid resin is 25%.
Preferably, the mass ratio of described Si-69:KH550 is 1:1.
Present invention also offers the protectant preparation method of the anti-aging sun-proof of a kind of air brushing colour painting, it is characterized in that, comprise the following steps:
S1: take according to above-mentioned weight part and turn light rare earth, oxidation inhibitor, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent;
S2: get oxidation inhibitor in step S1, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent; at 10 ~ 30 DEG C; under the condition of sealing; stir; then add and turn light rare earth, continue mix and blend 2 ~ 10 hours, use strainer filtering; then load black pail pack filling and sealing, obtain the anti-aging sun-proof protective material of air brushing colour painting.
Preferably, described stirring velocity is 80 revs/min.
Preferably, described filter screen is 360 mesh filter screens.
Beneficial effect of the present invention:
(1) the anti-aging sun-proof protective material of air brushing colour painting of the present invention have employed turn light rare earth, oxidation inhibitor, photostabilizer, free radical blocker work in coordination with stabilization protective mechanism, be aided with organosilicon modified crylic acid resin, organosilicon coupling solidifying agent be composited.Its transfer light rare earth can absorb 300 ~ 360nm UV-light, changes and sends that 591.8nm, 614.1nm, 621.2nm, 701.8nm are red, gold-tinted, thus reduces ultraviolet and reduce its destructive force, reaches the age inhibiting effect of sun-proof.
(2) air brushing colour painting of the present invention anti-aging sun-proof protective material lighter color (for water white transparency), modest viscosity, spreadability good, easily construct; After color jet-ink, more anti-aging for ink-jet colour painting of the present invention sun-proof protective material is sprayed on colour painting surface, due to protective material lighter color, is sprayed on the bright colors that colour painting still can be kept original after on colour painting, on the perception of colour painting without impact.
(3) the anti-aging sun-proof of air brushing colour painting of the present invention is short for protectant time of drying, and has good high and low temperature resistance and good anti-aging sun-proof performance, time of drying (normal temperature 25 DEG C): surface drying≤15min, does solid work≤4h; Resistant of high or low temperature: high temperature of 120 DEG C, low temperature-20 DEG C.
(4) after spraying the anti-aging sun-proof protective material of air brushing colour painting of the present invention, carry out the test of accelerated deterioration method, after result shows sprayed protection agent, the anti-aging sun-proof performance of air brushing colour painting can improve 2.1 times.
Embodiment
In order to understand the present invention better, illustrate content of the present invention further below in conjunction with embodiment, but content of the present invention is not only confined to the following examples, embodiment should not regard as limiting the scope of the present invention.
Embodiment 1
The anti-aging sun-proof protective material of a kind of air brushing colour painting, fills a prescription as follows: turn light rare earth 1 part, 5 parts, oxidation inhibitor, photostabilizer 10 parts, free radical blocker 10 parts, organosilicon modified crylic acid resin 39 parts, 35 parts, organosilicon coupling solidifying agent.
The described light rare earth that turns selects Europium trichloride; Monothioester kind antioxidant selected by described oxidation inhibitor; Described photostabilizer is hindered amine as light stabilizer; BHT selected by described free radical blocker; Described organosilicon modified crylic acid resin is that dimethyl is silica-based acrylic resin modified, and the acrylic resin modified molecular weight of dimethyl-silicon is 6000 ~ 8000; The mass content of organosilicon radical part is 25%, and described organosilicon coupling solidifying agent is silane coupling agent Si-69 and Silane coupling agent KH550 mixture, described silane coupling agent Si-69: the mass ratio of Silane coupling agent KH550 is 1:1.
Wherein, monothioester kind antioxidant is the two dodecane ester of thio-2 acid, and CAS is: 123-28-4, and being called for short DLTDP, is a kind of thioesters class auxiliary antioxidant of good performance; BHT is 2,6 ditertiary butyl p cresol, and CAS is: 128-37-0, is called for short BHT.Silane coupling agent Si-69 is two-[γ-(triethoxysilicane) propyl group] tetrasulfide, and Silane coupling agent KH550 is γ-aminopropyl triethoxysilane.
The protectant preparation method of the anti-aging sun-proof of above-mentioned air brushing colour painting, comprises the following steps:
S1: take according to above-mentioned weight part and turn light rare earth, oxidation inhibitor, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent;
S2: get oxidation inhibitor in step S1, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent, at 20 DEG C, under the condition of sealing, stir, then add and turn light rare earth, continue mix and blend 10 hours, use strainer filtering, use black pail pack filling and sealing, obtain the anti-aging sun-proof protective material of air brushing colour painting; Above-mentioned stirring velocity is 80 revs/min; Filter screen used is 360 mesh filter screens.
Product performance test result:
Use time of drying (normal temperature 25 DEG C): surface drying 12min, do solid work 3.3h; After products solidifying, high temperature of 120 DEG C places 4 hours, or low temperature-20 DEG C is placed 4 hours, apparent without considerable change.
Anti-aging sun-proof experiment:
Testing method: adopt desk-top xenon lamp accelerated deterioration method to test, optical filter is " S " class borosilicate glass.
Accelerated ageing measuring condition:
(1) irradiance under normal operation, and sample is subject to the radiation of 290 ~ 340nm wavelength, and its irradiance controls at 0.6W/ (m
2nm);
(2) envrionment temperature: in each round-robin test process, UV illumination is 60 DEG C; Be condensed into 50 DEG C;
(3) water of condensation: use ordinary tap water;
(4) rainfall: rainfall cycle is defined as 4h/4h (rain time/not rain time).
Evaluation leading indicator is: loss of gloss, variable color, efflorescence, crackle, bubble, come off.These indexs summarise the destructive characteristics and change and progress thereof that the aging result of air brushing colour painting occurs on paint film appearance.The reason producing these breakoff phenomenons is caused by molecular resin chain ruptures, the character of crosslinked or pigment, structure change.
Relatively adopt and do not use the protectant air brushing colour painting of this anti-aging sun-proof, by 200g/m
2after using air brushing colour painting antiaging agent, air brushing colour painting ageing-resistant performance can improve 2.1 times.
Embodiment 2
The anti-aging sun-proof protective material of a kind of air brushing colour painting, fills a prescription as follows: turn light rare earth 0.5 part, 8 parts, oxidation inhibitor, photostabilizer 11 parts, free radical blocker 9 parts, organosilicon modified crylic acid resin 39 parts, 38 parts, organosilicon coupling solidifying agent.
The anti-aging sun-proof protective material of a kind of air brushing colour painting, fills a prescription as follows: turn light rare earth 1 part, 5 parts, oxidation inhibitor, photostabilizer 10 parts, free radical blocker 10 parts, organosilicon modified crylic acid resin 40 parts, 35 parts, organosilicon coupling solidifying agent.
The described light rare earth that turns selects Europium trichloride; Monothioester kind antioxidant selected by described oxidation inhibitor; Described photostabilizer is hindered amine as light stabilizer; BHT selected by described free radical blocker; Described organosilicon modified crylic acid resin is that dimethyl is silica-based acrylic resin modified, and the acrylic resin modified molecular weight of dimethyl-silicon is 6000 ~ 8000; The mass content of organosilicon radical part is 25%, and described organosilicon coupling solidifying agent is silane coupling agent Si-69 and Silane coupling agent KH550 mixture, described silane coupling agent Si-69: the mass ratio of Silane coupling agent KH550 is 1.2:1.
Wherein, monothioester kind antioxidant is the two dodecane ester of thio-2 acid, and CAS is: 123-28-4, and being called for short DLTDP, is a kind of thioesters class auxiliary antioxidant of good performance; BHT is 2,6 ditertiary butyl p cresol, and CAS is: 128-37-0, is called for short BHT.Silane coupling agent Si-69 is two-[γ-(triethoxysilicane) propyl group] tetrasulfide, and Silane coupling agent KH550 is γ-aminopropyl triethoxysilane.
The protectant preparation method of the anti-aging sun-proof of above-mentioned air brushing colour painting, comprises the following steps:
S1: take according to above-mentioned weight part and turn light rare earth, oxidation inhibitor, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent;
S2: get oxidation inhibitor in step S1, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent, at 30 DEG C, under the condition of sealing, stir, then add and turn light rare earth, continue mix and blend 5 hours, use strainer filtering, use black pail pack filling and sealing, obtain the anti-aging sun-proof protective material of air brushing colour painting; Above-mentioned stirring velocity is 80 revs/min; Filter screen used is 360 mesh filter screens.
Product performance test result:
Use time of drying (normal temperature 25 DEG C): surface drying 15min, do solid work 3.6h; After products solidifying, high temperature of 120 DEG C places 4 hours, or low temperature-20 DEG C is placed 4 hours, apparent without considerable change.
Anti-aging sun-proof experiment:
Testing method: adopt desk-top xenon lamp accelerated deterioration method to test, optical filter is " S " class borosilicate glass.
Accelerated ageing measuring condition:
(1) irradiance under normal operation, and sample is subject to the radiation of 290 ~ 340nm wavelength, and its irradiance controls at 0.6W/ (m
2nm);
(2) envrionment temperature: in each round-robin test process, UV illumination is 60 DEG C; Be condensed into 50 DEG C;
(3) water of condensation: use ordinary tap water;
(4) rainfall: rainfall cycle is defined as 4h/4h (rain time/not rain time).
Evaluation leading indicator is: loss of gloss, variable color, efflorescence, crackle, bubble, come off.These indexs summarise the destructive characteristics and change and progress thereof that the aging result of air brushing colour painting occurs on paint film appearance.The reason producing these breakoff phenomenons is caused by molecular resin chain ruptures, the character of crosslinked or pigment, structure change.
Relatively adopt and do not use the protectant air brushing colour painting of this anti-aging sun-proof, by 200g/m
2after using air brushing colour painting antiaging agent, air brushing colour painting ageing-resistant performance can improve 2 times.
Embodiment 3
The anti-aging sun-proof protective material of a kind of air brushing colour painting, fills a prescription as follows: turn light rare earth 2 parts, 8 parts, oxidation inhibitor, photostabilizer 12 parts, free radical blocker 8 parts, organosilicon modified crylic acid resin 45 parts, 30 parts, organosilicon coupling solidifying agent.
The described light rare earth that turns selects Europium trichloride; Monothioester kind antioxidant selected by described oxidation inhibitor; Described photostabilizer is hindered amine as light stabilizer; BHT selected by described free radical blocker; Described organosilicon modified crylic acid resin is that dimethyl is silica-based acrylic resin modified, and the acrylic resin modified molecular weight of dimethyl-silicon is 6000 ~ 8000; The mass content of organosilicon radical part is 25%, and described organosilicon coupling solidifying agent is silane coupling agent Si-69 and Silane coupling agent KH550 mixture, described silane coupling agent Si-69: the mass ratio of Silane coupling agent KH550 is 0.8:1.
Wherein, monothioester kind antioxidant is the two dodecane ester of thio-2 acid, and CAS is: 123-28-4, and being called for short DLTDP, is a kind of thioesters class auxiliary antioxidant of good performance; BHT is 2,6 ditertiary butyl p cresol, and CAS is: 128-37-0, is called for short BHT.Silane coupling agent Si-69 is two-[γ-(triethoxysilicane) propyl group] tetrasulfide, and Silane coupling agent KH550 is γ-aminopropyl triethoxysilane.
The protectant preparation method of the anti-aging sun-proof of above-mentioned air brushing colour painting, comprises the following steps:
S1: take according to above-mentioned weight part and turn light rare earth, oxidation inhibitor, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent;
S2: get oxidation inhibitor in step S1, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent, at 25 DEG C, under the condition of sealing, stir, then add and turn light rare earth, continue mix and blend 3 hours, use strainer filtering, use black pail pack filling and sealing, obtain the anti-aging sun-proof protective material of air brushing colour painting; Above-mentioned stirring velocity is 80 revs/min; Filter screen used is 360 mesh filter screens.
Product performance test result:
Use time of drying (normal temperature 25 DEG C): surface drying 15min, do solid work 3.6h; After products solidifying, high temperature of 120 DEG C places 4 hours, or low temperature-20 DEG C is placed 4 hours, apparent without considerable change.
Anti-aging sun-proof experiment:
Testing method: adopt desk-top xenon lamp accelerated deterioration method to test, optical filter is " S " class borosilicate glass.
Accelerated ageing measuring condition:
(1) irradiance under normal operation, and sample is subject to the radiation of 290 ~ 340nm wavelength, and its irradiance controls at 0.6W/ (m
2nm);
(2) envrionment temperature: in each round-robin test process, UV illumination is 60 DEG C; Be condensed into 50 DEG C;
(3) water of condensation: use ordinary tap water;
(4) rainfall: rainfall cycle is defined as 4h/4h (rain time/not rain time).
Evaluation leading indicator is: loss of gloss, variable color, efflorescence, crackle, bubble, come off.These indexs summarise the destructive characteristics and change and progress thereof that the aging result of air brushing colour painting occurs on paint film appearance.The reason producing these breakoff phenomenons is caused by molecular resin chain ruptures, the character of crosslinked or pigment, structure change.
Relatively adopt and do not use the protectant air brushing colour painting of this anti-aging sun-proof, by 200g/m
2after using air brushing colour painting antiaging agent, air brushing colour painting ageing-resistant performance can improve 1.9 times.
Though be described in detail the present invention above in conjunction with the embodiments, but described those skilled in the art can understand, and under the prerequisite not departing from present inventive concept, in the scope of claim protection, can also change above-described embodiment.
Claims (10)
1. the anti-aging sun-proof protective material of air brushing colour painting, it is characterized in that, be made up of the raw material of following weight: turn light rare earth 0.5 ~ 5 part, 0 ~ 20 part, oxidation inhibitor, photostabilizer 1 ~ 20 part, free radical blocker 1 ~ 20 part, organosilicon modified crylic acid resin 5 ~ 90 parts, 1 ~ 50 part, organosilicon coupling solidifying agent;
Described oxidation inhibitor is monothioester kind antioxidant or phosphite ester kind antioxidant 168; Described photostabilizer is hindered amine light stabilizer, and described free radical blocker is BHT;
The described light rare earth that turns is Europium trichloride.
2. the anti-aging sun-proof protective material of a kind of air brushing colour painting according to claim 1; it is characterized in that, be made up of the raw material of following weight: turn light rare earth 1 part, 5 parts, oxidation inhibitor, photostabilizer 10 parts, free radical blocker 10 parts, organosilicon modified crylic acid resin 39 parts, 35 parts, organosilicon coupling solidifying agent.
3. the anti-aging sun-proof protective material of a kind of air brushing colour painting according to claim 1 and 2; it is characterized in that; described organosilicon modified crylic acid resin is that dimethyl is silica-based acrylic resin modified; described organosilicon coupling solidifying agent is silane coupling agent Si-69 and Silane coupling agent KH550, described silane coupling agent Si-69: the mass ratio of Silane coupling agent KH550 is 0.5 ~ 1.5:1.
4. the anti-aging sun-proof protective material of a kind of air brushing colour painting according to claim 3, it is characterized in that, described oxidation inhibitor is monothioester kind antioxidant.
5. the anti-aging sun-proof protective material of a kind of air brushing colour painting according to claim 3, it is characterized in that, the acrylic resin modified molecular weight of described dimethyl-silicon is 6000 ~ 8000.
6. the anti-aging sun-proof protective material of a kind of air brushing colour painting according to claim 3, is characterized in that, the mass content of the organosilicon radical part of described organosilicon modified crylic acid resin is 25%.
7. the anti-aging sun-proof protective material of a kind of air brushing colour painting according to claim 3, is characterized in that, the mass ratio of described Si-69:KH550 is 1:1.
8. the protectant preparation method of the anti-aging sun-proof of air brushing colour painting, is characterized in that, comprise the following steps:
S1: weight part according to claim 1 takes and turns light rare earth, oxidation inhibitor, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent;
S2: get oxidation inhibitor in step S1, photostabilizer, free radical blocker, organosilicon modified crylic acid resin, organosilicon coupling solidifying agent; at 10 ~ 30 DEG C; under the condition of sealing; stir; then add and turn light rare earth, continue mix and blend 2 ~ 10 hours, use strainer filtering; then load black pail pack filling and sealing, obtain the anti-aging sun-proof protective material of air brushing colour painting.
9. the protectant preparation method of the anti-aging sun-proof of a kind of air brushing colour painting according to claim 8, is characterized in that, described stirring velocity is 80 revs/min.
10. the protectant preparation method of the anti-aging sun-proof of a kind of air brushing colour painting according to claim 9, is characterized in that, described filter screen is 360 mesh filter screens.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310264599.5A CN103333567B (en) | 2013-06-27 | 2013-06-27 | Anti-aging sun-proof protective material of a kind of air brushing colour painting and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310264599.5A CN103333567B (en) | 2013-06-27 | 2013-06-27 | Anti-aging sun-proof protective material of a kind of air brushing colour painting and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103333567A CN103333567A (en) | 2013-10-02 |
| CN103333567B true CN103333567B (en) | 2016-04-27 |
Family
ID=49241776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310264599.5A Active CN103333567B (en) | 2013-06-27 | 2013-06-27 | Anti-aging sun-proof protective material of a kind of air brushing colour painting and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103333567B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108219550A (en) * | 2017-12-29 | 2018-06-29 | 广西平果宝信涂料有限公司 | Polyester-type exempts from Lacquer finish Huang bottom powder and preparation method thereof |
| CN109161291A (en) * | 2018-07-14 | 2019-01-08 | 宁波高新区诠宝绶新材料科技有限公司 | A kind of method of the in-situ method preparation outer layer of leather containing europium finishing agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3851282B2 (en) * | 2002-02-18 | 2006-11-29 | 関西ペイント株式会社 | Paint composition |
| CN101982512A (en) * | 2010-09-21 | 2011-03-02 | 常州大学 | Silicone acrylate coating resin and preparation method thereof |
| CN102850880A (en) * | 2012-09-11 | 2013-01-02 | 浙江天女集团制漆有限公司 | Varnish resisting ultraviolet and preventing bottom-layer discoloration, and preparation method thereof |
-
2013
- 2013-06-27 CN CN201310264599.5A patent/CN103333567B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3851282B2 (en) * | 2002-02-18 | 2006-11-29 | 関西ペイント株式会社 | Paint composition |
| CN101982512A (en) * | 2010-09-21 | 2011-03-02 | 常州大学 | Silicone acrylate coating resin and preparation method thereof |
| CN102850880A (en) * | 2012-09-11 | 2013-01-02 | 浙江天女集团制漆有限公司 | Varnish resisting ultraviolet and preventing bottom-layer discoloration, and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 稀土Eu3+有机配合物转光剂在抗紫外整理中的应用研究;尹桂波，陈和春，耿琴玉，闻娜;《染印助剂》;江苏苏豪传媒有限公司;20101031;第27卷(第10期);第44页标题1.2的内容、标题2.1的内容、图1和图2、第45页标题2.2的内容 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103333567A (en) | 2013-10-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101885937B (en) | Colored and transparent heat-insulating energy-saving protecting function coating and preparation method thereof | |
| CN102702933B (en) | Ultraviolet curing woodware colored paint coating and preparation method thereof | |
| CN105733361B (en) | A kind of anti-etching ink-jet ink and its application | |
| CN103602224B (en) | A kind of white solvent-free finish paint and its preparation method and construction technology | |
| CN107236367B (en) | Temperature-sensing reversible color-changing UV (ultraviolet) ink for PVC (polyvinyl chloride), and preparation method and use method thereof | |
| CN108546540B (en) | Preparation method of ultraviolet curing transfer adhesive for glass substrate | |
| CN1950472B (en) | Coating composition | |
| KR20120111875A (en) | Fast drying inkjet-ink composition, not-melting coating layer | |
| CN103740205A (en) | Water-based spray lacquer and preparation method thereof | |
| CN104004451A (en) | Automotive UV (Ultraviolet) light-cured camouflage coating and preparation method thereof | |
| CN110256883B (en) | Water-based UV (ultraviolet) woodware high-gloss varnish, preparation method and implementation process | |
| CN107513309B (en) | Three-dimensionally shaped photocuring transparent ink composition and its preparation method and application | |
| CN103333567B (en) | Anti-aging sun-proof protective material of a kind of air brushing colour painting and preparation method thereof | |
| CN103483527A (en) | Quick-drying weather-proof finish coat for polyurea coating and preparation method thereof | |
| KR101638407B1 (en) | Acryl-based semi-matt powder coating composition with high transparency | |
| CN101033280A (en) | Resin for water paint and its preparing process | |
| CN103525293A (en) | Non-yellowing UV (Ultraviolet) gloss oil as well as preparation method thereof | |
| CN111171611B (en) | Green and environment-friendly UV coating and preparation method thereof | |
| CN110845951A (en) | Waterborne polyurethane coating for engineering machinery and preparation method thereof | |
| CN111849295A (en) | Substrate coloring agent and preparation method thereof | |
| CN104149431A (en) | Ultraviolet-blocking colored antifogging and heat-insulating window film | |
| MX2009011245A (en) | Resin compositions for wrinkle-pattern paint purposes. | |
| CN108560267A (en) | A kind of aqueous heat discoloration printing treatment agent of use for synthetic leather and its preparation method and application | |
| CN102977708B (en) | Water-soluble stoving varnish suitable for craft glass products and preparation method thereof | |
| CN101967326A (en) | Exterior-wall reflectorized soluble paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An anti-aging and sun resistant protective agent for ink-jet color painting and its preparation method Effective date of registration: 20221226 Granted publication date: 20160427 Pledgee: Shizhong Branch of Qilu Bank Co.,Ltd. Pledgor: JINAN APOLLO STATIONERY COMMODITY CO.,LTD. Registration number: Y2022980028382 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |