CN103333450A - High-strength plastic - Google Patents
High-strength plastic Download PDFInfo
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- CN103333450A CN103333450A CN2013102263793A CN201310226379A CN103333450A CN 103333450 A CN103333450 A CN 103333450A CN 2013102263793 A CN2013102263793 A CN 2013102263793A CN 201310226379 A CN201310226379 A CN 201310226379A CN 103333450 A CN103333450 A CN 103333450A
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- highstrenghtpiston
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Abstract
The invention relates to a high-strength plastic which comprises the following components in parts by weight: 40-70 parts of ABS (acrylonitrile-butadiene-styrene), 3-8 parts of interfacial coupling agent, 3-10 parts of toughener, 0.5-1.0 part of dispersing and lubricating agent, 5-10 parts of silicon dioxide and 10-15 parts of glass fiber. The high-strength plastic provided by the invention has excellent strength, can be widely used in automobile industry, and is often used for manufacturing daily necessities, such as automobile parts, home appliance industry, architectural decoration industry, crash helmets, motorcycle fenders, heelpieces, snowfield sporting goods, toys, clocks, loudspeaker shells, suitcases, buttons, cosmetic cases and the like, and advertising products of nameplates, ornaments and the like.
Description
Technical field
The present invention relates to the plastics field, specifically, the present invention relates to a kind of highstrenghtpiston.
Background technology
The ABS(acrylonitrile-butadiene-styrene (ABS)) resin is important general synthetic resin, and main body is vinyl cyanide, divinyl and cinnamic blend or terpolymer, is a kind of tough and tensile and the thermoplastics of rigidity is arranged.Its purposes is very extensive, automotive industry is usually used in making automobile component such as dashboard, vehicle-body outer panel, inner trim panels, bearing circle, insulating board, door lock, collision bumper, vent-pipe etc., household electric appliances are usually used in making as refrigerator, televisor, washing machine, vacuum cleaner, food mixer, the housing of telephone set etc., be usually used in making as sanitary apparatus at architectural decoration, the swimming pool lining, tubing and pipe fitting etc. are in addition also for the manufacture of safety helmet, the motorcycle plate washer, heel, the snowfield sporting goods, toy, clock, casing of loudspeaker box, suitcase, button, daily necessities and nameplates such as minaudiere, advertising matters such as ornament.
Although ABS is widely used, because the characteristic of the molecular structure performance of ABS own, make ABS deficiency aspect intensity.
Summary of the invention
The object of the present invention is to provide a kind of highstrenghtpiston.
In order to realize purpose of the present invention, the invention provides a kind of highstrenghtpiston, comprise following components by part by weight:
Preferably, described interface coupling agent is one or more in γ-An Bingjisanyiyangjiguiwan (KH550), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH560), γ-(methacryloxypropyl) propyl trimethoxy silicane (KH570), ABS grafting toxilic acid (ABS-g-MAH), styrene-maleic anhydride copolymer (SMA), polycthylene grafted maleic anhydride (LDPE-g-MAH), linear low density polyethylene grafted maleic anhydride (LLDPE-g-MAH), the Racemic glycidol ether type epoxy.
Preferably, described toughner is MBS (MBS), MBS, hydrogenated styrene/Butadiene) in the segmented copolymer (SEBS) one or more.
Preferably, described dispersed lubricant is one or more in glyceryl monostearate, Tristearoylglycerol, ethylene bis stearamide, the bimonthly osmanthus of ethylene acid amides, the two amine hydroxybenzenes of ethylene, lower molecular weight ionomer, ethylene-acrylic acid copolymer, the ethylene-vinyl acetate copolymer.
Highstrenghtpiston of the present invention has excellent intensity, can be widely used for automotive industry and be usually used in making daily necessities and advertising matters such as nameplate, ornament such as automobile component, household electric appliances, architectural decoration, safety helmet, motorcycle plate washer, heel, snowfield sporting goods, toy, clock, casing of loudspeaker box, suitcase, button, minaudiere.
Embodiment
Below the invention will be further described for the description by embodiment, but this is not to be limitation of the present invention, those skilled in the art are according to basic thought of the present invention, can make various modifications or improvement, but only otherwise break away from basic thought of the present invention, all within the scope of the present invention.
Embodiment 1
The ABS that take by weighing 600 grams are following dry 4 hours in 90 ℃, then with silicon-dioxide 80 grams, glass fibre 130 grams, γ-An Bingjisanyiyangjiguiwan 50 grams, MBS 50 grams and glyceryl monostearate 8 grams, in homogenizer, stirred 5 minutes with 1100 rev/mins, emit after treating evenly.To add length-to-diameter ratio (L/D) be in 40 the twin screw extruder mixing equal materials of spoon, the processing temperature of twin screw extruder: 180 ℃ of district's temperature, two district's temperature are 185 ℃, three district's temperature are 195 ℃, and four district's temperature are 210 ℃, and five district's temperature are 215 ℃, six district's temperature are 225 ℃, seven district's temperature are 235 ℃, and eight district's temperature are 240 ℃, and engine speed is 320 commentaries on classics/min; Through extruding back cooling check rod, air-dry pelletizing, namely prepare highstrenghtpiston of the present invention.
Embodiment 2
According to preparing the highstrenghtpiston with embodiment 1 identical mode, difference is not use silicon-dioxide.
Embodiment 3
According to preparing the highstrenghtpiston with embodiment 1 identical mode, difference is not use glass fibre.
Experimental example
Impact property is tested by the ISO180-93 requirement, tensile property by the ISO527-93 requirement test, condition is 50mm/min, bending property control ISO178-93 requires to test, condition is 2mm/min, the result is as follows:
| Project | Testing method | Unit | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Notched Izod impact strength | ISO180-93 | KJ/m 2 | 7.7 | 5.3 | 4.0 |
| Tensile strength | ISO527-93 | MPa | 168 | 121 | 119 |
| Elongation at break | ISO527-93 | % | 15.2 | 11.0 | 10.5 |
| Flexural strength | ISO178-93 | MPa | 189 | 136 | 137 |
| Modulus in flexure | ISO178-93 | MPa | 6500 | 6100 | 6210 |
| Outward appearance | ? | ? | True qualities, smooth | True qualities, smooth | True qualities, smooth |
This shows, add silicon-dioxide and glass fibre and produced synergy unexpectedly.
Claims (5)
1. a highstrenghtpiston is characterized in that, comprises following components by part by weight:
2. highstrenghtpiston according to claim 1, it is characterized in that described interface coupling agent is one or more in γ-An Bingjisanyiyangjiguiwan (KH550), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH560), γ-(methacryloxypropyl) propyl trimethoxy silicane (KH570), ABS grafting toxilic acid (ABS-g-MAH), styrene-maleic anhydride copolymer (SMA), polycthylene grafted maleic anhydride (LDPE-g-MAH), linear low density polyethylene grafted maleic anhydride (LLDPE-g-MAH), the Racemic glycidol ether type epoxy.
3. highstrenghtpiston according to claim 1, it is characterized in that described toughner is MBS (MBS), MBS, hydrogenated styrene/Butadiene) in the segmented copolymer (SEBS) one or more.
4. highstrenghtpiston according to claim 1, it is characterized in that described dispersed lubricant is one or more in glyceryl monostearate, Tristearoylglycerol, ethylene bis stearamide, the bimonthly osmanthus of ethylene acid amides, the two amine hydroxybenzenes of ethylene, lower molecular weight ionomer, ethylene-acrylic acid copolymer, the ethylene-vinyl acetate copolymer.
5. according to each described highstrenghtpiston in the claim 1 to 4, it is characterized in that, comprise following components by part by weight:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310226379.3A CN103333450B (en) | 2013-06-07 | 2013-06-07 | A kind of highstrenghtpiston |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310226379.3A CN103333450B (en) | 2013-06-07 | 2013-06-07 | A kind of highstrenghtpiston |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103333450A true CN103333450A (en) | 2013-10-02 |
| CN103333450B CN103333450B (en) | 2015-10-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310226379.3A Expired - Fee Related CN103333450B (en) | 2013-06-07 | 2013-06-07 | A kind of highstrenghtpiston |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103333450B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897330A (en) * | 2013-11-08 | 2014-07-02 | 东南大学 | High-strength plastic |
| CN104292740A (en) * | 2014-09-29 | 2015-01-21 | 苏州博利迈新材料科技有限公司 | Fatigue-resistant mud guard material and preparation method thereof |
| CN105348634A (en) * | 2015-10-29 | 2016-02-24 | 浙江伟星实业发展股份有限公司 | Rock-imitating button and preparation method thereof |
| CN107057267A (en) * | 2016-12-29 | 2017-08-18 | 江阴标榜汽车部件有限公司 | Car high-low temperature resistant antiseep breather pipe and preparation method thereof |
| CN107418129A (en) * | 2017-03-31 | 2017-12-01 | 长乐巧通工业设计有限公司 | A kind of highstrenghtpiston for building trade |
| CN108192266A (en) * | 2017-12-12 | 2018-06-22 | 常州可赛成功塑胶材料有限公司 | A kind of preparation method of the dedicated activeness and quietness lubricants of ABS |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219980A (en) * | 2011-05-31 | 2011-10-19 | 王剑伟 | Formula of ABS (acrylonitrile butadiene styrene) extinction board and manufacturing process of ABS extinction board |
| CN102276955A (en) * | 2011-07-18 | 2011-12-14 | 余姚市中发工程塑料有限公司 | Antistatic glass fiber reinforcement ABS (acrylonitrile butadiene styrene) composite material |
-
2013
- 2013-06-07 CN CN201310226379.3A patent/CN103333450B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219980A (en) * | 2011-05-31 | 2011-10-19 | 王剑伟 | Formula of ABS (acrylonitrile butadiene styrene) extinction board and manufacturing process of ABS extinction board |
| CN102276955A (en) * | 2011-07-18 | 2011-12-14 | 余姚市中发工程塑料有限公司 | Antistatic glass fiber reinforcement ABS (acrylonitrile butadiene styrene) composite material |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897330A (en) * | 2013-11-08 | 2014-07-02 | 东南大学 | High-strength plastic |
| CN103897330B (en) * | 2013-11-08 | 2016-04-06 | 东南大学 | A kind of highstrenghtpiston |
| CN104292740A (en) * | 2014-09-29 | 2015-01-21 | 苏州博利迈新材料科技有限公司 | Fatigue-resistant mud guard material and preparation method thereof |
| CN105348634A (en) * | 2015-10-29 | 2016-02-24 | 浙江伟星实业发展股份有限公司 | Rock-imitating button and preparation method thereof |
| CN107057267A (en) * | 2016-12-29 | 2017-08-18 | 江阴标榜汽车部件有限公司 | Car high-low temperature resistant antiseep breather pipe and preparation method thereof |
| CN107418129A (en) * | 2017-03-31 | 2017-12-01 | 长乐巧通工业设计有限公司 | A kind of highstrenghtpiston for building trade |
| CN108192266A (en) * | 2017-12-12 | 2018-06-22 | 常州可赛成功塑胶材料有限公司 | A kind of preparation method of the dedicated activeness and quietness lubricants of ABS |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103333450B (en) | 2015-10-07 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: NINGBO KANGDE NEW MATERIALS CO., LTD. Free format text: FORMER OWNER: NINGBO KANGSHI PLASTIC TECHNOLOGY CO., LTD. Effective date: 20150908 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Kang Jianxun Inventor before: Wang Yongwang Inventor before: Kang Jianxun |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20150908 Address after: Qin Yan Cun Henghe town of Cixi city 315318 Zhejiang city of Ningbo Province Applicant after: Ningbo Kangshi Plastic Technology Co., Ltd. Address before: 315318 Zhejiang city of Ningbo province Cixi city Henghe Zhen Shi Yan Cun Applicant before: Ningbo Kangshi Plastic Technology Co., Ltd. |
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| C14 | Grant of patent or utility model | ||
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151007 Termination date: 20160607 |